Two Distinct Phenolic Reactants Or Two Or More Hydroxy Groups Or Phenate Groups Bonded To Nuclear Carbon Atoms Of The Same Benzene Ring Patents (Class 528/155)
  • Patent number: 4112160
    Abstract: Rubber cement compositions which consist of rubbers and multi- (three and more) functional phenol-aldehyde modified bifunctional phenol resins, which are made by first obtaining the bifunctional phenolic resin by condensing 1 mole of bifunctional phenol with 0.5 to 3.0 moles of aldehydes in the presence of an alkaline catalyst, and then co-condensing 0.05 to 2.5 moles of multifunctional (three and more) phenols against 1 mol of the bifunctional phenols in the above-mentioned resin in the presence of an acidic catalyst, said co-condensed resin having a number average molecular weight of 700 - 1900, a resin melting point of 80.degree. - 160.degree. C, being curable and also being soluble in aromatic hydrocarbon solvents.
    Type: Grant
    Filed: December 15, 1976
    Date of Patent: September 5, 1978
    Assignee: Sumitomo Durez Company, Ltd.
    Inventors: Yuji Kako, Toyoji Kikuga, Akira Toko
  • Patent number: 4110279
    Abstract: A polymer derived by heating in the presence of an acid catalyst at between about 65.degree. C. and 260.degree. C.I. a reaction product, a cogeneric mixture of alkoxy functional compounds, having average equivalent weights in the range from about 220 to about 1200, obtained by heating in the presence of a strong acid at about 50.degree. C. to about 250.degree. C.(a) a diaryl compound selected from naphthalene, diphenyl oxide, diphenyl sulfide, their alkylated or halogenated derivatives or mixtures thereof,(B) formaldehyde or formaldehyde-yielding derivative,(C) water, and(D) a hydroxy aliphatic hydrocarbon compound having at least one free hydroxyl group and from 1 to 4 carbon atoms, which mixture contains up to 50 percent by weight unreacted (A); withIi. at least one monomeric phenolic reactant selected from the group ##STR1## WHEREIN R is selected from the group consisting of ##STR2## HYDROGEN, ALKYL RADICAL OF 1-20 CARBON ATOMS, ARYL RADICAL OF 6-20 CARBON ATOMS, WHEREIN R.sub.
    Type: Grant
    Filed: February 3, 1977
    Date of Patent: August 29, 1978
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Nelson, Norman T. Herbert
  • Patent number: 4110540
    Abstract: A process for the preparation of multinuclear phenols alkylated in the nucleus, wherein bisphenol A is reacted with a phenyl alkenyl compound in the presence of a catalytic quantity of aluminium phenolate and resols obtained from said alkylated phenols.
    Type: Grant
    Filed: July 27, 1976
    Date of Patent: August 29, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Erhard Tresper, Rolf Kuchenmeister, Wolfgang Beer
  • Patent number: 4108809
    Abstract: Liquid prepolymers are prepared by interpolymerizing monomers including a hydroxy aromatic compound, an aldehyde and furfuryl alcohol. The resultant liquid prepolymers have a viscosity of about 100-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde and about 3.1-15 moles of interpolymerized furfuryl alcohol for each mole of interpolymerized hydroxy aromatic compound. The prepolymers are highly reactive and may be polymerized with or without other monomers to produce flame retardant solid or cellular interpolymers. In one variant, flame retardant solid or cellular polymers are produced by interpolymerizing organic polyisocyanates with the prepolymers. In another variant, solid or cellular interpolymers are produced by polymerizing the prepolymers without monomers such as polyisocyanate in the presence of unreacted furfuryl alcohol. Processes are provided for preparing the aforementioned novel liquid prepolymers and solid or cellular interpolymers.
    Type: Grant
    Filed: November 29, 1976
    Date of Patent: August 22, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: Thirumurti Narayan, Moses Cenker
  • Patent number: 4107127
    Abstract: A resinous product has high resistance to flame spread, low heat release, and exhibits a low smoke-developed rating when exposed to flame or to indirect or radiant heat, and is flexible, tough, free of hydraulic cement, and resistant to cracking and embrittlement upon curing. Such a product is the condensation product of resorcinol with or without included phenol, and a minor amount of paraformaldehyde and aqueous formaldehyde solution. The resorcinol starting material of this invention can also suitably be used in the form of a B-stage or partially cured resin of resorcinol-phenol-formaldehyde which is then condensed with the paraformaldehyde and, if necessary, additional formaldehyde. The product is useful as a cast material or as laminated with fiberglass or can contain fillers or the like. A method of making the product and articles is provided.
    Type: Grant
    Filed: April 29, 1977
    Date of Patent: August 15, 1978
    Inventor: Lawrence E. Shea
  • Patent number: 4098770
    Abstract: A method of preparing a modified phenol-formaldehyde resin in solid particulate form comprising reacting together, in an aqueous medium, phenol and formaldehyde, in a ratio of 1.0 mole phenol to between 1.8 and 3.5 moles of formaldehyde, in the presence of between 0.1 and 1.0 moles of a basic catalyst; continuing this reaction until a desired viscosity is reached; modifying the reaction system by adding thereto between 0 and 30%, based on the weight of phenol originally taken of a non-phenolic polyhydroxy compound; spray drying the thus modified liquid resin in a pressure nozzle drier, and chilling the spray dried particulate solid. These solid resins are redispersible in water and stable on storage, compared to the known aqueous, equivalent, systems.
    Type: Grant
    Filed: September 15, 1976
    Date of Patent: July 4, 1978
    Assignee: Reichhold Chemicals Limited
    Inventors: Antoine Berchem, Krishan Kumar Sudan, Edward Michael Gres