With Reactant Compound Containing At Least Two -c-c(=x)-x-c Groups And Which Compound Is Devoid Of C-nh, C=nh Or C-n(h)-h Groups Patents (Class 528/80)
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Patent number: 11981769Abstract: A polyurethane foam is obtained by foaming a blend containing a polyol and a polyisocyanate. The polyol contains a polycarbonate diol that has a polyester structure and a polycarbonate diol obtained by developing a polymerization reaction using 1,5-pentanediol and 1,6-hexanediol. The polyurethane foam has a density from 0.1 to 0.4 g/cm3.Type: GrantFiled: September 19, 2019Date of Patent: May 14, 2024Assignee: The Yokohama Rubber Co., Ltd.Inventors: Yutaro Yamamoto, Kazushi Kimura, Hirokazu Kageyama
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Patent number: 11980805Abstract: A method of installing a binder-based overlay system may include contacting a layer of geotextile fabric to a surface of a substrate and applying a primer layer to a surface of the geotextile fabric. Two or more binder layers including infill particles may be applied over the primer layer. A resurfacer layer followed by one or more color layers may be applied over the two or more binder layers. The primer layer, one or more binder layers, resurfacer layer, and two or more color layers may cure upon application to form a monolithic layer upon the substrate.Type: GrantFiled: October 26, 2022Date of Patent: May 14, 2024Assignee: RS Sports Surfaces, LLCInventors: Timothy Sadick, David Rich
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Patent number: 11926701Abstract: The present invention relates to novel high-value polycarbonate polyols, to processes for the production thereof, to polyisocyanate prepolymers obtainable therefrom and also polyurethane (PUR) and polyurethane urea elastomers which under particularly demanding applications show unique combinations of processing characteristics, hydrolysis and oxidation stability, mechanical and dynamic mechanical properties.Type: GrantFiled: December 12, 2018Date of Patent: March 12, 2024Assignee: Covestro Deutschland AGInventors: Hartmut Nefzger, Harald Knaup, Hans-Peter Huber, Andreas Stumpf, Stephan Reiter
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Patent number: 11814476Abstract: A polyester elastomer resin composition having excellent anti-noise properties and wear resistance that achieves sustained wear resistance over a long period of time; enables lubricants to bleed out even in a low-temperature environment, so that the effects of the lubricants are maintained; and further prevents the lubricants from being dissolved in water, even when a molded article is washed with water.Type: GrantFiled: December 6, 2018Date of Patent: November 14, 2023Assignee: TOYOBO MC CORPORATIONInventors: Yuki Maeda, Takuya Akaishi
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Patent number: 11814551Abstract: The present disclosure relates to an adhesive composition and a method of manufacturing a nonpneumatic tire using the same, and more specifically, to an adhesive composition comprising a linear structured prepolymer for polyurethane having a cyclic carbonate group at both ends thereof and a polyfunctional amine, and a method of manufacturing a nonpneumatic tire using the same.Type: GrantFiled: December 10, 2019Date of Patent: November 14, 2023Assignee: Hankook Tire & Technology Co., Ltd.Inventors: Seokju Choi, Daeil Lee
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Patent number: 11807754Abstract: A thermosetting urethane resin composition having excellent self-healing properties, antifouling properties, and elongation, a film including a curable coating of the thermosetting urethane resin composition, and a product including the film are provided. The thermosetting urethane resin composition contains a main agent containing a urethane prepolymer and an organic solvent and a curing agent. The urethane prepolymer contains a composition containing a polyol, a polyisocyanate, and a chain extender and has a hydroxy group at an end. The polyol contains a polyol having no aromatic ring. The polyol having no aromatic ring contains liquid and solid polycarbonate polyols. The polyisocyanate contains a polyisocyanate having no aromatic ring. The chain extender contains a low molecular weight triol. The curing agent contains triisocyanate. The percentage of the total amount of the low molecular weight triol and the triisocyanate is 10 mass % or higher and 35 mass % or lower.Type: GrantFiled: November 1, 2018Date of Patent: November 7, 2023Assignee: DIC CorporationInventors: Daichi Higuchi, Yuichiro Shiba
