Nonaldehyde Or Nonaldehyde Derivative Heterocyclic Compound Contains An Oxygen Atom As A Ring Member Of The Heterocyclic Compound Patents (Class 528/249)
  • Patent number: 10961384
    Abstract: Poly-1,3-dioxepane, poly-1,3-dioxolane, polytetrahydrofurane or mixtures thereof are used in molding materials comprising polyoxymethylene or a copolymer containing a majority of oxymethylene units, for improving the flexural toughness of moldings formed from the molding materials.
    Type: Grant
    Filed: May 20, 2015
    Date of Patent: March 30, 2021
    Assignee: BASF SE
    Inventors: Bernd-Steffen Von Bernstorff, Marie-Claire Hermant, Martin Blömacher
  • Patent number: 10035882
    Abstract: Hexahydrotriazine (HT) materials and hemiaminal (HA) materials derived from aromatic, aliphatic, and/or polyether diamines may be used as a platform for creating flame retardant materials. Various flame retardant material precursors may be incorporated into the HA and HT materials. Examples of flame retardant precursors may include organohalogen materials, organophosphorous materials, melamines, and dianiline compounds, among others. The flame retardant materials and precursors may be single molecule species, oligomers, and/or polymers (i.e., polyhexahydrotriazine, PHT, polyhemiaminal, PHA). The flame retardant materials may be made using an aromatic diamine, an aliphatic diamine, a polyether diamine, or a mixture thereof to react with an aldehyde (i.e. formaldehyde or paraformaldehyde). Such flame retardant material precursors will complex with the diamine monomers via a copolymerization reaction to form the flame retardant materials.
    Type: Grant
    Filed: August 24, 2016
    Date of Patent: July 31, 2018
    Assignee: International Business Machines Corporation
    Inventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Rudy J. Wojtecki
  • Patent number: 9487602
    Abstract: The present invention relates to the polymeric reaction product of compounds according to Formula (I) and Formulae (II) or (III). Formula (I) has the following structure: where R1, R2, R3 and R4 are independently H, OH, optionally substituted C1-12alkyl, optionally substituted C1-12alkenyl, C1-12aldehyde, C3-12acetals, C2-12 ether, and/or C2-12 ester; where optionally at least one of R1, R2, R3 and R4 is H. Formulae (II) and (III) have the following structure: where X is H or C1-4alkyl; Y is OH or OR5 where R5 is C1-12alkyl, C3-12aryl, C4-12aralkyl or C3-12cycloalkyl; and Z is an electron-withdrawing group.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: November 8, 2016
    Assignee: DSM IP ASSETS B.V.
    Inventors: Rudolfus Antonius Theodorus Maria Van Benthem, Stijn Witters
  • Patent number: 9453108
    Abstract: Hexahydrotriazine (HT) materials and hemiaminal (HA) materials derived from aromatic, aliphatic, and/or polyether diamines may be used as a platform for creating flame retardant materials. Various flame retardant material precursors may be incorporated into the HA and HT materials. Examples of flame retardant precursors may include organohalogen materials, organophosphorous materials, malamines, and dianiline compounds, among others. The flame retardant materials and precursors may be single molecule species, oligomers, and/or polymers (i.e., polyhexahydrotriazine, PHT, polyhemiaminal, PHA). The flame retardant materials may be made using an aromatic diamine, an aliphatic diamine, a polyether diamine, or a mixture thereof to react with an aldehyde (i.e. formaldehyde or paraformaldehyde). Such flame retardant material precursors will complex with the diamine monomers via a copolymerization reaction to form the flame retardant materials.
    Type: Grant
    Filed: August 22, 2014
    Date of Patent: September 27, 2016
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Rudy J. Wojtecki
  • Patent number: 9388269
    Abstract: Amino-formaldehyde resins, articles of manufacture from the amino-formaldehyde resins, and processes for making the resins and articles are provided herein. In one embodiment, the amino-formaldehyde resins may be prepared using a reaction mixture including formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof. In another embodiment, the amino-formaldehyde resins are produced by reacting formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof, and the monohydroxy cyclic compound may be added as a front addition, an intermediate addition, a back addition, or a combination thereof, to the reaction mixture of formaldehyde and the at least one amino compound.
