Nonaldehyde Or Nonaldehyde Derivative Heterocyclic Compound Contains An Oxygen Atom As A Ring Member Of The Heterocyclic Compound Patents (Class 528/249)
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Patent number: 10961384Abstract: Poly-1,3-dioxepane, poly-1,3-dioxolane, polytetrahydrofurane or mixtures thereof are used in molding materials comprising polyoxymethylene or a copolymer containing a majority of oxymethylene units, for improving the flexural toughness of moldings formed from the molding materials.Type: GrantFiled: May 20, 2015Date of Patent: March 30, 2021Assignee: BASF SEInventors: Bernd-Steffen Von Bernstorff, Marie-Claire Hermant, Martin Blömacher
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Patent number: 10035882Abstract: Hexahydrotriazine (HT) materials and hemiaminal (HA) materials derived from aromatic, aliphatic, and/or polyether diamines may be used as a platform for creating flame retardant materials. Various flame retardant material precursors may be incorporated into the HA and HT materials. Examples of flame retardant precursors may include organohalogen materials, organophosphorous materials, melamines, and dianiline compounds, among others. The flame retardant materials and precursors may be single molecule species, oligomers, and/or polymers (i.e., polyhexahydrotriazine, PHT, polyhemiaminal, PHA). The flame retardant materials may be made using an aromatic diamine, an aliphatic diamine, a polyether diamine, or a mixture thereof to react with an aldehyde (i.e. formaldehyde or paraformaldehyde). Such flame retardant material precursors will complex with the diamine monomers via a copolymerization reaction to form the flame retardant materials.Type: GrantFiled: August 24, 2016Date of Patent: July 31, 2018Assignee: International Business Machines CorporationInventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Rudy J. Wojtecki
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Patent number: 9487602Abstract: The present invention relates to the polymeric reaction product of compounds according to Formula (I) and Formulae (II) or (III). Formula (I) has the following structure: where R1, R2, R3 and R4 are independently H, OH, optionally substituted C1-12alkyl, optionally substituted C1-12alkenyl, C1-12aldehyde, C3-12acetals, C2-12 ether, and/or C2-12 ester; where optionally at least one of R1, R2, R3 and R4 is H. Formulae (II) and (III) have the following structure: where X is H or C1-4alkyl; Y is OH or OR5 where R5 is C1-12alkyl, C3-12aryl, C4-12aralkyl or C3-12cycloalkyl; and Z is an electron-withdrawing group.Type: GrantFiled: December 19, 2012Date of Patent: November 8, 2016Assignee: DSM IP ASSETS B.V.Inventors: Rudolfus Antonius Theodorus Maria Van Benthem, Stijn Witters
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Patent number: 9453108Abstract: Hexahydrotriazine (HT) materials and hemiaminal (HA) materials derived from aromatic, aliphatic, and/or polyether diamines may be used as a platform for creating flame retardant materials. Various flame retardant material precursors may be incorporated into the HA and HT materials. Examples of flame retardant precursors may include organohalogen materials, organophosphorous materials, malamines, and dianiline compounds, among others. The flame retardant materials and precursors may be single molecule species, oligomers, and/or polymers (i.e., polyhexahydrotriazine, PHT, polyhemiaminal, PHA). The flame retardant materials may be made using an aromatic diamine, an aliphatic diamine, a polyether diamine, or a mixture thereof to react with an aldehyde (i.e. formaldehyde or paraformaldehyde). Such flame retardant material precursors will complex with the diamine monomers via a copolymerization reaction to form the flame retardant materials.Type: GrantFiled: August 22, 2014Date of Patent: September 27, 2016Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Rudy J. Wojtecki