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Patent number: 11787983Abstract: A description is given of a method of making film laminates using a lamination adhesive comprising (a) at least one acrylic polymer A with anhydride groups which are reactive with primary or secondary amine groups; and (b) at least one compound B with at least two amine groups selected from primary and secondary amine groups. The acrylic polymer A has a molecular weight of from 3000 to 50000 and the lamination adhesive is free of organic solvents, free of water and free of compounds with isocyanate groups.Type: GrantFiled: August 10, 2020Date of Patent: October 17, 2023Assignee: BASF SEInventors: Karl-Heinz Schumacher, Matthias Gerst, Peter Preishuber-Pfluegl, Kevin Payne, Timothy Klots
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Patent number: 11767439Abstract: Cellulose-based composite material comprising an electrically conductive material dispersed in a matrix comprising at least one plant-derived protein and a polymer of aleuritic acid, said composite material being obtainable by a process comprising the steps of dissolving at least one plant-derived protein and aleuritic acid in a dissolving solution to achieve a first mixture, dispersing an electrically conductive material in said first mixture to achieve a conductive ink, distributing said conductive ink on at least one side of a cellulose substrate to achieve a coated cellulose substrate, hot-pressing said coated cellulose substrate to obtain i) impregnation of the cellulose substrate with said conductive ink and ii) polymerization of aleuritic acid.Type: GrantFiled: July 19, 2019Date of Patent: September 26, 2023Assignee: Fondazione Istituto Italiano di TecnologiaInventors: Ilker S. Bayer, Pietro Cataldi, Athanasia Athanasiou
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Patent number: 11746267Abstract: The present disclosure provides a two-component solvent-based adhesive composition. The two-component solvent-based adhesive composition contains the reaction product of (A) an isocyanate component; (B) a polyol component containing a polyester-amide polycarbonate polyol; and (C) a solvent. The present disclosure also provides a method of forming the two-component solvent-based adhesive composition.Type: GrantFiled: March 4, 2020Date of Patent: September 5, 2023Inventors: Tuoqi Li, Joseph J. Zupancic, Matthew M. Yonkey, Paul G. Clark, Thorsten Schmidt, Ken Kawamoto, Wenwen Li
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Patent number: 11560450Abstract: The present invention relates to an aliphatic-aromatic polyester having a whiteness index according to ASTM E 313-73 of at least 25, to a process for preparation thereof and to the use of the aliphatic-aromatic polyester for production of polyester fibers (PF). The present invention further relates to the polyester fibers (PF) comprising the aliphatic-aromatic polyester.Type: GrantFiled: May 22, 2018Date of Patent: January 24, 2023Assignee: BASF SEInventors: Klaus Scheuermann, Robert Loos, Andreas Garbe, Kevin Müller
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Patent number: 11479630Abstract: Provided is a prepeg resin composition, containing: a urethane (meth)acrylate (A) that is a reaction product of polyisocyanate (a1), polyol (a2), and hydroxy alkyl (meth)acrylate (a3); and a polymerization initiator (B), as an essential component, in which the polyisocyanate (a1) is at least one polyisocyanate selected from 2,4?-diphenyl methane diisocyanate, 4,4?-diphenyl methane diisocyanate, a carbodiimide modified product of 4,4?-diphenyl methane diisocyanate, and polymethylene polyphenyl polyisocyanate, and the polyol (a2) has an aromatic-ring and an oxyalkylene structure. The prepreg resin composition of the invention is excellent in workability and molding properties, and is capable of forming a molded article excellent in various physical properties such as external appearance and heat resistance, and thus, can be preferably used in a prepreg and a molded article thereof.Type: GrantFiled: September 11, 2018Date of Patent: October 25, 2022Assignee: DIC CorporationInventors: Yuko Takikawa, Tomoaki Shinchi
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Patent number: 11396574Abstract: The disclosure relates to a self-healing omniphobic composition including a self-healing omniphobic polymer with a crosslinked backbone. The crosslinked backbone includes a reaction product between a polyisocyanate, a functionalized omniphobic polymer reactive therewith, a reversible polyfunctional linker including a hindered secondary amino group and/or an aromatic hydroxy group, and one or more polymeric backbone components. The crosslinked backbone includes reversible urea or reversible urethane bonds between the reversible polyfunctional linker and the polyisocyanate, which in turn provide self-healing properties to the omni-phobic composition. The self-healing omniphobic composition has favorable omniphobic properties, for example as characterized by water and/or oil contact and/or sliding angles. The omniphobic composition can be used as a coating on any of a variety of substrates to provide self-healing omniphobic properties to a surface of the substrate.Type: GrantFiled: January 2, 2020Date of Patent: July 26, 2022Assignee: BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITYInventors: Muhammad Rabnawaz, Ajmir Khan, Kun Huang