    Type: Grant
    Filed: March 10, 2014
    Date of Patent: July 12, 2016
    Assignee: HEXION INC.
    Inventors: Valter E. Lessmann, Gilberto E. Saboia, Cicero L. da Silva, Edielma D. Chipanski, David M. Harmon, Rajamani Nagarajan
  • Publication number: 20140322309
    Abstract: ?-Aminoamidine polymers and methods of preparing a-aminoamidine polymers by reacting by reacting one or more amines with one or more isocyanides and one or more aldehydes are described. Methods of preparing a-aminoamidine polymers from commercially available starting materials are also provided, wherein the starting materials are racemic or stereochemically pure. a-Aminoamidine polymers or salt forms thereof are preferably biodegradable and biocompatible and may be used in a variety of drug delivery systems and for other purposes as well such as, for example, coatings, additives, excipients, plastics, and materials, etc. Given the amino moiety of these ?-aminoamidine polymers, they are particularly suited for the delivery of polynucleotides. Complexes, micelles, liposomes or particles containing the inventive ?-aminoamidine polymers and polynucleotides can be prepared. The inventive ?-aminoamidine polymers may also be used in preparing microparticles for drug delivery.
    Type: Application
    Filed: December 15, 2012
    Publication date: October 30, 2014
    Applicant: Massachusetts Institute of Technolo
    Inventors: Arturo Jose Vegas, Kathryn Ann Whitehead, Daniel Griffith Anderson, Robert S. Langer, Joseph R. Dorkin
  • Publication number: 20140275353
    Abstract: Amino-formaldehyde resins, articles of manufacture from the amino-formaldehyde resins, and processes for making the resins and articles are provided herein. In one embodiment, the amino-formaldehyde resins may be prepared using a reaction mixture including formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof. In another embodiment, the amino-formaldehyde resins are produced by reacting formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof, and the monohydroxy cyclic compound may be added as a front addition, an intermediate addition, a back addition, or a combination thereof, to the reaction mixture of formaldehyde and the at least one amino compound.
    Type: Application
    Filed: March 10, 2014
    Publication date: September 18, 2014
    Applicant: Momentive Specialty Chemicals Inc.
    Inventors: Valter E. Lessman, Gilberto E. Saboia, Cícero L. da Silva, Edielma D. Chipanski, David M. Harmon, Rajamani Nagarajan
  • Publication number: 20140048740
    Abstract: The present invention relates primarily to a mixture that is suitable for use in the no-bake process for producing cores and moulds for the foundry industry, and a reaction mixture comprising said mixture and an acid hardener (i.e. an acid catalyst). The present invention further relates to a method of producing a mixture according to the invention and a method of producing a mould or a core. The invention also relates to a mould or a core for producing metal objects and a kit comprising a mixture according to the invention and certain acid hardeners. The invention further relates to the use of a mixture according to the invention as cold-setting binder and the use of said mixtures or reaction mixtures in a no-bake process for producing metal objects.
    Type: Application
    Filed: December 16, 2011
    Publication date: February 20, 2014
    Applicant: HUETTENES-ALBERTUS CHEMISCHE WERKE GMBH
    Inventors: Christian Fourberg, Gérard Ladégourdie, Norbert Benz, Eckard Piech
  • Patent number: 8378144
    Abstract: A process for preparing polyoxymethylene homopolymers or copolymers (7) by homopolymerization or copolymerization of trioxane, starting from methanol (1), in which methanol (1) is oxidized in a first reactor in a first production plant (A) to give an aqueous formaldehyde-comprising stream (2) which is fed to a second production plant (B) in which pure trioxane (6) is obtained and removal of low boilers (5) by distillation is carried out and the pure trioxane (6) is fed to a third production plant (C) in which it is homopolymerized or copolymerized to form polyoxymethylene homopolymers or copolymers (7), wherein the low boiler stream (5) from the low boiler removal column (K 2) is recycled to the feed stream into the first reactor in the first production plant (A), is proposed.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: February 19, 2013
    Assignee: BASF SE
    Inventors: Markus Siegert, Tobias Kortekamp, Eckhard Stroefer, Christoph Sigwart, Neven Lang
  • Publication number: 20120123085
    Abstract: Alcohols are catalytically oxidized to aldehydes, in particular to benzaldehyde and diformylfuran, which are useful as intermediates for a multiplicity of purposes. The invention also relates to the polymerization of the dialdehyde and to the decarbonylation of the dialdehyde to furan.
