Material Contains A Group Viii Metal Atom Patents (Class 528/15)
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Patent number: 9556313Abstract: This invention is a vinylcarbosiloxane resin that is the hydrosilation reaction product of 1,3,5,7 -tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane and a hydride-terminated linear polysiloxane, siloxane, or silane, having two terminal Si—H hydrogens reactive with vinyl groups in a hydrosilation reaction, in the presence of a platinum catalyst. Suitable hydride-terminated linear polysiloxanes, siloxances, and silanes include those having the structures: In another embodiment, the vinylcarbosiloxane resin can be reacted with one or more other hydrido-silanes and hydrido-polysiloxanes in the presence of a platinum catalyst to form a curable composition.Type: GrantFiled: December 8, 2014Date of Patent: January 31, 2017Assignees: Henkel AG & Co. KGaA, Henkel IP & Holding GmbHInventors: Shengqian Kong, Liwei Zhang, Yong Zhang, Wentao Thomas Xing, Daniel J. Duffy
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Patent number: 9540500Abstract: Processes for producing polyether siloxanes are provided in which unsaturated polyethers are reacted with one or more SiH-functional siloxanes in the presence of Pt(0) compounds and tertiary amines Also, provided is the use of Pt(0) compounds and tertiary amines for producing polyether siloxanes and to the use of the polyether siloxanes thus obtained.Type: GrantFiled: December 4, 2015Date of Patent: January 10, 2017Assignee: EVONIK DEGUSSA GMBHInventors: Michael Ferenz, Stephan Hofmann, Horst Dudzik, Carsten Schiller
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Patent number: 9533918Abstract: A method for a fabricating a ceramic material includes providing a mixture of a reactive metallic filler material with a preceramic polysilazane material. The preceramic polysilazane material is then polymerized to form a green body. The green body is then thermally treated in an environment that is substantially free of oxygen to convert the polymerized preceramic polysilazane material into a ceramic material that includes at least one nitride phase that is a reaction product of the reactive metallic filler material and a preceramic polysilazane material.Type: GrantFiled: September 30, 2011Date of Patent: January 3, 2017Assignee: United Technologies CorporationInventors: Michael A. Kmetz, Timothy P. Coons, Justin W. Reutenauer
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Patent number: 9446272Abstract: The invention relates to fire extinguishing foams or concentrates thereof, these comprising a carbohydrate-containing siloxane surfactant.Type: GrantFiled: September 3, 2012Date of Patent: September 20, 2016Assignee: Universität zu KölnInventors: Dirk Blunk, Ralf Helmut Hetzer, Angela Sager-Wiedmann, Kai Wirz
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Patent number: 9394320Abstract: A method for fixing metal onto a surface of the substrate. The present method includes steps of: providing a substrate and a mercaptoalkylsilatrane compound; dissolving the mercaptoalkylsilatrane compound in a solvent; performing a condensation reaction of the substrate with and the dissolved mercaptoalkylsilatrane compound to complete the surface modification of the substrate; and performing a covalent bonding process to metal with the mercaptoalkylsilatrane compound already modified onto the surface of the substrate to fix the metal onto the surface of the substrate.Type: GrantFiled: March 17, 2014Date of Patent: July 19, 2016Assignee: National Chung Cheng UniversityInventors: Lai-Kwan Chau, Wen-Hao Chen, Yen-Ta Tseng, Chin-Wei Wu, Chao-Wen Chen
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Patent number: 9314078Abstract: A universal case has a single, unitary, elastic body of flexible and resilient material that can stretch to cover both smaller and larger mobile devices. The body has a side wall, a front perimeter lip, a rear perimeter lip and a web defining a cavity and being integral with one another and formed together from the flexible and resilient material as the single, unitary, elastic body. The side wall, the front perimeter lip and the rear perimeter lip define a perimeter channel to extend around a perimeter of the mobile device. The front perimeter lip defines a cavity and has corner lips with a wider width to define corner pockets. A groove is disposed in the channel, and extends into an inner surface of the side wall.Type: GrantFiled: November 17, 2014Date of Patent: April 19, 2016Assignee: American Covers, Inc.Inventors: Bryce Haymond, Jason Fogg
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Patent number: 9283152Abstract: The invention relates to a dental impression composition comprising a hardenable matrix and glass beads having a particle size (d50/?m) equal or below about 60 ?m. The invention also relates to a method of producing this composition and its use.Type: GrantFiled: October 1, 2008Date of Patent: March 15, 2016Inventors: Johann Fetz, Joachim W. Zech