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Patent number: 9388269Abstract: Amino-formaldehyde resins, articles of manufacture from the amino-formaldehyde resins, and processes for making the resins and articles are provided herein. In one embodiment, the amino-formaldehyde resins may be prepared using a reaction mixture including formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof. In another embodiment, the amino-formaldehyde resins are produced by reacting formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof, and the monohydroxy cyclic compound may be added as a front addition, an intermediate addition, a back addition, or a combination thereof, to the reaction mixture of formaldehyde and the at least one amino compound.Type: GrantFiled: March 10, 2014Date of Patent: July 12, 2016Assignee: HEXION INC.Inventors: Valter E. Lessmann, Gilberto E. Saboia, Cicero L. da Silva, Edielma D. Chipanski, David M. Harmon, Rajamani Nagarajan
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Publication number: 20140322309Abstract: ?-Aminoamidine polymers and methods of preparing a-aminoamidine polymers by reacting by reacting one or more amines with one or more isocyanides and one or more aldehydes are described. Methods of preparing a-aminoamidine polymers from commercially available starting materials are also provided, wherein the starting materials are racemic or stereochemically pure. a-Aminoamidine polymers or salt forms thereof are preferably biodegradable and biocompatible and may be used in a variety of drug delivery systems and for other purposes as well such as, for example, coatings, additives, excipients, plastics, and materials, etc. Given the amino moiety of these ?-aminoamidine polymers, they are particularly suited for the delivery of polynucleotides. Complexes, micelles, liposomes or particles containing the inventive ?-aminoamidine polymers and polynucleotides can be prepared. The inventive ?-aminoamidine polymers may also be used in preparing microparticles for drug delivery.Type: ApplicationFiled: December 15, 2012Publication date: October 30, 2014Applicant: Massachusetts Institute of TechnoloInventors: Arturo Jose Vegas, Kathryn Ann Whitehead, Daniel Griffith Anderson, Robert S. Langer, Joseph R. Dorkin
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Publication number: 20140275353Abstract: Amino-formaldehyde resins, articles of manufacture from the amino-formaldehyde resins, and processes for making the resins and articles are provided herein. In one embodiment, the amino-formaldehyde resins may be prepared using a reaction mixture including formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof. In another embodiment, the amino-formaldehyde resins are produced by reacting formaldehyde, a monohydroxy cyclic compound, and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof, and the monohydroxy cyclic compound may be added as a front addition, an intermediate addition, a back addition, or a combination thereof, to the reaction mixture of formaldehyde and the at least one amino compound.Type: ApplicationFiled: March 10, 2014Publication date: September 18, 2014Applicant: Momentive Specialty Chemicals Inc.Inventors: Valter E. Lessman, Gilberto E. Saboia, Cícero L. da Silva, Edielma D. Chipanski, David M. Harmon, Rajamani Nagarajan
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Publication number: 20140048740Abstract: The present invention relates primarily to a mixture that is suitable for use in the no-bake process for producing cores and moulds for the foundry industry, and a reaction mixture comprising said mixture and an acid hardener (i.e. an acid catalyst). The present invention further relates to a method of producing a mixture according to the invention and a method of producing a mould or a core. The invention also relates to a mould or a core for producing metal objects and a kit comprising a mixture according to the invention and certain acid hardeners. The invention further relates to the use of a mixture according to the invention as cold-setting binder and the use of said mixtures or reaction mixtures in a no-bake process for producing metal objects.Type: ApplicationFiled: December 16, 2011Publication date: February 20, 2014Applicant: HUETTENES-ALBERTUS CHEMISCHE WERKE GMBHInventors: Christian Fourberg, Gérard Ladégourdie, Norbert Benz, Eckard Piech
