Material Contains A Group Ivb Metal Atom Patents (Class 528/17)
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Patent number: 7879407Abstract: The invention relates to coating agents, containing (A) at least 50 wt. %, (in relation to the content of non-volatile substances in said coating agent), of at least one compound (A1) and/or (A1?) comprising at least two reactive groups of formula (I): —X—SiR?x(OR?)3-x, in which R?=hydrogen, alkyl or cycloalkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, Ra=alkyl, cycloalkyl, aryl or aralkyl, X=a linear and/or branched alkene or cycloalkene group comprising between 2 and 20 carbon atoms, R?=alkyl, cycloalkyl, aryl or aralkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, and x=0 to 2, (B) a catalyst for cross-linking the —Si(OR?)3-x units, and (C) an organic solvent or a mixture of organic solvents.Type: GrantFiled: October 8, 2005Date of Patent: February 1, 2011Assignee: BASF CorporationInventors: Andreas Poppeq, Guenter Klein, Michael Kutschera
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Patent number: 7868116Abstract: High-molecular-weight siloxane polymers are prepared in a multi-step process wherein an Si—H functional linear siloxane containing silanol groups is reacted with a hydrosilylatable organic compound, and the product is then condensed.Type: GrantFiled: June 19, 2007Date of Patent: January 11, 2011Assignee: Wacker Chemie AGInventor: Christian Herzig
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Patent number: 7851023Abstract: An essential aim of the invention is a treatment which permits: (i) coating a textile material and/or threads, fibers and/or filaments making up the textile material, the silicone formulation cross-linking around the threads, fibers and/or filaments making up the textile material and forming a cross-linked silicone coating around the same and ii) durably imparting water-repellency and impermeability to said textile material without substantially affecting the intrinsic respirability of the textile material. Said aim is achieved by means of the present invention using at least one cross-linkable silicone formulation as a base for the textile coating material, particularly, of a textile material which may be used for the production of sports clothing.Type: GrantFiled: January 21, 2005Date of Patent: December 14, 2010Assignee: Rhodia ChimieInventors: Martial Deruelle, Yves Giraud
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Publication number: 20100280173Abstract: A process for producing a conjugated diene-based polymer which comprises, in the first modification, modifying a conjugated diene-based polymer having active chain ends, which is obtained by polymerizing a diene-based monomer singly or with other monomers and has a content of a cis-1,4 unit of 75% by mole or greater in the conjugated diene portion of the main chain, by reacting the active chain ends with a hydrocarbyloxysilane compound and reacting the modified polymer with a specific compound such as a hydrocarbyloxysilane compound, and a rubber composition containing the polymer modified in accordance with the above process and, preferably, 10 to 100 parts by weight of silica and/or carbon black per 100 parts by weight of the rubber component containing the modified polymer, are provided. The rubber composition containing silica and/or carbon black exhibits improved fracture properties, abrasion resistance, low heat buildup property and excellent workability.Type: ApplicationFiled: July 2, 2010Publication date: November 4, 2010Applicant: BRIDGESTONE CORPORATIONInventors: Youichi OZAWA, Hejime Kondou, Noriko Endou
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Patent number: 7799870Abstract: Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.Type: GrantFiled: March 23, 2006Date of Patent: September 21, 2010Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Chenchy Jeffrey Lin, Terrence E. Hogan, Ashley S. Hilton
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Patent number: 7795360Abstract: A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.Type: GrantFiled: June 25, 2004Date of Patent: September 14, 2010Assignee: Dow Corning Toray Company, Ltd.Inventors: Toru Masatomi, Motoshi Sasaki, Hideki Kobayashi
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Patent number: 7723457Abstract: Polysilanes, inks containing the same, and methods for their preparation are disclosed. The polysilane generally has the formula H-[(AHR)n(c-AmHpm-2)q]—H, where each instance of A is independently Si or Ge; R is H, -AaHa+1Ra, halogen, aryl or substituted aryl; (n+a)?10 if q=0, q?3 if n=0, and (n+q)?6 if both n and q?0; p is 1 or 2; and m is from 3 to 12. In one aspect, the method generally includes the steps of combining a silane compound of the formula AHaR14-a, the formula AkHgR1?h and/or the formula c-AmHpmR1fm with a catalyst of the formula R4xR5yMXz (or an immobilized derivative thereof) to form a poly(aryl)silane; then washing the poly(aryl)silane with an aqueous washing composition and contacting the poly(aryl)silane with an adsorbent to remove the metal M. In another aspect, the method includes the steps of halogenating a polyarylsilane to form a halopolysilane; and reducing the halopolysilane with a metal hydride to form the polysilane.Type: GrantFiled: December 31, 2008Date of Patent: May 25, 2010Assignee: Kovio, Inc.Inventors: Wenzhuo Guo, Vladimir K. Dioumaev, Joerg Rockenberger, Brent Ridley