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Patent number: 9242616Abstract: A curable coating composition that exhibits improved cure and adhesion to various substrates, especially synthetic textiles used in the manufacture of air bags, and good air pressure holding performance.Type: GrantFiled: April 4, 2014Date of Patent: January 26, 2016Assignees: BLUESTAR SILICONES FRANCE SAS, BLUESTAR SILICONES FRANCE USA CORPInventors: Remi Thiria, Pascale Jackson
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Patent number: 9240443Abstract: A method of preparing a gap filler agent includes adding a halosilane to a basic solvent, and, to the basic solvent and the halosilane, adding ammonia in an amount of about 50 to about 70 parts by weight based on 100 parts by weight of the halosilane at a rate of about 1 g/hr to about 15 g/hr.Type: GrantFiled: December 31, 2013Date of Patent: January 19, 2016Assignee: CHEIL INDUSTRIES, INC.Inventors: Jin-Hee Bae, Han-Song Lee, Taek-Soo Kwak, Go-Un Kim, Bo-Sun Kim, Sang-Kyun Kim, Yoong-Hee Na, Eun-Su Park, Jin-Woo Seo, Hyun-Ji Song, Sang-Hak Lim, Wan-Hee Lim, Seung-Hee Hong, Byeong-Gyu Hwang
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Patent number: 9172011Abstract: A composition for an encapsulant, an encapsulant, and an electronic device, the composition including an adhesion-promoting agent, the adhesion-promoting agent including an epoxy group in an amount of about 2.0 to about 5.0 mmol/g, at least one first polysiloxane that includes a hydrogen bound to a silicon at a terminal end thereof, and at least one second polysiloxane that includes an alkenyl group bound to a silicon at a terminal end thereof.Type: GrantFiled: December 27, 2013Date of Patent: October 27, 2015Assignee: CHEIL INDUSTRIES, INC.Inventors: Hong-Jung Yoo, Woo-Han Kim, Ha-Neul Kim, Chi-Won An, Eun-Seon Lee, Dong-il Han
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Patent number: 9169405Abstract: Disclosed is an at least partly crosslinked coating (K) composed of a near-surface coating zone (K1) and a volume coating zone (K2), the coating obtained from a composition comprising at least two different crosslinkable components (D1) and (D2), at least part of component (D1) having one or more surface-active structural units, wherein (i) the coating both in zone (K1) and in zone (K2) is at least partly crosslinked, and (ii) the crosslinking density of the coating in zone (K1) is higher than the crosslinking density of the coating in zone (K2). Also disclosed are coatings (K) wherein the concentration of component (D1) in the near-surface coating zone (K1) is higher than in the volume coating zone (K2), and the micropenetration hardness and/or the dry scratch resistance of the coating (K) is higher than that of an at least partly crosslinked coating (K?) obtained from a composition with no crosslinkable component (D1).Type: GrantFiled: January 23, 2008Date of Patent: October 27, 2015Assignee: BASF COATINGS GMBHInventors: Andreas Poppe, Egon Wegner, Michael Kutschera, Manfred Essig
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Patent number: 9169424Abstract: Disclosed are perfluoroethers and perfluoroether compositions useful in high temperature aerospace applications. The perfluoroethers can be adapted for use with various curing chemistries.Type: GrantFiled: January 6, 2015Date of Patent: October 27, 2015Assignee: PRC-DeSoto International, Inc.Inventors: Chandra Rao, Juexiao Cai, Renhe Lin
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Patent number: 9156948Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.Type: GrantFiled: October 4, 2012Date of Patent: October 13, 2015Assignee: Dow Corning CorporationInventors: Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, Ming-Shin Tzou, Thomas Galbraith, James Shoemaker
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Patent number: 9157009Abstract: The invention relates to the use of novel stable carbenes in solution as organopolysiloxane polycondensation catalysts.Type: GrantFiled: July 6, 2012Date of Patent: October 13, 2015Assignee: Bluestar Silicones France SASInventors: Christian Maliverney, Laurent Saint-Jalmes
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Patent number: 9150692Abstract: The use of a polyamide including hydroxyaromatic units in order to increase the acid resistance of a polyamide composition is described. A polyamide composition comprising a polyamide that includes hydroxyaromatic units and use thereof for the manufacture of various plastic articles such as, for example, calibrated particles or injection-molded parts is also described. Such a composition is especially useful in the field of the recovery of slurries, liquids and gases present in underground reservoirs, and in particular in the field of the extraction of hydrocarbons, such as crude oil or natural gas.Type: GrantFiled: June 30, 2010Date of Patent: October 6, 2015Assignee: RHODIA OPERATIONSInventors: Gilles Orange, Mathilde Mercier, Franck Touraud, Stéphane Jeol, Roland Durand
