Plural Benzene Rings Bonded Directly To Each Other And Are Between The Azo Groups Patents (Class 534/746)
  • Patent number: 5298609
    Abstract: Compounds of formula I ##STR1## wherein R is a radical of formula --OR.sub.3 or --NHR.sub.3, A is a radical of formula II or III ##STR2## and B is a radical of formula ##STR3## wherein n is 1 or 2,R.sub.1 is --H or --Cl,R.sub.2 is --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3, C.sub.2 -C.sub.5 alkoxycarbonyl, --CONH--phenyl, --NHCO-phenyl or phenoxy, each unsubstituted or substituted in the phenyl nucleus by one or two chlorine atoms or by one or two methyl, methoxy or ethoxy groups,R.sub.3 is C.sub.5 -C.sub.12 cycloalkyl, which is unsubstituted or substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl or C.sub.5 -C.sub.6 cycloalkyl groups,R.sub.4 and R.sub.5 are each independently of the other --H, halogen, --NO.sub.2, --CN, --CF.sub.3, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,R.sub.6 is --H, --Cl, --Br, --CH.sub.3 or --OCH.sub.3, andX is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2,are suitable for use as pigments, especially for colouring polyolefins.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: March 29, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Stefan Hari
  • Patent number: 5266110
    Abstract: The invention relates to three new crystal modifications (.gamma., .delta., .epsilon. modification) of C.I. Pigment Yellow 16 ##STR1## having their characteristic reflections in the X-ray diffraction spectrum. The new crystal modifications are prepared by heat treatment of the known .alpha. or .beta. modification in selected organic solvents.
    Type: Grant
    Filed: October 29, 1992
    Date of Patent: November 30, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Rieper, Edwin Baier
  • Patent number: 5034063
    Abstract: A disazo pigment composition which can provide a printing ink having excellent fluidity, gloss and storage stability, and which contains:a disazo pigment obtained by a coupling reaction between a tetrazo compound of dihalogenobenzidine and acetoacetanilides, anda reaction product from a coupling reaction between an acetoacetylation product and a tetrazo compound of dihalogenobenzidine.
    Type: Grant
    Filed: October 4, 1989
    Date of Patent: July 23, 1991
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Yoshie Suzuki, Ataru Chiba, Kenji Kitamura, Akimitsu Mochizuki
  • Patent number: 5030247
    Abstract: Mixtures of azo pigments of the formulae ##STR1## wherein each R.sub.1 is independently C.sub.1-4 alkyl, andeach R.sub.2 is independently 1,4-phenylene; 1,4-phenylene substituted by 1 or 2 substituents independently selected from chloro, bromo, methyl, methoxy, trifluoromethyl (maximum of one) and nitro (maximum of one); 4,4'-diphenylene substituted by 1 or 2 substituents independently selected from chloro, bromo, methyl and methoxy, each substituent being in the 3- or 3'-position; 1,4-naphthylene or 1,5-naphthylene, the mixture containing from 8 to 20% mole of benzoic acid ester residues and from 92 to 80% mole of terephthalic acid ester residues, useful for pigmenting in the mass synthetic polymers, for example, polyethylene, polypropylene, polystyrene, polyvinyl chloride, synthetic leather and rubber latices.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: July 9, 1991
    Assignee: Sandoz Ltd.
    Inventor: Jurgen Goldmann
  • Patent number: 4981489
    Abstract: Disazo compounds based on 4,4'-diaminodiphenyl compounds contain not less than 50% by weight of a disazo compound of the general formulaA--N.dbd.N--Z--N.dbd.N--B (I)where Z is a radical of an unsubstituted or symmetrically substituted diphenylene, A is a radical of a coupling component of a 1-phenylpyrazolone or of an acetoacetarylide, where the phenyl and the aryl radical is subtsituted by sulfo or carboxyl groups, and B is a radical of a coupling component based on 1-phenylpyrazolone or acetoacetarylide, which are free of sulfo and/or carboxyl groups.The disazo compounds can be obtained by coupling the tetrazotized diamine H.sub.2 N--Z--NH.sub.2 to the coupling component AH containing an acidic group in a medium containing a mineral acid, and then coupling the product to BH in a buffered medium (pH about 4).The novel disazo compounds are suitable as additives to pigments, in particular azo and disazo pigments, for improving the transparency and heat stability of the pigment particles, and the flow behavior.
    Type: Grant
    Filed: October 23, 1989
    Date of Patent: January 1, 1991
    Assignee: BASF Lacke & Farben Aktiengesellschaft
    Inventors: Wolfgang Ruff, Egon Liedek, Gerhard Berger, Hans W. Sonneborn
  • Patent number: 4780533
    Abstract: A disazo pigment is prepared by coupling the tetrazo compound of 3,3'-dichlorobenzidine with an acetoacetanilide compound which is other than those represented by the below-described general formula (I) and is free of water-soluble groups. In the present invention, about 0.5-50 mole % of the acetoacetanilide compound is replaced by a compound represented by the following general formula (I): ##STR1## wherein R means a methyl, ethyl, propyl or butyl group or a substituted or unsubstituted phenyl group.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: October 25, 1988
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Naonori Takami, Tetsuo Fukuda, Takeshi Uehara
  • Patent number: 4767844
    Abstract: An azo lake pigment is obtained by coupling an aromatic diazo component having a sulfonic acid group with a mixture of 2-hydroxy-3-naphthoic acid and a 2-hydroxy-3-naphthoic acid derivative represented by formula [I] ##STR1## wherein R represents a hydrogen atom, a naphthalene residue, a cyclohexyl group, or a group of the formula ##STR2## in which each of X, Y and Z represents a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, an acetylamino group, a benzoylamino group, a carbomoyl group or a phenylcarbamoyl group, and X and Y together may form a cyclized benzimidazolone, benzthiazole or benzoxazole group,and laking the resulting dye with an alkaline earth metal salt or a manganese salt.
    Type: Grant
    Filed: August 21, 1987
    Date of Patent: August 30, 1988
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hirohito Ando, Zenji Takada, Shigeto Aoki, Yuko Shigeta
  • Patent number: 4665163
    Abstract: Diaryl pigments having an excellent stability to heat are obtained by carrying out the coupling of bis-diazotized 3,3'-dichloro-4,4'-diaminobiphenyl with acetoacetanilides in the presence of an added quantity of acetoacetanilides which are monosubstituted or disubstituted in the 3-position or 4-position of the nucleus. As a result of their good heat stability, these pigments are particularly suitable for pigmenting plastics having processing temperatures above 200.degree. C.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: May 12, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Hunger, Heinrich Frolich, Hans-Joachim Lenz
  • Patent number: 4664709
    Abstract: This invention is directed to new azoacylacetamide dispersing agents for azo pigments and azo pigment compositions made therefrom. The pigment compositions of this invention comprise a mixture of dispersing agents which are represented below by abbreviated Formula I and pigments which are represented by the abbreviated Formula II, wherein said dispersing agents are present in an amount of 1-25% and said pigments are present in an amount of 99 to 75%: ##STR1## where: A is an aromatic or heterocyclic amino group;B is an aromatic or heterocyclic bisdiazonium group;D is an aliphatic polyamino group containing at least three nitrogen atoms.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: May 12, 1987
    Assignee: American Hoechst Corporation
    Inventor: Richard Castenson