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Patent number: 7678842Abstract: Provided is a radiation-curable silicone rubber composition comprising: (A) a specific organopolysiloxane, which at each molecular chain terminal contains two or three silicon-containing groups that each contain a plurality of (from 2 to 9) (meth)acryloyl groups (in other words, a specific organopolysiloxane containing from 8 to 54 (meth)acryloyl groups within each molecule); and (B) a radiation sensitizer. The composition cures easily and favorably upon irradiation with low intensity, low energy radiation, and in particular upon irradiation with ultraviolet light emitted from a UV-LED light source. A cured coating generated from the composition rapidly develops favorable adhesion to a wide variety of substrates, and provides excellent corrosion prevention for the substrate, even under severe conditions.Type: GrantFiled: November 13, 2006Date of Patent: March 16, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Tsutomu Kashiwagi
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Patent number: 7674857Abstract: The present invention provides for a room temperature cured silicone thermoplastic resin sealant composition with reduced gas permeability useful in the manufacture of glazing such as windows and doors.Type: GrantFiled: November 18, 2005Date of Patent: March 9, 2010Assignee: Momentive Performance Materials Inc.Inventors: Shayne J. Landon, David A. Williams, Vikram Kumar, Sachin Askok Shelukar, Edward Joseph Nesakumar, Indumathi Ramakrishnan
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Patent number: 7658972Abstract: A silicone emulsion composition for wood treatment is prepared by emulsifying and dispersing (A) an organopolysiloxane, (B) the reaction product of an amino-containing organoxysilane and an acid anhydride, (C) an epoxy-containing organoxysilane, (D) colloidal silica and/or polysilsesquioxane, and (E) a curing catalyst in water to form a silicone emulsion, and adding and mixing (F) a boron compound with the silicone emulsion.Type: GrantFiled: August 9, 2006Date of Patent: February 9, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuyuki Matsumura, Akira Yamamoto
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Publication number: 20100025724Abstract: Disclosed is a resin composition for LED encapsulation including an organic oligosiloxane hybrid prepared by non-hydrolytic condensation of organoalkoxysilane. More particularly, the resin composition for LED encapsulation includes an organic oligosiloxane hybrid prepared by non-hydrolytic condensation of organoalkoxysilane with organosilanediol or non-hydrolytic condensation of a mixture containing organoalkoxysilane and metal alkoxide with organosilanediol. The prepared organic oligosilane hybrid has an inorganic network structure with a high degree of condensation and contains at least one organic group or organic functional group. In addition, an encapsulated LED fabricated using the above resin composition for LED encapsulation is provided.Type: ApplicationFiled: May 8, 2009Publication date: February 4, 2010Inventors: Byeong-Soo Bae, Seung-Cheol Yang
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Patent number: 7632574Abstract: A method of cross-linking a composition comprising firstly a polyethylene-based silane-grafted polymer, and secondly a filler. The invention is remarkable in that the cross-linking method consists in mixing the composition with a condensation catalyst constituted by lauryl stannoxane of formula [(C4H9)2Sn(OOCC11H23)]2O.Type: GrantFiled: October 18, 2006Date of Patent: December 15, 2009Assignee: NexansInventors: Christele Kensicher, Linda Boudiaf
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Patent number: 7632909Abstract: A self-adhesive organopolysiloxane composition is provided comprising (A) an organopolysiloxane containing at least two silicon-bonded alkenyl groups, (B) an organohydrogenpolysiloxane containing at least two SiH groups, (C) a hydrosilylation catalyst, and (D) an adhesive component obtained by previously mixing (i) a titanium chelate catalyst and/or a tetraorganoxytitanium and (ii) a silane coupling agent and aging the mixture. The composition cures at room temperature or lower temperature while it is fully adhesive to metal and plastic substrates.Type: GrantFiled: June 22, 2006Date of Patent: December 15, 2009Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tadashi Araki, Takeshi Miyao
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Patent number: 7625990Abstract: A curable composition having good curability and adhesion comprising: (A) an reactive silicon group-containing organic polymer, (B) a titanium chelate represented by the general formula (1) or (2) and (C) a high molecular weight plasticizer having a number average molecular weight of 1,000 to 15,000. General formula (1): wherein each of n R1s is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2s is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1s and (4-n) A2s is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2 or 3. General formula (2): wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 20 carbon atoms.Type: GrantFiled: April 25, 2005Date of Patent: December 1, 2009Assignee: Kaneka CorporationInventors: Katsuyu Wakabayashi, Toshihiko Okamoto, Masato Kusakabe
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Patent number: 7572842Abstract: The present invention relates to a multicomponent automixable putty impression material, its components, mixtures of the components and a method for obtaining impressions with the multicomponent automixable putty impression material.Type: GrantFiled: July 30, 2004Date of Patent: August 11, 2009Assignee: 3M ESPE AGInventors: Joachim W. Zech, Peter Bissinger, Henning Hoffmann, Wolf Steiger
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Patent number: 7550547Abstract: The present invention provides a curable composition which has a high recovery ratio, a high creep resistance, a practical curability and storage stability. The present invention relates to a curable composition comprising a reactive silicon group containing organic polymer (A) and a carboxylic acid (B), wherein the composition comprises (I), as the carboxylic acid (B), a carboxylic acid (C) in which the carbon adjacent to the carbonyl group is a quaternary carbon atoms and/or the composition comprises (II) a metal carboxylate (D) formed between a carboxylic acid in which the carbon atoms adjacent to the carbonyl group is a quaternary carbon atoms and a metal atom of 208 or less in atomic weight.Type: GrantFiled: March 29, 2005Date of Patent: June 23, 2009Assignee: Kaneka CorporationInventors: Katsuyu Wakabayashi, Toshihiko Okamoto, Hiroshi Ando
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Patent number: 7550204Abstract: The present invention provides a composition for sealing an optical device comprising (i) a silylated organopolysiloxane with a polystyrene equivalent weight average molecular weight of 5×104 or greater, represented by an average composition formula: R1a(OX)bSiO(4?a?b)/2 (wherein, R1 represents an alkyl group, alkenyl group, or aryl group; X represents a combination of a group represented by a formula —SiR2R3R4 (wherein, RE to R4 are monovalent hydrocarbon groups), and an alkyl group, alkenyl group, alkoxyalkyl group or acyl group; a represents a number within a range from 1.00 to 1.5; b represents a number that satisfies 0 b 2, and a+b satisfies 1.00 a+b 2), and (ii) a condensation catalyst, as well as a transparent cured product obtained by curing the composition, and a method of sealing a semiconductor element that comprises a step of applying the composition to a semiconductor element, and a step of curing the composition that has been applied to the semiconductor element.Type: GrantFiled: October 26, 2006Date of Patent: June 23, 2009Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hisashi Shimizu, Toshio Shiobara, Tsutomu Kashiwagi
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Patent number: 7534820Abstract: The present invention provides a novel photocurable composition containing an organic polymer having an epoxy group and/or oxetane group-containing silicon group at an end and a cationic photoinitiator. For example, the photocurable composition contains an organic polymer (A) having an epoxy group and/or oxetane group-containing silicon group at an end, and a cationic photoinitiator (B), the organic polymer (A) being produced by addition reaction between an organic polymer terminated with an unsaturated group and a hydrosilane compound having an epoxy group and/or an oxetane group.Type: GrantFiled: March 13, 2006Date of Patent: May 19, 2009Assignee: Kaneka CorporationInventors: Yoshiyuki Kohno, Hiroshi Ando
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Patent number: 7527870Abstract: A moisture curable composition capable of cure to an elastomeric body, the composition comprising (a) an organopolysiloxane having not less than two silicon-bonded hydroxyl or hydrolyzable groups; (b) a silane of the general formula G2-Si—R12, wherein each group is reactable with the hydroxyl or hydrolyzable groups in (a), and each R1 group is an alkyl group having from 1 to 10 carbon atoms, an alkenyl group, an alkynyl group an aryl group or a fluorinated alkyl group; (c) one or more fillers and (d) a photocatalyst. Preferably at least one R1 group is unsaturated, but in the absence of this there is provided an additional component in the form of (e) an unsaturated compound selected from the group of an unsaturated short chain siloxane, an unsaturated cyclic siloxane, an unsaturated fatty acid an unsaturated fatty alcohol or an unsaturated fatty acid ester. The cured product is generally used as a sealant, which avoids dirt pick-up after cure and has a protective layer on the sealant interface with air.Type: GrantFiled: March 16, 2004Date of Patent: May 5, 2009Assignee: Dow Corning CorporationInventors: Andrew Beger, Timothy Lueder, Nagambai Subramaniam