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Patent number: 9117757Abstract: Novel compositions and methods of using those compositions to form high refractive index coatings are provided. The compositions comprise a mixture of two silicone polymers, a catalyst, and an inhibitor for the catalyst. The preferred catalyst comprises platinum. Unlike prior art silicone systems, the inventive composition can be provided in a one-part form due to a substantially improved pot life. The compositions can be spin- or spray-applied, followed by baking to crosslink the polymers and form a cured layer. The inventive cured layers have high refractive indices and light transmissions.Type: GrantFiled: October 16, 2013Date of Patent: August 25, 2015Assignee: Brewer Science Inc.Inventors: Jyoti K. Malhotra, Xing-Fu Zhong
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Patent number: 9066821Abstract: A suspension liner sleeve adapted to provide an interface between a residual limb and a prosthetic socket, and having outer and inner surfaces. The liner sleeve includes an elongate, generally conical body portion formed from at least one material segment defining the liner outer surface. The at least one material segment being at least radially elastically extensible from a relaxed non-extended condition and including proximal and distal end areas. The liner sleeve includes a layer of polymeric material disposed on the at least one material segment and defining the liner sleeve inner surface, and a plurality of resilient seal elements protruding radially from the liner sleeve outer surface. The plurality of seal elements extend around at least one peripheral portion of the liner body portion. A pair of opposed annular recesses may be adjacently located above and below each of the at least one seal element.Type: GrantFiled: March 11, 2014Date of Patent: June 30, 2015Assignee: OSSUR HFInventors: Egill Sveinbjorn Egilsson, Sigurdur Asgeirsson, Jenny Ruth Hrafnsdottir, Grimur Jonsson
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Patent number: 9060885Abstract: A suspension liner sleeve adapted to provide an interface between a residual limb and a prosthetic socket, and having outer and inner surfaces. The liner sleeve includes an elongate, generally conical body portion formed from at least one material segment defining the liner outer surface. The at least one material segment being at least radially elastically extensible from a relaxed non-extended condition and including proximal and distal end areas. The liner sleeve includes a layer of polymeric material disposed on the at least one material segment and defining the liner sleeve inner surface, and a plurality of resilient seal elements protruding radially from the liner sleeve outer surface. The plurality of seal elements extend around at least one peripheral portion of the liner body portion. A pair of opposed annular recesses may be adjacently located above and below each of the at least one seal element.Type: GrantFiled: February 24, 2014Date of Patent: June 23, 2015Assignee: OSSUR HFInventors: Egill Sveinbjorn Egilsson, Sigurdur Asgeirsson, Jenny Ruth Hrafnsdottir, Grimur Jonsson
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Patent number: 9045639Abstract: A curable composition comprises the following: (A) a polymer having at least two silicon-bonded alkenyl groups and having an average unit formula (I?): (R12SiO2/2)a1(R23SiO1/2)b1(CH2CH2)e1; (B) a branched organopolysiloxane having at least one silicon-bonded alkenyl group and having a siloxane unit of formula R4SiO3/2; (C) an organopolysiloxane having an average unit formula (II) being capped with H: (R52SiO2/2)f(R63SiO1/2)g(R7SiO3/2)h(SiO4/2)i(CH2CH2)j; and (D) a catalyst, wherein R1, R2 and R4 to R7 and a1, b1, e1 and f to j are as defined in the specification.Type: GrantFiled: April 30, 2014Date of Patent: June 2, 2015Assignee: Eternal Materials Co., Ltd.Inventors: Chih Chiang Yang, Kwei Wen Liang, Hsin Hung Chen, Wan Hsi Yang
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Publication number: 20150148510Abstract: The present invention provides a curable composition, comprising: (A) at least one polycarbosilane A represented by the following formula (1): [R1R2R3SiX1/2]M[R4R5SiX2/2]D[R6SiX3/2]T[SiX4/2]Q??(1) (B) at least one organopolysiloxane B represented by the following formula (2): [R7R8R9SiO1/2]M?[R10R11SiO2/2]D?[R12SiO3/2]T?[SiO4/2]Q?,??(2), and (C) at least a catalyst, as well as a cured product obtainable by heating such composition, and the use of the composition as semiconductor encapsulating material and/or electronic elements packaging material.Type: ApplicationFiled: January 30, 2015Publication date: May 28, 2015Inventors: Thomas Xing, Liwei Zhang, Pasing Zhiming Li, Yong Zhang, Juan Du