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Patent number: 8378144Abstract: A process for preparing polyoxymethylene homopolymers or copolymers (7) by homopolymerization or copolymerization of trioxane, starting from methanol (1), in which methanol (1) is oxidized in a first reactor in a first production plant (A) to give an aqueous formaldehyde-comprising stream (2) which is fed to a second production plant (B) in which pure trioxane (6) is obtained and removal of low boilers (5) by distillation is carried out and the pure trioxane (6) is fed to a third production plant (C) in which it is homopolymerized or copolymerized to form polyoxymethylene homopolymers or copolymers (7), wherein the low boiler stream (5) from the low boiler removal column (K 2) is recycled to the feed stream into the first reactor in the first production plant (A), is proposed.Type: GrantFiled: December 11, 2008Date of Patent: February 19, 2013Assignee: BASF SEInventors: Markus Siegert, Tobias Kortekamp, Eckhard Stroefer, Christoph Sigwart, Neven Lang
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Publication number: 20120123085Abstract: Alcohols are catalytically oxidized to aldehydes, in particular to benzaldehyde and diformylfuran, which are useful as intermediates for a multiplicity of purposes. The invention also relates to the polymerization of the dialdehyde and to the decarbonylation of the dialdehyde to furan.Type: ApplicationFiled: January 25, 2012Publication date: May 17, 2012Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: Vladimir Grushin, Walter Partenheimer, Leo E. Manzer
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Publication number: 20110184089Abstract: The invention relates to a process for extruding plastic compositions, in particular polymer melts and mixtures of polymer melts, above all thermoplastics and elastomers, particularly preferably polycarbonate and polycarbonate blends, also with the incorporation of other substances such as for example solids, liquids, gases or other polymers or other polymer blends with improved optical characteristics, with the assistance of a multi-screw extruder with specific screw geometries.Type: ApplicationFiled: June 12, 2009Publication date: July 28, 2011Applicant: Bayer MaterialScience AGInventors: Michael Bierdel, Thomas König, Carsten Conzen, Ulrich Liesenfelder, Klemens Kohlgrüber, Reiner Rudolf, Johann Rechner
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Publication number: 20110021740Abstract: The present invention relates to the polymeric reaction product of compounds according to Formula (I) and Formula (II) or (III). Formula (I) has the following structure: where R1, R2, R3 and R4 are independently H, OH, optionally substituted C1-12alkyl, optionally substituted C1-12alkenyl, C1-12aldehyde, C3-12acetals, C2-12 ether, and/or C2-12 ester; where optionally at least one of R1, R2, R3 and R4 is H. Formulae (II) and (III) have the following structure: where X is H or C1-4alkyl; Y is OH or OR5 where R5 is C1-12alkyl, C3-12aryl, C4-12aralkyl or C3-12cycloalkyl; and Z is an electron-withdrawing group.Type: ApplicationFiled: December 18, 2008Publication date: January 27, 2011Inventors: Rudolfus Antonius Theodorus Maria Van Benthem, Stijn Witters
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Publication number: 20080234459Abstract: A process for preparing polyoxymethylene homopolymers or copolymers by homopolymerization or copolymerization of trioxane or additionally of suitable comonomers, in which trioxane which still comprises residual monomers is firstly prepared in a monomer plant and is degassed in one or more stages to give one or more vapor streams (13, 14) which are, if appropriate, fed to a condenser (K) in which the condensable fractions of these vapor streams are condensed to give a condensate (15) which is recycled to the polymerization reactor (P) and one or more gaseous, formaldehyde-comprising streams (16) and also a partially degassed polyoxymethylene homopolymer or copolymer (17) which is fed to an extruder (E) or kneader and is mixed with customary additives and processing aids in this to give a polymer melt (19) and extraction of a formaldehyde-comprising extruder or kneader offgas (18) from the extruder (E) or kneader, wherein the formaldehyde-comprising secondary streams (14, 16, 18) from the polymer plant are rType: ApplicationFiled: August 25, 2006Publication date: September 25, 2008Applicant: BASF SEInventors: Neven Lang, Knut Zollner, Achim Stammer, Elmar Stockelmann
