Nonaldehyde Or Nonaldehyde Derivative Heterocyclic Reactant Contains A Six Membered Ring Having Three Nitrogen And Three Carbon Atoms As Ring Members Patents (Class 528/254)
  • Patent number: 5710239
    Abstract: The present invention relates to a sulfonated water-soluble melamine-formaldehyde resin, to a method of manufacturing the resin, and to insulation products prepared using the resin. The resin is particularly useful for making thermal insulation having low moisture adsorption, high tensile strength and low formaldehyde emissions.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: January 20, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: Kim K. Tutin
  • Patent number: 5708121
    Abstract: This invention relates to an emulsifiable melamine-modified phenolic resole resin composition useful as a binder for glass fibers. The invention is more particularly directed to the process of preparing the resole resin composition using an alkaline condensation in the presence of a polyhydroxyl compound.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: January 13, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Claude Phillip Parks, Kurt Forrest Anderson
  • Patent number: 5693743
    Abstract: The invention relates to aminoplastics, which are created by reacting comnds that contain amide groups with glutaric dialdehyde, and to a process for their preparation and to their use. The aminoplastic according to the invention is free of formaldehyde and can be hardened without difficulty by acidic catalysis or thermal processes. The aminoplastic is prepared by polycondensation of compounds that contain amide groups with glutaric dialdehyde in aqueous solution.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: December 2, 1997
    Assignee: Fraunhofer Gesellschaft zur Forderung der Angewandten Forschung e.V.
    Inventors: Rudolf Nastke, Gerald Rafler
  • Patent number: 5693725
    Abstract: Novel polymers of general formula: ##STR1## wherein where n is a whole number from 2 to 10; R is a spacing group comprising (a) at least one of m methylene units where m is a whole number from 1 to 20, m' methine units where m' is a whole number from 0 to 20, a mixture of m methylene units and m' methine units where m+m'.ltoreq.20, and units of formula --(CH.sub.2 -CHX-O).sub.m" --, where m" is a whole number from 0 to 200 and X is H, CH.sub.3 or C.sub.2 H.sub.5, or (b) an aromatic ring having one, two or three members; R' is H, an alkyl group having no more than 20 carbon atoms, an aryl group having no more than three rings, or a combination thereof; R" is a group containing at least two active hydrogen atoms and having at least two but no more than 20 carbon atoms; and R'" is a group containing at least two active hydrogen atoms and is selected from the group consisting of alkyl, aryl and mixed alkyl-aryl species having from 1 to 200 carbon atoms; polyalkylene oxides; and urea formaldehyde resin.
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: December 2, 1997
    Assignees: Lifesource International, Ltd., Jojani, Inc.
    Inventor: Nicholas M. Irving
  • Patent number: 5691426
    Abstract: A resin composition useful as a binder is provided comprising a mixture of a formaldehyde-based resin with a resin substitute comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with 1 to 2 moles of a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is mixed, preferably reacted, with a polyol.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: November 25, 1997
    Assignee: Sequa Chemicals, Inc.
    Inventor: William Floyd
  • Patent number: 5684118
    Abstract: A method of scavenging formaldehyde in formaldehyde-based resins using a low mole ratio melamine-urea-formaldehyde resin composition. In addition, a formaldehyde-based resin containing a storage-stable low mole ratio melamine-urea-formaldehyde resin composition as a formaldehyde scavenger.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: November 4, 1997
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Robert A. Breyer, Bill R. Arndell, Semyon Stompel
  • Patent number: 5681917
    Abstract: A low mole ratio melamine-urea-formaldehyde resin useful as a binder for making a variety of products, and a method for making the resin. The melamine-urea-formaldehyde resin thus produced is stable and has low formaldehyde emissions (release).
