Carboxylic Acid Or Derivative Is A Reactant Patents (Class 528/173)
  • Patent number: 11439948
    Abstract: A modular structure for a mitigating evaporative fuel emissions, such as for an automobile, is described. The structure may include a plurality of frames and membranes for flowing fuel vapor and reducing the emission of hydrocarbon therefrom. The structure may include flow guides that provide a meandering flow path for both the fuel vapor and a permeate. A flow guide providing parallel flow paths is also described.
    Type: Grant
    Filed: December 9, 2019
    Date of Patent: September 13, 2022
    Assignee: MAHLE International GmbH
    Inventors: Thomas Ehlert, Achim Gommel, John Jackson, Simon Streng, Melanie Volz
  • Patent number: 11208348
    Abstract: As described herein, a polyimide chemical composition may be used for coating glass articles. According to embodiments, a coated glass article may include a glass container which may include a first surface and a second surface opposite the first surface, and a low-friction coating bonded to at least a portion of the first surface of the glass container. The low-friction coating may include a polyimide chemical composition. The polyimide chemical composition may be halogenated and the polyimide chemical composition may include a siloxane moiety.
    Type: Grant
    Filed: September 29, 2016
    Date of Patent: December 28, 2021
    Assignee: CORNING INCORPORATED
    Inventors: David Henry, Valerie Claudine Lacarriere
  • Patent number: 9673491
    Abstract: A vehicle battery system has a vehicle battery, a cooling device to cool the vehicle battery and which includes a heat sink in thermal contact with the battery cells to transfer heat from the battery cells to the heat sink. The heat sink has at least one cooling channel through which a coolant may flow and connection ends formed by delimitations of the at least one cooling channel. A coolant distributor is provided at and connected to at least one end of the heat sink at a receiving region which is adhesive bonded to the heat sink, the receiving region of the coolant distributor surrounding the connection ends of the heat sink, in which the end faces of the delimitations of the cooling channel form stops for the coolant distributor which abut contact surfaces of the coolant distributor.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: June 6, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Harald Fabian, Miran Kojc, Boris Lobnik, Volker Matl
  • Patent number: 9464183
    Abstract: This invention provides a rubber composition comprising 1-10 parts by mass of sulfur and 0.1-10 parts by mass of a compound represented by the following general formula (1) or a composition containing the compound as a main component based on 100 parts by mass of a rubber component as well as a pneumatic tire in which at least one of a carcass (4) and a belt (6) includes a layer composed of steel cords covered with a coating rubber, characterized in that the above rubber composition is used as the coating rubber covering the steel cords in at least one of the carcass (4) and the belt (6): (wherein R represents a divalent aliphatic group having a carbon number of 1-16 or a divalent aromatic group).
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: October 11, 2016
    Assignee: BRIDGESTONE CORPORATION
    Inventors: Kazunori Kaneda, Yoshinori Kuriya, Kazuya Tsukamoto, Nobumasa Arashiba, Akinori Nagatomo, Kouki Oogaki, Takeshi Kobayashi
  • Patent number: 9273181
    Abstract: Provided is a novel aromatic polyester-based polymer. The aromatic polyester-based polymer includes the repeating unit represented by the following Chemical Formula I and contains at least one aromatic diol monomer. The aromatic polyester-based polymer has a high glass transition temperature and excellent heat resistance, mechanical properties and transparency, as well as shows excellent formability and processability into films or the like, and thus solves the problems occurring in the conventional crystalline or amorphous engineering plastic materials. In addition, the aromatic polyester-based polymer may be applied to next-generation engineering plastic composite materials, such as matrix resins of composite materials for cars and airplanes. The aromatic polyester-based polymer may also be applied to flexible substrates for next-generation flexible displays, solar cells or electronic paper requiring transparency and high heat resistance at the same time.
    Type: Grant
    Filed: October 10, 2014
    Date of Patent: March 1, 2016
    Assignee: IUCF-HYU (INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY)
    Inventors: Yang-Kyoo Han, Minhee Jang, Byung Kook Lee, Injoon Byun
  • Publication number: 20150053608
    Abstract: A membrane including a polyarylnitrile copolymer is presented. The polyarylnitrile copolymer includes structural units having a formula (I) and at least one terminal group having a formula (II): wherein “a” is 0, 1, 2, or 3; “m” is an integer having a value of 35 to 150; R1 is independently at each occurrence a hyrogen atom, a halogen atom, a nitro group, a cyano group, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, or a C3-C12 aromatic radical; R2 and R3 are independently a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, or a C3-C12 aromatic radical; L is an oxygen atom or a sulfur atom; and Ar is independently at each occurrence a residue of an aromatic diol or a residue of an aromatic dihalide.