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Patent number: 7348128Abstract: A photosensitive resin which exhibits excellent storage stability, affinity, miscibility, or solubility with respect to a variety of compounds, and high sensitivity can be solidified even under hydrous conditions as well as exhibiting high cure-related sensitivity and high flexibility and being uniformly solidified even under highly hydrous conditions, a photosensitive resin composition containing the resin, and a novel compound. The photosensitive resin is a saponified poly(vinyl acetate)-based photosensitive resin having a structural unit represented by formula (1): (wherein R1 represents H or Me; R2 represents a linear or branched C2-C10 alkylene group; n is an integer of 1 to 3; X represents m is an integer of 0 to 6; and Y represents an aromatic ring or a single bond).Type: GrantFiled: November 13, 2003Date of Patent: March 25, 2008Assignee: Toyo Gosei Co., Ltd.Inventors: Seigo Yamada, Masahiro Takano, Mitsuharu Miyazaki, Shin Utsunomiya
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Patent number: 7087683Abstract: A crosslinking agent that is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin such that the crosslinking agent is essentially free of functional groups reactive with an aminoplast resin and has a glass transition temperature of at least 10° C. is disclosed. Compound (b) is, more specifically, a monofunctional sulfonamide having only one active hydrogen. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating compositions and substrates coated therewith are also disclosed. Methods for modifying aminoplasts are also disclosed.Type: GrantFiled: December 5, 2002Date of Patent: August 8, 2006Assignee: PPG Industries Ohio, Inc.Inventors: Shengkui Hu, Anthony M. Chasser, William H. Retsch, Ronald R. Ambrose
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Patent number: 7030207Abstract: The invention is to provide a polymer, having a high affinity to water, is liquid in spite of being a polymer, simultaneously possesses also a thermal stability and is suitably used as a heating medium or a lubricant. It is the polyacetal (co)polymer, being liquid at room temperature, prepared by copolymerizing (A) 75 to 100 mol % of 1,3-dioxolane and (B) 25 to 0 mol % of trioxane and having the total amount of terminal groups of 15 to 300 mmol/kg and an amount of a hemiformal terminal group of 80 mmol/kg or less.Type: GrantFiled: July 23, 2002Date of Patent: April 18, 2006Assignee: Polyplastics Co., Ltd.Inventors: Yoshihisa Tajima, Hiroaki Nakao, Kuniaki Kawaguchi
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Patent number: 7022805Abstract: The present invention relates to a process for the preparation of acetal polymers, in particular of polyoxymethylene (POM) by cationic polymerization where organophosphonic and/or organophosphinic acids and/or their derivatives and/or their precursors are used as the initiator.Type: GrantFiled: September 10, 2004Date of Patent: April 4, 2006Assignee: Ticona GmbHInventors: Michael Haubs, Stanislaw Penczek
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Patent number: 7001959Abstract: Copolymers are described containing blocks of the structural repeat units of the formula I and blocks containing structural units of the formula II [—O—CH2—]x,??(I) [—O—R1—],??(II) where R1 is a divalent radical derived from a hydroxy-terminated aliphatic or cycloaliphatic oligomer or polymer which, where appropriate, has ether groups and/or carbonyloxy groups in the chain, and x is a whole number, at least 10. The copolymers may be used for producing moldings.Type: GrantFiled: November 3, 2003Date of Patent: February 21, 2006Assignee: Ticona GmbHInventors: Karl-Friedrich Mück, Klaus Kurz, Michael Hoffmockel
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Patent number: 6809161Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.Type: GrantFiled: July 1, 2003Date of Patent: October 26, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
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Patent number: 6635724Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.Type: GrantFiled: July 31, 2001Date of Patent: October 21, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
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Publication number: 20020161135Abstract: The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.Type: ApplicationFiled: August 22, 2001Publication date: October 31, 2002Inventors: Keimpe Jan van den Berg, Klaus Hobel, Huig Klinkenberg, Arie Noomen, Josephus Christiaan van Oorschot