    Type: Application
    Filed: January 25, 2012
    Publication date: May 17, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Vladimir Grushin, Walter Partenheimer, Leo E. Manzer
  • Publication number: 20110184089
    Abstract: The invention relates to a process for extruding plastic compositions, in particular polymer melts and mixtures of polymer melts, above all thermoplastics and elastomers, particularly preferably polycarbonate and polycarbonate blends, also with the incorporation of other substances such as for example solids, liquids, gases or other polymers or other polymer blends with improved optical characteristics, with the assistance of a multi-screw extruder with specific screw geometries.
    Type: Application
    Filed: June 12, 2009
    Publication date: July 28, 2011
    Applicant: Bayer MaterialScience AG
    Inventors: Michael Bierdel, Thomas König, Carsten Conzen, Ulrich Liesenfelder, Klemens Kohlgrüber, Reiner Rudolf, Johann Rechner
  • Publication number: 20110021740
    Abstract: The present invention relates to the polymeric reaction product of compounds according to Formula (I) and Formula (II) or (III). Formula (I) has the following structure: where R1, R2, R3 and R4 are independently H, OH, optionally substituted C1-12alkyl, optionally substituted C1-12alkenyl, C1-12aldehyde, C3-12acetals, C2-12 ether, and/or C2-12 ester; where optionally at least one of R1, R2, R3 and R4 is H. Formulae (II) and (III) have the following structure: where X is H or C1-4alkyl; Y is OH or OR5 where R5 is C1-12alkyl, C3-12aryl, C4-12aralkyl or C3-12cycloalkyl; and Z is an electron-withdrawing group.
    Type: Application
    Filed: December 18, 2008
    Publication date: January 27, 2011
    Inventors: Rudolfus Antonius Theodorus Maria Van Benthem, Stijn Witters
  • Publication number: 20080234459
    Abstract: A process for preparing polyoxymethylene homopolymers or copolymers by homopolymerization or copolymerization of trioxane or additionally of suitable comonomers, in which trioxane which still comprises residual monomers is firstly prepared in a monomer plant and is degassed in one or more stages to give one or more vapor streams (13, 14) which are, if appropriate, fed to a condenser (K) in which the condensable fractions of these vapor streams are condensed to give a condensate (15) which is recycled to the polymerization reactor (P) and one or more gaseous, formaldehyde-comprising streams (16) and also a partially degassed polyoxymethylene homopolymer or copolymer (17) which is fed to an extruder (E) or kneader and is mixed with customary additives and processing aids in this to give a polymer melt (19) and extraction of a formaldehyde-comprising extruder or kneader offgas (18) from the extruder (E) or kneader, wherein the formaldehyde-comprising secondary streams (14, 16, 18) from the polymer plant are r
    Type: Application
    Filed: August 25, 2006
    Publication date: September 25, 2008
    Applicant: BASF SE
    Inventors: Neven Lang, Knut Zollner, Achim Stammer, Elmar Stockelmann
  • Patent number: 7348128
    Abstract: A photosensitive resin which exhibits excellent storage stability, affinity, miscibility, or solubility with respect to a variety of compounds, and high sensitivity can be solidified even under hydrous conditions as well as exhibiting high cure-related sensitivity and high flexibility and being uniformly solidified even under highly hydrous conditions, a photosensitive resin composition containing the resin, and a novel compound. The photosensitive resin is a saponified poly(vinyl acetate)-based photosensitive resin having a structural unit represented by formula (1): (wherein R1 represents H or Me; R2 represents a linear or branched C2-C10 alkylene group; n is an integer of 1 to 3; X represents m is an integer of 0 to 6; and Y represents an aromatic ring or a single bond).
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: March 25, 2008
    Assignee: Toyo Gosei Co., Ltd.