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: October 28, 1997
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Robert A. Breyer, Solona G. Hollis, Joseph J. Jural, deceased
  • Patent number: 5665852
    Abstract: Novel substituted urea and oxime carbamate modified amino crosslinking agents, curable compositions containing the same, including curable powder coating compositions, are disclosed. Also disclosed is a novel process for preparing pyrrolidone urea.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 9, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Balwant Singh, Laurence W. Chang, Larry S. Anderson, Stephen F. Donovan
  • Patent number: 5648446
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 15, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5646240
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: July 8, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5629373
    Abstract: A coating composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 13, 1997
    Assignee: United Catalysts, Inc.
    Inventors: Charles W. Glancy, Alan L. Steinmetz
  • Patent number: 5610263
    Abstract: This invention provides a polymeric vehicle and formulated coating composition which are high in solids and use water to effect viscosities to permit application of such polymeric vehicles and formulated coating compositions with existing commercial application equipment. The polymeric vehicles and formulated coatings include at least one oligoester diol, a carbamate hardener, and in some instances, an additional crosslinking agent. The combination of oligoester diol with carbamate hardener provides a low viscosity coating composition with low to zero VOC content, and provides a coating binder with extremely good film properties.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 11, 1997
    Assignee: Eastern Michigan University
    Inventors: Frank N. Jones, Shou-Kuan Fu, Wen Jing, Suru Zhang
  • Patent number: 5597557
    Abstract: A process for making solid colored particles by preparing a reaction solution in water comprising formaldehyde, urea, a cyclic polyamine functional triazine compound, and acid. A dye can be incorporated into the reaction solution if a color other than white is desired. Particles are formed having an average particle size between 1 and 70 microns without the need to resort to crushing to break up agglomerates. Particles made by this process provide excellent color and are easily washable from a substrate when incorporated into a washable formulation.Additionally, it has been found that the incorporation of colored microcapsules of average size of 1-70 microns where the color is located primarily on or in the shell of the microcapsule also provides excellent washable compositions when incorporated into a washable formulation.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: January 28, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kanta Kumar, Robert A. Davis, Sheila M. Nichols, Howard J. Buttery
  • Patent number: 5596039
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: January 21, 1997
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5563224
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 8, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5558709
    Abstract: Disclosed is a flow improving agent for binder suspensions containing cement which is composed of a) amino-s-triazine-formaldehyde-sulfite condensation products having a molar ratio of amino-s-triazine:formaldehyde:sulfite of 1:1.3 to 6.0: 0.3 to 1.5 and a low content of free formaldehye as well as b) casein. The flow improving agents have the advantage that the flowability is considerably improved compared to casein (alone) for example and the increased flowability remains constant even over a longer time period.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: September 24, 1996
    Assignee: SKW Trostberg
    Inventors: Josef Weichmann, Aloisia Stadler, Alfred Kern
  • Patent number: 5554718
    Abstract: Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: September 10, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Flory, Andreas Stange, Michael Kroener, Norbert Sendhoff
  • Patent number: 5547753
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-tri-azines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: August 20, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5545702
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5539077
    Abstract: A resin composition useful as a binder is provided comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is then mixed with a polyol.
    Type: Grant
    Filed: December 7, 1994
    Date of Patent: July 23, 1996
    Assignee: Sequa Chemicals, Inc.