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Patent number: 7504468Abstract: Single-component silicone compositions which are stable on storage in the absence of moisture and which crosslink by polycondensation reactions catalyzed using a mixed titanium/metal catalyst to give non-yellowing elastomers which adhere to various supports, the reactions being carried out at ambient temperature and in the presence of water; each single-component POS composition comprises: 100 parts by weight of linear diorganopolysiloxane(s) A functionalized at the chain ends by functional group Rfo of alkoxy, acyloxy, iminoxy or enoxy type; 0 to 30 parts by weight of polysiloxane resin(s) B; 0 to 15 parts by weight of crosslinking agent(s) C; 0 to 2 parts by weight of aliphatic alcohol(s) E; 0 to 30 parts by weight of non-functionalized and unreactive linear diorganopolysiloxane(s) F; 2 to 40 parts by weight of inorganic filler G; 0 to 20 parts by weight of auxiliary agent(s) H; and 1 to 150 ?g.Type: GrantFiled: June 9, 2004Date of Patent: March 17, 2009Assignee: Rhodia ChimieInventors: Nathalie Guennouni, Marc Chaussade
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Publication number: 20090048416Abstract: The present invention relates to new high-functionality, highly branched or hyperbranched polylysines, to processes for preparing them, and to their use.Type: ApplicationFiled: November 15, 2006Publication date: February 19, 2009Applicant: BASF SEInventors: Bernd Bruchmann, Harm-Anton Klok, Markus Thomas Scholl
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Patent number: 7485691Abstract: Polysilanes, inks containing the same, and methods for their preparation are disclosed. The polysilane generally has the formula H—[(AHR)n(c-AmHpm?2)q]—H, where each instance of A is independently Si or Ge; R is H, —AaHa+1Ra, halogen, aryl or substituted aryl; (n+a)?10 if q=0, q?3 if n=0, and (n+q)?6 if both n and q?0; p is 1 or 2; and m is from 3 to 12. In one aspect, the method generally includes the steps of combining a silane compound of the formula AHaR14?a, the formula AkHgR1?h and/or the formula c-AmHpmR1rm with a catalyst of the formula R4xR5yMXz (or an immobilized derivative thereof) to form a poly(aryl)silane; then washing the poly(aryl)silane with an aqueous washing composition and contacting the poly(aryl)silane with an adsorbent to remove the metal M. In another aspect, the method includes the steps of halogenating a polyarylsilane to form a halopolysilane; and reducing the halopolysilane with a metal hydride to form the polysilane.Type: GrantFiled: October 6, 2005Date of Patent: February 3, 2009Assignee: Kovio, IncInventors: Wenzhuo Guo, Vladimir K. Dioumaev, Joerg Rockenberger, Brent Ridley
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Publication number: 20090018302Abstract: The invention relates to polyisocyanates containing allophanate groups and silane groups, to a process for preparing them and to their use as a starting component in the production of polyurethane polymers, more particularly as a crosslinker component in polyurethane paints and coatings.Type: ApplicationFiled: July 11, 2008Publication date: January 15, 2009Applicant: Bayer MaterialScience AGInventors: Hans-Josef Laas, Reinhard Halpaap
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Patent number: 7462678Abstract: A process for producing a film forming composition, the process including hydrolyzing and condensing: (A) at least one silane compound selected from a compound (A-1) shown by the following general formula (1), a compound (A-2) shown by the following general formula (2), and a compound (A-3) shown by the following general formula (3), RaSi(OR1)4-a??(1) Si(OR2)4??(2) R3b(R4O)3-bSi—(R7)d—Si(OR5)3-cR6c??(3); and (B) a cyclic silane compound shown by the following general formula (4):Type: GrantFiled: September 23, 2004Date of Patent: December 9, 2008Assignee: JSR CorporationInventors: Masahiro Akiyama, Seitaro Hattori, Masaki Obi, Koichi Hasegawa
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Publication number: 20080287636Abstract: [PROBLEMS] There is provided a curable composition having good curability and adhesiveness. [MEANS FOR SOLVING] A curable composition by comprising (A) an reactive silicon group-containing organic polymer, (B) a titanium chelate represented by the general formula (1) or (2), (C) a high molecular weight plasticizer having a number average molecular weight of 1000 to 15000: General Formula (1): wherein each of n R1's is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2's is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1's and (4-n) A2's is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2, or 3. General Formula wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group havimg 1 to 20 carbon atoms.Type: ApplicationFiled: April 25, 2005Publication date: November 20, 2008Inventors: Katsuyu Wakabayashi, Toshihiko Okamoto, Masato Kusakabe