    Inventors: Seigo Yamada, Masahiro Takano, Mitsuharu Miyazaki, Shin Utsunomiya
  • Patent number: 7087683
    Abstract: A crosslinking agent that is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin such that the crosslinking agent is essentially free of functional groups reactive with an aminoplast resin and has a glass transition temperature of at least 10° C. is disclosed. Compound (b) is, more specifically, a monofunctional sulfonamide having only one active hydrogen. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating compositions and substrates coated therewith are also disclosed. Methods for modifying aminoplasts are also disclosed.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: August 8, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shengkui Hu, Anthony M. Chasser, William H. Retsch, Ronald R. Ambrose
  • Patent number: 7030207
    Abstract: The invention is to provide a polymer, having a high affinity to water, is liquid in spite of being a polymer, simultaneously possesses also a thermal stability and is suitably used as a heating medium or a lubricant. It is the polyacetal (co)polymer, being liquid at room temperature, prepared by copolymerizing (A) 75 to 100 mol % of 1,3-dioxolane and (B) 25 to 0 mol % of trioxane and having the total amount of terminal groups of 15 to 300 mmol/kg and an amount of a hemiformal terminal group of 80 mmol/kg or less.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: April 18, 2006
    Assignee: Polyplastics Co., Ltd.
    Inventors: Yoshihisa Tajima, Hiroaki Nakao, Kuniaki Kawaguchi
  • Patent number: 7022805
    Abstract: The present invention relates to a process for the preparation of acetal polymers, in particular of polyoxymethylene (POM) by cationic polymerization where organophosphonic and/or organophosphinic acids and/or their derivatives and/or their precursors are used as the initiator.
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: April 4, 2006
    Assignee: Ticona GmbH
    Inventors: Michael Haubs, Stanislaw Penczek
  • Patent number: 7001959
    Abstract: Copolymers are described containing blocks of the structural repeat units of the formula I and blocks containing structural units of the formula II [—O—CH2—]x,??(I) [—O—R1—],??(II) where R1 is a divalent radical derived from a hydroxy-terminated aliphatic or cycloaliphatic oligomer or polymer which, where appropriate, has ether groups and/or carbonyloxy groups in the chain, and x is a whole number, at least 10. The copolymers may be used for producing moldings.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: February 21, 2006
    Assignee: Ticona GmbH
    Inventors: Karl-Friedrich Mück, Klaus Kurz, Michael Hoffmockel
  • Patent number: 6809161
    Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: October 26, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
  • Patent number: 6635724
    Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: October 21, 2003
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
  • Publication number: 20020161135
    Abstract: The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.
    Type: Application
    Filed: August 22, 2001
    Publication date: October 31, 2002
    Inventors: Keimpe Jan van den Berg, Klaus Hobel, Huig Klinkenberg, Arie Noomen, Josephus Christiaan van Oorschot
  • Patent number: 6426393
    Abstract: To provide polyacetal which has excellent shock resistance, rigidity and creep resistance as essential properties of the polymer and makes a high flowability and an excellent molding property upon molding possible by improving the thermal stability. In the manufacture of a polyacetal copolymer by a copolymerization of 100 parts by weight of trioxane (a) with 0.05-20 parts by weight of a cyclic ether compound (b) which is copolymerizable with trioxane and 0.001-10 parts by weight of a mono-functional glycidyl compound (c), the mono-functional glycidyl compound (c) having a chlorine content of not more than 0.3% by weight is used.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: July 30, 2002
    Assignee: Polyplastics Co., Ltd.
    Inventors: Yoshihisa Tajima, Hidetoshi Okawa
  • Patent number: 6365704
    Abstract: To provide a resin material in which various properties of a polyacetal resin such as excellent appearance, slidability and thermal stability are maintained and a rigidity is improved as well. That is, a polyacetal copolymer which is prepared by a copolymerization of 100 parts by weight of trioxane (A), 0.0005 to 2 parts by weight of the component (B), which is a compound (B-1) having at least three glycidyl groups in the molecule or a compound (B-2) having at least two epoxy groups in the molecule, and 0 to 20 parts by weight of a cyclic ether compound (C) copolymerizable with trioxane, and which has a total terminal group amount of 15 to 150 mmol/kg, when (B) is (B-2).
