Nitrogen-containing Reactant Patents (Class 528/208)
  • Patent number: 7790831
    Abstract: In accordance with the present invention there are provided hyperbranched benzobisazole polymers having repeating units of the formulas: and hyperbranched bibenzazole polymers having repeating units of the formulas: wherein Q is —S— or —NH—; the terminal groups X and Y are COOH and respectively, with their total number (X+Y) equals n+1, where n=degree of polymerization. The ratio X:Y can be controlled by varying the stoichiometric ratio of trimesic acid (A3 monomer) and 2,5-diamino-1,4-dimercaptobenzene dihydrochloride (B2 monomer) from 1:1 to 1.1.35.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: September 7, 2010
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Loon-Seng Tan, David H. Wang, Jong-Beom Baek
  • Publication number: 20100119969
    Abstract: There is provided a positive photosensitive resin composition that is excellent in electric insulating properties, heat resistance, mechanical strength and electrical characteristics, and capable of forming a high-resolution circuit pattern. The positive photosensitive resin composition comprises at least one type of a polyhydroxyamide resin containing a repeating unit represented by Formula (1) and having a weight average molecular weight of 3,000 to 100,000, and a compound generating an acid by light irradiation. (where X represents a tetravalent aliphatic group or an aromatic group; R1 and R2 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atom(s); Ar1 and Ar2 independently represent an aromatic group; Y represents an organic group containing an aromatic group substituted with at least one OH group; n represents an integer of 1 or more; and l and m independently represent an integer of 0 or 1 or more and satisfy l+m?2).
    Type: Application
    Filed: May 27, 2008
    Publication date: May 13, 2010
    Applicant: NISSAN CHEMICAL INDUSTRIES LTD.
    Inventors: Kazuya Ebara, Hideo Suzuki, Takayuki Tamura
  • Publication number: 20100081782
    Abstract: The present invention provides a compound having a formula: where R1 is selected from the group consisting of alkyl, CH2(OC2H4)OCH3, and —(OC2H4)OCH3; n is 0-4; Olig is an oligomer having a formula: -L-O-PAGR.R2]q where L is a optional linker moiety selected from the group consisting of —CH2O—, —CH2OX—, —OX—, —C(O)—, —C(O)X, —NH—, —NHC(O)—, —XNHC(O)—, —NHC(O)X—, —C(O)NH—, —C(O)NHX—, and where X is alky1-6 or is not present, Y is N or O or is not present, and R3 is alkyl1-6; PAG is a linear or branched polyalkylene glycol moiety; R2 is an alkyl1-22 capping moiety if X is present or alkyl2-22 if X is not present; and q is a number from 1 to the maximum number of branches on PAG; and m is 1-5.
    Type: Application
    Filed: November 20, 2009
    Publication date: April 1, 2010
    Inventors: Nnochiri N. Ekwuribe, Amy L. Odenbaugh
  • Publication number: 20100010189
    Abstract: A gas-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Application
    Filed: July 8, 2008
    Publication date: January 14, 2010
    Inventors: KEITH W. HUTCHENSON, AARON MINTER, GREGG SUNSHINE
  • Publication number: 20090304610
    Abstract: The invention concerns synthetic polymers obtainable by oxidative polymerization of vegetal tannins, alone or in combination with eumelanin and/or pyrocatechic precursors, method of preparation and uses thereof in the cosmetic and dermato-logic fields; complexes of said polymers with metals and their use in dyeing processes are also disclosed.
    Type: Application
    Filed: November 29, 2005
    Publication date: December 10, 2009
    Inventor: Carlo Ghisalberti
  • Publication number: 20090286094
    Abstract: A novel polyimide as a high molecular weight material having a low dielectric constant, a low dielectric loss tangent and low water absorptivity, a polyamic acid capable of generating the above polyimide, the above polyimide and the polyamic acid being obtained by reacting an aromatic diamine, obtained by introducing aromatic amino groups into both terminals of a specific bifunctional phenylene ether oligomer, with an acid anhydride, a process for the production of the polyimide, a process for the production of the polyimide, a film of the polyimide, and a laminate comprising the above film.