    Inventor: William C. Floyd
  • Patent number: 5536795
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 16, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5530031
    Abstract: Water-insoluble condensation products, obtained by the condensation of a mixture containing as essential components(A) from 80 to 99.9 mol %, based on the sum of (A), (B) and (C), of a mixture consisting essentially of(a) from 30 to 99 mol % of melamine and(b) from 1 to 70 mol % of a substituted melamine of the formula I ##STR1## where X, X' and X" are each selected from the group consisting of --NH.sub.2, --NHR and --NRR', and X, X' and X" are not all --NH.sub.2 at one and the same time, and R and R' are each selected from the group consisting of hydroxy-C.sub.2 -C.sub.10 -alkyl, hydroxy-C.sub.2 -C.sub.4 -alkyl-(oxa-C.sub.2 -C.sub.4 -alkyl).sub.n, where n is from 1 to 5, and amino-C.sub.2 -C.sub.12 -alkyl, or mixtures of melamines I,(B) from 0.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: June 25, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Erhard Guenther, Wolfgang Reuther, Uwe Kirchgassner
  • Patent number: 5480947
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: January 2, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5478656
    Abstract: Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: December 26, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Flory, Andreas Stange, Michael Kroener, Norbert Sendhoff
  • Patent number: 5424390
    Abstract: A process of producing an aqueous solution of a sulfonated melamine-formaldehyde resin. The process comprises condensing melamine and formaldehyde or a precursor of formaldehyde (e.g. paraformaldehyde) in an aqueous mixture having a pH in the range of 8-10 to form a reaction mixture containing a condensation product of melamine and formaldehyde. The condensation product is then reacted in an aqueous mixture having a pH of 8-10, preferably 8-9, with a sulfonating agent to produce a mixture containing a sulfonated condensation product. Finally, polymerizing the said sulfonated condensation product in an aqueous mixture having a pH of 5-7 to form a resin solution. In the process, at least one of the sulfonation step and the polymerizing step is carried out under superatmospheric pressure (generally 5 to 70 p.s.i.) and at an elevated temperature of, in the case of the sulfonating step, 100.degree.-130.degree. C. for a time of 1 to 5 hours or of, in the case of the polymerizing step, 105-150.degree. C.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: June 13, 1995
    Assignee: Handy Chemicals Limited
    Inventors: Mario Dupuis, Ioan Spiratos
  • Patent number: 5411802
    Abstract: A process for making solid colored particles by preparing a reaction solution in water comprising formaldehyde, urea, a cyclic polyamine functional triazine compound, and acid. A dye can be incorporated into the reaction solution if a color other than white is desired. Particles are formed having an average particle size between 1 and 70 microns without the need to resort to crushing to break up agglomerates. Particles made by this process provide excellent color and are easily washable from a substrate when incorporated into a washable formulation.Additionally, it has been found that the incorporation of colored microcapsules of average size of 1-70 microns where the color is located primarily on or in the shell of the microcapsule also provides excellent washable compositions when incorporated into a washable formulation.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: May 2, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kanta Kumar, Robert A. Davis, Sheila M. Nichols, Howard J. Buttery
  • Patent number: 5386003
    Abstract: Water dispersible polyester polymers, polyesteramides polymers and blends of these polymers are dispersed in water and spray dried to form fine powders. In the solid state, these powders can absorb oils and/or diffuse ambient light, thereby resulting in the production of significant reduction in gloss and tack of lipids in cosmetic and personal care products when applied to ordinarily oily skin.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: January 31, 1995
    Assignee: Eastman Chemical Company
    Inventors: Carol J. Greene, Stephen H. Wu
  • Patent number: 5380815
    Abstract: Condensation compounds obtained by means of the polymerization of polyami compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: January 10, 1995
    Assignee: Ministero Dell `Universita` E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5371140
    Abstract: A emulsifiable, phenolic-resole-resin-based composition comprising a low salt, urea-extended phenol aldehyde resin and an emulsifying agent, wherein the resin has a water dilutability ranging from about 2:1 to about 10:1 v/v water to resin prior to neutralization and aldehyde scavenger addition, and the method for making the same.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: December 6, 1994
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: Claude P. Parks
  • Patent number: 5344874
    Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: September 6, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takao Doi, Noriko Itaya, Masami Yamashita, Nobuaki Kunii
  • Patent number: 5328978
    Abstract: The present invention relates to a triazine/formaldehyde resin which contains a compound of the general formula I ##STR1## wherein R.sup.1 and R.sup.2 are defined as stated in claim 1, a process for its preparation and its use as a curing agent in surface coating systems.
