Spray Drying Or Atomization Patents (Class 528/502E)
  • Patent number: 6133345
    Abstract: The invention provides for a process for preparing pulverulent polymers by drying aqueous polymer dispersions in the presence of copolymers based on ethylenically unsaturated C.sub.3 -C.sub.6 carboxylic acids and their hydroxyalkyl esters as assistants;polymer powders obtainable by this process;aqueous polymer dispersions obtainable by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of the novel copolymers, and the powders obtainable therefrom, anda polymeric binder as well as and mineral building materials which comprise the novel polymer powders.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: October 17, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Maximilian Angel, Peter Claassen, Andree Dragon
  • Patent number: 6114414
    Abstract: Systems, apparatus combinations and methods for producing a powder coating are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.
    Type: Grant
    Filed: June 25, 1997
    Date of Patent: September 5, 2000
    Assignee: Morton International, Inc.
    Inventors: Andrew T. Daly, Owen H. Decker, Karl R. Wursthorn, Frank R. Houda, Leo T. Grundowski, Carl W. Ernst
  • Patent number: 6080804
    Abstract: Processes for producing free flowing, Mannich and glyoxal polyacrylamide water soluble and water-swellable granules from a water-in-oil emulsion and compositions comprising such dry polymer granules are disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 27, 2000
    Assignee: Cytec Technology Corp.
    Inventors: William Bloor Davies, Gary Kaui Lani Miller
  • Patent number: 6075074
    Abstract: Systems, apparatus combinations and methods for producing a coating powder are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: June 13, 2000
    Assignee: Morton International, Inc.
    Inventors: Andrew T. Daly, Owen H. Decker, Karl R. Wursthorn, Frank R. Houda, Leo T. Grundowski, Carl W. Ernst
  • Patent number: 6028167
    Abstract: Phenolsulfonic acid-formaldehyde condensates are used as assistants in the drying of aqueous polymer dispersions.Also described are a process for preparing polymer powders by drying, using these condensates; the polymer powders obtainable by the process; and their use as binders.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: February 22, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Maximilian Angel, Joachim Roser, Andree Dragon, Heinrich Sack
  • Patent number: 5981696
    Abstract: The invention concerns a process for preparing coating powder compositions in which one or a plurality of base resins and one or a plurality of hardeners, each of which is in solid form, is dissolved with a low-molecular compound above its critical pressure and critical temperature. This low-molecular compound is inert with respect to the base resins and hardeners and is in gaseous form under normal operating conditions with respect to pressure and temperature. The pressure of the resultant solution is then reduced, for example, by spraying. The resultant coating powder composition can be sprayed directly onto a substrate to be coated. Coating powders can also be recycled according to the process of the invention.
    Type: Grant
    Filed: February 10, 1997
    Date of Patent: November 9, 1999
    Assignee: Herberts GmbH
    Inventors: Dietrich Saatweber, Karin Maag, Wolfgang Diener, Peter Klostermann, Thomas Berger
  • Patent number: 5981653
    Abstract: The present invention relates to a process for the production of aqueous dispersions which form powder coatings at room temperature, have an average particle size of 0.1 to 10 .mu.m, contain polyols and blocked polyisocyanate crosslinking agents, and, after stoving, yield coatings with improved water and solvent resistance, in particular on metallic substrates.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: November 9, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Oswald Wilmes, Lothar Kahl, Bernd Klinksiek, Christian Wamprecht, Manfred Bock, Klaus Nachtkamp
  • Patent number: 5879796
    Abstract: This invention concerns an organic/inorganic composite in particulate form prepared by spray drying a solution or dispersion comprising an organic polymer and an inorganic glassy polymer precursor under such conditions that the inorganic glassy polymer precursor forms an inorganic glassy polymer to yield the particulate. Such particulates are useful as reinforcing agents for polymers and in monolithic structures prepared by compression of a plurality of said particulates.
    Type: Grant
    Filed: August 8, 1997
    Date of Patent: March 9, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Israel A. David
  • Patent number: 5849862
    Abstract: Processes for spray drying water-soluble and water-swellable vinyl-addition polymer-containing dispersions, emulsions and microemulsions to obtain substantially dry water-soluble or water-swellable polymer particles, compositions of substantially dry water-soluble or water-swellable polymer particles, methods of agglomerating spray-dried polymer particles, and methods of using spray-dried polymer particles and agglomerates in water-treating, mining, paper, food processing, soil conditioning, solution thickening, biotechnological, and oil recovery applications are disclosed.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: December 15, 1998
    Assignee: Cytec Technology Corp.
