Abstract: A method of analyzing a metal component contained as an impurity in a polymer composition that contains a polymer and an organic solvent including a step (i) of preparing a dispersion by mixing the polymer composition with an acid aqueous solution, a step (ii) of separating the dispersion prepared in the step (i) into a dispersoid layer containing the polymer and a dispersion medium layer containing the metal component, and a step (iii) of quantifying the metal component contained in the dispersion medium layer separated in the step (ii).

Abstract: A method for manufacturing a rubber-reinforced styrenic resin powder comprising 40% by mass or more of a rubbery polymer, satisfying the following conditions (1) to (4): (1) at least first and second coagulation baths are provided; (2) the first and second coagulation baths are connected; (3) an emulsified dispersion of fatty acid amide is supplied to the connecting part in an amount of 0.2 parts by mass to 2.0 parts by mass (solid content) with respect to 100 parts by mass (solid content) of a slurry; and (4) a temperature in the second coagulation bath is equal to or higher than a temperature in the first coagulation bath.

Abstract: The present disclosure relates the polymer compositions, fibers, and yarns having near-permanent antimicrobial activity, and a method of producing the same. In one embodiment, the antimicrobial polymer composition from 50 wt % to 99.9 wt % of a polymer, from 5 wppm to 1000 wppm of zinc, and from 0.005 wt % to 1 wt % of phosphorus, wherein fibers formed from the polymer composition demonstrate a zinc retention rate of greater than 20% when tested in a dye bath test.

Abstract: Residual hydrogenation catalyst produced from reduction of nitrile rubber is recovered by a chelation step using a chelating agent and a series of extraction using semi-coagulation with polar solvents and an optional washing steps for the separation of catalyst-chelating agent complex from hydrogenated nitrile rubber solution. The chelating agent is selected from xanthate, dithiocarbamate, and trithiocarbonate compounds.

Abstract: A method for reducing outgassing of a polyester composed of repeat units derived from 1,4-butanediol is melt blending the polyester with 0.2 to 2 weight percent water, based on the weight of the polyester. In addition to water, the polyester can also be blended with 0.01 to 0.5 weight percent of a quencher. The method results in formation of a polyester composition which exhibits reduced outgassing, and is suitable for molding into articles, for example an automotive headlight reflector or bezel.

Abstract: The present invention relates to a process for efficiently enriching and recovering noble metals of platinum and palladium based on solvent extraction, wherein isoamyl alcohol is used as extracting agent and 2-methoxyphenyl thiourea is used as extraction-assisted complexing agent. 2-methoxy-phenyl thiourea is added to aqueous phase to react with platinum and palladium, and isoamyl alcohol is used as extracting agent to extract the organic phase, thus realizing the purpose of separating and extracting noble metals from base metals while enriching noble metals of platinum and palladium. The present invention, which can not only realize the separation of noble metals and base metals, but also enhance the enrichment and recovery ratios of noble metals of platinum and palladium, with low cost reagents, small influence on the environment and simple technical process, thus is a new and efficient extraction and enrichment system for noble metals.

Abstract: The present invention relates to new condensation resins formed from urea, formaldehyde and CH-acidic aldehydes, to processes for preparing them, and to use thereof.

Abstract: The present invention relates to a process for preparing high-functionality polyetherols by reacting at least one trifunctional or higher-functionality alcohol and if appropriate further di- and/or monofunctional alcohols and/or modifying reagents, with the aid of acidic catalysts, where the trifunctional or higher-functionality alcohol is not glycerol. The present invention further relates to high-functionality polyetherols obtainable by such a process and to the use of these high-functionality polyetherols as adhesion promoters, thixotropic agents, rheology modifiers of polymers, phase transfer reagents, micro- or nanocontainers for biologically active compounds, for example for active medical ingredients, biocides, herbicides or fungicides, as pigment dispersants, an additive in printing inks or as structural units for preparing polyaddition or polycondensation polymers or for treatment of seed.