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Patent number: 11028217Abstract: This invention relates to the field of polymers. More specifically, the invention comprises thermoplastic polyurethane elastomers comprising polyesters comprising nitro-substituted dicarboxylic acids that are products obtained by decomposition of polyethylene. The thermoplastic polyurethane elastomers described herein exhibit higher glass transition temperatures and higher Shore A hardness compared to thermoplastic polyurethane elastomers synthesized from similar polyester diols made from virgin monomers that do not contain nitro substitution.Type: GrantFiled: August 4, 2020Date of Patent: June 8, 2021Assignee: BioCellection Inc.Inventors: Katrina Marie Knauer, Jennifer Le Roy, Cody James Higginson, Russell Clayton Pratt, David Samuel Pilsk
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Patent number: 10526507Abstract: A golf ball paint composition includes primarily a urethane paint containing polyol as a base resin and polyisocyanate as a curing agent. Two types of polyester polyol are used as the polyol, and the composition has an elastic work recovery of at least 70%. The paint composition has a high self-repairing ability and is of high quality as a golf ball paint. Golf balls coated with this composition are able to maintain a good durability, in addition to which they have an excellent abrasion resistance and an excellent ball appearance.Type: GrantFiled: November 9, 2017Date of Patent: January 7, 2020Assignee: Bridgestone Sports Co., Ltd.Inventor: Hirotaka Shinohara
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Patent number: 10399935Abstract: A method for producing 3-mercaptopropionic acid and methods using same for producing a carbonic acid ester compound having a mercapto group and a thiourethane-based optical material. The present invention improves a process during the production of 3-mercaptopropionic acid, significantly increases yield, and reduces the temperature and time during vacuum distillation, thereby preventing the destruction of a product and significantly increasing productivity. The present invention allows high-purity 3-mercaptopropionic acid having an excellent color to be finally yielded; accordingly, by using same, a high-purity carbonic acid ester compound having an excellent color and a mercapto group can be inexpensively obtained. A thiourethane-based polymeric composition and a thiourethane-based optical material obtained by polymerizing same can likewise be inexpensively obtained by using said carbonic acid ester compound.Type: GrantFiled: June 17, 2016Date of Patent: September 3, 2019Assignee: KOC SOLUTION, LTD.Inventors: Dong Gyu Jang, Soo Gyun Roh
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Patent number: 10100233Abstract: A pressure sensitive adhesive formed from a blend of an acrylate polymer having at least one crosslinkable functional group, and a liquid oligomer having at least one crosslinkable functional group, wherein at least one of the acrylate polymer and the oligomer is crosslinked in the presence of the other.Type: GrantFiled: March 20, 2008Date of Patent: October 16, 2018Assignee: Avery Dennison CorporationInventors: Michael J. Zajaczkowski, Christopher Lee Lester
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Patent number: 9452975Abstract: The present invention relates to novel biobased carbodiimides, a process for production thereof and use thereof. The biobased carbodiimides according to the invention comprise the reaction product of at least one carbodiimide and a carbon acid compound isolated or produced from renewable raw materials and having a functionality>1 and/or a hydroxy carboxylic ester having 2-24 carbon atoms.Type: GrantFiled: May 22, 2014Date of Patent: September 27, 2016Assignee: Rhein Chemie Rheinau GmbHInventors: Wilhelm Laufer, Armin Eckert, Franco Orsini, Robert Eiben
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Patent number: 9249253Abstract: The process of obtaining a polylactide-urethane copolymer is described which includes contacting an ?, ? dihydroxyl polylactide prepolymer of general formula I wherein X is NH or O, R is an alkyl or an aryl group, n and n? are integer numbers which are substantially the same and are in the range from 20 to 140, with a diisocyanate compound of general formula II O?C?N—R?—N?C?O wherein R? is an alkyl or an aryl group and with an amine or an alcohol of general formula III R?X?]2 wherein R? is an alkyl or an aryl group and X? is NH2 or OH, and with the proviso that at least one of R or R? is an aryl group.Type: GrantFiled: September 27, 2007Date of Patent: February 2, 2016Assignee: FUTERRO S.A.Inventors: Philippe Dubois, Philippe Coszach, Gloria Vendrell, Philippe Degee, Michael Alexandre, Ibrahim Barakat, Jean Marie Raquez
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Patent number: 9227109Abstract: Disclosed herein are polyurethane golf ball compositions. The compositions are prepared by adding a UV absorber to a polyol prior to reacting the polyol with an isocyanate to form a prepolymer, which is then reacted with a curing agent to form the polyurethane.Type: GrantFiled: September 13, 2012Date of Patent: January 5, 2016Assignee: Acushnet CompanyInventors: Michael Michalewich, Brian Comeau, Shawn Ricci, Manjari Kuntimaddi, Matthew F. Hogge, Nicholas M. Nardacci, Michael R. Madson
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Publication number: 20150141609Abstract: Embodiments of the invention encompass polyurethane elastomers which are a reaction product of a reaction mixture that includes a) at least one polyester made using a dicarboxylic acid having a carbon chain of from 9 to 20; b) at least one chain extender; and c) at least one polyisocyanate. At least 20% of the total carbon content of the polyurethane elastomer is from renewable carbon.Type: ApplicationFiled: June 25, 2013Publication date: May 21, 2015Applicant: Dow Global Technologies LLCInventors: Giuseppe Lista, Luciano Zanacchi
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Patent number: 9034378Abstract: This invention relates to biocompatible, biodegradable thermoplastic polyurethane or polyurethane/ureas comprising isocyanate, polyol and a conventional chain extender and/or a chain extender having a hydrolysable linking group and their use in tissue engineering and repair applications, particularly as stents and stent coating.Type: GrantFiled: March 24, 2005Date of Patent: May 19, 2015Assignee: PolyNovo Biomaterials Pty LtdInventors: Timothy G. Moore, Raju Adhikari, Pathiraja A. Gunatillake
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Publication number: 20150133623Abstract: The invention relates to novel processes for improving hydrolysis resistance in polyurethane (PU) based systems, preferably PU adhesives, PU casting resins, PU elastomers or PU foams.Type: ApplicationFiled: March 22, 2013Publication date: May 14, 2015Inventors: Wilhelm Laufer, Armin Eckert, Uwe Haas, Uwe Wuertz
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Patent number: 9012590Abstract: The present invention relates to an electrostatic dissipative thermoplastic polyurethane composition made by reacting (a) at least one polyester polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender. The polyester polyol intermediate, may be derived from at least one dialkylene glycol and at least one dicarboxylic acid, or an ester or anhydride thereof. The invention further provides for methods of making said thermoplastic polyurethane composition, polymer blends containing said thermoplastic and polymer articles made from said thermoplastic.Type: GrantFiled: October 1, 2010Date of Patent: April 21, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Qiwei Lu, Donald A. Meltzer, Yona Eckstein
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Publication number: 20150105530Abstract: The present invention relates to chain extenders, processes for their preparation and their use in the preparation of biocompatible biodegradable polyurethanes and polyurethane ureas for biomedical applications such as stents, scaffolds for tissue engineering.Type: ApplicationFiled: December 17, 2014Publication date: April 16, 2015Inventors: Pathiraja Arachchillage Gunatillake, Timothy Graeme Moore, Raju Adhikari
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Publication number: 20150079151Abstract: A composition comprising the reaction product of (a) an isocyanate group-containing component having an average functionality of at least 2; and (b) an active hydrogen group-containing component having an average functionality of at least 2. The composition is biodegradable, a solid at 22° C. and below, and has pressure sensitive adhesive properties at a temperature of 37° C. and relative humidity of 100%. The composition may be used to adhere polymer meshes or films to biological tissue.Type: ApplicationFiled: November 24, 2014Publication date: March 19, 2015Inventors: Eric J. Beckman, Jessica L. Meyers
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Patent number: 8980430Abstract: Multilayer fluoropolymer-containing films having improved interlayer adhesion. More particularly, multilayer films including a fluoropolymer layer attached to a thermoplastic polymer layer via an intermediate poly(ester-urethane) copolymer containing adhesive layer, articles produced therefrom, and products which are encased by the multilayer films. The films are suitable for encasing the sensitive luminescent components of electroluminescent lamps.Type: GrantFiled: August 28, 2006Date of Patent: March 17, 2015Inventors: Frank J. Colombo, Yuan-Ping R. Ting
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Patent number: 8971766Abstract: The present invention provides an electrophotographic member capable of more definitely suppressing occurrence of a C set image. The electrophotographic member has a surface layer including a modified polysiloxane having a structure represented by the following formula (1). In the formula (1), G represents a bivalent group having an ethylene oxide chain represented by (—O—C2H4—) and L represents polysiloxane having at least a SiO4/2(Q) unit or a SiO3/2(T) unit.Type: GrantFiled: June 4, 2013Date of Patent: March 3, 2015Assignee: Canon Kabushiki KaishaInventors: Tomohito Taniguchi, Hiroshi Mayuzumi, Yusuke Yagisawa
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Patent number: 8969452Abstract: The present invention relates to quick-drying two-component polyurethane coating compositions, to processes for preparing them, and to their use.Type: GrantFiled: December 8, 2009Date of Patent: March 3, 2015Assignee: BASF SEInventors: Monika Haberecht, Angelika Maria Steinbrecher, Christof Kujat, Alexander Traut
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Patent number: 8957177Abstract: The present invention is directed to a composition comprising an amide moiety containing polyol wherein the amide moiety is formed by the reaction of an amine reactive compound with an amine containing compound.Type: GrantFiled: August 9, 2011Date of Patent: February 17, 2015Assignee: Huntsman International LLCInventors: Steve Diamanti, Howard P. Klein
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Publication number: 20150031848Abstract: The present invention relates to a polyester polyol, suitable for use in the manufacture of a polyurethane, suitable for use in the manufacture of a polyurethane, the polyester polyol having an ABA-structure, in which A represents a lactide-oligomer and in which B represents an initiator. The initiator includes a reaction product having long chain dicarboxylic acid components having 18 or more carbon atoms. The invention also relates to a method for the manufacture of the polyester polyol. The invention further pertains to polyurethanes including the before-mentioned polyester polyol as well as the use of these polyurethanes as an elastomer having a high toughness. The toughness is believed to originate from the combination of the hydrophobic character of the initiator and the hydrophilic character of the lactide parts in the polyol structure. The strength of the invented polylactide-polyurethane elastomers can be further improved by incorporating a carbodiimide in the elastomer material.Type: ApplicationFiled: April 15, 2013Publication date: January 29, 2015Inventors: Wilhelmus Jacobus Adrianus Honcoop, Chris François Hubert Schaekens, Jurgen Cornelis Henricus Maas, Mauraline Alison Maxine Gumbs
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Publication number: 20150018509Abstract: The invention relates to an isocyanate-containing prepolymer obtainable by reacting at least one isocyanate which comprises methylene diphenyl diisocyanate with at least one first compound selected from the group comprising monohydric alcohols, thiols and secondary amines and with at least one second compound selected from the group comprising monohydric alcohols, thiols and secondary amines.Type: ApplicationFiled: March 19, 2013Publication date: January 15, 2015Inventors: Wesley Verbeke, Dimitri Leroy
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Publication number: 20150018508Abstract: The invention relates to an isocyanate-containing prepolymer obtainable by reacting at least one isocyanate with at least one first compound selected from the group comprising monohydric alcohols, thiols and secondary amines; wherein the ratio of the NCO value of the isocyanate-containing prepolymer, to the OH, SH or NH value, of said monohydric alcohol, thiol or secondary amine respectively ranges from 0.0005 to 1.0000 and wherein said at least one first compound is present in a total amount of at least 40% by weight based on the total weight of the isocyanate-containing prepolymer.Type: ApplicationFiled: March 19, 2013Publication date: January 15, 2015Inventors: Wesley Verbeke, Dimitri Leroy
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Patent number: 8933188Abstract: The tendency of a two component laminating adhesive based on polyurethane chemistry to form a mist of fine droplets when applied at a high line speed may be reduced by including both a high functionality polyol and a lower functionality polymeric polyol in Component B which is combined and reacted with an isocyanate-functionalized polyurethane prepolymer in Component A.Type: GrantFiled: November 12, 2004Date of Patent: January 13, 2015Assignee: Henkel US IP LLCInventors: J. Brandon Simons, Grant B. Kenion