    Type: Application
    Filed: May 13, 2009
    Publication date: November 19, 2009
    Inventors: Kazuyoshi Uera, Daisuke Ohno, Kenji Ishii
  • Patent number: 7582719
    Abstract: Hyperbranched benzazole polymers having repeating units of the formula: wherein Q is —O—, —S— or —NH—, and the terminal groups R are carboxylic acids with their total number equals n+1. A generic method for preparing the polymers is provided. Also provided are the star block copolymers derived from these hyperbranched benzazole polymers and linear poly(ether-ketones) having the following generic formula where x and y are the numbers of repeat units for each poly(ether-ketone) chain; the placement of the carbonyl moieties in the repeat units of the poly(ether-ketone) chains can be either meta or para to the phenoxy groups; the maximal number of poly(ether-ketone) chains is n+1, where n=number of repeat units for hyperbranched polybenzazole). A general method for synthesizing these star block copolymers is provided.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: September 1, 2009
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Loon-Seng Tan, Jong-Beom Baek
  • Publication number: 20090179000
    Abstract: A method of manufacturing an inkjet printhead, in which a solvent included in a positive photoresist composition or in a non-photosensitive soluble polymer composition which is used to form a sacrificial layer has a different polarity from that of a solvent included in a negative photoresist composition that is used to form at least one of a channel forming layer and a nozzle layer.
    Type: Application
    Filed: June 24, 2008
    Publication date: July 16, 2009
    Applicants: Samsung Electronics Co., Ltd, Korea Advanced Institute of Science and Technology
    Inventors: Jong-jin Park, Su-min Kim, Jin-baek Kim, Yong-ung Ha, Yong-seop Yoon, Byung-ha Park
  • Publication number: 20090170927
    Abstract: The present invention relates to compounds of formula I, which are functionalized phenolic compounds, and polymers formed from the same. Ar—[O—(X)p—R?]q??I Polymers formed from the functionalized phenolics are expected to have controllable degradation profiles, enabling them to release an active component over a desired time range. The polymers are also expected to be useful in a variety of medical applications.
    Type: Application
    Filed: October 16, 2006
    Publication date: July 2, 2009
    Applicant: BEZWADA BIOMEDICAL, LLC
    Inventor: Rao S. Bezwada
  • Patent number: 7544762
    Abstract: A polyester having a good color tone (a high L value and a low b value) and a low acetaldehyde content is obtained by using a catalyst containing a reaction product of (A) a titanium compound (1) represented by the general formula (I) and/or a titanium compound (2) obtained by reacting the titanium compound (1) of the general formula (I) with an aromatic polyhydric carboxylic acid represented by the general formula (II) or an anhydride thereof, with (B) a phosphorus compound (3) represented by the general formula (III). [wherein R1, R2, R3, R4 and R5=a C2-C10 alkyl group, k=1 to 3, m=2 to 4, and R6=a substituted or non-substituted C6-C20 aryl group or a C6-C20 alkyl group].
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: June 9, 2009
    Assignee: Teijin Limited
    Inventors: Tomoyoshi Yamamoto, Hiroki Nagano, Minoru Suzuki, Hiroshi Toyao, Tomoyuki Kishino, Nobuo Minobe, Ryoji Tsukamoto, Kenichi Ishihara
  • Publication number: 20090131624
    Abstract: Morpholino compounds are provided having the structure: where R1 is selected from the group consisting of lower alkyl, di(lower alkyl)amino, and phenyl; R2 is selected from the group consisting of lower alkyl, monocyclic arylmethyl, and monocyclic (aryloxy)methyl; R3 is selected from the group consisting of triarylmethyl and hydrogen; and Y is selected from the group consisting of: a protected or unprotected hydroxyl or amino group; a chlorophosphoramidate group; and a phosphorodiamidate linkage to the ring nitrogen of a further morpholino compound or a morpholino oligomer. Such compounds include doubly protected morpholino guanine (MoG) monomers. Also described is their use in synthesis of morpholino oligomers.