Abstract: The present invention provides nano-sized particles of melanin, and the method for formation of the melanin particles comprise the following steps: adding a base to a dopamine.H+X?-containing solution (wherein H+X? is an acid) and allowing an acid-base neutralization reaction; and forming nano-sized particles of melanin by controlling the addition of nucleic dopamine.H+X? (a) to base (b) at a ratio of a:b=1:0.1-1, and allow concurrent or consecutive formation of melanin by oxidation curing of the dopamine in air (polymerization). The manufacturing method according to the present invention can produce nano-sized melanin particles in a short period of time. Furthermore, the nano-sized melanin particles made according to the present invention are distinctive from conventional solvents containing dispersions of natural melanin and synthetic melanin, and have excellent application in various fields.

Abstract: Provided herein are methods for preparing vinylidene-terminated polyolefins. Further provided herein are sulfide-terminated polyolefins.

Abstract: Disclosed is a method for preparing a phosphorus-containing polyphenylene oxide resin with a low molecular weight, comprising the steps of: step 1: providing a phosphorus-containing phenolic compound and a raw polyphenylene oxide resin having a number-average molecular weight of more than 10000; step 2: dissolving the raw polyphenylene oxide resin into a solvent to make a solution of the raw polyphenylene oxide resin; step 3: adding the phosphorus-containing phenolic compound into the solution of the raw polyphenylene oxide resin; step 4: introducing an initiator, and carrying out a re-dispersing reaction at a reaction temperature of above 60° C. under the effect of the initiator; and step 5: after the reaction is finished, the product obtained being phosphorus-containing polyphenylene oxide resin with a low molecular weight, the number-average molecular weight thereof being 1000-6000.

Abstract: A process for forming a vulcanized elastomer composition. An alternating electric field is applied to a first composition comprising vulcanized crosslinked elastomer particles while the composition is compressed to thereby devulcanize the crosslinked elastomer particles and form a second composition comprising devulcanized elastomer particles A crosslinking agent is added to the second composition comprising the devulcanized elastomer particles. The second composition having the crosslinking agent is then vulcanized to form the vulcanized elastomer composition.

Abstract: Disclosed are flexible polyamines, flexible amine-terminated polyformal adducts, flexible-amine-terminated polythioether adducts, compositions comprising flexible polyamines and isocyanate-terminated prepolymers, and compositions comprising flexible amine-terminated adducts and isocyanate-terminated prepolymers. Uses of the compositions as sealants, and particularly as aerospace sealants, are also disclosed.

Abstract: The present invention provides a method for depolymerization of a mixture comprising oligomeric cyclic ethers resulting from copolymerization of at least one tetrahydrofuran and at least one other cyclic ether to recover tetrahydrofuran monomer.

Abstract: An abrasive product includes a plurality of abrasive particles and a resin cured with a polythiol group. A method of preparing the abrasive product includes contacting the plurality of abrasive particles with a curable composition that includes a resin and a polythiol group, and curing the curable composition to produce the abrasive product. A method of abrading a work surface includes applying an abrasive product to a work surface in an abrading motion to remove a portion of the work surface. A curable composition includes a formaldehyde resin and a polythiol group. A formaldehyde resin is crosslinked by a polythiol group. A method of crosslinking the formaldehyde resin includes reacting the polythiol group with the formaldehyde resin.

Abstract: A novel process for producing a polyamidoamine-epihalohydrin resin composition comprises (a) reacting a polyamidoamine with epihalohydrin to obtain a reaction mixture comprising a polyamidoamine-epihalohydrin resin; (b) adding a first acid to the reaction mixture obtained in step (a) to obtain an acid treatment composition; (c) adding a base to the acid treatment composition in step (b) to obtain a base treatment composition; and (d) adding a second acid to the base treatment composition in step (c) to obtain a polyamidoamine-epihalohydrin resin composition; wherein the polyamidoamine-epihalohydrin resin composition obtained in step (d) has less than about 700 ppm of dihalopropanol (DHP) and 3-halopropanediol (HPD).