    Type: Application
    Filed: August 20, 2013
    Publication date: February 26, 2015
    Applicant: General Electric Company
    Inventors: Gary William Yeager, Julia Lam Lee, Paul Edward Howson, Hongyi Zhou, Cathryn Ellen Olsen, Patrick Joseph McCloskey, Matthew Jeremiah Misner, Louisa Ruth Carr, Daniel Steiger
  • Patent number: 8907042
    Abstract: A polyetherimide manufactured by reaction of an alkali metal salt of a dihydroxy aromatic compound of the formula MO—Z—OM wherein M is an alkali metal salt and Z is an aromatic C6-24 monocyclic or polycyclic moiety optionally substituted with 1 to 6 C1-8 alkyl groups, 1 to 8 halogen atoms, or a combination thereof, with a bis(halophthalimide) composition comprising, based on the weight of the bis(halophthalimide) composition, from more than 45 to less than 75 weight percent of a 3,3?-bis(halophthalimide) of the formula less than 10 weight percent of a 3,4?-bis(halophthalimide) of the formula and from more than 45 to less than 75 weight percent of a (4,4?-bis(halophthalimide) of the formula
    Type: Grant
    Filed: October 28, 2011
    Date of Patent: December 9, 2014
    Assignee: Sabic Global Technologies B.V.
    Inventors: Matthew L. Kuhlman, Gurulingamurthy M. Haralur
  • Patent number: 8883957
    Abstract: The present invention relates to a process for the preparation of a lactone or lactam homopolymer, comprising the stage consisting in reacting a lactone or lactam with a nonpolymeric initiator comprising at least one hydroxyl or thiol functional group in a nonchlorinated solvent in the presence of a sulfonic acid of formula R—SO3H. It also relates to the polymer composition thus obtained and to its uses, in particular as antistatic additive.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: November 11, 2014
    Assignees: Arkema France, Centre National de la Recherche Scientifique-CNRS
    Inventors: Stéphanie Magnet, Christophe Navarro, Stéphanie Gazeau-Bureau, Bianca Martin-Vaca, Didier Bourissou
  • Patent number: 8754186
    Abstract: An object of the present invention is to provide a polyimide precursor composition that can be cured at low temperatures (250° C. or lower), while having a low viscosity even at a high concentration, and a method of producing the same. Another object of the present invention is to provide a polyimide coating film obtained from the polyimide precursor composition and having good physical properties, and a method of producing the same. Furthermore, another object of the present invention is to provide a photosensitive resin composition containing the polyimide precursor composition, and a method of producing the same. These objects can be achieved by the polyimide precursor composition containing an imidized tetracarboxylic acid having a specific structure and a diamine having a specific structure.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: June 17, 2014
    Assignee: Kaneka Corporation
    Inventors: Kan Fujihara, Tetsuya Kogiso, Yoshihide Sekito
  • Patent number: 8703901
    Abstract: The present invention relates to an aqueous alkali-developable photosensitive polyimide precursor resin composition that is appropriate for highly heat-resistant transparent protection layers and insulation layers for liquid crystal display devices.
    Type: Grant
    Filed: May 30, 2012
    Date of Patent: April 22, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Dong-seok Kim, Yong-sik Ahn, Kyung-jun Kim, Mi-hie Yi
  • Publication number: 20140087149
    Abstract: An aromatic copoly(ester-sulfone) that contains one or more aromatic ester repeating units and one or more aromatic sulfonyl repeating units is provided. While a wide variety of aromatic ester repeating units may be employed, the polymer is nevertheless “low naphthenic” to the extent that it contains a minimal content of repeating units derived from naphthenic hydroxycarboxylic acids and naphthenic dicarboxylic acids. Despite the absence of a high level of conventional naphthenic acid repeating units, the present inventors have discovered that selective control over the type and relative concentration of the aromatic sulfonyl repeating units can lead to “low naphthenic” polymers that are not only soluble in certain solvents, but also capable of exhibiting good mechanical properties. Thus, the ability of the resulting polymer to be dissolved or dispersed in various solvents can be enhanced without sacrificing performance.