    Type: Application
    Filed: November 14, 2008
    Publication date: May 21, 2009
    Applicant: AVI BIOPHARMA, INC.
    Inventors: MATTHEW DALE REEVES, DWIGHT D. WELLER
  • Patent number: 7511081
    Abstract: The present invention relates to a recycling method of a mixed waste of polyester and polyamide (hereinafter, referred to as “mixed waste”) in which polyesters including polyethylene terephthalate and polyamides are inseparable from one another. In accordance with the recycling method of the present invention, it is possible to prepare a solid block polymer having an acid value of 1 to 150 mgKOH/g, a weight average molecular weight of 3,000 to 50,000 and a softening point of 10 to 150° C., or a liquid polyester-amide block polymer composition having good compatibility, solubility and dispersibility. In addition, the polymer having an acid value of more than 20 mgKOH/g is reacted with a basic compound to form a neutralized salt which is then used to prepare a water-soluble polyester-amide block polymer composition.
    Type: Grant
    Filed: March 24, 2005
    Date of Patent: March 31, 2009
    Inventors: Do-Gyun Kim, Hyo-Sung Kim
  • Patent number: 7511113
    Abstract: An aromatic ether oligomer or polyaromatic ether comprising the formula: O—Arn; wherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula: formed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: March 31, 2009
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Dawn D. Dominguez
  • Patent number: 7507784
    Abstract: Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. They are highly processable by a variety of melt process shape forming and blending techniques. Once processed and shaped, the end-capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures.
    Type: Grant
    Filed: April 29, 2005
    Date of Patent: March 24, 2009
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Theodorus J. Dingemans, Erik S. Weiser, Terry L. St. Clair
  • Patent number: 7452959
    Abstract: An aromatic ether oligomer or polyaromatic ether comprising the formula: O—Arn; wherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula: formed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: November 18, 2008
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Dawn D. Dominguez
  • Publication number: 20080275206
    Abstract: Disclosed herein is a poly(carbonate-co-urea-co-ester) copolymer comprising incorporated urea compound, dihydroxy compound and diacid compound residues. Also disclosed herein is a poly(carbonate-co-urea) copolymer comprising incorporated urea compound and dihydroxy compound residues.
    Type: Application
    Filed: May 3, 2007
    Publication date: November 6, 2008
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Jan Henk Kamps, Edward Kung, Jan-Pleun Lens
  • Publication number: 20080269455
    Abstract: PROBLEMS The present invention relates to a process for producing a polybenzoxazole polymer and provides a process for producing the polybenzoxazole polymer within a short reaction time. MEANS FOR SOLVING PROBLEMS A process for producing a polybenzazole polymer comprises producing the polybenzazole polymer in a non-oxidizing dehydrating solvent while employing a compound represented by the following general formula (1) as a raw material including a first polymerization step in which polymerization is performed at a temperature of 150° C. or less and a latter polymerization step in which polymerization is performed at a temperature of 200° C.
    Type: Application
    Filed: September 11, 2006
    Publication date: October 30, 2008
    Applicant: Toyo Boseki Kabushiki Kaisha
    Inventors: Naoki Watanabe, Go Mastuoka, Fuyuhiko Kubota, Yukihiro Abe, Yasuko Mitooka
  • Publication number: 20080187567
    Abstract: Biocompatible, bioresorbable polymers comprising a plurality of monomeric repeating units containing an amide group, wherein said amide groups are N-substituted and the N-substituent and degree of N-substitution are effective to lower the melt viscosity, the solution viscosity, or both, compared to the same polymer without N-substitution.
    Type: Application
    Filed: October 17, 2007
    Publication date: August 7, 2008
    Inventors: Joachim B. Kohn, Durgadas Bolikal, Jaap Schut, Ernest G. Baluca
  • Publication number: 20080152690
    Abstract: Polymers with a hydrolytically labile polymer backbones with non-toxic biocompatible diphenolic repeating units having the structure: wherein R9 is an alkyl, aryl or alkylaryl group with up to 18 carbon atoms having a pendent carboxylic acid group or the benzyl ester thereof; and non-toxic biocompatible diphenolic repeating units having the structure: wherein R12 is an alkyl, aryl or alkylaryl group with up to 18 carbon atoms having a pendent carboxylic acid ester group selected from straight and branched alkyl and alkylaryl esters containing up to 18 carbon atoms and ester derivatives of biologically and pharmaceutically active compounds covalently bonded to the polymer, provided that said ester group is not a benzyl group or a group that is removed by hydrogenolysis. Implantable medical devices and treatment methods using the polymers are also disclosed.
    Type: Application
    Filed: March 11, 2008
    Publication date: June 26, 2008
    Applicant: Rutgers, The State University of New Jersey
    Inventors: Joachim B. Kohn, Durgadas Bolikal, Shuiyum Guan
  • Patent number: 7388035
    Abstract: A method for preparing poly(2,5-benzimidazole) whereby 3,4-diaminobenzoic acid is polymerized using a dehydrating reagent containing P2O5 and CX3SO3H where X is H or F. The poly(2,5-benzimidazole) has good proton conductivity and low methanol permeability, and therefore can be used as a polymer electrolyte membrane for a fuel cell.
    Type: Grant
    Filed: October 26, 2004
    Date of Patent: June 17, 2008
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Hyoung-Juhn Kim, Yeong-Chan Eun, Sung-Yong Cho, Ho-Jin Kweon
  • Patent number: 7348395
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: March 25, 2008
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M Keller, Matthew Laskoski
  • Patent number: 7307137
    Abstract: The present invention is directed to low dielectric polymers and to methods of producing these low dielectric constant polymers, dielectric materials and layers, and electronic components. In one aspect of the present invention, an isomeric mixture of thermosetting monomers, wherein the monomers have a core structure and a plurality of arms, is provided, and the isomeric mixture of thermosetting monomers is polymerized, wherein polymerization comprises a reaction of an ethynyl group that is located in at least one arm of a monomer.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: December 11, 2007
    Assignee: Honeywell International Inc.
    Inventors: Kreisler Lau, Feng Quan Liu, Paul Apen, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek, Roger Leung
  • Patent number: 7087707
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: August 8, 2006
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Matt Laskoski
  • Patent number: 7049386
    Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arlyene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: May 23, 2006
    Assignee: Honeywell International Inc.
    Inventors: Kreisler S. Lau, Feng Quan Liu, Boris A. Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Patent number: 6939940
    Abstract: Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and were end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The resulting reactive end-capped liquid crystal oligomers exhibit a variety of improved and preferred physical properties. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: September 6, 2005
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Theodorous J. Dingemans, Erik S. Weiser, Terry L. St. Clair
  • Patent number: 6803441
    Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: October 12, 2004
    Assignee: Honeywell International Inc.
    Inventors: Kreisler Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Patent number: 6767970
    Abstract: PPE copolymers comprise three repeating units. The PPE copolymers are polymerized with 2,6-DMP, dialkenylamide or dialkenylamine phenol, and another phenol derivative. A resin composition having a low cross-linking temperature is also disclosed, which comprises the PPE copolymer and a free radical initiator.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: July 27, 2004
    Assignee: Industrial Technology Research Institute
    Inventors: Shin-Shin Wang, Jie-Hwa Ma, Jong-Lieh Yang, Kuo-Yuan Hsu, Li-Chung Liang
  • Patent number: 6762277
    Abstract: A method of manufacturing a new N-carboxyamino acid anhydride and polyamino acid using a simple process operation. The method for manufacturing N-carboxyamino acid anhydride comprising reacting &agr;-amino acid with di-tert-butyltricarbonate. The method for manufacturing polyamino acid comprising decarboxylating the N-carboxyamino acid anhydride obtained by reacting &agr;-amino acid with di-tert-butyltricarbonate.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: July 13, 2004
    Assignee: JSR Corporation
    Inventors: Hiroto Kudoh, Takeshi Endoh
  • Patent number: 6756470
    Abstract: An aromatic ether oligomer or polyaromatic ether comprising the formula: wherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula: formed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: June 29, 2004
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Dawn D. Dominguez
  • Patent number: 6590022
    Abstract: A method is provided for producing protective colloid-stabilized vinyl aromatic-1.3-diene-copolymers in the form of their aqueous polymer dispersions or in the form of a powder which can be re-dispersed in water, by emulsion-polymerizing a mixture containing at least one vinyl aromatic and at least one 1,3-diene in the presence of a protective colloid and optionally, drying the resulting polymer dispersions. In the method part of the protective colloid is provided straightaway and part is metered.