Abstract: The present invention provides an aliphatic polycarbonate production method which, using carbon dioxide and an epoxide, easily produces aliphatic polycarbonates having a low metal catalyst content. The invention relates to an aliphatic polycarbonate production method which includes a step of polymerization by reacting carbon dioxide with an epoxide in the presence of a metal catalyst; and a step of treating a polymer obtainable in the polymerization step with a surfactant. High-purity aliphatic polycarbonate having a low metal catalyst content can be easily provided by the aliphatic polycarbonate production method of the invention.

Abstract: The present invention relates to novel polyazoles, a proton-conducting polymer membrane based on these polyazoles and its use as polymer electrolyte membrane (PEM) for producing membrane-electrode units for PEM-fuel cells, and also other shaped bodies comprising such polyazoles.

Abstract: Provided herein are methods for preparing vinylidene-terminated polyolefins. Further provided herein are sulfide-terminated polyolefins.

Abstract: A process for devulcanizing crosslinked elastomer particles comprising applying an alternating electric field to a composition comprising crosslinked elastomer particles under compression. The alternating electric field preferably has a frequency between 1 and 100 MHz and a voltage between 1000 and 10,000 V, and may be applied between an apparatus that continuously conveys the particles through the field.

Abstract: The present invention is related to palladium complexes having substituted diarylideneacetone ligands and coupling and polymerization processes thereof.

Abstract: Provided herein are methods for preparing vinylidene-terminated polyolefins. Further, provided herein are novel sulfide-terminated polyolefins of the formula: wherein R1 is a polyolefin group and R2 is hydrocarbyl; and methods for producing the same.

Abstract: A process for devulcanizing crosslinked elastomer particles comprising applying an alternating radio frequency dielectric field to a composition comprising crosslinked elastomer particles. The alternating radio frequency dielectric field preferably has a frequency between 1 and 100 MHz and a voltage between 1000 and 10,000 V.

Abstract: The invention relates to a biocompatible, non-biodegradable, and non-toxic polymer of formula (I), comprising of three monomeric units, selected from 1-Vinylpyrrolidone (VP), N-Isopropylacrylamide (NIPAM), and ester of Maleic anhydride and Polyethylene glycol (MPEG), cross-linked with a bi-functional vinyl derivative, of high purity and substantially free of respective toxic monomeric contaminants, and a process for preparation thereof. The invention further relates to nanoparticulate pharmaceutical compositions of poorly water-soluble drugs or compounds comprising the polymer of the invention, which are safe, less-toxic and convenient for bedside administration to patients in need thereof. Furthermore, the invention relates to a highly selective method for preparation of nanoparticulate pharmaceutical compositions of poorly water-soluble drugs or compounds.

Abstract: A process for the preparation of functional molecules using the thiol-ene coupling reaction and a process for the preparation of protected functional thiols, specifically thioesters is provided. The methods may be used to make functional polymers and other molecules. The method of making a functionalized polymer using a thiol-ene reaction comprises: providing a functionalized thioester having the following formula: wherein R is a functional group and COR? is a protecting group; cleaving the functionalized thioester, forming a functional thiol and an acyl group; providing a polymer having a pendant vinyl group; and reacting the polymer with the functional thiol whereby a functionalized polymer is formed, wherein the functional thiol is not isolated prior to reacting with the polymer.

Abstract: Polyester compositions based on 1,3-propanediol and aromatic and aliphatic diacids that can contain a large fraction of biologically derived content are disclosed. Transesterification between polyesters in blends of such compositions is greatly reduced using phosphorous-containing additives. The blends have properties similar to poly(ethylene terephthalate).