    Type: Application
    Filed: September 16, 2013
    Publication date: March 27, 2014
    Applicant: Ticona LLC
    Inventors: Kamlesh P. Nair, Young Shin Kim, James P. Shepherd, Prabuddha Bansal
  • Publication number: 20140087165
    Abstract: An aromatic polyester that contains one or more aromatic ester repeating units and one or more biphenyl repeating units is provided. While a wide variety of aromatic ester repeating units may be employed, the polymer is nevertheless “low naphthenic” to the extent that it contains a minimal content of repeating units derived from naphthenic hydroxycarboxylic acids and naphthenic dicarboxylic acids. Despite the absence of a high level of conventional naphthenic acid repeating units, the present inventors have discovered that selective control over the type and relative concentration of the biphenyl repeating units can lead to “low naphthenic” polymers that are not only soluble in certain solvents, but also capable of exhibiting good mechanical properties. Thus, the ability of the resulting polymer to be dissolved or dispersed in various solvents can be enhanced without sacrificing performance.
    Type: Application
    Filed: September 16, 2013
    Publication date: March 27, 2014
    Applicant: Ticona LLC
    Inventors: Kamlesh P. Nair, Young Shin Kim, James P. Shepherd, Prabuddha Bansal
  • Publication number: 20130338332
    Abstract: The invention is directed to sulfonated aromatic polyesters and methods of making said polymers. These polymers are useful as fibers and other articles. The polymer has a property of increased flame retardancy.
    Type: Application
    Filed: June 12, 2013
    Publication date: December 19, 2013
    Inventors: Justin W. Chan, Michael W. Cobb, Surbhi Mahajan, Sharlene Renee Williams
  • Patent number: 8586700
    Abstract: Disclosed is a method for preparing a poly(ethersulfonimide or ethersulfonamide) copolymer using cyclic oligomers, and more particularly, to a method for preparing a poly(ethersulfonimide or ethersulfonamide) copolymer by preparing a cyclic ether sulfone oligomer and a cyclic imide or amide oligomer and subjecting the cyclic ether sulfone oligomer and the cyclic imide or amide oligomer to ring-opening copolymerization in the presence of an alkali metal fluoride catalyst.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: November 19, 2013
    Assignee: Korea Reasearch Institute of Chemical Technology
    Inventors: Yong Seok Kim, Hyun Min Jung, Jong Chan Won, Jae Heung Lee
  • Publication number: 20130281619
    Abstract: Provided is a polyester polymer including a repeating unit derived from a dicarboxylic acid compound containing a partial structure represented by the following Formula (C) and a repeating unit derived from a diol compound containing a cyclic structure, in which the partial structure represented by Formula (C) constitutes a portion of the main chain: wherein in Formula (C), RA and RB each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; n and in each independently represent an integer from 0 to 2; Cy represents an unsaturated 6-membered or 7-membered ring which may contain a heteroatom; and * and ** each represent a bonding hand, while * may be a bonding hand extending from RA.
    Type: Application
    Filed: June 19, 2013
    Publication date: October 24, 2013
    Inventors: Shigeki UEHIRA, Toshimitsu SAKUMA, Toshihide YOSHITANI, Kozo SATO
  • Patent number: 8536298
    Abstract: A process for preparing polyimide resins comprises stirring a diamine and a dianhydride in a solvent to form a slurry; heating the slurry to a temperature sufficient for the diamine and dianhydride to react wherein the temperature is below the melting point of the dianhydride, below the melting point of the diamine, or below the melting points of the dianhydride and diamine; and reacting the diamine and dianhydride to form a polyimide having sufficient molecular weight to precipitate from the solvent.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: September 17, 2013
    Assignee: SABIC Innovative Platics IP B.V.