    Type: Grant
    Filed: May 21, 2000
    Date of Patent: July 8, 2003
    Assignee: Wacker-Chemie GmbH
    Inventors: Thomas Bastelberger, Reinhard Haerzschel, Theo Mayer, Peter Weitzel, Peter Ball
  • Publication number: 20020188095
    Abstract: A method of manufacturing a new N-carboxyamino acid anhydride and polyamino acid using a simple process operation.
    Type: Application
    Filed: April 26, 2002
    Publication date: December 12, 2002
    Applicant: JSR CORPORATION
    Inventors: Hiroto Kudoh, Takeshi Endoh
  • Patent number: 6482915
    Abstract: The invention provides a method for producing a thermotropic liquid crystalline polymer of high quality at high yield and in short polymerization time, which method includes polymerizing staring monomers I, II, III, and IV, i.e., (I) an aromatic hydroxycarboxylic acid, etc.; (II) an aromatic dicarboxylic acid and an alicyclic dicarboxylic acid; (III) an aromatic diol, an alicyclic diol, an aliphatic diol, etc.; and (IV) an aromatic hydroxylamine, an aromatic diamine, etc. in the presence of an acylating agent, wherein the starting materials are charged so as to satisfy the following equations (1) to (4): 0.0015≦((A)−(B))/((A)+(B))≦0.006  (1); 1.01≦(D)/(C)≦1.08  (2); 0≦(E)≦40  (3); and (D)/(C)≧−0.002 ×(E)+1.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: November 19, 2002
    Assignee: Polyplastics Co., Ltd.
    Inventor: Toshiaki Yokota
  • Patent number: 6469123
    Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: October 22, 2002
    Assignee: Honeywell International Inc.
    Inventors: Kreisler S. Lau, Feng Quan Liu, Boris A. Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Publication number: 20020151668
    Abstract: A multi-dimensional copolymer array of a plurality of copolymers, polymerized from at least two independently variable sets of monomers, wherein the polymerization is characterized by:
    Type: Application
    Filed: April 13, 1999
    Publication date: October 17, 2002
    Inventors: KEN JAMES, BROCCHINI STEPHEN, VARAWUT TANGPASUTHADOL, JOACHIM KOHN
  • Patent number: 6388045
    Abstract: Provided is a liquid crystalline polymer which is obtained by copolymerizing at least one polyfunctional aromatic monomer selected from the group consisting of the compounds represented by the formulae (I), (II) and (III) below with at least one polymerizable monomer. The liquid crystalline polymer of the present invention is excellent in heat resistance, molding properties, flow properties and mechanical properties, especially it provide molded article with improved weld strength.
    Type: Grant
    Filed: January 8, 2001
    Date of Patent: May 14, 2002
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kiichi Kometani, Taihei Hamasaki, Motoki Asahara
  • Patent number: 6177182
    Abstract: Provided herein are novel polymeric coating materials for direct digital imaging by laser. More specifically the novel coating materials are thermally reactive near infrared absorption polymers designed for use with near infrared laser imaging devices. This invention further extends to the preparation and methods of use of the novel materials. The invention is particularly useful in the preparation of lithographic printing plates for computer-to-plate and digital-offset-press technologies. The invention extends to photoresist applications, to rapid prototyping of printed circuit boards and to chemical sensor development.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: January 23, 2001
    Assignee: American Dye Source, Inc.