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Patent number: 9025203Abstract: A method for generating print parameters includes: obtaining a printed paper of a test sample sheet obtained by a printing device after performing double-sided printing on the test sample sheet using preset front print parameters and preset back print parameters; detecting a front effect index of a front print effect and a back effect index of a back print effect for the printed paper of the test sample sheet by a print parameter generating device; comparing the front effect index and the back effect index with a standard effect index to obtain a comparison result, or comparing the front effect index with the back effect index to obtain a comparison result; determining from the comparison result and store in the printing device front print parameters and back print parameters used for double-sided printing on a paper to be printed with the same material and attributes as the test sample sheet.Type: GrantFiled: December 4, 2013Date of Patent: May 5, 2015Assignees: Peking University Founder Group Co., Ltd., Founder Information Industry Holdings Co., Ltd., Beijing Founder Electronics Co., Ltd.Inventor: Guoxin Jiang
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Patent number: 9018777Abstract: An encapsulating composition for a light emitting element, a light emitting diode (LED) and a liquid crystal display device (LCD) are provided. A silicone-cured product included as a main ingredient and a conductivity-providing agent having excellent compatibility and capable of providing superior conductivity can be used to significantly reduce the surface resistivity of the silicone-cured product. Therefore, the encapsulating composition for a light emitting element, the LED and the LCD can be useful in solving the problems regarding attachment of a foreign substance such as dust due to static electricity, and degradation of transparency since the composition has low surface resistivity when used as a semiconductor encapsulation material for an LED, and also in providing a cured product having excellent properties such as light resistance, heat resistance, durability and optical transparency.Type: GrantFiled: March 7, 2014Date of Patent: April 28, 2015Assignee: LG Chem, Ltd.Inventors: Sang Ki Chun, In Seok Hwang, Dong-Wook Lee, Ji Young Hwang
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Patent number: 9012586Abstract: A curable organopolysiloxane composition that can be used as a sealant or a bonding agent for optical semiconductor elements and comprises at least the following components: (A) an alkenyl-containing organopolysiloxane that comprises constituent (A-1) of an average compositional formula and constituent (A-2) of an average compositional formula; (B) an organopolysiloxane that contains silicon-bonded hydrogen atoms and comprises constituent (B-1) containing at least 0.5 wt. % of silicon-bonded hydrogen atoms and represented by an average molecular formula, constituent (B-2) containing at least 0.5 wt. % of silicon-bonded hydrogen atoms and represented by an average compositional formula, and, if necessary, constituent (B-3) of an average molecular formula; and (C) a hydrosilylation-reaction catalyst. The composition can form a cured body that possesses long-lasting properties of light transmittance and bondability, and relatively low hardness.Type: GrantFiled: June 28, 2011Date of Patent: April 21, 2015Assignee: Dow Corning Toray Co., Ltd.Inventors: Makoto Yoshitake, Mieko Yamakawa
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Patent number: 9005361Abstract: The present application relates to compositions comprising at least one siloxane and at least one superplasticizer based on polycarboxylate ethers or sulphonates of lignin, melamine or naphthalene or of resins thereof, and to the use of such compositions as or in building-product mixtures or building products, especially mortar mixtures or concrete mixtures. Preferably the siloxane is a branched siloxane containing at least one “T” unit and containing at least two different polyoxyalkylene moieties.Type: GrantFiled: December 19, 2012Date of Patent: April 14, 2015Assignee: Evonik Industries AGInventors: Frauke Henning, Anke Reinschmidt, Ralph Scheuermann, George-Hans Bayne, Kerstin Klein, Markus Roos
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Patent number: 8987401Abstract: Methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule are provided.Type: GrantFiled: June 14, 2012Date of Patent: March 24, 2015Assignee: Dow Global Technologies LLCInventors: Kamesh R. Vyakaranam, Ling Zhang, Venkat S. Minnikanti, Rajat Duggal, William A. Koonce, Amarnath Singh, Phillip S. Athey