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Publication number: 20080269406Abstract: The invention relates to ?-ethoxysilane modified polymers of the average general formula (I): in which R is a mono- to tetravalent polymer radical, not more than a third of the radicals R1, R2, and R3 present in the polymer of the formula (I), independently of one another, are alkyl radicals having 1 to 4 carbon atoms, at least a quarter of the radicals R1, R2, and R3 present in the polymer of the formula (I), independently of one another, are ethoxy radicals, any remaining radicals R1, R2, and R3, independently of one another, are methoxy radicals, and in which n is 1 to 4. The invention further relates to a process for preparing the polymers of the formula (I), and also to their use in adhesives, sealants, and coating materials.Type: ApplicationFiled: April 18, 2008Publication date: October 30, 2008Inventors: Thomas Bachon, Jennifer Schmidt, Thomas Tamcke, Patrick Gawlik
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Patent number: 7368519Abstract: The invention provides fast moisture and photo/moisture curing silicone compositions and methods for the preparation thereof. More particularly, the compositions provided are prepared from silanol and silane cappers; the cappers have an ?-carbon bonded to the silicon atom allowing for a favorable hypervalent silicon transition state when reacting the silane and silanol. This favorable transition state enables both a fast endcapping reaction and contributes to the fast moisture curing properties of the inventive compositions.Type: GrantFiled: October 15, 2003Date of Patent: May 6, 2008Assignee: Henkel CorporationInventor: Hsien-Kun Chu
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Patent number: 7365145Abstract: The present invention relates to moisture-curable silylated polymers having unreacted or “free” hydroxyl groups prior to cure with improved physical properties, lower viscosity and lower cost, suitable for preparing coatings, adhesives and sealants.Type: GrantFiled: September 14, 2005Date of Patent: April 29, 2008Assignee: Momentive Performance Materials Inc.Inventors: Yurun Yang, Shen Min, Misty Huang
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Patent number: 7351782Abstract: The present invention provides a one-part curable composition, comprising (A) an organic polymer having a silicon-containing group capable of cross-linking by forming siloxane bonds; (B) a metal carboxylate; and (C) a carboxylic acid smaller in molar quantity than the (B) component metal carboxylate, the one-part curable composition being simultaneously practical in recovery ratio, durability, creep resistance, storage stability and adhesion.Type: GrantFiled: September 22, 2003Date of Patent: April 1, 2008Assignee: Kaneka CorporationInventors: Katsuyu Wakabayashi, Toshihiko Okamoto, Hiroshi Ando
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Patent number: 7345130Abstract: The invention is an adhesive composition comprising a) one or more silane functional prepolymers comprising a polyether or a polyolefin backbone and silane moieties capable of silanol condensation; b) one or more isocyanate functional prepolymers comprising a polyether backbone and isocyanate moieties; c) one or more organotin compounds or titanate or zirconate compounds having one or more ligands comprising a hydrocarbyl phosphate ester or a hydrocarbyl sulfonate ester, or a mixture thereof; d) a tertiary amine or an anhydrous strong organic acid which is miscible with the polymer and enhances the bonding of the adhesive to a coated unprimed substrate. In one embodiment, the invention is a method of bonding two or more substrates together using the adhesive compositions of this invention. The process comprises applying an adhesive as described herein to one or more of the substrates; contacting the one or more substrates with the adhesive disposed between the substrates; and allowing the adhesive to cure.Type: GrantFiled: October 23, 2006Date of Patent: March 18, 2008Assignee: Dow Global Technologies Inc.Inventors: Huide D. Zhu, Syed Z. Mahdi, Matthew B. Feldpausch
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Patent number: 7338996Abstract: Primer compositions comprising (A) organopolysiloxanes having at least four ethylenically unsaturated radicals R1 per molecule, (B) organosilane or organocarbosilane compounds having at least one hydrolyzable group selected from —OR2, —NR22, R2—C(?O)—N(R2)— or —O—N?CR22, where R2 is an optionally substituted alkyl group, (C) fillers, such as reinforcing fillers, silicone resins or hydrolysis condensates of at least one organosilicon compound (B) defined above, and (D) solvents, such as organic solvents of low molecular weight cyclic or linear polyorganosilicon compounds, provide high adhesive strength between a variety of substrates and silicone rubber compositions, such that composites of improved properties may be produced.Type: GrantFiled: June 21, 2004Date of Patent: March 4, 2008Assignee: Wacker Chemie AGInventors: Armin Fehn, Arvid Kuhn