    Inventor: My T. Nguyen
  • Patent number: 6124425
    Abstract: Provided herein are novel polymeric coating materials for direct digital imaging by laser. More specifically the novel coating materials are thermally reactive near infrared absorption polymers designed for use with near infrared laser imaging devices. This invention further extends to the preparation and methods of use of the novel materials. The invention is particularly useful in the preparation of lithographic printing plates for computer-to-plate and digital-offset-press technologies. The invention extends to photoresist applications, to rapid prototyping of printed circuit boards and to chemical sensor development.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: September 26, 2000
    Assignee: American Dye Source, Inc.
    Inventor: My T. Nguyen
  • Patent number: 6001926
    Abstract: A fiber-reinforced phthalonitrile composite is made by impregnating or coating a fibrous material with a phthalonitrile prepolymer mixture containing a phthalonitrile monomer and an aromatic amine curing agent that is thermally stable and nonvolatile at a temperature up to about 375.degree. C., and that contains at least one electron withdrawing substituent effective to reduce the reactivity of the aromatic amine curing agent with the phthalonitrile monomer.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: December 14, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Satya B. Sastri, Teddy M. Keller
  • Patent number: 5973072
    Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
  • Patent number: 5948881
    Abstract: Curative compositions of amine terminated polyamide resins blended with a deaminated bis-(p-aminocyclohexyl)methane composition (DeAms) are useful for curing adhesive epoxy resin compositions. The polyamides comprise combinations of fatty mono-acids, dimer acids, polyethyleneamines, and piperazine ring containing polyamines which are piperazine or N-aminoalkylpiperazine, where the alkyl chain is a C2 to C6 alkyl chain, wherein the ratio of equivalents of fatty mono-acid to dimer acid can range from about 0.001:1 to about 1:1, the ratio of moles of piperazine ring containing polyamine to polyethylene amine can range from about 0.1:1 to about 1:1, and the ratio of moles of polyamine to equivalents of acid can range from about 0.6:1 to about 1.2:1. DeAms is blended at 2 to 40 wt % based on polyamide. Adhesive compositions comprising these curatives are also disclosed.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: September 7, 1999
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Dilipkumar Nandlal Shah, William Edward Starner
  • Patent number: 5922807
    Abstract: A fiber-reinforced phthalonitrile composite is made by impregnating or coating a fibrous material with a phthalonitrile prepolymer mixture containing a phthalonitrile monomer and an aromatic amine curing agent that is thermally stable and nonvolatile at a temperature up to about 375.degree. C., and that contains at least one electron withdrawing substituent effective to reduce the reactivity of the aromatic amine curing agent with the phthalonitrile monomer.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: July 13, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Satya B. Sastri, Teddy M. Keller
  • Patent number: 5919890
    Abstract: A method for producing polybenzazole, which comprises reacting a PBZ monomer salt with an AA-PBZ monomer or a BB-PBZ monomer in a non-oxidizing solvent having a dehydrating action to give an oligomer, and adding the AA-PBZ monomer or BB-PBZ monomer, which has not been subjected to the above reaction, to allow reaction with the oligomer, whereby to give a polymer having a desired polymerization degree. According to this method, the polymerization degree of the polymer to be obtained finally and of the polymer during production process can be easily controlled.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: July 6, 1999
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Kiyoshi Hotta, Fuyuhiko Kubota, Yoshio Araki, Masakatsu Ohguchi
  • Patent number: 5886130
    Abstract: A new class of polyarylene co-polymers include repeating units comprising one or more arylene units having the general formula (--Ar--/--Y--).sub.n, where Y is a divalent group chosen from nil, --Z--, --Z--Ph--, and --Ph--Z--Ph--, where Z is a divalent group chosen from the group consisting of --O--, --S--, --NR--, --O(CO)--, --O(CO.sub.2)--,--(CO)NH(CO)--, --NR(CO)--, phthalimide, pyromellitimide, --CO--, --SO--, --SO.sub.2 --, --P(O)R--, --CH.sub.2 --, --CF.sub.2 --, and --CRR'--; Ph is phenylene (ortho, meta or para); and n is greater than 4. The co-polymers are useful as molding resins, and composite matrix resins, and where Ar is heteroarylene as ion exchange resins.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: March 23, 1999
    Assignee: Maxdem Incorporated
    Inventors: Mark S. Trimmer, Ying Wang, Matthew L. Marrocco III, Virgil J. Lee
  • Patent number: 5852155
    Abstract: Disclosed are polyesteramide resin compositions having amide units of formula (I): ##STR1## and the units of the formula (II): ##STR2## wherein the polyesteramide is substantially devoid of units derived from butane diol. The ratio of (I) to (II) in the polyesteramide is preferably less than 1:3. Preferred polyesteramides have at least 80% of units of formula (I) separated by at least one of the units of formula (II).