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Patent number: 8980973Abstract: The invention relates to a composition for taking dental impressions, the composition comprising a siloxane component (A) comprising terminal vinyl groups, a siloxane component (B) comprising Si—H groups, a catalyst (C) being able to catalyze a curing reaction between components (A) and (B) and a silicone oil (D), wherein the silicone oil has a viscosity at 23 DEG C of at least about 600,000 mPa*s and is present in an amount from about 1 to about 20 wt.% with respect to the weight of the whole composition. The invention also relates to a method of producing such a composition and a method for adjusting the Shore hardness A of a composition.Type: GrantFiled: June 5, 2012Date of Patent: March 17, 2015Assignee: 3M Innovative Properties CompanyInventors: Peter Uwe Osswald, Hyung-Min Shim, Johann Fetz, Joachim Wilhelm Zech, Bernd Kuppermann
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Patent number: 8962746Abstract: Methods of forming blocked-mercapto alkoxy-modified silsesquioxanes are provided. The blocked-mercapto alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber as alcohol (a volatile organic compound (VOC)), during compounding and further processing. The blocked-mercapto alkoxy-modified silsesquioxane compounds also contain a blocked mercapto group which, when de-blocked, allows the mercapto group to interact with the polymer(s) in a rubber composition. Further described are rubber compounds containing the blocked-mercapto alkoxy-modified silsesquioxanes.Type: GrantFiled: December 29, 2008Date of Patent: February 24, 2015Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Chenchy Jeffrey Lin, James H. Pawlow, Terrence E. Hogan
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Publication number: 20150050498Abstract: Water-absorbable silicone rubber particles which are particles of a silicone rubber, each of which has a particle diameter ranging from 0.1 to 1,000 ?m and is elastic, wherein the silicone rubber is an organopolysiloxane having a polyoxyalkylene group, contains an oxyethylene unit represented by the formula —OCH2CH2— in an amount of 20 to 80 mass %, and can absorb water in an amount of 10 parts by mass or more relative to 100 parts by mass of the silicone rubber. The silicone particles according to the present invention can impart soft touch, a soft-focusing effect and the like to a make-up cosmetic such as a foundation or an antiperspirant when added to the make-up cosmetic or the antiperspirant. In addition, since the particles have high water absorption performance, the particles can absorb sweat and therefore is expected to exhibit an effect of reducing unpleasantness such as stickiness and greasiness, oiliness of the skin and make-up deterioration.Type: ApplicationFiled: February 21, 2013Publication date: February 19, 2015Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventor: Yoshinori Inokuchi
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Patent number: 8957165Abstract: An addition-curable silicone composition that provides a cured product having a particularly high transparency, an excellent light extraction efficiency and a favorable strength characteristic by subjecting the cured product to a lower refractive index by using a specific composition. The present invention was accomplished by an addition-curable silicone composition, including at least: (A) a linear organopolysiloxane having 2 or more aliphatic unsaturated groups bonded to a silicon atom and 1 or more CF3—(CF2)y—(CH2)z— groups bonded to a silicon atom in one molecule; (B) an organopolysiloxane having 2 or more aliphatic unsaturated groups bonded to a silicon atom and 1 or more CF3—(CF2)y—(CH2)z— groups bonded to a silicon atom in one molecule and having a branch structure of a siloxane unit represented by an SiO4/2 and/or an RSiO3/2; (C) an organosilicon compound represented by the following general formula (1); and (D) a platinum group metal-based catalyst.Type: GrantFiled: December 3, 2013Date of Patent: February 17, 2015Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Mitsuhiro Iwata, Toshiyuki Ozai, Yukito Kobayashi
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Patent number: 8940851Abstract: Silicone fibers suitable for use as optical fibers are prepared by crosslinking an extruded mixture of a silicone resin and an organopolysiloxane, both containing aliphatically unsaturated groups, an organopolysiloxane bearing Si—H groups, and a light activatable trimethyl(methylcyclopentadienyl) platinum catalyst.Type: GrantFiled: October 19, 2011Date of Patent: January 27, 2015Assignee: Wacker Chemie AGInventor: Philipp Mueller