Abstract: The method comprises chemical modification of an optionally metallized polymer surface, for example a polycarbonate surface or a polymethacryllate surface functionalized with amino groups, said surfaces being optionally metallized, by treating said polymer surface with a mercaptoalkanoic acid or the salts or derivates thereof. The surfaces obtained by said method may be used as solid supports for immobilizing biomolecules, such as nucleic acids, proteins or membranes.

Abstract: The present invention is directed to conjugates of hydrolytically stabilized maleimide-functionalized water soluble polymers and to methods for making and utilizing such polymers and their precursors.

Abstract: Methods of forming materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity. In the preferred embodiment, additives are added to a solution containing a solvent and the precursor or electrically conductive polymer. The additives are preferably plasticizer of diluents. As the solvent is removed the material dries and contains a higher degree of crystallinity than in the absence of the additive.

Abstract: Provided herein are methods for preparing vinylidene-terminated polyolefins. Further, provided herein are novel sulfide-terminated polyolefins of the formula: wherein R1 is a polyolefin group and R2 is hydrocarbyl; and methods for producing the same.

Abstract: A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO—, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

Abstract: Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.

Abstract: Objects of the present invention are to provide a purification process that enables Pd contained in an organic electronics material to be removed effectively, to provide an electroluminescent device middle layer material purified by the process, and to provide an electroluminescent device employing the middle layer material. The present invention relates to a process for purifying an organic electronics material, the process involving treating, with a phosphorus-containing material, an organic electronics material that contains Pd as an impurity so as to remove the Pd.

Abstract: A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO—, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

Abstract: A method for producing a polyether-polyol having a narrow molecular weight distribution, which comprises carrying out selective fractional extraction of the low-molecular weight component from a polyether-polyol (A) having an average molecular weight of from 500 to 4500 represented by formula (1): HO—[(CH2)4O]n—[(CR1R2)pO]q—H??(1) wherein R1 and R2, which may be the same or different, each represents a hydrogen atom or a linear or branched alkyl group having from 1 to 5 carbon atoms; n indicates a positive integer; p indicates an integer of from 1 to 8; and q indicates 0 or a positive integer, by the use of an aqueous solution (C) containing from 15 to 70 wt % sulfuric acid at a room temperature to 100° C., to thereby suitably determine the amount of the aqueous sulfuric acid solution to the overall organic layer and the sulfuric acid concentration in accordance with the molecular weight and molecular weight distribution of the intended polyether-polyol to be fractionally extracted.

Abstract: The present invention relates to a precipitation process for removing transition metals from polymer solutions. Specifically, it comprises the removal of transition metal complexes which usually comprise copper from polymer solutions after a completed atom transfer radical polymerization.

Abstract: A catalytic lactide and glycolide copolymerization system comprising a trifluoromethane sulfonate as a catalyst and copolymerization additive and a copolymerization process.

Abstract: A process for producing a crosslinked type or non-crosslinked type layered metal phosphonate compound including a reaction step of reacting two or more members selected from organic diphosphonic acids or monophosphonic acids, or derivatives thereof having predetermined conditions and a metal source capable of forming an ion of a hexacoordinate metal atom as a central atom (M) of a metal oxide octahedron upon reaction under the presence of a sulfuric acid catalyst, a crosslinked or non-crosslinked metal phosphonate compound obtained by the process, as well as a stock solution used for the synthesis of the crosslinked or non-crosslinked type layered metal phosphonate compound described above.

Abstract: The invention relates to a method for preparing halogen-free flameproof epoxy resins, in which a halogen-free epoxy resin is reacted with a polyfunctional aldehyde or ketone and a phosphinic acid derivative, wherein the phosphinic acid derivative contains at least one P—H-active structural unit of the formula ?PH(O) and is used in an amount equivalent to the polyfunctionality of the aldehyde or ketone, to a halogen-free flameproof epoxy resin obtainable by this method, to the use of the epoxy resin as a base material for the manufacture of printed circuit boards and printed circuits and to intermediates used to prepare the epoxy resins.

Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.

Abstract: The present application provides novel nitrile rubbers comprising repeating units of at least one ?,?-unsaturated nitrile, at least one conjugated diene and optionally one or more further copolymerizable monomers which nitrile rubbers are distinguished by a specific calcium content as well as a specific chlorine content and dispose of specific thio end groups. Additionally, an improved polymerization and work-up process is provided to produce the aforementioned nitrile rubbers.

Abstract: Disclosed is a method for removing a metallic compound catalyst residue from a polymer solution which is prepared in the presence of a catalyst containing metal of Group 10 using a thiourea compound, a polymer from which the metallic compound catalyst residue is removed using the method, and a film produced using the method.

Abstract: A process for producing a polythiourethane resin which comprises (A) a step of synthesizing a polythiol oligomer having disulfide bond by reaction of a polythiol compound having a functionality of two or greater and sulfur and (B) a step of bringing the polythiol oligomer obtained in step (A) and a compound having poly(thio)isocyanate groups into reaction with each other, wherein step (A) is conducted in the absence of solvents using no catalysts or a catalyst substantially inert to the compound having poly(thio)isocyanate groups. A polythiol oligomer exhibiting a greater refractive index than that of the polythiol compound having a functionality of two or greater used as the starting material is produced at a low cost, and a process for producing a practically useful polythiourethane resin exhibiting a stable great refractive index and a great Abbe number is provided.

Abstract: The present invention is directed to methods of preparing linear polymers such as polyalkylene oxides containing a terminal amine in high purity. One preferred method includes reacting a polyalkylene oxide such as polyethylene glycol containing a terminal azide with a phosphine-based reducing agent such as triphenylphosphine or an alkali metal borohydride reducing agent such as sodium borohydride in a solvent to reflux. The resultant polymer-amines are of sufficient purity so that expensive and time consuming purification steps required for pharmaceutical grade polymers are avoided.

Abstract: The invention embraces polyester resins and containers that include surface-modified talc. The invention also embraces a method for the late introduction of surface-modified talc via a reactive carrier to achieve a polyester resin that is capable of being formed into low-haze, high-clarity bottles possessing reduced coefficient of friction.

Abstract: The invention relates to a method enabling the ambient-temperature spinning of ligning originating from Alcell- and Organosolv-type extraction processes. The invention also relates to a method and device for the ambient-temperature production of lignin fibres of micro- and nanometric diameter, by means of electrospinning and co-electrospinning. The resulting fibres can be single strand (electrospinning) and hollow or coaxial (co-electrospinning) fibres. The lignin fibres are transformed into carbon nanofibres after a suitable heat treatment.

Abstract: A process for altering the shape of a polymer particle is disclosed. The process comprises suspending polymer particles in a suspending medium at a temperature that effects melting of the polymer and agitating the suspension for a time sufficient to change the shape of the particles. The shape altered particles are combined with a pharmaceutically acceptable agent to give a drug delivery particle system.

Abstract: The present invention relates to a method of surface cross-linking superabsorbent polymer particles using UV irradiation. The superabsorbent polymer particles for use in the method of the present invention have a relatively high degree of neutralization. Bronsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.

Abstract: The present invention relates to a method for preparing a high molecular weight latex resin powder, and more precisely, a method for preparing a high molecular weight latex resin powder which comprises the steps of preparing a slurry by coagulating a high molecular weight latex; stabilizing the slurry; and aging the stabilized slurry, and is characterized by the direct addition of a colloidal modifier to the high molecular weight latex reactant during the preparation of the slurry. According to the present invention, the high molecular weight latex resin powder prepared by the method of the present invention has excellent particle size distribution, apparent specific gravity, caking property and thermo-stability, even with high solid content, compared with the conventional slow coagulation, and at the same time the method has an advantage of reducing energy costs and waste water generation.