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Patent number: 8912291Abstract: Embodiments include oxazolidone ring containing adducts obtainable by combining an aliphatic epoxy compound, an aromatic epoxy compound, and a diisocyanate. Embodiments further include a curable powder coating composition including a resin component and a hardener component, where the resin component includes the oxazolidone ring containing adduct.Type: GrantFiled: December 20, 2010Date of Patent: December 16, 2014Assignee: DOW Global Technologies LLCInventors: Joseph Gan, Emile C. Trottier
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Patent number: 8889787Abstract: A problem to be solved by the present invention is to provide a polyurethane film that offers both soft texture and high strength. The present invention relates to a polyurethane film obtained by solidifying a polyurethane (A) obtained by reacting a polyol (a1) including an aliphatic polyester polyol having an anionic group (a1-1), and a polyester polyol (a1-2) other than the aliphatic polyester polyol (a1-1) with a polyisocyanate (a2), using a metal salt, in which the polyurethane (A) has an aromatic structure in the range of 500 mmol/kg to 2,000 mmol/kg with respect to the entire polyurethane (A).Type: GrantFiled: June 29, 2012Date of Patent: November 18, 2014Assignee: DIC CorporationInventors: Sadamu Nagahama, Hiroki Tanaka, Mitsuru Kitada
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Publication number: 20140327869Abstract: The present invention relates to a polymerizable composition comprising polyisocyanate(s) (A), polythiol(s) (B), thiol(s) (C) and catalyst(s) (D). The polyisocyanate(s) (A) is at least one bifunctional or higher functional alicyclic polyisocyanate; the polythiol(s) (B) is at least one compound selected from polythiols represented by the following general formula (B1); the thiol(s) (C) is at least one compound selected from thiols having general formula (3); and the catalyst(s) (D) is at least one polymerization catalyst selected from metal compounds, quaternary ammonium salts, organic sulfonic acids, tertiary amines and relative inorganic or organic salts.Type: ApplicationFiled: November 16, 2012Publication date: November 6, 2014Inventors: Fiorenzo Renzi, Roberto Forestieri, Andrea Vecchione, Willem Bos
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Publication number: 20140302398Abstract: The invention relates to an electrode binder composition, an electrode made using the described binder composition, and an electrochemical cell made using the described electrode, where the all of these materials are made using a composition of a poly(dialkylene ester) thermoplastic polyurethane composition. The electrode is made using the described thermoplastic polyurethane and an electrode active material. The electrochemical cells can be made using the described electrodes and also using (i) membranes and/or separators made using the described poly(dialkylene ester) thermoplastic polyurethane composition; (ii) an electrolyte system based on the described poly(dialkylene ester) thermoplastic polyurethane composition; or (iii) a combination thereof.Type: ApplicationFiled: October 24, 2012Publication date: October 9, 2014Inventors: Tesham Gor, Qiwei Lu, Feina Cao
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Publication number: 20140296428Abstract: The present invention relates to isocyanate functional prepolymers, aqueous polyurethane dispersions produced from the prepolymers and various uses of such dispersions. The prepolymers are prepared by reacting a diisocyanate, a dihydroxy compound having a number average molecular weight of from about 700 to about 16,000, and a trihydroxy component of the formula: R—(OH)3 where R is a saturated straight chain or branched chain aliphatic group of from 2 to 8 carbon atoms. The invention also relates to polyurethane dispersions prepared from the prepolymers and to various uses of the resultant dispersions.Type: ApplicationFiled: February 21, 2014Publication date: October 2, 2014Applicant: Bayer MaterialScience LLCInventors: Lyubov K. Gindin, Richard R. Roesler, Poli C. Yu, Joseph Kleer, Thomas Muenzmay, Yuliya Berezkin, Mary A. Crisci
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Patent number: 8846776Abstract: Composite materials and methods for their preparation are described herein. The composite materials include a polyurethane made from the reaction of an isocyanate and a mixture of polyols, and coal ash (e.g., fly ash). The mixture of polyols comprises at least two polyols including a high hydroxyl number polyol having a hydroxyl number greater than 250 and comprising from about 1% to about 25% by weight of the total polyol content used to form the polyurethane, and a low hydroxyl number polyol having a hydroxyl number of 250 or lower. The coal ash is present in amounts from about 40% to about 90% by weight of the composite material. Also described is a method of preparing a composite material, including mixing an isocyanate, a mixture of at least two polyols, coal ash (e.g., fly ash), and a catalyst.Type: GrantFiled: August 12, 2010Date of Patent: September 30, 2014Assignee: Boral IP Holdings LLCInventors: Ronald M. Herrington, Kengqing Jian