    Inventors: Philip L. Angermeier, Robert Edgar Colborn, Robert R. Gallucci, Paul Edward Howson, Tara Jane Mullen, Roy Ray Odle, Albert Santo Stella, John Morgan Whitney
  • Patent number: 8507634
    Abstract: Exemplary embodiments provide an intermediate transfer belt, materials and processes for producing an intermediate transfer belt, and an image transfer apparatus used in electrophotographic printing devices, wherein the intermediate transfer belt can comprise a thermosetting polyimide comprising the reaction product of a polyamic acid and a hydroxyl-terminated polybutadiene.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: August 13, 2013
    Assignee: Xerox Corporation
    Inventor: Jin Wu
  • Patent number: 8507635
    Abstract: The present invention relates to polycarbonates comprising imide-containing aryl mono- or dihydroxy compounds as chain terminators and, respectively, monomer units, and also to compositions comprising the said polycarbonates, to their use for the production of mouldings, and to mouldings obtainable therefrom.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: August 13, 2013
    Assignee: Bayer Intellectual Property GmbH
    Inventors: Alexander Meyer, Helmut-Werner Heuer, Rafael Oser, Rolf Wehrmann
  • Patent number: 8487066
    Abstract: Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
    Type: Grant
    Filed: January 16, 2012
    Date of Patent: July 16, 2013
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Daniel J. Brunelle, Martino Colonna, Maurizio Fiorini, Corrado Berti, Enrico Binassi
  • Publication number: 20130053530
    Abstract: Disclosed is a method for preparing a poly(ethersulfonimide or ethersulfonamide) copolymer using cyclic oligomers, and more particularly, to a method for preparing a poly(ethersulfonimide or ethersulfonamide) copolymer by preparing a cyclic ether sulfone oligomer and a cyclic imide or amide oligomer and subjecting the cyclic ether sulfone oligomer and the cyclic imide or amide oligomer to ring-opening copolymerization in the presence of an alkali metal fluoride catalyst.
    Type: Application
    Filed: October 7, 2010
    Publication date: February 28, 2013
    Inventors: Yong Seok Kim, Hyun Min Jung, Jong Chan Won, Jae Heung Lee
  • Publication number: 20130041125
    Abstract: The invention provides an amorphous polyester resin that can sufficiently achieve the reciprocal performance properties of hot offset resistance and cold offset resistance, which is a major issue for a toner for electrostatic image development, while allowing adequate blocking resistance to be obtained, as well as a binder resin for toner for electrostatic image development, and an amorphous polyester resin production method, the amorphous polyester resin being obtained by reaction between a polybasic carboxylic acid compound and a polyhydric alcohol, wherein the polybasic carboxylic acid compound comprises (a) the reaction product between an aromatic polybasic carboxylic acid compound and a C2-4 glycol at 60 mol % or greater based on the total amount of the polybasic carboxylic acid compound, and the amorphous polyester resin has a glass transition point of 55° C. to 75° C. and a weight-average molecular weight of 10,000 to 50,000.
    Type: Application
    Filed: April 23, 2010
    Publication date: February 14, 2013
    Applicant: NICCA CHEMICAL CO., LTD.
    Inventors: Tatsuhiro Hishida, Koji Ogawa, Yasumichi Moriyama, Masaaki Hosoda, Kazuo Tanabe
  • Patent number: 8232366
    Abstract: The present invention relates to an aqueous alkali-developable photosensitive polyimide precursor resin composition that is appropriate for highly heat-resistant transparent protection layers and insulation layers for liquid crystal display devices. In more detail, the present invention relates to a negative-type photosensitive transparent polyimide precursor resin composition manufactured in two steps.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: July 31, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Dong-seok Kim, Yong-sik Ahn, Kyung-jun Kim, Mi-hie Yi
  • Publication number: 20110301320
    Abstract: A method for purifying a polymer comprising providing a first mixture comprising at least one solvent and at least one polymeric material, diluting the first mixture with veratrole to produce a second mixture in which the polymeric material is substantially dissolved at a temperature less than 100° C., performing at least one step selected from (i) contacting the second mixture with an aqueous wash solution, and (ii) filtering the second mixture.
    Type: Application
    Filed: August 15, 2011
    Publication date: December 8, 2011
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventor: David Bruce HALL
  • Patent number: 8066966
    Abstract: A process for producing a filmy graphite includes the steps of forming a polyimide film having a birefringence of 0.12 or more and heat-treating the polyimide film at 2,400° C. or higher.