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: April 2, 2002
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hidetoshi Okawa, Kaoru Yamamoto
  • Patent number: 6297329
    Abstract: The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: October 2, 2001
    Assignee: Akzo Nobel NV
    Inventors: Keimpe Jan van den Berg, Klaus Hobel, Huig Klinkenberg, Arie Noomen, Josephus Christiaan van Oorschot
  • Patent number: 6255440
    Abstract: Polyacetal copolymers, obtained by copolymerizing (A) 100 parts by weight of trioxane, (B) 0.01 to 10 part(s) by weight of at least one compound selected from among glycidyl ether compounds of the following general formula (I), (II) or (III) and (C) 0 to 20 part(s) by weight of a cyclic ether compound [excluding the glydicyl ether compound (B)] copolymerizable with trioxane, are a polyacetal resin having a high rigidity, excellent creep properties, a high surface hardness and excellent sliding properties: wherein R1 is a C1-12 alkyl group, an aryl group or a substtituted aryl group; wherein R2 represents a C2-20 polyalkylene oxide glycol residue; wherein R4 represents an alkyl group having 1 to 30 carbon atoms; R5 represents an alkylene group having 1 to 30 carbon atoms.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: July 3, 2001
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hidetoshi Okawa, Yoshihisa Tajima
  • Patent number: 6037439
    Abstract: To provide a process for stable and continuous production of a polyacetal resin, mainly comprising a copolymer of 1,3-dioxolane and trioxane under the presence of a catalyst, in a high yield on an industrial scale for a long period of time. In the continuous production of a polyacetal resin by mixing 1,3-dioxolane with boron trifluoride and/or a coordination compound of boron trifluoride and then, mixing the obtained mixture with trioxane to conduct bulk polymerization in a polymerization machine, 1,3-dioxolane is brought into contact with boron trifluoride and/or a coordination compound of boron trifluoride while feeding both at the same direction and they are mixed together for 0.1 to 30 seconds under the condition of at least 0.1 m/sec of the linear velocity of the mixture and subsequently mixed with trioxane.
    Type: Grant
    Filed: August 10, 1998
    Date of Patent: March 14, 2000
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hajime Serizawa, Kaoru Yamamoto, Kuniaki Kawaguchi, Yuichi Fukui, Tsugio Tenda
  • Patent number: 5994455
    Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: November 30, 1999
    Assignee: Ticonna GmbH
    Inventors: Karl-Friedrich Muck, Horst Roschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood
  • Patent number: 5962623
    Abstract: A continuous process for the preparation of polyacetal copolymers from 1,3,5-trioxane and the comonomers known for this purpose using strong protic acids as an initiator, in which the initiator is added in an amount of 0.01 to 0.6 ppm, based on the total amount of monomers, in finely divided form to the monomer mixture, after the polymerization step the crude polymer is transferred from the polymerization reactor to a mixing unit without further intermediate steps, excess monomer is removed from the crude polymer in the mixing unit or between polymerization reactor and mixing unit by applying reduced pressure and, if desired, generally customary stabilizers, assistants, fillers, reinforcing materials and/or colorants are incorporated into the polymer in the mixing unit.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: October 5, 1999
    Assignee: Ticona GmbH
    Inventors: Peter Eckardt, Michael Hoffmockel, Karl-Friedrich Muck, Gerhard Reuschel, Satyajit Verma, Michael G. Yearwood
  • Patent number: 5942595
    Abstract: Disclosed is a process for copolymerization of formaldehyde with cyclic ethers in the presence of organic nitro compounds. The process enhances the selectivity for the cyclic copolymer.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: August 24, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Douglas John Adelman, Richard Beckerbauer
  • Patent number: 5929195
    Abstract: A branched or crosslinked polyacetal resin is excellent in blow moldability, has impact resistances such as plane impact resistance, and the smoothness of the inner surfaces of moldings produced therefrom, and is suitable for molding, particularly blow molding. It can be produced by the bulk polymerization of (A) trioxane with (B) a cyclic ether and/or cyclic formal and (C) a polyfunctional glycidyl ether compound in the presence of (D) a cationic polymerization catalyst, a mixture prepared by mixing the cyclic ether and/or cyclic formal (B) with the polyfunctional glycidyl ether compound (C) and the cationic polymerization catalyst (D) is added to trioxane (A) to conduct the polymerization.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: July 27, 1999
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kuniaki Kawaguchi, Kaoru Yamamoto, Hajime Serizawa
  • Patent number: 5886110
    Abstract: Branched, dendrimeric macromolecules having a central nucleus and a series of polyoxaalkylene chains that radiate from the nucleus and spread into the surrounding space branching a cascade fashion until the desired size results. Molecules formed in this manner are free of excessive functional crowding on their outer surfaces. Synthetic methods of preparing these molecules and their uses are described.