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Patent number: 8834522Abstract: Described herein are a group of degradable, thermoplastic polymers, which are able to change their shape after an increase temperature. Their shape memory capability enables bulky implants to be placed in the body through small incisions or to perform complex mechanical deformations automatically. The shape memory polymers are preferably biocompatible and can be biodegradable or non-degradable polymers. Preferably, the biodegradable polymer has a linear degradation rate. In a specifically preferred embodiment, the suture is formed of biodegradable polymer capable of forming a self-tightening knot. In a most preferred embodiment, the suture is used to close a wound or body scission.Type: GrantFiled: August 28, 2012Date of Patent: September 16, 2014Assignee: Helmholtz-Zentrum Geestahacht Zentrum fur Material und KustenforschungInventors: Andreas Lendlein, Robert S Langer
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Patent number: 8829146Abstract: The invention relates to high-reactivity polyurethane compositions which contain uretdione groups and cure at low baking temperatures, to a process for the preparation and to their use for producing coating materials, especially surface coatings and adhesives, and also plastics.Type: GrantFiled: June 12, 2009Date of Patent: September 9, 2014Assignee: Evonik Degussa GmbHInventor: Emmanouil Spyrou
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Publication number: 20140243496Abstract: The present invention relates to a urethane optical member containing at least one kind of structures represented by the following formulae (1) and (2) in a structure constituting the optical member, and a method for producing the same.Type: ApplicationFiled: August 20, 2012Publication date: August 28, 2014Applicant: HOYA CORPORATIONInventors: Masahisa Kousaka, Yasuhisa Okamoto
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Patent number: 8816036Abstract: Catalysts, which are free of tin, are described which are useful in the reaction between an isocyanate and an alcohol, which is a key step for preparing polyurethane polymers. The catalyst is a metal complex or salt of formula (1): [Zn(L1)l1(L2)l2(Y)x]??(1) in which: l1?1 and l2=0 or 1; with l1+l2=2, x=1 or 2, the symbol L1 represents a ligand which is a ?-dicarbonylato anion or the enolate anion of a ?-dicarbonyl compound or an acetylacetato anion derived from a ?-ketoester, when l1=2, the symbols L1 are identical or different, the symbol L2 represents an anionic ligand which is different from L1, and the symbol Y represents a neutral ligand; where the metal complex or salt C of formula (1) is not zinc diacetylacetonate.Type: GrantFiled: October 12, 2009Date of Patent: August 26, 2014Assignee: Bluestar Silicones France SASInventors: Christian Maliverney, Laurent Saint-Jalmes
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Patent number: 8802770Abstract: The present invention discloses a semicrystalline, thermoplastic polyurethane which is comprised of the reaction product of (1) a hydrophobic polyol, (2) a polyisocyanate, and (3) a linear chain extender containing 5 carbon atoms or 7 to 12 carbon atoms; wherein the hydrophobic polyol has a number average molecular weight which is within the range of about 1,000 to about 4,000; wherein the semicrystalline, thermoplastic polyurethane has a weight average molecular weight which is within the range of 50,000 to 1,000,000; and wherein the semicrystalline, thermoplastic polyurethane has a melting point which is within the range of 80° C. to 150° C. This hydrophobic thermoplastic polyurethane offers a unique array of characteristics that are highly desirable for utilization in manufacturing a variety of products. For instance, it can be used in overmolding soft grips onto consumer products, in adhesives, and in protective coatings.Type: GrantFiled: January 21, 2009Date of Patent: August 12, 2014Assignee: Lubrizol Advanced Materials, Inc.Inventors: Donald A. Meltzer, Jacques P. E. J. Horrion
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Patent number: 8765012Abstract: A thermosetting composition including an organic solvent, a liquid crystalline thermoset oligomer, and either a crosslinking agent or an epoxy resin or both is disclosed. A printed circuit board which includes the thermosetting composition is also disclosed. The printed circuit board is produced by impregnating the thermosetting composition into a reinforcing material.Type: GrantFiled: November 18, 2009Date of Patent: July 1, 2014Assignees: Samsung Electronics Co., Ltd., Samsung Electro-Mechanics Co., Ltd., Samsung Fine Chemicals Co., Ltd.Inventors: Myung Sup Jung, Chung Kun Cho, Kwang Hee Kim, Kalinina Fedosya, Man Jong Kim, Tae Jun Ok