    Type: Grant
    Filed: July 2, 2010
    Date of Patent: November 29, 2011
    Assignee: Kaneka Corporation
    Inventors: Yasushi Nishikawa, Mutsuaki Murakami, Kiyokazu Akahori
  • Patent number: 8030433
    Abstract: Tailorable polyimide resin systems suitable for processing by resin transfer molding (RTM) and resin infusion (RI) methods. An exemplary resin system includes first and second prepolymer components present in respective amounts to provide the desired processibility. The cured polyimide system exhibits high glass transition temperature and other properties required for gas turbine engine applications. The first and second prepolymer components independently comprise a monomeric mixture or a reaction product of a diamine component, a dianhydride component, and an end group component.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: October 4, 2011
    Assignee: General Electric Company
    Inventors: Stephen Mark Whiteker, Lisa Vinciguerra Shafer, Warren Rosal Ronk
  • Patent number: 8030437
    Abstract: A method for forming a polyimide composite article utilizes a polyimide resin system including at least a first prepolymer component and a second prepolymer component. A preform structure is tackified with the first prepolymer component. Using resin infusion or resin transfer molding techniques, the tackified preform structure is contacted with the second prepolymer component. The polyimide resin system is cured under suitable cure conditions so that the first and second prepolymer components mix and react to produce the polyimide composite structure.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: October 4, 2011
    Assignee: General Electric Company
    Inventors: Stephen Mark Whiteker, Lisa Vinciguerra Shafer, Warren Rosal Ronk
  • Patent number: 8003749
    Abstract: Disclosed is a fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: August 23, 2011
    Assignee: Central Glass Company, Limited
    Inventors: Satoru Narizuka, Yuji Hagiwara, Masashi Nagamori, Kazuhiro Yamanaka
  • Patent number: 7989578
    Abstract: The present invention relates to a negative photosensitive polyimide polymer having a repeating unit of formula (1) as a polymerized unit: wherein G, Q and P* are as defined in the specification. The polyimide polymer of the present invention is developable in an aqueous alkaline solution, and has the properties associated with an insulating layer and photoresist.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: August 2, 2011
    Assignee: Eternal Chemical Co., Ltd.
    Inventor: Chung-Jen Wu
  • Publication number: 20110168631
    Abstract: Membranes for use in methods and apparatuses for water filtration are composed of at least one polyarylethernitrile membrane having structural units of formula 1 and structural units of formula 2, 3, or a combination thereof wherein Z is independently a direct bond, O, S, CH2, SO, SO2, CO, RPO, CH2, alkenyl, alkynyl, a C1-C12 aliphatic radical, a C6-C12 cycloaliphatic radical, a C6-C12 aromatic radical or a combination thereof, and wherein R is equal to C6-C12 aryl radical; Q is a direct bond, O, S, CH2, alkenyl, alkynyl, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C6-C12 aromatic radical or a combination thereof; R1, R2, R3 and R4 are independently H, halo, nitro, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C6-C12 aromatic radical, or a combination thereof; a is 0, 1, 2 or 3; b, c, and d are independently 0, 1, 2, 3 or 4; and p, m and n are independently 0 or 1; and Q and Z are different.
    Type: Application
    Filed: March 18, 2011
    Publication date: July 14, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Gary William Yeager, Daniel Steiger, Yanshi Zhang
  • Publication number: 20110098371
    Abstract: Disclosed are sulfonated polymers of formula (I) or a salt thereof: wherein X is (a) or (b), R is hydrogen or an organic moiety, n is an integer from 10 to 10,000, p is 1 or 2, and m is 0 or 1 for a particular monomer unit such that the polymer has a degree of sulfonation of 0.50 or greater. Such polymers are useful in proton exchange membranes (PEMs) having high ion exchange capacity with higher proton conductivity than Nafion™, while having lower methanol permeability and lower water uptake than previously disclosed polymers.
    Type: Application
    Filed: July 3, 2009
    Publication date: April 28, 2011
    Applicant: NATIONAL RESEARCH COUNCIL OF CANADA
    Inventors: Dae Sik Kim, Michael D. Guiver
  • Publication number: 20110027726
    Abstract: A polymer compound for photoresists contains alkali-soluble groups being protected by protecting groups capable of leaving with an acid, and is thereby insoluble or sparingly soluble in an alkaline developer, in which part or all of the protecting groups are multifunctional protecting groups each protecting two or more alkali-soluble groups. The alkali-soluble groups may be phenolic hydroxyl groups. The polymer compound may correspond to a polyol compound having an aliphatic group and an aromatic group bound to each other alternately, the aromatic group having an aromatic ring and two or more hydroxyl groups bound to the aromatic ring, except with phenolic hydroxyl groups of the polyol compound being protected by protecting groups capable of leaving with an acid. The polymer compound for photoresists can give a resist film with less line edge roughness (LER), while exhibiting excellent workability and resolution.
    Type: Application
    Filed: April 2, 2009
    Publication date: February 3, 2011
    Inventors: Kiyoharu Tsutsumi, Arimichi Okumura
  • Publication number: 20100233617
    Abstract: A photosensitive composition includes: (A) a resin containing a repeating unit corresponding to a compound represented by the following formula (I); the resin being capable of producing an acid group upon irradiation with an actinic ray or radiation: Z-A-X—B—R ??(I) wherein Z represents a group capable of becoming an acid group resulting from leaving of a cation upon irradiation with an actinic ray or radiation; A represents an alkylene group; X represents a single bond or a heteroatom-containing divalent linking group; B represents a single bond, an oxygen atom or —N(Rx)-; Rx represents a hydrogen atom or a monovalent organic group; R represents a monovalent organic group substituted by Y; when B represents —N(Rx)-, R and Rx may combine with each other to form a ring; and Y represents a polymerizable group.
    Type: Application
    Filed: September 18, 2008
    Publication date: September 16, 2010
    Applicant: FUJIFILM CORPORATION
    Inventor: Kenji Wada
  • Publication number: 20100174042
    Abstract: Sulfonated polymers have excellent processability and methanol resistance.
    Type: Application
    Filed: April 24, 2007
    Publication date: July 8, 2010
    Applicant: JSR CORPORATION
    Inventors: Yoshitaka Yamakawa, Yousuke Konno, Teruhiko Umehara
  • Patent number: 7714095
    Abstract: Polyether polymers, such as polyetherimides, are prepared by the reaction of a dihydroxy-substituted aromatic hydrocarbon alkali metal salt, such as bisphenol A disodium salt, with a bis(N-(chlorophthalimido))aromatic compound, such as 1,3- and/or 1,4-bis(N-(4-chlorophthalimido))benzene, in a solvent such as o-dichlorobenzene and in the presence of a phase transfer catalyst such as a hexaalkylguanidinium chloride. Several embodiments may be employed to improve the method. They comprise employing substantially dry reagents, employing a high solids level in solvent, beginning with an excess of bis(N-(chlorophthalimido))-aromatic compound and incrementally adding alkali metal salt, employing alkali metal salt of small particle size, and using reagents of high purity.
    Type: Grant
    Filed: February 28, 2006
    Date of Patent: May 11, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Daniel Joseph Brunelle, Havva Yagci Acar, Farid Fouad Khouri, Thomas Link Guggenheim, David Winfield Woodruff, Norman Enoch Johnson
  • Patent number: 7709592
    Abstract: Processes for preparing polyestercarbonates are disclosed. The processes allow for the consistent incorporation of adipic acid into a polymer generated from a dihydroxy compound, such as bisphenol-A, at levels greater than 99%. The polyestercarbonates so produced, as well as articles formed from the polyestercarbonates, are also disclosed herein.
    Type: Grant
    Filed: April 11, 2008
    Date of Patent: May 4, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventor: James Alan Mahood
  • Patent number: 7678874
    Abstract: This invention relates to a novel polyimide silicone having an alcoholic hydroxyl group and a process for the preparation thereof. The polyimide of the invention having a primary alcoholic hydroxyl group is represented by the following general formula (1), wherein X represents a tetravalent organic group, Y represents a divalent group having at least one monovalent group selected from the group consisting of a phenolic hydroxyl group and a carboxyl group, with at least one being a divalent organic group having an alcoholic hydroxyl group, Z represents a divalent organic group, W represents a divalent organic group having an organosiloxane structure, k is a positive number, and each of m and n is equal to 0 (zero) or a positive number, with 0.1?k/(k+m+n)?1, 0?m/(k+m+n)?0.8, 0?n/(k+m+n)?0.8.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: March 16, 2010
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Michihiro Sugo, Hideto Kato, Tomoyuki Goto
  • Publication number: 20100041837
    Abstract: A method for making a polyarylether having amide functionality includes reacting a dihydroxyaromatic compound having amide functionality with a dihaloaromatic sulfone or dinitroaromatic sulfone in the presence of a base. Polyarylethers having amide functionality and blends are also provided.
    Type: Application
    Filed: August 13, 2008
    Publication date: February 18, 2010
    Inventors: Gary William Yeager, Daniel Steiger, Yanshi Zhang
  • Publication number: 20100041853
    Abstract: A membrane including a polyarylether having amide functionality. The polyarylether having amide functionality includes units from at least one of structure I or structure II: R1 and R2 are separate groups or are covalently connected to form a cyclic moiety; R1 and R2 are each, independently, hydrogen, C1-20 alkyl, C3-C30 aryl or a substituted C3-30 aryl; R3, R4, R5, R6, R7 and R8 are each, independently, a nitro group, C1-C12 alkyl, C3-C30 aryl or a combination; Y is hydrogen, C1-20 alkyl or C3-C30 aryl; k is from about 0 to about 10; a, b, c, d, e and f are each, independently, 0, 1, 2, 3 or 4; and m and n are each, independently, 0 or 1.
    Type: Application
    Filed: August 13, 2008
    Publication date: February 18, 2010
    Inventors: Gary William Yeager, Daniel Steiger, Yanshi Zhang
  • Patent number: 7662904
    Abstract: The present invention relates to aromatic polyether resins crosslinked with amic acid or imide side chain, and more particularly, to the aromatic polyether resin crosslinked by amic acid or imide side chain, which is produced by heat curing of amic acid, wherein introduction of imide groups to the basic backbone provides excellent chemical resistance as well as heat resistance and improves surface roughness when coated as a thin film so that it can be suitable for films and flexible display plate substrate.
    Type: Grant
    Filed: February 13, 2006
    Date of Patent: February 16, 2010
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Jong Chan Won, Yong Seok Kim, Eun Sang Lee, Jae Heung Lee
  • Publication number: 20090043069
    Abstract: A process of making a sulfonated telechelic polycarbonate is described. A dihydroxy compound, a carbonate ester, and an activated ester of a sulfobenzoic acid salt are reacted together. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
    Type: Application
    Filed: August 6, 2007
    Publication date: February 12, 2009
    Applicant: General Electric Company
    Inventors: Daniel J. Brunelle, Martino Colonna, Maurizio Fiorini, Corrado Berti, Enrico Binassi
  • Publication number: 20090036633
    Abstract: An aromatic polycarbonate having a high refractive index and good processing and mechanical properties is provided. The aromatic polycarbonate comprises a thiodiphenol monomer and a biphenyl monomer. The refractive index of the polycarbonate may be greater than 1.670.
    Type: Application
    Filed: July 30, 2007
    Publication date: February 5, 2009
    Applicant: General Electric Company
    Inventors: Subash Scindia, Subarna Shyamroy
  • Publication number: 20080287610
    Abstract: Provided is a copolycarbonate which can meet a wide range of molding conditions as a raw material and which results in providing good optical molded articles. It is a copolycarbonate comprising repetitive units represented by the following Formulas (I) and (II), wherein a content of the repetitive unit represented by Formula (II) described below is 1 to 30 mass %, and a viscosity number is 30 to 71. In the formulas, R1 and R2 represent an alkyl group having 1 to 6 carbon atoms; X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, —S—, —SO—, —SO2—, —O—, —CO— or the like; R3 and R4 represent an alkyl group having 1 to 3 carbon atoms; Y represents a linear or branched alkylene group having 2 to 15 carbon atoms; a to d each are an integer of 0 to 4; and n is an integer of 2 to 450.
    Type: Application
    Filed: February 21, 2005
    Publication date: November 20, 2008
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Yasuhiro Ishikawa, Hiroshi Kawato, Atsushi Sato
  • Publication number: 20080097070
    Abstract: The present invention is drawn to an aqueous composition containing: (a) at least one polyamine compound comprising at least three amino groups; (b) at least one nonionic surfactant; (c) at least one compound chosen from an alkyl ether carboxylic acid, an alkyl ether carboxylate, a fatty acid having from about 6 to about 40 carbon atoms, and mixtures thereof; and (d) at least one water-insoluble material, and wherein the composition is both homogeneous and clear to substantially clear in appearance.
    Type: Application
    Filed: October 19, 2006
    Publication date: April 24, 2008
    Applicant: L'OREAL
    Inventors: Nghi Van Nguyen, Sawa Hashimoto, David W. Cannell
  • Patent number: 7288603
    Abstract: An object of the present invention is to obtain a novel polymeric material capable of forming a solid polymer electrolyte excellent not only in processability, solvent resistance and durability/stability but also in ion conductivity by introducing sulfonic acid group or phosphonic acid group into a polybenzazole compound having excellent properties in view of heat resistance, solvent resistance, mechanical characteristics and the like. Means attaining the object of the present invention is a polybenzazole compound including an aromatic dicarboxylic acid bond unit having sulfonic acid group and/or phosphonic acid group and satisfying either a condition that inherent viscosity measured in concentrated sulfuric acid is in the range of 0.25 to 10 dl/g or a condition that inherent viscosity measured in a methanesulfonic acid solution is in the range of 0.1 to 50 dl/g.
    Type: Grant
    Filed: November 12, 2001
    Date of Patent: October 30, 2007
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Yoshimitsu Sakaguchi, Kota Kitamura, Hiroaki Taguchi, Junko Nakao, Shiro Hamamoto, Hiroshi Tachimori, Satoshi Takase
  • Patent number: 7274854
    Abstract: An optical waveguide has a core layer made by a film containing a cross-linked polyamide based on a repeating unit of general formula (I) and a method for the production thereof.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: September 25, 2007
    Assignee: Pirelli & C. S.p.A.