    Inventors: William Bloor Davies, John Edward Healy, Gary Kaui Lani Miller, Joseph J. Kozakiewicz
  • Patent number: 5767231
    Abstract: A method for lowering the residual monomer content of non-vitrified processing aids for thermoplastic polymers involves subjecting an emulsion polymerizate containing methylmethacrylate and, optionally, up to 50% by weight of a comonomer to a post-catalysis step to reduce the residual monomer content followed by a spray-drying step where the residual monomer content is further reduced. The spray-drying step is performed at an exit temperature which is either above the boiling point of methylmethacrylate or if an optional comonomer is present which has a higher boiling point than methacrylate, at a temperature above the boiling point of the comonomer. The resulting product which is suitable for use as a non-vitrified processing aid has a residual monomer content of 100 ppm or less. The processing aid can be used with thermoplastics to form containers, e.g., beverage bottles of PVC, which would not adversely affect odor or taste of the contained food product.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: June 16, 1998
    Assignee: Agomer Gesellschaft Mit Beschrankter Haftung
    Inventors: Volker Schull, Detlef Arnoldi
  • Patent number: 5723518
    Abstract: A method is described for the preparation of aqueous coating compositions based on resin binders containing isocyanate-reactive hydrogen atoms and polyisocyanates, by mixing the components with water, wherein the mixture is forced at a pressure of from 1 to 30 MPa through a nozzle of small size in at least one dimension.
    Type: Grant
    Filed: January 6, 1997
    Date of Patent: March 3, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Lothar Kahl, Bernd Klinksiek, Dieter Schleenstein, Manfred Bock, Nusret Yuva
  • Patent number: 5696228
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: December 9, 1997
    Assignee: Cytec Technology Corp.
    Inventor: Michael W. Coville
  • Patent number: 5606015
    Abstract: A method for improved polymer powder stability is provided, particularly spray-dried emulsion polymers, by spray-drying emulsion polymers with selected low HLB surfactants. Stable spray-dried emulsion polymers are particularly useful as cement modifiers.
    Type: Grant
    Filed: February 16, 1995
    Date of Patent: February 25, 1997
    Assignee: Rohm and Haas Company
    Inventors: Shang J. Chiou, Miao-Hsun L. Sheng
  • Patent number: 5554707
    Abstract: A granular vinyl chloride resin having a mixture comprising the following vinyl chloride resin particles (A), (B) and (C) as main components granulated to have a spherical shape with a diameter of from 50 to 300 .mu.m or a cylindrical shape with a diameter of from 0.1 to 20 mm:(A) from 90 to 10% by weight of fine particles with diameters within a range of not larger than 3 .mu.m (hereinafter referred to as fine particles (A)),(B) from 10 to 90% by weight of particles with diameters within a range of from 5 to 65 .mu.m (hereinafter referred to as particles (B)), and(C) from 0 to 10% by weight of particles with diameters other than those of particles (A) and (B).
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: September 10, 1996
    Assignee: Mitsubishi Chemical MKV Company
    Inventors: Tokio Niikuni, Yukio Noro
  • Patent number: 5475084
    Abstract: A process for the production of a polycarbonate powder comprising introducing an organic solvent solution of polycarbonate and steam into a mixing nozzle and obtaining the polycarbonate powder from a mixture ejected from the mixing nozzle, wherein the organic solvent solution contains 3 to 45% by weight of the polycarbonate, and the ratio of the weight of steam/the weight of an organic solvent in the organic solvent solution is 1/10 to 1/5.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: December 12, 1995
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Masaya Okamoto, Noriyuki Kunishi
  • Patent number: 5449747
    Abstract: A method for producing a vinyl chloride resin, which comprises spray drying a vinyl chloride polymer latex by means of a double fluid nozzle, wherein steam or a gas mixture of steam and an inert gas is used as spray gas.
    Type: Grant
    Filed: November 3, 1993
    Date of Patent: September 12, 1995
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Sadaki Kuroda, Hideo Aritake, Tokio Niikuni
  • Patent number: 5426137
    Abstract: Apparatus and method of hydrating a particulated polymer and producing a well treatment gel includes a mixer for spraying the polymer with water at a substantially constant water velocity and at a substantially constant water spray pattern at all flow rates of the water. A centrifugal diffuser is connected to the mixer for receiving the mixture, centrifugally diffusing the motive energy of the mixture, and hydrating the mixture into a gel. A centrifugal separator and constant velocity jet pump may be connected between the mixer and the centrifugal diffuser. A dilution valve is connected to the discharge of the centrifugal diffuser for mixing water with the gel at a substantially constant mixing energy at all flow rates of the gel and producing a diluted gel. A viscometer may be connected to the discharge of the dilution valve for measuring the viscosity of the diluted gel and regulating the flow of gel from the centrifugal diffuser to the dilution valve in order to control the viscosity of the diluted gel.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: June 20, 1995
    Assignee: Halliburton Company
    Inventor: Thomas E. Allen
  • Patent number: H1839
    Abstract: A process for the preparation of toner additive wax particles which comprises the micronization of said particles from a supercritical solution.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: February 1, 2000
    Assignee: Xerox Corporation
    Inventors: James R. Combes, Samir Kumar, Lewis S. Smith, Hadi K. Mahabadi, Peter G. Odell