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Patent number: 8759469Abstract: The present invention relates to a process for preparing a compound comprising at least a urethane group —HN—C(?O)—O, said process comprising a step (E) in which a compound (I) comprising at least an isocyanate functional group —N?C?O is reacted with an organic compound (II) carrying at least a hydroxyl group —OH, said reaction being carried out in a presence of a carbene (III) used as a catalyst.Type: GrantFiled: July 25, 2008Date of Patent: June 24, 2014Assignees: Vencorex Frence, Centre National de la Recherche Scientifique (C.N.R.S)Inventors: Gerard Mignani, Mathias Destarac, Daniel Taton, Yves Gnanou, Antoine Baceiredo, Tsuyoshi Kato, Fabien Bonnette, Gopakumar Sivasankarapillai
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Patent number: 8754183Abstract: To provide a water/oil repellent agent and a water/oil repellent composition which are capable of imparting sufficient water/oil repellency to the surface of an article and which have low environmental impact. One comprising a reaction product obtained by reacting a fluorinated alcohol or amine having a polyfluoroalkyl moiety having at most 6 carbon atoms with a polyisocyanate compound, which is, when applied to an article, capable of imparting sufficient water/oil repellency, while presenting little environmental impact. When applied to an article, the water/oil repellent composition of the present invention is capable of imparting a high quality water/oil repellency to the article.Type: GrantFiled: December 4, 2012Date of Patent: June 17, 2014Assignee: Asahi Glass Company, LimitedInventor: Taiki Hoshino
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Patent number: 8748558Abstract: Methods for producing biocompatible compositions are provided. The biocompatible compositions include an aliphatic polyester macromer produced without the use of solvents or catalysts. The resulting aliphatic polyester macromer may be reacted with a polyisocyanate to form an end-capped aliphatic polyester macromer which, in turn, may be reacted with a polyol to produce a polyurethane. The polyurethane, in turn, may be reacted with a second polyisocyanate to produce an isocyanate-functional polyurethane. The compositions prepared by the methods of the present disclosure may be used as adhesives or sealants for medical/surgical uses.Type: GrantFiled: April 21, 2008Date of Patent: June 10, 2014Assignee: Covidien LPInventors: Walter Skalla, Allison Calabrese, Ahmad R. Hadba, Nadya Belcheva
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Patent number: 8735526Abstract: A method of making a polymer by providing an imine and reacting the imine with a polyisocyanate in the presence of a hydroxyl group. The imine is a polyaldimine, hydroxyaldimine, polyketimine, or hydroxyketimines. The polymer has urea linkages formed from the imine and polyisocyanate and urethane linkages formed from the hydroxyl group and the polyisocyanate. The polymer has at least as many urea linkages as urethane linkages. A polymer having urea units and urethane units having a molar ratio of at least about 2:1. A polymer comprising a urea-urethane repeat unit.Type: GrantFiled: September 15, 2005Date of Patent: May 27, 2014Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Jozef Verborgt, Arthur Webb
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Patent number: 8716427Abstract: A two-component curable solventless adhesive which enables a laminated composite film comprising a barrier layer and a plastic film laminated with each other to maintain excellent appearance and adhesive strength for a long period even after a sterilization treatment at high temperature, and to appropriately adjust a reaction between a base resin and a curing agent during a production of the laminated composite film. The two-component curable solventless adhesive comprises a base resin and a curing agent, wherein the base resin contains a polyol having an acid group and a secondary or tertiary terminal hydroxyl group accounting for 30% or more of the entire terminal hydroxyl groups of the polyol, and the curing agent contains an isocyanate group-terminated urethane prepolymer containing at least an aralkyl polyisocyanate and/or a modified substance thereof as a raw polyisocyanate, and a content of a low molecular weight polyisocyanate is defined.Type: GrantFiled: February 4, 2005Date of Patent: May 6, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Akihiro Imai, Kazuaki Imamura, Taiji Morimoto, Hiroshi Kawasaki, Mikio Matsufuji