Heavy Metal Or Aluminum Containing Patents (Class 534/692)
  • Patent number: 11493678
    Abstract: An optical film includes: a protective layer; and a contrast ratio improvement layer including a first resin layer and a second resin layer facing the first resin layer, the second resin layer and the first resin layer being sequentially stacked from a lower surface of the protective layer, wherein the second resin layer has a refractive index greater than that of the first resin layer. The first resin layer has a patterned portion with at least two embossed optical patterns and flat sections immediately adjacent to and between the embossed optical patterns. The patterned section is in at least a portion thereof facing the second resin layer. A polarizing plate including the optical film and a liquid crystal display apparatus including the polarizing plate are also provided.
    Type: Grant
    Filed: January 19, 2021
    Date of Patent: November 8, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Dae Gyu Lee, Yong Un Jung
  • Patent number: 10441666
    Abstract: The present invention relates to novel tricarbocyanine-cyclodextrin(s) conjugates useful as markers in the diagnosis of kidney diseases, a diagnostic composition comprising said conjugates, their use and their production.
    Type: Grant
    Filed: May 15, 2015
    Date of Patent: October 15, 2019
    Assignee: CYANAGEN S.R.L.
    Inventors: Leopoldo Della Ciana, Norbert Gretz, Rossana Perciaccante, Federica Rodeghiero, Stefania Geraci, Jiaguo Huang, Zeneida Herrera Pérez, Johannes Pill, Stefanie Weinfurter
  • Patent number: 7781044
    Abstract: A recording layer including a novel organic compound for a high density optical recording medium is provided. The information may be recorded on the recording layer at a 2× speed or higher speed with a relatively lower writing power so that heat distribution of the recording layer in the irradiated area is not likely to become steep both in time and space. The organic compound incorporated in the recording layer has the following general chemical structural formula (I).
    Type: Grant
    Filed: September 5, 2007
    Date of Patent: August 24, 2010
    Assignee: Industrial Technology Research Institute
    Inventors: Ming-Chia Li, An-Tse Lee, Chien-Liang Huang, Chung-Ta Cheng, Kuo-Chi Chiu, Tzuan-Ren Jeng
  • Patent number: 7638610
    Abstract: A self-dispersible metal complex colorant is represented by formula 1, which has improved storage stability, may embody various colors and has improved fastness, such as light resistance, water resistance and the like: wherein each of A1 and A2 is independently a moiety which includes a substituted or unsubstituted C2-C30 alkenylene group having at least one double bond and is conjugated with an azo group; each of X1 and X2 is selected from the group consisting of a hydroxy group, a C1-C4 alkoxy group, a carboxyl group, and a substituted or unsubstituted amino group; M is a polyvalent transition metal; L is a neutral or anionic ligand; T is a mono- or poly-substituted hydrophilic functional group; n is an integer between 1 and 3; and J is a linker. The self-dispersible metal complex colorant may be used in various fields employing colors, such as fibers, foods, drugs, cosmetics, coatings, inks or ceramics.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: December 29, 2009
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
  • Patent number: 7598358
    Abstract: A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
    Type: Grant
    Filed: March 6, 2006
    Date of Patent: October 6, 2009
    Assignee: Sony Corporation
    Inventors: Eriko Matsui, Yuriko Kaino, Toshiyuki Kunikiyo, Tatsushiro Hirata, Yoshifumi Mori
  • Patent number: 7578880
    Abstract: A method of producing fine particles of metal complex pigment, containing the step of reacting a solution of an alkali metal salt of a ligand that constitutes the metal complex with a solution of salts of a metal that constitutes the metal complex, in the course of a laminar flow in a channel; and a method of producing fine particles of metal complex pigment, containing the step of bringing a solution of an alkali metal salt of a ligand that constitutes the metal complex and a solution of salts of a metal that constitutes the metal complex into contact with each other in a channel having an equivalent diameter of 1 mm or less to form a liquid flow.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: August 25, 2009
    Assignee: FUJIFILM CORPORATION
    Inventors: Tadahisa Sato, Jun Tanabe, Hideki Maeta
  • Patent number: 7479360
    Abstract: The charge control agent comprises aggregate particles including an azo-type iron complex salt represented by the following chemical formula [VI] (in the chemical formula [VI], B+ is (H+)x(Na+) 1?x and x is mole ratio and 0.6 to 0.9, or B+ is (H+)y(Na+)1?y and y is mole ratio and 0 to 0.2) and the aggregate particles have 0.5 to 5.0 microns of an average particle size. A toner for developing an electrostatic image comprises a resin for the toner and the charge control agent. An image formation process of electrophotography comprises a step for developing an electrostatic latent image on an electrostatic latent image frame by a developer including the toner.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: January 20, 2009