    Inventors: Antonio Zaopo, Yuri A. Dubitsky, Marco Colombo
  • Patent number: 7226980
    Abstract: A curable composition includes a poly(arylene ether) and a fused alicyclic (meth)acrylate monomer. Also described are a method of preparing the composition, a cured composition derived from the curable composition, and an article comprising the cured composition. The composition is useful, for example, as a bulk molding compound.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: June 5, 2007
    Assignee: General Electric Company
    Inventor: Gary William Yeager
  • Patent number: 7211640
    Abstract: The present invention relates to an emulsion type adhesive applicable for over-laminating films, the preparation and the use thereof. The emulsion type adhesive comprises: (a) 60 to 99.5 parts per hundred of monomers of one or more alkyl acrylates containing 4-12 carbon atoms on the alkyl group; (b) 0.5 to 40 parts per hundred of monomers of an alkyl acrylate containing 1-3 carbon atoms in the alkyl group or an alkyl methacrylate containing 1-6 carbon atoms in the alkyl group; (c) 0.1 to 5 parts per hundred of monomers of dicarboxylic acids; (d) 1 to 5 parts per hundred of a reactive surfactant; (e) 0.1 to 15 parts per hundred of an organic acid vinyl ester; and (f) 100 parts per hundred of soft water, (a) and (b) are 100 parts by hundred, while (c), (d), (e) and (f) are calculated based on the total weight of (a)+(b). The products of this invention have excellent properties.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: May 1, 2007
    Assignee: Four Pillars Enterprise Co., Ltd.
    Inventors: Bin-Yen Yang, Chi-Lin Kao, Chih-Kuo Wan, Shu-Hei Lin, Shih-Shang Lo
  • Patent number: 7186454
    Abstract: A material for dielectric films is a polymerizable composition containing an organic solvent, and an adamantanepolycarboxylic acid derivative represented by following Formula (1): wherein X is hydrogen atom, a hydrocarbon group or R4; R1, R2, R3 and R4 and are each independently a protected or unprotected carboxyl group, etc.; and Y1, Y2, Y3 and Y4 are each independently a single bond or a bivalent aromatic cyclic group; and an aromatic polyamine derivative represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R5, R6, R7 and R8 are each a substituent bound to Ring Z and are each independently a protected or unprotected amino group, etc., dissolved in the organic solvent.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: March 6, 2007
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Shinya Nagano, Jiichiro Hashimoto, Kiyoharu Tsutsumi, Yoshinori Funaki
  • Patent number: 7169878
    Abstract: A diamine compound represented by the formula (1): wherein R1 is a trivalent organic group, each of X1 and X2 is a bivalent organic group, X3 is an alkyl or fluoroalkyl group having from 1 to 22 carbon atoms, or a cyclic substituent selected from aromatic rings, aliphatic rings, heterocyclic rings and their substituted groups, and n is an integer of from 2 to 5. And, a polyimide precursor and a polyimide synthesized by using the diamine compound; and a treating agent for liquid crystal alignment containing the polyimide precursor and/or the polyimide.
    Type: Grant
    Filed: December 26, 2001
    Date of Patent: January 30, 2007
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Kazuyoshi Hosaka, Hideyuki Nawata
  • Patent number: RE43880
    Abstract: This invention relates to the composition and a solvent-free process for preparing novel imide oligomers and polymers specifically formulated with effective amounts of a dianhydride such as 2,3,3?,4-biphenyltetra carboxylic dianydride (a-BPDA), at least one aromatic diamine and an endcapped of 4-phenylethynylphthalic anhydride (PEPA) or nadic anhydride to produce imide oligomers that possess a low-melt viscosity of 1-60 poise at 260-280° C. When the imide oligomer melt is cured at about 371° C. in a press or autoclave under 100-500 psi, the melt resulted in a thermoset polyimide having a glass transition temperature (Tg) equal to and above 310° C. A novel feature of this process is that the monomers; namely the dianhydrides, diamines and the endcaps, are melt processable to form imide oligomers at temperatures ranging between 232-280° C. (450-535° F.) without any solvent.
    Type: Grant
    Filed: May 8, 2006
    Date of Patent: December 25, 2012
    Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space Administration
    Inventor: Chun-Hua Chuang