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Patent number: 8933177Abstract: To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.Type: GrantFiled: July 9, 2009Date of Patent: January 13, 2015Assignee: Dow Corning Toray Company, Ltd.Inventors: Seiji Hori, Takateru Yamada, Chung Mien Kuo
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Patent number: 8920931Abstract: A phosphosiloxane resin comprises a plurality of covalently bonded monomer units selected from phosphosiloxane units SiR23—O—P(?O)(R1)—(OR3)q(O1/2—)p and organosiloxane units R2m(OR3)nSiO(4-m-n)/2. R1 and each R2 are independently selected from the group consisting of hydrogen, C1 to C10 hydrocarbyl, and C1 to C10 hydrocarbylene; each R3 is independently selected from the group consisting of hydrogen and C1 to C10 hydrocarbyl; p is 0 or 1; q=1?p; m is 0, 1, 2, 3, or 4; n is 0, 1, or 2; and m+n is 0, 1, 2, 3, or 4. Curable silicone compositions comprise a phosphosiloxane resin having greater than one silicon-bonded alkenyl group, an organosilicon compound having at least two silicon-bonded hydrogen atoms, and a hydrosilylation catalyst. Fiber-reinforced free-standing films may comprise fibers dispersed in a cured product of the silicone composition. Laminated substrates comprise at least one fiber-reinforced free-standing film.Type: GrantFiled: August 23, 2011Date of Patent: December 30, 2014Assignee: Dow Corning CorporationInventor: Bizhong Zhu
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Patent number: 8921496Abstract: A curable composition and use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening, under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.Type: GrantFiled: July 5, 2013Date of Patent: December 30, 2014Assignee: LG Chem, Ltd.Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
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Patent number: 8907036Abstract: Self-adhesive crosslinkable silicone compositions may be transparent and prepared without conventional adhesion promoters, and contain (1) an organopolysiloxane having a minimum of two aliphatically unsaturated carbon-carbon bond-containing groups, (2) a pendant Si—H functional organopolysiloxane having at least 3 Si—H groups and a minimum of 0.7 weight percent of Si-bonded hydrogen, and (3) a linear organopolysiloxane bearing terminal Si—H groups, wherein the mol ratio of silicon-bonded hydrogen in (2) to that in [(2) and (3)] is from 0.05 to 1.Type: GrantFiled: February 17, 2012Date of Patent: December 9, 2014Assignee: Wacker Chemie AGInventor: Christian Ochs
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Patent number: 8900654Abstract: Compositions and methods for controlled polymerization and/or oligomerization of silane (and optionally cyclosilane) compounds, including those of the general formulae SinH2n and SinH2n+2, as well as halosilanes and arylsilanes, to produce soluble polysilanes, polygermanes and/or polysilagermanes having low levels of carbon and metal contaminants, high molecular weights, low volatility, high purity, high solubility and/or high viscosity. The polysilanes, polygermanes and/or polysilagermanes are useful as a precursor to silicon- and/or germanium-containing conductor, semiconductor and dielectric films.Type: GrantFiled: July 29, 2011Date of Patent: December 2, 2014Assignee: Thin Film Electronics, Inc.Inventors: Klaus Kunze, Gregory Nyce, Wenzhuo Guo
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Patent number: 8889809Abstract: One object of the present invention is to provide a silicone resin composition having remarkably low gas permeability which is useful for a purpose requiring lower gas permeability. Further, another object of the present invention is to provide an optical semiconductor device provided with a cured product obtained by curing the silicone resin composition which has discoloration resistance, durable reflection efficiency and high reliability. The present invention provides a silicone resin composition comprising (A) an organopolysiloxane having at least two alkenyl groups per molecule, and is represented by the average compositional formula (1), (B) an organohydrogenpolysiloxane having at least two hydrogen atoms bonded to a silicon atom, and is represented by the average compositional formula (2), (C) a catalytic amount of a curing catalyst, and (D) 0.001 to 3 parts by mass of an antioxidant, relative to a total 100 parts by mass of components (A) and (B).Type: GrantFiled: June 21, 2011Date of Patent: November 18, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshihira Hamamoto, Tsutomu Kashiwagi
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Patent number: 8883950Abstract: A silicone resin composition contains a silicon-containing component including a silicon atom to which a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group is bonded and a silicon atom to which an alkenyl group is bonded. The number of moles of alkenyl group per 1 g of the silicon-containing component is 200 to 2000 ?mol/g.Type: GrantFiled: August 2, 2012Date of Patent: November 11, 2014Assignee: Nitto Denko CorporationInventors: Ryuichi Kimura, Munehisa Mitani
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Patent number: 8877885Abstract: Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.Type: GrantFiled: June 29, 2011Date of Patent: November 4, 2014Assignee: Dow Global Technologies LLCInventors: Kamesh R. Vyakaranam, Ling Zhang, William A. Koonce, Juan Carlos Medina, Ganesh Kailasam, Rajat Duggal, Nathan Wilmot
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Patent number: 8877860Abstract: A two-part curable liquid silicone rubber composition comprises a first liquid composition and a second liquid composition. The first and second liquid compositions are stored separately and yield, upon mixing, a silicone rubber forming composition. The silicone rubber composition comprises: (A) an alkenyl group-containing organopolysiloxane comprising (A-1) an organopolysiloxane having only a silicon-bonded alkenyl group at each molecular terminal and (A-2) an organopolysiloxane having from 1 to 4 silicon-bonded alkenyl groups in side molecular chains and containing not greater than 2.0 wt. % of alkenyl groups; (B) a calcium carbonate powder; (C) a hydrosilylation reaction catalyst; and (D) an organohydrogenpolysiloxane having silicon-bonded hydrogen atoms.Type: GrantFiled: March 28, 2012Date of Patent: November 4, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Tomoko Tasaki, Yuichi Tsuji
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Patent number: 8877886Abstract: To provide a method of producing a polyoxyalkylene-modified polysiloxane composition that is free of acid-mediated carbon-oxygen bond and silicon-oxygen bond cleavage, that is substantially deodorized and also does not generate odor with elapsed time, and that is therefore well suited for use in cosmetic applications, e.g., for hair cosmetics, skin cosmetics, and so forth. A production method of this invention is characterized by removing the odor-causing substance from a polyoxyalkylene-modified polysiloxane composition that has been synthesized by a hydrosilylation reaction, by subjecting the polyoxyalkylene-modified polysiloxane composition to a hydrolysis treatment in the presence of an acidic inorganic salt that is a solid at 25° C. and gives a specific pH at 25° C. in aqueous solution; for example, potassium hydrogensulfate.Type: GrantFiled: December 2, 2010Date of Patent: November 4, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Tatsuo Souda, Seiki Tamura
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Patent number: 8859635Abstract: Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it.Type: GrantFiled: June 27, 2011Date of Patent: October 14, 2014Assignee: Bluestar Silicones France SASInventors: John White, Michel Feder, Alain Pouchelon, Yassine Maadadi, Lucile Gambut-Garel
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Patent number: 8859689Abstract: Polymer compositions based on polyaniline and carbonyl-functionalized polysilicones, and methods for making these polymer compositions are disclosed in the present application. The polymer compositions have, for example, good solubility, processability, mechanical performance and conductivity.Type: GrantFiled: November 10, 2011Date of Patent: October 14, 2014Assignee: Nanjing UniversityInventors: Yun Lu, Hongjuan Wang
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Patent number: 8852844Abstract: There is disclosed a thermosetting composition for forming a silicon-containing film to form a silicon-containing film formed in a multilayer resist process used in lithography, including at least (A) a silicon-containing compound obtained by hydrolyzing and condensing a hydrolyzable silicon compound using an acid as a catalyst, (B) a thermal crosslinking accelerator (C) a monovalent or bivalent or more organic acid having 1 to 30 carbon atoms, (D) trivalent or more alcohol and (E) an organic solvent. There can be provided a composition for a silicon-containing film which can form a good pattern in a photoresist film, can form a silicon-containing film for an etching mask having a good dry etching resistance, can give a good storage stability and can be delaminated with a solution used in a delamination process in a multilayer resist process used for lithography, a substrate on which the silicon-containing film is formed, and further a method for forming a pattern.Type: GrantFiled: August 10, 2009Date of Patent: October 7, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tsutomu Ogihara, Takafumi Ueda, Toshiharu Yano
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Publication number: 20140296467Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.Type: ApplicationFiled: October 4, 2012Publication date: October 2, 2014Applicant: Dow Corning CorporationInventors: Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, Ming-Shin Tzou, Thomas Galbraith, James Shoemaker
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Publication number: 20140291872Abstract: A gel has improved thermal stability and is the ultraviolet hydrosilylation reaction product of (A) an organopolysiloxane having an average of at least 0.1 silicon-bonded alkenyl group per molecule and (B) a cross-linker having an average of at least 2 silicon-bonded hydrogen atoms per molecule. (A) and (B) react via hydrosilylation in the presence of (C) a UV-activated hydrosilylation catalyst comprising at least one of platinum, rhodium, ruthenium, palladium, osmium, and iridium, and (D) a thermal stabilizer. The (D) thermal stabilizer is present in an amount of from about 0.01 to about 30 weight percent based on a total weight of (A) and (B) and having transparency to UV light sufficient for the ultraviolet hydrosilylation reaction product to form.Type: ApplicationFiled: October 5, 2012Publication date: October 2, 2014Inventors: Brian R. Harkness, Malinda N. Howell, Daesup Hyun, Jing Jiang, John J. Kennan, Kent R. Larson, Randall G. Schmidt, Shengqing Xu
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Publication number: 20140296468Abstract: A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains an iron-organosilicon ligand complex that can be prepared by reacting an iron carbonyl compound and an organosilicon ligand.Type: ApplicationFiled: November 8, 2012Publication date: October 2, 2014Applicant: Dow Corning CorporationInventors: Agnieszka Kownacka, Ireneusz Kownacki, Bogdan Marciniec, Binh Nguyen, Avril Surgenor, Richard Taylor, Ming-Shin Tzou
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Patent number: 8847414Abstract: A resin for an encapsulation material includes a first polysiloxane including hydrogen bound to silicon (Si—H) at its terminal end, and a second polysiloxane including an alkenyl group bound to silicon (Si—Vi) at its terminal end, wherein a ratio (Si—H/Si—Vi) of hydrogen bound to silicon (Si—H) in the first polysiloxane to the alkenyl group bound to silicon (Si—Vi) in the second polysiloxane is about 1 to about 1.Type: GrantFiled: December 29, 2011Date of Patent: September 30, 2014Assignee: Cheil Industries, Inc.Inventors: Sung-Hwan Cha, Sang-Ran Koh, Yong Kook Kim, Woo-Han Kim, Ha Neul Kim, Chi Won An
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Patent number: 8846842Abstract: The present invention relates to new high-functionality, highly branched or hyperbranched polylysines, to processes for preparing them, and to their use.Type: GrantFiled: June 4, 2010Date of Patent: September 30, 2014Assignee: BASF AktiengesellschaftInventors: Bernd Bruchmann, Harm-Anton Klok, Markus Thomas Scholl
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Patent number: 8841400Abstract: The invention relates to organomodified additives, emulsifiers, dispersants and/or active nourishing ingredients present in the silicon part of branched siloxane block copolymers, to the use thereof, in particular for producing cosmetic, dermatological or pharmaceutical formulations as well as care and cleansing products, and to the preparations as such. Specifically the invention relates to branched polysiloxanes having trifunctional T units as well as polyether groups, alkyl radicals of more than 7 carbon atoms or multi-hydroxy functional radicals.Type: GrantFiled: March 17, 2010Date of Patent: September 23, 2014Assignee: Evonik Degussa GmbHInventors: Frauke Henning, Juergen Meyer, Christian Hartung, Michael Ferenz, Wilfried Knott, Sascha Herrwerth
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Publication number: 20140275445Abstract: A composition containing a metal compound and a siloxane compound (A) represented by general formula (1): wherein X is represented by general formula X1 or X2: wherein the number of X1 is 1-8; the number of X2 is 0-7; the sum of the number of X1 and the number of X2 is 8; R1 to R4 represent a hydrogen atom, a C1-8 alkyl group, alkenyl group, alkynyl group, or a C6-8 aryl group, a hydrogen atom thereof optionally being substituted by a fluorine atom; R5 represents a C1-18 alkyl group, alkenyl group, alkynyl group or aryl group, a hydrogen atom thereof being optionally substituted by a fluorine atom, a carbon atom being optionally substituted by an oxygen atom or a nitrogen atom; R6 represents a hydrogen atom, a vinyl group or an allyl group; m and n represent an integer of 1-4; and 3?m+n.Type: ApplicationFiled: October 16, 2012Publication date: September 18, 2014Applicant: Central Glass Company, LimitedInventors: Kazuhiro Yamanaka, Hiroshi Eguchi, Junya Nakatsuji, Takeshi Suda, Katsuhiro Akiyama