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Patent number: 7332196Abstract: The present invention provides a fiber-reinforced glass having excellent heat resistance and toughness, or a composite comprising a heat-resistant fiber and a siloxane polymer, which has a modified surface structure and is useful as a heat-resistant fiber.Type: GrantFiled: March 28, 2003Date of Patent: February 19, 2008Assignees: Kazari-Ichi Co., Ltd., Sakase Adtech Co., Ltd.Inventors: Kazuhiko Kosuge, Hideo Nakamura, Tsutomu Yamamoto, Yoko Iwamiya, Osamu Yagi
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Patent number: 7309732Abstract: The present invention is directed to silicone formulations which are capable of being rapidly cured to tough elastomeric materials through exposure to UV radiation, and optionally through exposure to moisture as well. The cured products demonstrate high resistance to flammability and combustibility.Type: GrantFiled: April 21, 2003Date of Patent: December 18, 2007Assignee: Henkel CorporationInventor: Bahram Issari
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Patent number: 7294669Abstract: An object of the present invention is to provide a low-modulus, high elongation sealant having improved dynamic durability, desirable mechanical properties, and good workability. The present invention provides a sealant containing an oxyalkylene polymer (A) having a number-average molecular weight of 20,000 to 50,000 and 0.8 or more of reactive silicon groups per molecule on average; 10 parts by weight or more of a plasticizer (B) per 100 parts by weight of the polymer (A); a filler (C); and a curing catalyst (D). This sealant has an improved durability and can achieve the above-described object.Type: GrantFiled: April 8, 2005Date of Patent: November 13, 2007Assignee: Kaneka CorporationInventor: Hiroshi Ito
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Patent number: 7253243Abstract: There is provided a method of synthesizing an organosilicon compound. This method comprises polymerizing, as a starting material, allyl-(4-alkynyl-phenyl) silane represented by the following general formula (3) in a solvent selected from methylene chloride, chloroform, carbon tetrachloride and 1,2-dichloroethane and under the presence of hafnium tetrachloride to obtain an organosilicon compound represented by the following general formula (1). (wherein R is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a phenyl group, R's may be the same or different and are individually an alkyl group having 1 or 2 carbon atoms or a phenyl group, and n is an integer of 4 to 2500).Type: GrantFiled: August 18, 2006Date of Patent: August 7, 2007Assignee: Japan Science and Technology AgencyInventors: Yoshinori Yamamoto, Naoki Asao, Hisamitsu Tomeba
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Publication number: 20070179244Abstract: An organopolysiloxane composition suited for magnesium alloy bonding comprises (A) a specific organopolysiloxane, (B) a non-reactive silicone oil, (C) zinc oxide surface treated with a silane or siloxane treating agent, (D) heavy calcium carbonate surface treated with a paraffin treating agent, (E) an organosilicon compound having at least three hydrolyzable radicals or a partial hydrolyzate thereof, (F) a silane coupling agent having at least one epoxy radical, and (G) a titanium chelate catalyst. The composition has improved chemical resistance.Type: ApplicationFiled: January 31, 2007Publication date: August 2, 2007Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Tadashi Araki, Mamoru Teshigawara, Tsuneo Kimura
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Patent number: 7232864Abstract: The present invention is a coupled radial anionic polymer comprising a polyhedral oligosilsesquioxane [POSS] of the formula [R—SiO3/2]n. POSS compounds having R=vinyl, glycidyldimethyl silyl, and isobutyl have been found effective in coupling anionic living polymers to yield radial polymers having 2 to 10 arms. Radial polymers of the present invention have been formed using POSS octamers and mixtures of POSS octamers, decamers and dodecamers. The present invention also relates to a process for coupling living anionic polymers with POSS compounds.Type: GrantFiled: October 14, 2004Date of Patent: June 19, 2007Inventor: Robert C. Bening
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Patent number: 7205050Abstract: An RTV seal forming silicone composition has a silicone base material that includes a lipophilic secondary phase insoluble in the silicone base material upon cure thereof. The resulting silicone has a shear adhesion strength as measured by transverse displacement of less than 50 pounds per square inch allowing for polymerized silicone removal without damage to an oil pan assembly.Type: GrantFiled: June 9, 2004Date of Patent: April 17, 2007Assignee: Permatex, Inc.Inventor: Hans E. Haas
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Patent number: 7160962Abstract: Elastomer-modified Epoxy-polysiloxane compositions of this invention are prepared by combining a silicone intermediate, with an epoxy resin, an elastomeric resinous intermediate, a polyfunctional amine, an optional organometallic catalyst, and optional fillers, pigments, and processing agents. The composition is prepared using a sufficient amount of water to promote hydrolysis of the polysiloxane and the polycondensation of the silanols produced by such hydrolysis. In its cured form, the epoxy-polysiloxane composition exists as a uniformly dispersed arrangement of linear epoxy chain fragments that are cross-linked with a continuous polysiloxane polymer chain, wherein either or both of the epoxy and/or polysiloxane polymers are elastomer modified to provide coatings and floorings having significantly improved properties of impact resistance, flexibility, crack resistance, and abrasion resistance with compared to conventional epoxy systems.Type: GrantFiled: October 27, 2003Date of Patent: January 9, 2007Assignee: Ameron International CorporationInventor: Haruji Sakugawa
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Patent number: 7081508Abstract: A primer composition comprises (a) a fluoroalkylene or fluoropolyether compound having at least one alkenyl radical and at least one hydrolyzable silyl radical, (b) an organic titanic acid ester, (c) an organic tin compound, and (d) a silane compound. The primer composition is fully adherent to various substrates of metals, glass, ceramics, cement, mortar, carbon, and plastics, and is particularly suited for use with a thermosetting elastomer composition based on a polymer having at least two alkenyl radicals and a perfluoropolyether structure in its backbone.Type: GrantFiled: June 25, 2004Date of Patent: July 25, 2006Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takashi Matsuda, Yasuhisa Osawa
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Patent number: 7049384Abstract: The present invention relates to polysiloxane compositions which cross-link by condensation and contain at least one cross-linkable polysiloxane, at least one basic filler, at least one phosphorus compound, at least one alkoxysilane cross-linking agent, at least one organometallic compound and optionally other auxiliary substances, a process for their production and their use, as well as surface-modified fillers and their use.Type: GrantFiled: March 1, 1996Date of Patent: May 23, 2006Assignee: GE Bayer Silicones GmbH & Co. KGInventors: Robert Friebe, Wilhelm Weber, Karl-Heinz Sockel
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Patent number: 7026426Abstract: A room temperature curable organopolysiloxane composition comprising (A) an organopolysiloxane of HO(SiR12O)nH and/or (R2O)3-mR1mSiO(SiOR12O)nSiR1m(OR2)3-m wherein R1 is a monovalent C1–10 hydrocarbon radical, R2 is a monovalent C1–6 hydrocarbon radical, n is an integer of at least 10, and m is 0 or 1, (B) a silane compound having at least two hydrolyzable radicals, the remaining radicals being methyl, ethyl, propyl, vinyl or phenyl, and/or a partial hydrolyzate thereof, and (C) an organosilicon compound of (RO)pR13-pSiR3—NH—R4—NH2 wherein R1 and R2 are as defined above, R3 is a divalent C1–10 hydrocarbon radical, R4 is a divalent aromatic ring-bearing C7–10 hydrocarbon radical, and p is 1, 2 or 3, at least one of the NH and NH2 radicals being not directly attached to the aromatic ring in R4, cures into silicone rubber which has improved adherence even upon exposure to hot steam.Type: GrantFiled: October 28, 2003Date of Patent: April 11, 2006Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Tsuneo Kimura
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Patent number: 7022800Abstract: A moisture curable composition capable of cure to an elastomeric body, comprising a polymeric material having not less than two hydroxyl or hydrolyzable groups an alkoxysilane curative and a catalyst comprising: a mixture and/or reaction product of a compound (i) M[OR]4 and compound (ii) M[OR?]x[Z]z, wherein M represents a metal having a valency of 4 selected from Group IVB of the Periodic Table, preferably titanium or zirconium.Type: GrantFiled: January 4, 2001Date of Patent: April 4, 2006Assignee: Dow Corning S.A.Inventors: Mamoru Tachikawa, Toshio Saruyama, Kazutoshi Okabe, Hiroshi Adachi, Francois De Buyl, Luo Cheng Zhang