    Type: Grant
    Filed: October 28, 1993
    Date of Patent: July 12, 1994
    Assignee: Cassella AG
    Inventors: Manfred Schon, Jurgen Ott, Uwe Kubillus, Elif Tas
  • Patent number: 5322915
    Abstract: A condensation polymer, obtainable by condensation of a mixture containing, as chief components,(A) from 90 to 99.9% molar of a mixture substantially consisting of(a) from 30 to 99% molar of melamine and(b) from 1 to 70% molar of a substituted melamine of the general formula I ##STR1## in which X, X', and X" are selected from the group consisting of --NH.sub.2, --NHR, and --NRR', and only one or two of X, X', and X" denote(s) --NH.sub.2, and R and R' are selected from the group consisting of hydroxy-C.sub.2 -C.sub.10 -alkyl, hydroxy-C.sub.2 -C.sub.4 -alkyl-(oxa-C.sub.2 -C.sub.4 -alkyl).sub.n, where n is an integer from 1 to 5, and amino-C.sub.2 -C.sub.12 -alkyl, or mixtures of melamines I, and(B) from 0.1 to 10% molar, based on (A) and (B), of unsubstituted phenols or phenols substituted by radicals selected from the group consisting of C.sub.1 -C.sub.9 -alkyl and hydroxy, or of C.sub.1 -C.sub.
    Type: Grant
    Filed: July 8, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Weiser, Wolfgang Reuther, Rolf Fikentscher, Wolfgang Fath, Heinz Berbner, Hans D. Zettler, Heinz Voelker
  • Patent number: 5306783
    Abstract: An aqueous resin solution for the impregnation of paper webs contains 2-40 parts by weight of a polyurea composed of urea and of a polyamine per 100 parts by weight of a melamine/formaldehyde precondensate. The impregnated paper webs are suitable for coating woodbase materials, especially chipboard.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: April 26, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Uwe Kirchgaessner, Jakob Decher, Christof Jaeckh, Otto Wittmann, Manfred Niessner, Harro Petersen
  • Patent number: 5300328
    Abstract: A method of producing a cured coating is described comprising the steps of:(A) applying a coating composition on a substrate, wherein the coating composition is a curable coating composition comprising:(1) a polymer comprising functional groups that are reactive with methylol and/or methylalkoxy substituents on the amino nitrogens of an aminoplast curing agent, and(2) an aminoplast curing agent that includes, as substituents on the amino nitrogens:(a) a plurality of methylol and/or methylalkoxy substituents, and(b) one or more substituents that are either nonreactive with the functional groups on the polymer or are reactive with the functional groups at a higher temperature than the temperature at which the methylol and/or methylalkoxy substituents are reactive with the functional groups, and(B) curing the coating at a cure temperature sufficient to react the functional groups on the polymer with the methylol and/or methylalkoxy substituents, but below the temperature for reaction, if any, between the functio
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: April 5, 1994
    Assignee: BASF Corporation
    Inventor: John W. Rehfuss
  • Patent number: 5298186
    Abstract: A composition and method of treating paint spray booth water to detackify organic solvent based paint particles. The composition comprises a melamine polymer obtained from the reaction of melamine, aldehyde and an amine selected from the group consisting of dicyandiamide and glycine. These melamine polymers may be used in combination with a polyacrylamide, which combination exhibits surprising and unexpected effects when used to detackify organic solvent paint particles.
    Type: Grant
    Filed: September 11, 1992
    Date of Patent: March 29, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David B. Mitchell, Thomas P. Curran, Wun T. Tai, Gary G. Engstrom
  • Patent number: 5294352
    Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: March 15, 1994
    Inventor: John J. Waldmann
  • Patent number: 5260405
    Abstract: A binding agent for molding compositions and molded bodies produced by reacting a low molecular weight lignin from the Organosolv process with phenol in a weight ratio of 1:20 to 3:1 at 100.degree. to 180.degree. C., adjusting the pH to an acidic value and condensing the mixture with 0.2 to 0.9 moles of formaldehyde per mole of phenol at 60.degree. to 120.degree. C. to form the binding agent useful for producing curable molding compositions, high-temperature molding compositions, refractory products, textile fleeces and friction coatings as well as carbon materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: November 9, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5254665
    Abstract: Ammeline-melamine-formaldehyde resins (AMFR) containing from 5-100% ammeline were synthesized by the polymerization of the sodium salt of ammeline, which must be made in advance, melamine, and formaldehyde in basic medium (pH=9.2-10.0). In this copolymerization, it is possible to make uniform random AMFR resins with any mole ratio of ammeline salt to melamine. Preferably the AMFR resin will contain from 5-10% ammeline. As an "ionomer" or a "polyelectrolyte," both the solid and solution properties of these resins (such as melting temperature, solubility, solution stability, etc.) depended directly on the mole ratio of ammeline to melamine and formaldehyde, and/or on the pH value of the medium in which the AMFR resin was present. The pH value controlled the ammeline rings/ammeline's salt groups and also the ratio of unprotonated to protonated amino groups on both the melamine and ammeline rings.
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: October 19, 1993
    Assignee: Melamine Chemicals, Inc.
    Inventors: George M. Crews, Shen Ji, Charles U. Pittman, Jr., Ruicheng Ran
  • Patent number: 5254639
    Abstract: A binding agent for molded bodies and molding compositions produced by prereacting a mixture of 5 to 60% by weight of lignin or a lignin fraction produced by the Organosolv process and 40 to 95% by weight of a phenol novolac resin and subjecting the latter to high shear forces in a kneader or extruder and optionally mixing the same with a curing agent useful in molding compositions and high temperature-stable molded products such as refractory products, friction coatings, textile fleeces and carbon or graphite materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: October 19, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5215828
    Abstract: Curable binders obtained by simultaneous reaction ofA) urethanes or ureas,B) acrylic or methacrylic compounds containing hydroxyl groups,C) paraformaldehyde andD) if appropriate, polyols,wherein, in the case where no polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger, and in the case where a polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger or a strong acid.These binders are suitable as coating compositions which can be cured by electron beams or by UV light.
    Type: Grant
    Filed: August 19, 1992
    Date of Patent: June 1, 1993
    Assignee: Hoechst AG
    Inventors: Gerhard Brindoepke, Inge Kurth, Michael Schwab, Gerd Walz
  • Patent number: 5206066
    Abstract: Melamine resin prepregs or melamine resin laminates which consist of a web-like fiber reinforcement which is impregnated with melamine resins which essentially comprisea) 40-85% by weight of at least partly etherified melamine resins, which are obtainable by reaction of melamine, formaldehyde and alkanols having 1 to 8 C atoms in a molar ratio of melamine formaldehyde:alkanol of 1:(5 to 6):(4 to 6), andb) 60-15% by weight of diols consisting of 25 to 75% by weight of polyester-diols and/or polyether-diols having a molecular weight of at least 400 g/mol and 75 to 25% by weight of low molecular weight diols having 2 to 12 C atoms.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: April 27, 1993
    Assignee: Chemie Linz Gesellschaft m.b.H.
    Inventor: Heinrich Horacek
  • Patent number: 5182379
    Abstract: Modified cellulose esters are described that are prepared by grafting melamine moieties onto the backbone of cellulose esters. The resulting materials are useful in coating applications for wood, leather, and metal substrates and yield highly solvent-resistant coatings with enhanced properties when heated in the presence of an acid catalyst.
    Type: Grant
    Filed: June 5, 1990
    Date of Patent: January 26, 1993
    Assignee: Eastman Kodak Company
    Inventors: Phillip M. Cook, David S. Kashdan
  • Patent number: 5162487
    Abstract: Moldings, in particular foams and fibers, based on melamine/formaldehyde condensation products, in which from 0.1 to 70 mol % of the melamine have been replaced by melamine substituted by from 1 to 3 hydroxyoxaalkyl groups of the formula--(CH.sub.2 --CH.sub.2 --O).sub.n --CH.sub.2 --CH.sub.2 --OHn=1-5)have increased elasticity.
    Type: Grant
    Filed: August 13, 1991
    Date of Patent: November 10, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Weiser, Wolfgang Reuther, Gerhard Turznik, Wolfgang Fath, Heinz Berbner, Onno Graalmann
  • Patent number: 5120821
    Abstract: A process of producing melamine formaldehyde resins using crude or impure melamine is described. The process using the impure or crude melamine includes the control of the pH within the range of from about 8 to 10, and preferably 9 to 9.2 during at least the initial stages of the formaldehyde/melamine reaction. The pH control provides resins having commercially acceptable characteristics, with the cook times of the resin formation also being commercially acceptable.
    Type: Grant
    Filed: February 22, 1991
    Date of Patent: June 9, 1992
    Assignee: Melamine Chemicals, Inc.
    Inventors: George M. Crews, Shen Ji
  • Patent number: 5110898
    Abstract: Ths invention relates to an improved method of preparing a solid amino-aldehyde condensation product wherein the solid condensation product precursor solution is fed to the bottom of the reaction vessel.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: May 5, 1992
    Assignee: Georgia-Pacific Corporation
    Inventor: Richard E. Formaini
  • Patent number: 5081163
    Abstract: Organic aerogels that are transparent and essentially colorless are prepa from the aqueous, sol-gel polymerization of melamine with formaldehyde. The melamine-formaldehyde (MF) aerogels have low densities, high surface areas, continuous porsity, ultrafine cell/pore sizes, and optical clarity.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: January 14, 1992
    Assignee: The United States of America as represented by the Department of Energy
    Inventor: Richard W. Pekala
  • Patent number: 5071945
    Abstract: A process for the production of sulphonic acid group-containing condensation products based on amino-s-triazines with at least two amino groups and formaldehyde with a low content of free formaldehyde, whereina) an amino-s-triazine, formaldehyde and sulphite is condensed in a mole ratio of 1:1.3 to 6:0.3 to 1.5 in aqueous solution at a pH value of 9.0 to 12.0 and at a temperature of 50.degree. to 90.degree. C. until sulphite is no longer detectable.b) subsequently, further condensation is carried out at a pH value of 2.0 to 7.0 and at a temperature of 50.degree. to 90.degree. C. until the viscosity of the solution is 4 to 1000 mm.sup.2 /s at 80.degree. C. andc) thereafter the condensation product is subjected to an after-treatment in a strongly alkaline range of pH.sqroot.11.0 and at an elevated temperature.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: December 10, 1991
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Josef Weichmann, Manfred Bichler, Alfred Kern, Hans-Gunter Rosenbauer
  • Patent number: 5066768
    Abstract: According to the present invention, spherical melamine resin particulates having a uniform particle size and crosslinked structure can be prepared by adding an acid catalyst to an aqueous solution containing at least 0.5 to less than 5% by weight of a melamine derivative which is polymerizable in the acid region, to adjust the pH of the aqueous solution to at least 4 to less than 5, and carrying out heat-treatment of the aqueous solution.The spherical melamine resin particulates thus obtained are useful as additives for coating compositions, pigments and other materials.
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: November 19, 1991
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Saburo Hiraoka, Kenji Niikawa
  • Patent number: 5059675
    Abstract: Disclosed are compositions useful as surface coatings for nonwoven substrates which compositions are reaction products of a melamine formaldehyde compound, long chain saturated alcohols and long chain saturated or unsaturated polyethoxylated alcohols. The invention compositions when used to surface size paper impart oil, water and polar solvent resistance thereto. The compositions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based surface sizes that are typically used to impart oil resistance to paper.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: October 22, 1991
    Assignee: PPG Industries, Inc.
    Inventors: William W. Carlin, Sai H. Hui, John D. Mansell
  • Patent number: 5057591
    Abstract: The invention is a solution of highly advanced phenolic resin with improved inherent foamability that is made from the reaction of phenol, aldehyde, water and alkali the improved foamability being brought about by the incorporation of up to 1.0% by weight, anhydrous basis, lime (calcium hydroxide) into the early stages of the reaction mix. In another embodiment, the invention is a plywood glue composition comprising a solution of lime-containing highly advanced phenolic resin, dried animal blood and preferably an aldehyde glue viscosity-lowering agent.
    Type: Grant
    Filed: August 25, 1988
    Date of Patent: October 15, 1991
    Assignee: Borden, Inc.
    Inventors: William D. Detlefsen, Lewis D. Creel, Lee R. Johnson