    Type: Grant
    Filed: March 1, 1995
    Date of Patent: December 22, 1998
    Assignee: General Electric Company
    Inventors: Jan Bussink, Reinoud Jaap Gaymans, Johannes Hubertus G. M. Lohmeijer, Ilias Nicholas Mamalis, Gary F. Smith, Antoinette Cornelia Maria van Bennekom
  • Patent number: 5807969
    Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid derivative with the following structure:M--CO--R*--CO--Mwhere M stands for the residue of an (optionally substituted) 2-hydroxybenzoxazole, 2-hydroxybenzothiazole, or 1-hydroxybenzotriazole or of corresponding mercapto compounds and R* is the parent body of the dicarboxylic acid.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: September 15, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne, Eberhard Kuehn, Roland Gestigkeit
  • Patent number: 5807972
    Abstract: The invention is directed to a hydrolytically polymerized polycaprolactam with new chain regulation, whereby the polymerization of caprolactam (I) is carried out with 0.1-0.7 weight percent of an aromatic dicarboxylic acid (II), 0.01-0.7 weight percent of an aliphatic or cycloaliphatic diamine (III) that carries a primary and a tertiary amino group, and/or 0.01-0.7 weight percent 4-amino-2,2,6,6-tetraalkyl piperidine (IV), whereby the quantities of constituents I through IV add up to 100 weight percent and the quantity of the constituents III and/or IV amounts to 0.01-0.7 weight percent.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: September 15, 1998
    Inventors: Hanns-Jorg Liedloff, Ernst Morf, Gerhard Schmidt
  • Patent number: 5783654
    Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid ester with the following structure:G--O--CO--R*--CO--O--G,where G is an (optionally substituted) succinimide or maleinimide group and R* is the parent body of the dicarboxylic acid.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: July 21, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne
  • Patent number: 5750711
    Abstract: The dicarboxylic acid derivatives according to the invention have the following structure ##STR1## wherein X denotes O, S, (CF.sub.2).sub.m, C(CF.sub.3).sub.2 or CF.sub.2 --CF(CF.sub.3) (m=1 to 10), and R stems from the following compounds: fluoro- or trifluoromethyl- and nitro- or cyanophenols, thiophenols or -aminobenzenes, 4-hydroxy-, 4-mercapto- or 4-aminocoumarins, N-hydroxysuccinimides or N-hydroxymaleimides, 2-hydroxy- or 2-mercaptobenzoxazoles or -benzothiazoles and 1-hydroxy- or 1-mercaptobenzotriazoles.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: May 12, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Racai Sezi, Hellmut Ahne, Eberhard Kuehn
  • Patent number: 5750638
    Abstract: A method for producing poly-o-hydroxy amides by heating a dicarboxylic acid to a temperature .gtoreq.80.degree. C., together with a sulfonic acid chloride and a tertiary amine in a suitable solvent, to form a reaction mixture and reacting the mixture obtained with a bis-o-aminophenol solution at a temperature <80.degree. C.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: May 12, 1998
    Assignee: Siemens Aktiengesesllschaft
    Inventors: Recai Sezi, Hellmut Ahne, Roland Gestigkeit
  • Patent number: 5747175
    Abstract: Liquid-crystalline polymer blends comprising two or more cholesteric liquid-crystalline polymers or at least one nematic liquid-crystalline polymer and at least one cholesteric liquid-crystalline polymer.All hues can be produced specifically and in a reproducible manner by variation in the blend components and in the mixing ratio. The polymer blends are suitable as materials or as effect pigments.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: May 5, 1998
    Inventors: Erwin Dietz, Axel Schonfeld