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Masashi Yasumatsu, Kazuyoshi Kuroda, Osamu Yamate, Kaori Sato, Jun Hikata, Heihachi Yushina
  • Patent number: 7364597
    Abstract: A metal complex colorant represented by formula 1 may embody various colors and has improved fastness, such as light resistance, water resistance and the like: wherein each of A1 and A2 is independently a moiety which includes a substituted or unsubstituted C2-C30 alkenylene group having at least one double bond and is conjugated with an azo group; each of X1 and X2 is selected from the group consisting of a hydroxy group, a C1-C4 alkoxy group, a carboxyl group, and a substituted or unsubstituted amino group; M is a polyvalent transition metal; L is a neutral or anionic ligand; n is an integer from 1 to 3; and J is a linker. The metal complex colorant may be used in various fields employing colors, such as fibers, foods, drugs, cosmetics, coatings, inks or ceramics.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: April 29, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yeon-kyoung Jung, Seung-min Ryu, Kyung-hoon Lee
  • Patent number: 7083674
    Abstract: A pigment dispersant represented by the following general formula (1) is provided: wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 each independently is —H, —Cl, —CH3, —CF3, —NO2, —COOCH(CH3)2 or —COOCH2CH2Cl; R11, R12, R13 and R14 each independently is —H, —Cl, —CH3 or —CN; M is one equivalent of a bivalent or trivalent metal; and n is an integer of 1 to 3.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: August 1, 2006
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Takashi Kamikubo, Tetsuya Sai
  • Patent number: 7038025
    Abstract: A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
    Type: Grant
    Filed: December 18, 2002
    Date of Patent: May 2, 2006
    Assignee: Sony Corporation
    Inventors: Eriko Matsui, Yuriko Kaino, Toshiyuki Kunikiyo, Yoshifumi Mori, Tatsushiro Hirata
  • Publication number: 20040215001
    Abstract: A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
    Type: Application
    Filed: August 25, 2003
    Publication date: October 28, 2004
    Inventors: Eriko Matsui, Yuriko Kaino, Toshiyuki Kunikiyo, Yoshifumi Mori
  • Publication number: 20040186007
    Abstract: The present invention relates to compounds of transition metals with azo ligands, a process for their production, the use of these compounds as catalysts, a process for olefin (co)polymerization using these compounds, reaction products of these compounds with co-catalysts, the olefin (co)polymer, the use of these olefin (co)polymers for the production of molded parts, as well as molded parts that are produced from the olefin (co)polymers.
    Type: Application
    Filed: January 30, 2004
    Publication date: September 23, 2004
    Inventor: Thomas Weiss
  • Patent number: 6764524
    Abstract: Asymmetrical 1:2 chromium complex dyes of formula (I), wherein X signifies —SO3M, —SO2NR1R2 or chlorine, Y signifies hydrogen, —SO3M or chlorine, R1 signifies hydrogen, C1-6alkyl, C2-3-hydroxyalkyl or a radical of formulae (a) or (b), R2 signifies hydrogen, C1-6alkyl or C2-3-hydroxyalkyl, or R1 and R2 together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated heterocycle, R3 signifies hydrogen, C1-2-alkyl, chlorine, —COOM or —SO3M, R4 signifies hydrogen, C1-2-alkyl, C1-2-alkoxy chlorine or —SO3M, n signifies from 0 to 3, M signifies in each case hydrogen or a nonhromophoric cation, and M+signifies hydrogen or a nonchromophoric cation, are useful for dyeing artificially produced oxide layers on aluminium or aluminium alloys, on which they produce grey dyeings in high color yield and hue reproducibility
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: July 20, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Klaus Körte
  • Patent number: 6712890
    Abstract: A water soluble compound of Formula (1) or a salt thereof: wherein: Y is an electron withdrawing group; Y1 is H, alkyl or aryl, OR or NR2 in which each R independently is H, optionally substituted alkyl or optionally substituted aryl; or Y and Y1 together form a 5- or 6- membered ring; X1 is a group or atom with co-ordinates with M; M is hexa co-ordinate metal; G is a group of Formula (2), (3) or (4); and L1, L2 and L3, each independently represent ligands required to complete hexa-coordinate geometry around metal M; wherein: S is a water solubilizing group; Ar is a benzene or naphthalene group in which X is located ortho to the azo group; X is a group or atom which co-ordinates with M; Z provides atoms or groups which complete an optionally substituted 5- or 6-membered aromatic heterocyclic ring; Ring A is an optionally substituted aromatic ring; Ring B is an optionally substituted 5- or 6-membered aromatic heterocyclic ring; n is 0, 1, 2 or 3; and the * signify the points of attachment of t
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: March 30, 2004
    Assignee: Avecia Limited
    Inventors: Maria Soteri Hadjisoteriou, Rachel Anne James
  • Publication number: 20030149251
    Abstract: The present invention provides a black dyestuff for inkjet recording which exhibits a good achromaticity as well as a good light-resistance and a recording liquid containing the black dyestuff.
    Type: Application
    Filed: August 12, 2002
    Publication date: August 7, 2003
    Applicant: Mitsubishi Chemical Corporation
    Inventor: Wataru Shimizu
  • Publication number: 20010029294
    Abstract: Azo colorants are prepared by conducting the diazotization of aromatic or hetaromatic amines or the azo coupling reaction or the diazotization and the azo coupling reaction in a microreactor.
    Type: Application
    Filed: February 9, 2001
    Publication date: October 11, 2001
    Applicant: Clariant International Ltd.
    Inventors: Uwe Nickel, Rudiger Jung, Klaus Saitmacher, Leonhard Unverdorben
  • Publication number: 20010004667
    Abstract: A organic metal complex compound represented by the following formula (1), which has an electroconductivity of at most 110 &mgr;S/cm when dispersed in ion-exchanged water in an amount of 1 wt %: 1
    Type: Application
    Filed: December 6, 2000
    Publication date: June 21, 2001
    Applicant: Hodogaya Chemical Co.,Ltd.
    Inventors: Masaki Okubo, Hiroshi Nanaumi, Masataka Sawano
  • Patent number: 6132894
    Abstract: A compound of formula (I) or a mixture thereof ##STR1## The compounds are useful as solvent dyestuffs and exhibit high solubility in alcoholic solvents, e.g. ethanol.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: October 17, 2000
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Dominique Pflieger
  • Patent number: 5962657
    Abstract: A cyanine dye complex of formula I ##STR1## consisting of a cyanine dye and a chromium or cobalt metal azo ligand complex is particularly useful in a process for optically recording, storing or reproducing information using a recording medium, especially when the process is carried out at the wavelength range from 600 to 800 nm.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: October 5, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Heinz Wolleb, Beat Schmidhalter
  • Patent number: 5698683
    Abstract: A process for preparing a mixed aluminium-heavy metal dyestuff complex, in which the amount of heavy metal present is 10-98% and that of aluminium is 2 to 90% comprisingi) reacting the metal free dyestuff with less than a stoichiometric amount of a heavy metal compound followed byii) reacting the product with an aluminium compound in an amount to produce a stoichiometric excess of metal (calculated on all the metal present) to form a mixed aluminium-heavy metal complex.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: December 16, 1997
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Dominique Pflieger
  • Patent number: 5512246
    Abstract: Methods and compositions for detecting and measuring the concentration in solution of polyhydroxyl compounds, such as sugars. The invention makes use of certain dye compositions that, when linked to a derivative of boronic acid (or boronate ion), arsenious acid (or arsenite ion), or germanic acid (or germanate ion), exhibit quantitative responses to the presence of polyhydroxyl species.
    Type: Grant
    Filed: November 17, 1993
    Date of Patent: April 30, 1996
    Assignee: Anthony P. Russell
    Inventors: Anthony P. Russell, Charles W. Zepp
  • Patent number: 5316553
    Abstract: Salts of ionic dyes with compounds which contain at least one ammonium, cycloammonium or immonium group and at least one aliphatic, cycloaliphatic or carbonyl radical-substituted aromatic group or containing a piperazine or piperidine group or a heteroaromatic group selected from those of the triazine, pyrimidine, quinazoline, quinoxaline, phthalazine or phthalimidine series or which contain at least two carboxylic acid groups, at least one amino group and at least one carboxylic acid group or at least one sulfonic acid group and one aliphatic, cycloaliphatic, monocyclic aromatic or heteroaromatic group are useful for dyeing synthetic materials, particularly synthetic polyamides in the mass. The obtained dyeings have exceptionally good wet fastness.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: May 31, 1994
    Assignee: Sandoz Ltd.
    Inventors: Bansi L. Kaul, Angelos-Elie Vougioukas
  • Patent number: 5149365
    Abstract: The invention concerns new diorganotin compounds derived from N-cyclohexyl-N'-hydroxy diazenium oxide, as well as bactericides and fungicides which are suitable as disinfectants, as preservatives for wood and other materials, for bactericidal and fungicidal finishing of textiles, plastics, building materials or as biocides for paint systems and which contain these diorganotin compounds as active ingredients.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: September 22, 1992
    Assignee: Schering Aktiengesellschaft
    Inventors: Horst Landsiedel, Hans Plum
  • Patent number: 5137833
    Abstract: A method for detecting and measuring the concentration in solution of polyhydroxyl compounds, such as sugars. The invention makes use of certain dyes that, when linked to a derivative of boronic acid (or boronate ion), arsenious acid (or arsenite ion), or germanic acid (or germanate ion), exhibit quantitative responses to the presence of polyhydroxyl species.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: August 11, 1992
    Inventor: Anthony P. Russell
  • Patent number: 5066695
    Abstract: High-molecular weight organic material containing at least one metal complex of a ligand of formula I: ##STR1## wherein A is a carbocyclic aromatic or heterocyclic aromatic radical, B is a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, it being necessary for at least one of the radicals A and B to be heterocyclic, and R.sub.1 is --C.sub.1 -C.sub.18 -alkyl, a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, and the metal is a transition metal cation carrying a double positive charge selected from Ni.sup.2+, Cu.sup.2+, Co.sup.2+, Zn.sup.2+, Mn.sup.2+, Fe.sup.2+, Cd.sup.2+ or Pt.sup.2+ or the radical VO.sup.2+.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: November 19, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard, Walter Wiedemann
  • Patent number: 4861869
    Abstract: This invention relates to bifunctional coupling agents useful in forming conjugates with biologically useful molecules, such as antibodies. These conjugates can be complexed with radionuclide metal ions to provide materials useful for in vivo diagnostic and therapeutic applications.
    Type: Grant
    Filed: May 29, 1986
    Date of Patent: August 29, 1989
    Assignee: Mallinckrodt, Inc.
    Inventors: Robert A. Nicolotti, Richard T. Dean
  • Patent number: 4775747
    Abstract: Transition metal complexes of the compounds of the formulae I and II ##STR1## in which A is an isocylic or heterocyclic aromatic radical, R is --H, halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, R.sub.1 is --H, C.sub.1 -C.sub.4 -alkyl or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, --NO.sub.2, --CONH.sub.2, --CONHR.sub.2 or C.sub.2 -C.sub.5 -N-alkylcarbamoyl, X is --CH.dbd. or --N.dbd. andB is --H, C.sub.1 -C.sub.4 -alkyl, --NHCONH.sub.2, --NHCONH-C.sub.1 -C.sub.4 -alkyl, --NHCONR.sub.2, --NHCSNH.sub.2, --NHCSR.sub.3, --NHC(NH)NH.sub.2, --NHR.sub.2, --NHCOR.sub.3, --NHSO.sub.2 R.sub.3 or a heterocyclic aromatic radical, and R.sub.2 and R.sub.3 are phenyl or substituted phenyl, are suitable for pigmenting high-molecular organic material.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: October 4, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard
  • Patent number: 4723001
    Abstract: The invention relates to chromium complexes of the formula ##STR1## in which B is the radical of a bidentate bianionic compound, L is H.sub.2 O, NH.sub.3, alkanol, alkylamine, dialkylamine, trialkylamine or pyridine, D is a benzene or naphthalene diazo component, Y is the nitrogen atom or the CH group, K is a coupling component, R is hydrogen, alkyl or phenyl, X is a fibre-reactive group,Ka is a cation, m is 1, 2 or 3, n is 1 or 2 and k is 0 or 1.These chromium complexes are suitable for dyeing nitrogen-containing or hydroxy-containing materials and they produce level dyeings having good all-round fastness properties.
    Type: Grant
    Filed: July 24, 1986
    Date of Patent: February 2, 1988
    Assignee: CIBA-GEIGY Corporation
    Inventors: Hans U. Schutz, Ulrich Schlesinger, Gerhard Back
  • Patent number: 4710198
    Abstract: A process of dyeing polyamide-containing material is disclosed using dyes of the following formula: ##STR1## wherein Me is cobalt or chromium,Ka.sup..sym. is a cation,p is 0 or 1,R and R' are each independently of the other hydrogen or a group of the formula --CO--(O).sub.n --Y, wheren is 0 or 1, andY is C.sub.1 -C.sub.5 alkyl, or phenyl which may be substituted by nitro, halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy,with the proviso that R and R' may not both be hydrogen if p is 1.Novel dyes within this class are also disclosed. The process is especially useful for dyeing leather.
    Type: Grant
    Filed: December 9, 1985
    Date of Patent: December 1, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Fabio Beffa, Hans U. Schutz