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Patent number: 7009021Abstract: A paint composition includes a layer organic-inorganic composite, and titanium alkoxide in an amount of from 1 to 50 parts by weight with respect to the layer organic-inorganic composite taken as 100 parts by weight. The layer organic-inorganic composite is composed of a laminated substance. The laminated substance includes a tetrahedral structural layer and an octahedral structural layer. The tetrahedral structural layer is made of tetrahedral structures whose central atom M? is Si or a first metallic atom substituting for a part the Si, at least a part of the central atom M? covalent-bonded to an organic group R involving or free from a polymerizable functional group. The octahedral structural layer is made of octahedral structures whose central atom M is a second metallic atom.Type: GrantFiled: July 29, 2003Date of Patent: March 7, 2006Assignee: Kabushiki Kaisha Toyota JidoshokkiInventors: Masaaki Tani, Yoshiaki Fukushima, Toshihisa Shimo, Hitotoshi Murase
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Patent number: 6902816Abstract: The invention relates to silicone compositions that are used in the production of varnishes that can be applied to supports in order to reduce the friction coefficient. The inventive composition comprises at least one polyorganosiloxane A (POS) which can be cationically and radically cross-linked by functional cross-linking groups (GFR) and a primer C chosen from onium borates, characterized in that the inventive composition also comprises molecules (POS D) which are substituted by secondary functional groups (GFS) carried by silicon atoms and selected from those that include at least one alkoxy and/or epoxy and/or carboxy motif and optionally a charge (e.g. silica). The invention can be used with anti-friction varnishes for RTV silicone coatings for material used in air bags, thermal transfer ribbons or packing films.Type: GrantFiled: April 5, 2000Date of Patent: June 7, 2005Assignee: Rhodia ChimieInventors: Jean-Louis Bertry, Jean-Marc Frances, Fabrice Bohin, Christian Priou
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Patent number: 6878769Abstract: A room temperature curable organopolysiloxane composition comprising (A) an organopolysiloxane having organooxysilyl groups on side chains or on side chains and ends of the polymer, (B) fumed silica, (C) an organooxysilane or a partial hydrolytic condensate thereof, and (D) a condensation catalyst is improved in stability during storage under sealed conditions and cures into an elastomeric product whose physical properties change little even when used under rigorous conditions as encountered in proximity to automotive engines.Type: GrantFiled: December 24, 2002Date of Patent: April 12, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takafumi Sakamoto, Tsuneo Kimura
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Patent number: 6867242Abstract: The invention relates to a method for producing a sealed impregnation and/or release coating of flat joints, in particular of cylinder-head gaskets such as composite seals, metallic joints and multi-layered steel joints. The invention uses a silicone composition including at least a polyorganosiloxane A crosslinkable by a cationic and/or radical process by appropriate crosslinking functional groups, for example, of the alkenyl ether, acrylic, acrylate, epoxide and/or oxethane type; at least an initiator salt B selected among onium borates or an organometallic complex; and at least a reactive diluent C including a nonorganosilicon or organosilicon compound comprising in its structure at least a crosslinking functional group and optionally a secondary functional group different from the crosslinking functional group but capable of chemically reacting with a crosslinking functional group, for example of the hydroxyl, alkoxy and/or carboxyl type.Type: GrantFiled: June 8, 2000Date of Patent: March 15, 2005Assignee: Rhodia ChimieInventors: Jean-Marc Frances, Olivier Loubet
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Patent number: 6864340Abstract: The present invention provides novel “hybrid” silyl-terminated polymers that contain at least two different reactive end-capping groups. The “hybrid” silyl-terminated polymers of the present invention are produced by a novel single multi-step end-capping reaction of at least one silanol-terminated polymer with at least two silanes in the presence of a catalyst.Type: GrantFiled: May 2, 2001Date of Patent: March 8, 2005Assignee: Henkel CorporationInventors: Michael P. Levandoski, Robert P. Cross, Alfred A. DeCato, Heath L. Salvati
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Patent number: 6846865Abstract: The invention relates to silicone rubber formulations comprising organopolysiloxanes and hydrophobicized silicas, which possess an extremely high level of whiteness.Type: GrantFiled: September 20, 2002Date of Patent: January 25, 2005Assignee: Degussa AGInventors: Christian Panz, Ralf Schmoll, Uwe Schachtely, Michael Kempf, Mario Scholz
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Patent number: 6833407Abstract: The present invention relates to a solvent free one-part room temperature vulcanizable organopolysiloxane rubber composition which crosslinks in the presence of moisture to form a high gloss coating with minimal shrinkage for surfaces.Type: GrantFiled: October 16, 2003Date of Patent: December 21, 2004Assignee: CSL Silicones Inc.Inventors: Farooq Ahmed, Faisal Huda, Serajul Huda, John Barr