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Patent number: 6426393Abstract: To provide polyacetal which has excellent shock resistance, rigidity and creep resistance as essential properties of the polymer and makes a high flowability and an excellent molding property upon molding possible by improving the thermal stability. In the manufacture of a polyacetal copolymer by a copolymerization of 100 parts by weight of trioxane (a) with 0.05-20 parts by weight of a cyclic ether compound (b) which is copolymerizable with trioxane and 0.001-10 parts by weight of a mono-functional glycidyl compound (c), the mono-functional glycidyl compound (c) having a chlorine content of not more than 0.3% by weight is used.Type: GrantFiled: February 1, 2001Date of Patent: July 30, 2002Assignee: Polyplastics Co., Ltd.Inventors: Yoshihisa Tajima, Hidetoshi Okawa
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Patent number: 6365704Abstract: To provide a resin material in which various properties of a polyacetal resin such as excellent appearance, slidability and thermal stability are maintained and a rigidity is improved as well. That is, a polyacetal copolymer which is prepared by a copolymerization of 100 parts by weight of trioxane (A), 0.0005 to 2 parts by weight of the component (B), which is a compound (B-1) having at least three glycidyl groups in the molecule or a compound (B-2) having at least two epoxy groups in the molecule, and 0 to 20 parts by weight of a cyclic ether compound (C) copolymerizable with trioxane, and which has a total terminal group amount of 15 to 150 mmol/kg, when (B) is (B-2).Type: GrantFiled: July 5, 2001Date of Patent: April 2, 2002Assignee: Polyplastics Co., Ltd.Inventors: Hidetoshi Okawa, Kaoru Yamamoto
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Patent number: 6297329Abstract: The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.Type: GrantFiled: February 21, 1997Date of Patent: October 2, 2001Assignee: Akzo Nobel NVInventors: Keimpe Jan van den Berg, Klaus Hobel, Huig Klinkenberg, Arie Noomen, Josephus Christiaan van Oorschot
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Patent number: 6255440Abstract: Polyacetal copolymers, obtained by copolymerizing (A) 100 parts by weight of trioxane, (B) 0.01 to 10 part(s) by weight of at least one compound selected from among glycidyl ether compounds of the following general formula (I), (II) or (III) and (C) 0 to 20 part(s) by weight of a cyclic ether compound [excluding the glydicyl ether compound (B)] copolymerizable with trioxane, are a polyacetal resin having a high rigidity, excellent creep properties, a high surface hardness and excellent sliding properties: wherein R1 is a C1-12 alkyl group, an aryl group or a substtituted aryl group; wherein R2 represents a C2-20 polyalkylene oxide glycol residue; wherein R4 represents an alkyl group having 1 to 30 carbon atoms; R5 represents an alkylene group having 1 to 30 carbon atoms.Type: GrantFiled: September 21, 2000Date of Patent: July 3, 2001Assignee: Polyplastics Co., Ltd.Inventors: Hidetoshi Okawa, Yoshihisa Tajima
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Patent number: 6037439Abstract: To provide a process for stable and continuous production of a polyacetal resin, mainly comprising a copolymer of 1,3-dioxolane and trioxane under the presence of a catalyst, in a high yield on an industrial scale for a long period of time. In the continuous production of a polyacetal resin by mixing 1,3-dioxolane with boron trifluoride and/or a coordination compound of boron trifluoride and then, mixing the obtained mixture with trioxane to conduct bulk polymerization in a polymerization machine, 1,3-dioxolane is brought into contact with boron trifluoride and/or a coordination compound of boron trifluoride while feeding both at the same direction and they are mixed together for 0.1 to 30 seconds under the condition of at least 0.1 m/sec of the linear velocity of the mixture and subsequently mixed with trioxane.Type: GrantFiled: August 10, 1998Date of Patent: March 14, 2000Assignee: Polyplastics Co., Ltd.Inventors: Hajime Serizawa, Kaoru Yamamoto, Kuniaki Kawaguchi, Yuichi Fukui, Tsugio Tenda
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Patent number: 5994455Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.Type: GrantFiled: September 8, 1998Date of Patent: November 30, 1999Assignee: Ticonna GmbHInventors: Karl-Friedrich Muck, Horst Roschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood
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Patent number: 5962623Abstract: A continuous process for the preparation of polyacetal copolymers from 1,3,5-trioxane and the comonomers known for this purpose using strong protic acids as an initiator, in which the initiator is added in an amount of 0.01 to 0.6 ppm, based on the total amount of monomers, in finely divided form to the monomer mixture, after the polymerization step the crude polymer is transferred from the polymerization reactor to a mixing unit without further intermediate steps, excess monomer is removed from the crude polymer in the mixing unit or between polymerization reactor and mixing unit by applying reduced pressure and, if desired, generally customary stabilizers, assistants, fillers, reinforcing materials and/or colorants are incorporated into the polymer in the mixing unit.Type: GrantFiled: September 8, 1998Date of Patent: October 5, 1999Assignee: Ticona GmbHInventors: Peter Eckardt, Michael Hoffmockel, Karl-Friedrich Muck, Gerhard Reuschel, Satyajit Verma, Michael G. Yearwood
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Patent number: 5942595Abstract: Disclosed is a process for copolymerization of formaldehyde with cyclic ethers in the presence of organic nitro compounds. The process enhances the selectivity for the cyclic copolymer.Type: GrantFiled: July 13, 1998Date of Patent: August 24, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Douglas John Adelman, Richard Beckerbauer
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Patent number: 5929195Abstract: A branched or crosslinked polyacetal resin is excellent in blow moldability, has impact resistances such as plane impact resistance, and the smoothness of the inner surfaces of moldings produced therefrom, and is suitable for molding, particularly blow molding. It can be produced by the bulk polymerization of (A) trioxane with (B) a cyclic ether and/or cyclic formal and (C) a polyfunctional glycidyl ether compound in the presence of (D) a cationic polymerization catalyst, a mixture prepared by mixing the cyclic ether and/or cyclic formal (B) with the polyfunctional glycidyl ether compound (C) and the cationic polymerization catalyst (D) is added to trioxane (A) to conduct the polymerization.Type: GrantFiled: July 14, 1998Date of Patent: July 27, 1999Assignee: Polyplastics Co., Ltd.Inventors: Kuniaki Kawaguchi, Kaoru Yamamoto, Hajime Serizawa
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Patent number: 5886110Abstract: Branched, dendrimeric macromolecules having a central nucleus and a series of polyoxaalkylene chains that radiate from the nucleus and spread into the surrounding space branching a cascade fashion until the desired size results. Molecules formed in this manner are free of excessive functional crowding on their outer surfaces. Synthetic methods of preparing these molecules and their uses are described.Type: GrantFiled: April 30, 1998Date of Patent: March 23, 1999Assignee: Dibra S.p.A.Inventors: Luigia Gozzini, Monica Muttoni, Christoph De Haen
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Patent number: 5874179Abstract: The invention relates to nitrogen-containing polymers containing structural units of formula (I), ##STR1## where the symbols and indices have the following meanings: Ar.sup.1, Ar.sup.2, Ar.sup.3 are, identically or differently, mono- and/or polynuclear and/or condensed aryl and/or heteroaryl groups which may or may not be linked via one or more bridges carbon atoms, which may or may not be substituted;X is a single bond, --O--, --S--, --SO--, --SO.sub.2, NR.sup.3, --CR.sup.4 R.sup.5 --, --CO--, --CR.sup.6 .dbd.CR.sup.7, CR.sup.8 R.sup.9 --CR.sup.10 R.sup.11 or SiR.sup.12 R.sup.13 ;R.sup.1 -R.sup.13 are, identically or differently, H, a hydrocarbon radical having from 1 to 22 carbon atoms or Ar.sup.4, where Ar.sup.4, identical with or different from Ar.sup.1, has the same meanings as Ar.sup.1 ;n=1, 2 or 3.Type: GrantFiled: March 28, 1997Date of Patent: February 23, 1999Assignee: Hoechst AktiengesellschaftInventors: Willi Kreuder, Hans-Heinrich Horhold, Henning Rost
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Patent number: 5849858Abstract: Furfuryl alcohol/formaldehyde resins exhibiting high water compatibility and low amounts of volatile organic compounds such as furfuryl alcohol.Type: GrantFiled: April 2, 1998Date of Patent: December 15, 1998Assignee: QO Chemicals, Inc.Inventors: George S. Everett, George R. MacLennan, Michael C. Chen
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Patent number: 5830978Abstract: A resin composition useful as a binder is provided comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is then reacted with a polyol.Type: GrantFiled: April 11, 1995Date of Patent: November 3, 1998Assignee: Sequa Chemicals, Inc.Inventor: William C. Floyd
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Patent number: 5756594Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.Type: GrantFiled: September 19, 1997Date of Patent: May 26, 1998Assignee: BASF AktiengesellschaftInventors: Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
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Patent number: 5728798Abstract: In preparing a polyacetal copolymer through copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-carbon bond as the comonomer, 0.05 to 100 ppm (on the weight basis), based on the total amount of the monomers, of a heteropoly-acid or an acidic salt thereof is used as a polymerization catalyst, and a liquid mixture preliminarily prepared by mixing at least part or the whole of the comonomer with the polymerization catalyst is added to trioxane to effect copolymerization. According to such the process, the polymerization yield and the degree of polymerization (molecular weight) are enhanced, and a polyacetal copolymer having an improved stability can be obtained.Type: GrantFiled: March 7, 1997Date of Patent: March 17, 1998Assignee: Polyplastics Co., Ltd.Inventors: Akira Nakai, Kaoru Yamamoto
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Patent number: 5691426Abstract: A resin composition useful as a binder is provided comprising a mixture of a formaldehyde-based resin with a resin substitute comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with 1 to 2 moles of a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is mixed, preferably reacted, with a polyol.Type: GrantFiled: February 28, 1997Date of Patent: November 25, 1997Assignee: Sequa Chemicals, Inc.Inventor: William Floyd
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Patent number: 5629373Abstract: A coating composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.Type: GrantFiled: June 7, 1995Date of Patent: May 13, 1997Assignee: United Catalysts, Inc.Inventors: Charles W. Glancy, Alan L. Steinmetz
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Patent number: 5627232Abstract: A water-containing composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.Type: GrantFiled: June 7, 1995Date of Patent: May 6, 1997Assignee: United Catalysts, Inc.Inventors: Charles W. Glancy, Alan L. Steinmetz
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Patent number: 5607986Abstract: This invention relates to nitrogen free heat cured foundry mixes essentially free of free formaldehyde comprising (a) a nitrogen free modified furan resin, (b) furfuryl alcohol, (c) polyvinyl acetate, preferably(d) a tar selected from the group consisting of resorcinol pitch, bisphenol A tar, and (e) a latent acid curing catalyst. The foundry mixes are used to prepare foundry shapes. They are cured in the presence of the latent acid curing catalyst by heating at an elevated temperature.Type: GrantFiled: April 17, 1995Date of Patent: March 4, 1997Assignee: Ashland Inc.Inventors: Young D. Kim, deceased, A. Leonard Haugse
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Patent number: 5587449Abstract: In the process for the preparation, with simultaneous end group stabilization, of polyacetal copolymers in a homogeneous phase and working up thereof, cyclic formaldehyde oligomers are copolymerized with cyclic acetals in the presence of an initiator in a polymerization reactor and immediately thereafter the initiator is deactivated by addition of basic substances, the unstable chain ends being degraded down to 0.01% to 1% in the presence of residual monomer, the product losing the majority of the residual monomer at the reactor outlet by letting down into a pelletizing device and the residual monomer which remains and the impurities dissolved in the product being removed by extraction with solvents and the product being pelletized, after drying and stabilization.Type: GrantFiled: August 31, 1995Date of Patent: December 24, 1996Assignee: Hoechst AktiengesellschaftInventors: Dietrich Fleischer, Michael Hoffmockel, Karl-Friedrich Muck, Gunter Sextro