    Type: Grant
    Filed: April 30, 1998
    Date of Patent: March 23, 1999
    Assignee: Dibra S.p.A.
    Inventors: Luigia Gozzini, Monica Muttoni, Christoph De Haen
  • Patent number: 5874179
    Abstract: The invention relates to nitrogen-containing polymers containing structural units of formula (I), ##STR1## where the symbols and indices have the following meanings: Ar.sup.1, Ar.sup.2, Ar.sup.3 are, identically or differently, mono- and/or polynuclear and/or condensed aryl and/or heteroaryl groups which may or may not be linked via one or more bridges carbon atoms, which may or may not be substituted;X is a single bond, --O--, --S--, --SO--, --SO.sub.2, NR.sup.3, --CR.sup.4 R.sup.5 --, --CO--, --CR.sup.6 .dbd.CR.sup.7, CR.sup.8 R.sup.9 --CR.sup.10 R.sup.11 or SiR.sup.12 R.sup.13 ;R.sup.1 -R.sup.13 are, identically or differently, H, a hydrocarbon radical having from 1 to 22 carbon atoms or Ar.sup.4, where Ar.sup.4, identical with or different from Ar.sup.1, has the same meanings as Ar.sup.1 ;n=1, 2 or 3.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: February 23, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Willi Kreuder, Hans-Heinrich Horhold, Henning Rost
  • Patent number: 5849858
    Abstract: Furfuryl alcohol/formaldehyde resins exhibiting high water compatibility and low amounts of volatile organic compounds such as furfuryl alcohol.
    Type: Grant
    Filed: April 2, 1998
    Date of Patent: December 15, 1998
    Assignee: QO Chemicals, Inc.
    Inventors: George S. Everett, George R. MacLennan, Michael C. Chen
  • Patent number: 5830978
    Abstract: A resin composition useful as a binder is provided comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is then reacted with a polyol.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: November 3, 1998
    Assignee: Sequa Chemicals, Inc.
    Inventor: William C. Floyd
  • Patent number: 5756594
    Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
  • Patent number: 5728798
    Abstract: In preparing a polyacetal copolymer through copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-carbon bond as the comonomer, 0.05 to 100 ppm (on the weight basis), based on the total amount of the monomers, of a heteropoly-acid or an acidic salt thereof is used as a polymerization catalyst, and a liquid mixture preliminarily prepared by mixing at least part or the whole of the comonomer with the polymerization catalyst is added to trioxane to effect copolymerization. According to such the process, the polymerization yield and the degree of polymerization (molecular weight) are enhanced, and a polyacetal copolymer having an improved stability can be obtained.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: March 17, 1998
    Assignee: Polyplastics Co., Ltd.
    Inventors: Akira Nakai, Kaoru Yamamoto
  • Patent number: 5691426
    Abstract: A resin composition useful as a binder is provided comprising a mixture of a formaldehyde-based resin with a resin substitute comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with 1 to 2 moles of a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is mixed, preferably reacted, with a polyol.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: November 25, 1997
    Assignee: Sequa Chemicals, Inc.
    Inventor: William Floyd
  • Patent number: 5629373
    Abstract: A coating composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 13, 1997
    Assignee: United Catalysts, Inc.
    Inventors: Charles W. Glancy, Alan L. Steinmetz
  • Patent number: 5627232
    Abstract: A water-containing composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 6, 1997
    Assignee: United Catalysts, Inc.
    Inventors: Charles W. Glancy, Alan L. Steinmetz
  • Patent number: 5607986
    Abstract: This invention relates to nitrogen free heat cured foundry mixes essentially free of free formaldehyde comprising (a) a nitrogen free modified furan resin, (b) furfuryl alcohol, (c) polyvinyl acetate, preferably(d) a tar selected from the group consisting of resorcinol pitch, bisphenol A tar, and (e) a latent acid curing catalyst. The foundry mixes are used to prepare foundry shapes. They are cured in the presence of the latent acid curing catalyst by heating at an elevated temperature.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: March 4, 1997
    Assignee: Ashland Inc.
    Inventors: Young D. Kim, deceased, A. Leonard Haugse
  • Patent number: 5587449
    Abstract: In the process for the preparation, with simultaneous end group stabilization, of polyacetal copolymers in a homogeneous phase and working up thereof, cyclic formaldehyde oligomers are copolymerized with cyclic acetals in the presence of an initiator in a polymerization reactor and immediately thereafter the initiator is deactivated by addition of basic substances, the unstable chain ends being degraded down to 0.01% to 1% in the presence of residual monomer, the product losing the majority of the residual monomer at the reactor outlet by letting down into a pelletizing device and the residual monomer which remains and the impurities dissolved in the product being removed by extraction with solvents and the product being pelletized, after drying and stabilization.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: December 24, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dietrich Fleischer, Michael Hoffmockel, Karl-Friedrich Muck, Gunter Sextro
  • Patent number: 5563224
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 8, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5547753
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-tri-azines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: August 20, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5539077
    Abstract: A resin composition useful as a binder is provided comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is then mixed with a polyol.
    Type: Grant
    Filed: December 7, 1994
    Date of Patent: July 23, 1996
    Assignee: Sequa Chemicals, Inc.
    Inventor: William C. Floyd
  • Patent number: 5532332
    Abstract: Provided are light-absorbing polymers useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: July 2, 1996
    Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
  • Patent number: 5376650
    Abstract: Provided are light-absorbing polymers which contain backbone unsaturations and which are produced by knoevenagel condensation and which are useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: December 27, 1994
    Assignee: Eastman Chemical Company
    Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
  • Patent number: 5286808
    Abstract: Crosslinked elastomeric acetal polymers are made by the copolymerization of 1,3-dioxolane with a smaller amount of one or more bifunctional monomers. The two functional groups of the bifunctional monomer react under the same cationic polymerization conditions as the 1,3-dioxolane. The elastomeric acetal polymer does not crystallize even when the temperature is as low as -50.degree. C. The elastomeric acetal polymer is particularly useful for blending with crystalline acetal polymers to yield a composition with improved impact resistance.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: February 15, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: George L. Collins, William M. Pleban, Paul Zema
  • Patent number: 5187019
    Abstract: Amino resins, e.g., urea-formaldehyde and melamine-formaldehyde thermosetting resins, are cured with a latent catalyst which is a thermally-decomposable adduct of an aromatic sulfonic acid (e.g., p-toluene sulfonic acid) and a bicyclic oxazolidines (e.g., 1-aza-3,7-dioxa-5-ethylbicyclo (3.3.0) octane. The coating compositions can contain other conventional co-reactants, such as polyols, polyacids, alkyd resins, polyester resins, epoxies, acrylics and the like. Coatings containing the amino resin, co-reactant, and latent catalyst have an acceptable viscosity stability, cure rapidly at temperatures lower than some other latent catalysts, and produce films with no wrinkles.
    Type: Grant
    Filed: September 6, 1991
    Date of Patent: February 16, 1993
    Assignee: King Industries, Inc.
    Inventors: Leonard J. Calbo, Robert D. Coughlin
  • Patent number: 5150132
    Abstract: A material for a liquid ejection ink-jet recording apparatus that is contactable with a recording liquid wherein the material is formed by a cured substance made from cyclic aliphatic epoxy resin and acid anhydride. The material is used in producing a liquid ejection recording head. The head is included in a liquid recording apparatus.
    Type: Grant
    Filed: April 6, 1990
    Date of Patent: September 22, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masako Shimomura, Hiromichi Noguchi, Akihiko Shimomura
  • Patent number: RE39182
    Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: July 11, 2006
    Assignee: Ticona GmbH
    Inventors: Karl-Friedrich Mück, Horst Röschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood