Abstract: Fluorosilicon polymers are disclosed that are prepared by a process comprising reacting a) iodinated oligomers having copolymerized units of perfluoro(methyl vinyl ether) and vinylidene fluoride or tetrafluoroethylene that contain 40-90 mole percent copolymerized units of vinylidene fluoride or tetrafluoroethylene and 10-60 mole percent copolymerized units of perfluoro(methyl vinyl ether), said oligomers having two functional endgroups and having a number average molecular weight between 1000 and 25,000 with b) a methoxyvinyl silane or an ethoxyvinyl silane to form a silicon-containing polymeric adduct that is further reacted with an acid to form a crosslinked fluorinated polymer.

Abstract: A moisture-curable silylated resin possessing improved storage stability and short cure time is obtained by reacting a prepolymer with a silylating reactant comprising silane (i) possessing three methoxy groups, silane (ii) possessing three alkoxy groups independently containing from 2 to 4 carbon atoms, and, optionally, silane (iii) possessing two methoxy groups and one alkoxy group of from 2 to 4 carbon atoms and/or silane (iv) possessing one methoxy group and two alkoxy groups independently containing from 2 to 4 carbon atoms.

Abstract: Matrix controlled diffusion drug delivery systems based on one or more silicon-containing monomers of the general formula: wherein L, X?, n, R1, R2, R3, R4, R5, R6, R7 and V are as set forth herein.

Abstract: The coating described herein attempts to provide this solution by synthesizing alkoxysilane-terminated N-substituted urea resins, then formulating them into moisture-curable single-component (1K) topside coatings. These coatings will provide greater external stability (to UV and visible radiation), cleanability, flexibility, cure times and lower VOC content than the currently qualified silicone alkyd topside coatings that are found on Navy ships. The single-component coating can include at least an alkoxysilane-terminated N-substituted urea resin, a reactive diluent, a pigment, a filler, and a catalyst. The resin can include an amino-functional silane substituted at the N-position and a non-aromatic isocyanate.

Abstract: Matrix controlled diffusion drug delivery systems are described herein which are based on one or more silicon-containing monomers of the general formula: wherein L, X?, n, R1, R2, R3, R4, R5, R6, R7 and V are as set forth herein.

Abstract: A room temperature fast-curing organopolysiloxane composition which has excellent fast curability as well as deep curability is provided without using an organic compound having C?O group and the organic compound having NH2 group which are the volatile components. A method for curing such composition is also provided. The room temperature fast-curing organopolysiloxane composition comprises: (A) 100 parts by weight of a diorganopolysiloxane having both ends terminated with hydroxy group and/or a hydrolyzable group; (B) 0.5 to 10 parts by weight of a silane and/or a siloxane having at least 3 alkenoxysilyl groups in its molecule and being capable of forming a compound having —NH2 group by hydrolysis; (C) 0.5 to 10 parts by weight of a silane and/or a siloxane having at least 3 aminosilyl groups in its molecule and being capable of forming a compound having —NH2 group by hydrolysis; and (D) 0.01 to 10 parts by weight of a curing catalyst.

Abstract: A silicone acrylate hybrid composition includes the reaction product of a silicon-containing pressure sensitive adhesive composition, an ethylenically unsaturated monomer, and an initiator. The silicon-containing pressure sensitive adhesive composition includes acrylate or methacrylate functionality. A method of making the hybrid composition includes polymerizing the ethylenically unsaturated monomer and the silicon-containing pressure sensitive adhesive composition in the presence of the initiator.

Abstract: Materials and methods are provided whereby polymers with least 0.5 mole % of the pendant group or end group containing —Si(OR?)3 are used to control aluminosilicate scaling in an industrial process having an alkaline process stream such as a pulping mill process stream or a high level nuclear waste processing plant. When materials of the present invention are added to the alkaline process stream, they reduce and even completely prevent formation of aluminosilicate scale on equipment surfaces such as evaporator walls and heating surfaces. The present materials are effective at treatment concentrations that make them economically practical.

Abstract: Disclosed is a moisture-curing type curable resin composition containing: a curable resin intramolecularly having a silicon-containing functional group; and a Lewis acid or a complex of the Lewis acid as a curing catalyst, the Lewis acid being selected from the group consisting of metal halides and boron halides, which is rapidly cured at room temperature. The silicon-containing functional group is represented by general formula: —SiX1X2X3 or —SiR1X1 X2 (wherein, X1, X2 and X3 respectively represent a hydrolytic group and may be the same as or different from each other, and R1 represents a substituted or unsubstituted organic group having 1 to 20 carbons). If the silicon-containing functional group is —SiR1X1 X2, the curable resin further contains intramolecularly a polar component that is one of urethane, thiourethane, urea, thiourea, substituted urea, substituted thiourea, amide, and sulfide bonds, and hydroxyl, secondary amino and tertiary amino groups.

Abstract: N-methylol-containing organosiloxane polymers further containing at least one Si-bonded N-hydrocarbyl-N-(methylol or methalkoxy)-hydrocarbyl group are storage stable and retain their ability to post-crosslink, and display excellent permanence on many substrates. They are particularly useful for the treatment of fibers, textiles, and leather.

Abstract: Disclosed is a room temperature curable silicon group-containing polymer composition containing a reactive silicon group-containing polymer (A) having a group represented by the formula (1) at an end of the main chain, which is obtained through a reaction between a polyoxypropylene polyol and a ?-isocyanate propyltrialkoxysilane, a curing catalyst (B), an amino-functional organosiloxane (C), and optionally an inorganic filler (D) which is surface-treated with glycol.

Abstract: A coating material is described herein that includes at least one inorganic compound, and at least one densifying agent, wherein the densifying agent increases the density of the coating material as compared to the density of the at least one inorganic compound. A method of producing a coating material is described herein that includes: providing at least one inorganic compound, providing at least one densifying agent, combining the at least one inorganic compound with the at least one densifying agent to form the coating material, wherein the densifying agent increases the density of the coating material as compared to the density of the at least one inorganic compound.

Abstract: A silicone-containing composition comprises the reaction product of a first component and an excess of an isocyanate component relative to the first component to form an isocyanated intermediary. The first component is selected from one of a polysiloxane and a silicone resin. The first component includes a carbon-bonded functional group selected from one of a hydroxyl group and an amine group. The isocyanate component is reactive with the carbon-bonded functional group of the first component. The isocyanated intermediary includes a plurality of isocyanate functional groups. The silicone-containing composition comprises the further reaction product of a second component, which is selected from the other of the polysiloxane and the silicone resin. The second component includes a plurality of carbon-bonded functional groups reactive with the isocyanate functional groups of the isocyanated intermediary for preparing the silicone-containing composition.

Abstract: Functional polymers having silyl end groups are prepared in a continuous process by polymer analogous reaction of a reactive polymer and inter-reactive silane. The polymer products are surprisingly uniform in properties and exhibit higher physicochemical properties as well.

Abstract: A vulcanizable rubber composition is presented that comprises an elastomer; a reinforcing filler selected from silica, carbon black, and mixtures thereof, a cure agent; and an amino alkoxy-modified silsesquioxane (AMS) comprising one or more compounds selected from the group consisting of an amino AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, mixtures thereof, and weak acid-neutralized solid and aqueous solutions thereof. Addition of such compounds to the rubber composition provides improved dynamic viscoelastic and mechanical properties of the vulcanized rubber compound and predict that tire components, especially tread stocks, will provide tires having improved snow traction, lower rolling resistance but equal wet traction, increased rebound, decreased hysteresis, and a general improvement in tire performance.

Abstract: The invention relates to a rollable tile structure, to a process for the production of the tile structure, and to the use of the tile structure in the production of a tiled covering. The invention relates further to the use of organic polysilazanes in the production of a rollable tile structure. The tile structure has a first carrier layer (1) and a surface layer (2), the surface layer (2) comprising a network of organic polysilazanes and the tile structure as a whole being in rollable form.

Abstract: Particles useful in curable coating systems are functionalized on their surface with a blocked isocyanate functionality. The blocked isocyanate is generated by reacting an organosilane having an oxygen, sulfur or nitrogen atom ? to the silyl group, or having a cyclic structure containing N or O in the ring, attached directly to silicon.

Abstract: Use of release fluids or agents constituting hyperbranched polymers. The three-dimensional structure imparts characteristics that make the hyperbranched polymers useful in xerographic processes. The hyperbranched polymer release fluids or agents may be used with a fuser member having a substrate, an outer layer covering the substrate, and a release coating on the outer layer, wherein the release coating includes a hyperbranched polymer.

Abstract: The invention concerns polyamino and/or polyammonium/polysiloxane copolymer compounds with polyalkylene oxide units in comb-shaped arrangement, a method for producing said compounds and their use, in particular for treating textiles and other natural or synthetic textile materials.

Abstract: Multicomponent silicone compositions which can be crosslinked via the click reaction and which, after mixing of the individual components, harden to give an elastomeric material contain: at least one compound (A) or (B), at least one compound (B) or (C), and at least one Cu catalyst (D), where (A) is an organic compound or an organosilicon compound which possesses at least two moieties having terminal aliphatic carbon-carbon triple bonds having terminally bonded hydrogen; (B) is an organic compound or an organosilicon compound which possesses at least two moieties having terminal aliphatic carbon-carbon triple bonds having terminally bonded hydrogen and simultaneously at least two moieties having carbon-bonded azide groups; (C) is an organic compound or an organosilicon compound which possesses at least two moieties having carbon-bonded azide groups.

Abstract: Polydiorganosiloxane polyamide, block copolymers having organic soft segments and methods of making the copolymers are provided.

Abstract: Disclosed is a light-emitting material including a polysilsesquioxane having a ladder structure with photoactive groups bonded to a siloxane backbone. In addition to superior heat resistance and mechanical property, the light-emitting material provides improved cotability and film property when prepared into a thin film. Further, it provides higher luminous efficiency than the existing organic-based light-emitting material.

Abstract: Compositions and methods for treating metal substrates and/or bonding metal substrates to polymeric materials, such as rubber, are provided. The compositions include at least one substantially hydrolyzed amino silane and at least one substantially hydrolyzed sulfur-containing silane Optionally, the compositions include a nano-size particulate material. The compositions provide coatings on metal substrates for protecting the metal from corrosion and for adhering rubber-like polymeric compositions to the metal with polymer-to-metal vulcanization conditions less dependent on the coating thickness, and with use of less coating materials.

Abstract: Two or multi-component condensation curing compositions can be cured in deep sections with low shrinkage, yet require no tin catalysts, or a significantly reduced tin catalyst level.

Abstract: Condensation crosslinkable compositions based on organosilicon compounds contain at least one heterocyclic compound A[CR12SiRa(OR2)3-a]x which contains at least one heteroatom from main groups 3 or 5 and is bonded to CR12 through one of these heteroatoms.

Abstract: A method for producing polymer particles, including (A) polymerizing and granulating a ring-opening polymerizable monomer in a compressive fluid with a catalyst in the presence of a surfactant, or (B) polymerizing and granulating an addition polymerizable monomer in a compressive fluid in the presence of a silicone surfactant.

Abstract: Storage stable compounds having at least two organopolysiloxane groups and at least one methylol group are useful as coatings on textile, paper, and other substrates, and are post-crosslinkable.

Abstract: Branched polydiorganosiloxane polyamide, block copolymers and methods of making the copolymers are provided. The method of making the copolymers involves reacting one or more amine compounds including at least one polyamine with a precursor having at least one polydiorganosiloxane segment and at least two ester groups.

Abstract: The invention relates to a use of a composition containing polyorganosiloxane S and a method of reducing corrosion on steel reinforcement in reinforced concrete constructions, and also a concrete structure which is produced using such compositions. It is highly suitable for the renovation of old concrete but also for inhibition of corrosion of reinforcing iron in fresh concrete.

Abstract: An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.

Abstract: The invention relates to ?-ethoxysilane modified polymers of the average general formula (I): in which R is a mono- to tetravalent polymer radical, not more than a third of the radicals R1, R2, and R3 present in the polymer of the formula (I), independently of one another, are alkyl radicals having 1 to 4 carbon atoms, at least a quarter of the radicals R1, R2, and R3 present in the polymer of the formula (I), independently of one another, are ethoxy radicals, any remaining radicals R1, R2, and R3, independently of one another, are methoxy radicals, and in which n is 1 to 4. The invention further relates to a process for preparing the polymers of the formula (I), and also to their use in adhesives, sealants, and coating materials.

Abstract: A polymeric material may be prepared by reacting a mixture comprising an amino functional polyorganosiloxane, polyisocyanate, and polyol. The polyol may comprise a hydroxy-functional poly(meth)acrylate. The polymeric material may be used as a coating for a substrate and may inhibit fouling on a surface exposed to aquatic conditions.

Abstract: The present invention provides one-component silicone compositions, particularly useful as sealants, having low modulus and high elongation, as well as good resistance to high temperatures and humidity, and methods for preparing these sealants. In particular, the present invention provides compositions including a chain-extended curable polyorganosiloxane, a high molecular weight silicone gum and a cure system. The compositions may be used, for example, in sealing the stitching of automotive airbags.

Abstract: Aqueous, storage-stable emulsions of ?-silyl terminated polymers are useful as adhesives, sealing compounds and coating materials. The ?-silyl terminated polymers correspond to the general formula (I): in which R1 is a linear or branched alkyl or alkoxy group containing 1 to 4 carbon atoms, R2 and R3 independently of one another are linear or branched alkyl groups containing 1 to 4 carbon atoms, R4 and R6 independently of one another are divalent organic connecting groups, R5 is a hydrophobic divalent polymer group; and R7 is a CH2SiR1(OR2)(OR3) group, in which R1, R2 and R3 have the above meaning or R7 stands for a group that lends the polymer of the general formula (I) the property of self-emulsification in water by forming an oil in water emulsion.

Abstract: [Problem] There is provided a curable composition having good curability and adhesion by use of a non-organotin catalyst. [Means to Solve] A curable composition comprising (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of from 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) in the composition to the total mole (b) of silicon atoms of the component (C) in the composition is more than 0.4.

Abstract: The present invention relates to a novel superconducting hybrid polymer material and to the preparation method and uses thereof, particularly for proton superexchange membranes usable as fuel cell electrolytes.

Abstract: To provide adhesive compositions for optical fibers which are curable with moisture and excellent in adhesiveness and resistance to moist heat. An Adhesive composition for optical fibers containing (A) a component having a reactive silicon containing group which contains (e) a compound obtained by reacting (a) an epoxy compound having at least one epoxy group with (b) a silane coupling agent having both a reactive silicon containing group and an epoxy-reactive group, wherein the component (A) has a molecular weight of 1000 or below per reactive silicon containing group; and an adhesive composition for optical fibers containing an alkylsilyl ester and (B) a compound other than the alkylsilyl ester which has at least one reactive silicon containing group.

Abstract: The invention relates to polysiloxanes of the general formula (I) [M?Dn]3T??(I), in which: M? is XSiY2O1/2 D is SiY2O2/2 T is SiZO3/2 and a process for the preparation thereof and their use as additives in aqueous surfactant-containing formulations.

Abstract: Disclosed herein are a nanocrystal-polydimethylsiloxane composite and a method for preparing the same. More specifically, provided are a nanocrystal-polydimethylsiloxane composite in which one or more polydimethylsiloxane derivatives having urea cross-links are bound to the surface of a nanocrystal, and a method for preparing the same. The nanocrystal-polydimethylsiloxane composite comprises optically transparent polydimethylsiloxane with remarkably high durability, thus imparting improved luminescence efficiency and product reliability to various electronic devices, when applied as a luminescent material to the electronic devices.

Abstract: Polybranched, particulate, organic/inorganic hybrid polymer in the form of a sol-gel product having the basic structure: Formula (I) where X is a linkage group chosen among C1-C18-alkylene and arylene, R1-R6 are chosen among hydrogen, C1-C18-alkyl, aryl, formyl, aliphatic or aromatic carbonyl, carbamoyl, sulphonyl, sulphoxyl, phosfonyl, sulphinyl or phosphinyl, or R1-R6 are chosen among condensation products and addition products of acids, alcohols, phenoles, amines, aldehydes or epoxides.

Abstract: Bottom antireflective coating (BARC) that exhibit enhanced wet strip rates, BARC compositions for fabricating such BARCs, and methods for manufacturing such BARC compositions are provided. According to one exemplary embodiment, a bottom antireflective coating (BARC) composition comprises an inorganic-based compound, an absorbing material, and a wet strip-rate modifier combination. The wet strip-rate modifier composition comprises a combination of a short chain linear alcohol and dipropylene glycol (DPG), a combination of the short chain linear alcohol and tetraethylene glycol (TEG), a combination of DPG and TEG, or a combination of the short chain linear alcohol, DPG, and TEG.

Abstract: A filler for filling a gap includes a hydrogenated polysiloxazane having an oxygen content of about 0.2 to about 3 wt %.

Abstract: Polydiorganosiloxane polyoxamide, linear, block copolymers and methods of making the copolymers are provided. The method of making the copolymers involves reacting a diamine with a polydiorganosiloxane precursor having oxalylamino groups. The polydiorganosiloxane polyoxamide block copolymers are of the (AB)n type.

Abstract: Organopolysiloxanes having aminoalkyl groups are prepared by (i) reacting (A) linear, cyclic or branched organopolysiloxanes with (B) aminoalkylsilanes which have an SiC-bonded, basic nitrogen-containing hydrocarbon radical and 2 or 3 hydrolyzable groups, or the partial or complete hydrolysis products thereof, optionally in the presence of (C) basic catalysts and/or (D) chain-terminating reagents, and (ii) optionally, after the reaction (i) neutralizing the optionally used basic catalysts (c), with the proviso that compounds (A), (B) and, when used, (D) are reacted continuously in a reaction space whose ratio of length to diameter is equal to or greater than four.

Abstract: Organosilicon compounds containing ?-ketoamide groups and organic polymer groups bound via enamine bonds are prepared by reaction of compounds bearing at least one ?-ketocarbonyl functionality with organosilicon compounds bearing aminoalkylaminoalkyl groups. The products have the same uses as siloxanes containing polyether and acetoacetate groups.

Abstract: The present Invention relates to a mixture comprising catenary, branched and for cyclic siloxanes of the general formula (I) where x is 1, 2 or 3, the substituents R are (i) organofunctional groups selected from —CH2—SH, —CH2—S—(CO)—R?, —CH2—(O—C2H4)a—OH with a=1 to 10, —CH2(O—C2H4)b—OR? with b=1 to 40, —(CH2)—NH2, —(CH2)—NHR?, —(CH2)—NR?2, —(CH2)—NH(CH2)2—NH2, —(CH2)—N[(CH2)2—NH2]2 and —(CH2)—NH(CH2)2—NH(CH2)2—NH2, In which R? is a linear, branched or cyclic alkyl group having 1 to 18 carbon atoms or an aryl group having 6 to 12 carbon atoms, (ii) hydroxyl, methoxy, ethoxy, 2-methoxyethoxy, isopropoxy, n-propoxy, isobutoxy and for n-butoxy groupe, and (iii) where appropriate, alkyl, alkenyl, isoalkyl, cycloalkyl or fluorcalkyl groups having 1 to 18 carbon atoms or aryl groups having 6 to 12 carbon atoms, whit the proviso that not more than one organofunctional group (i) is attached per silicon atom, the quotient of the molar ratio of the moiety (ii) to silicon le from I to 2, and the degree of oligornerizati

Abstract: New compositions and methods of using those compositions as bonding compositions are provided. The compositions are preferably thermoplastic and comprise imides, amideimides, and/or amideimide-siloxanes (either in polymeric or oligomeric form) dispersed or dissolved in a solvent system, and can be used to bond an active wafer to a carrier wafer or substrate to assist in protecting the active wafer and its active sites during subsequent processing and handling. The compositions form bonding layers that are chemically and thermally resistant, but that can also be softened to allow the wafers to slide apart at the appropriate stage in the fabrication process.

Abstract: An aqueous binder composition for a paint comprising an oligomeric or polymeric substance formed from at least one monomer of the general formula I: (R1O—)mSi(—NR2R3)4-m wherein at least one nitrogen radical within the group —NR2R3 is directly bonded to an Rz group, and Rz is —(C?O)R4 or —(C?O)—OR5.

Abstract: A process for providing interaction between particulate filler and a functionalized polymer involves a composition that includes at least three components: (1) a polymer that includes a functional group including an acidic cation of a primary or secondary amine functionality, (2) a material including a functionality capable of reacting with the acidic cation, and (3) particulate filler. The amine functionality from (1) is allowed to interact with (3) after being neutralized by the action of the acid-reactive functionality from (2). The process is useful in the formation of vulcanizates and articles made therefrom.

Abstract: The invention relates to high-functional polyisocyanates containing allophanate and silane groups, a method for their production and their use as a starting component in the production of polyurethane plastics, in particular as a crosslinker component in polyurethane paints and coatings.