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Patent number: 5563224Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.Type: GrantFiled: May 23, 1995Date of Patent: October 8, 1996Assignee: Cytec Technology Corp.Inventors: Jeno G. Szita, Paul S. Waterman
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Patent number: 5547753Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-tri-azines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.Type: GrantFiled: May 23, 1995Date of Patent: August 20, 1996Assignee: Cytec Technology Corp.Inventors: Jeno G. Szita, Paul S. Waterman
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Patent number: 5539077Abstract: A resin composition useful as a binder is provided comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is then mixed with a polyol.Type: GrantFiled: December 7, 1994Date of Patent: July 23, 1996Assignee: Sequa Chemicals, Inc.Inventor: William C. Floyd
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Patent number: 5532332Abstract: Provided are light-absorbing polymers useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.Type: GrantFiled: September 19, 1994Date of Patent: July 2, 1996Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
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Patent number: 5376650Abstract: Provided are light-absorbing polymers which contain backbone unsaturations and which are produced by knoevenagel condensation and which are useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.Type: GrantFiled: March 3, 1994Date of Patent: December 27, 1994Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
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Patent number: 5286808Abstract: Crosslinked elastomeric acetal polymers are made by the copolymerization of 1,3-dioxolane with a smaller amount of one or more bifunctional monomers. The two functional groups of the bifunctional monomer react under the same cationic polymerization conditions as the 1,3-dioxolane. The elastomeric acetal polymer does not crystallize even when the temperature is as low as -50.degree. C. The elastomeric acetal polymer is particularly useful for blending with crystalline acetal polymers to yield a composition with improved impact resistance.Type: GrantFiled: July 25, 1991Date of Patent: February 15, 1994Assignee: Hoechst Celanese CorporationInventors: George L. Collins, William M. Pleban, Paul Zema
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Patent number: 5187019Abstract: Amino resins, e.g., urea-formaldehyde and melamine-formaldehyde thermosetting resins, are cured with a latent catalyst which is a thermally-decomposable adduct of an aromatic sulfonic acid (e.g., p-toluene sulfonic acid) and a bicyclic oxazolidines (e.g., 1-aza-3,7-dioxa-5-ethylbicyclo (3.3.0) octane. The coating compositions can contain other conventional co-reactants, such as polyols, polyacids, alkyd resins, polyester resins, epoxies, acrylics and the like. Coatings containing the amino resin, co-reactant, and latent catalyst have an acceptable viscosity stability, cure rapidly at temperatures lower than some other latent catalysts, and produce films with no wrinkles.Type: GrantFiled: September 6, 1991Date of Patent: February 16, 1993Assignee: King Industries, Inc.Inventors: Leonard J. Calbo, Robert D. Coughlin
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Patent number: 5150132Abstract: A material for a liquid ejection ink-jet recording apparatus that is contactable with a recording liquid wherein the material is formed by a cured substance made from cyclic aliphatic epoxy resin and acid anhydride. The material is used in producing a liquid ejection recording head. The head is included in a liquid recording apparatus.Type: GrantFiled: April 6, 1990Date of Patent: September 22, 1992Assignee: Canon Kabushiki KaishaInventors: Masako Shimomura, Hiromichi Noguchi, Akihiko Shimomura
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Patent number: RE39182Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.Type: GrantFiled: November 30, 2001Date of Patent: July 11, 2006Assignee: Ticona GmbHInventors: Karl-Friedrich Mück, Horst Röschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood