Oxygen Double Bonded Directly To Sulfur Patents (Class 534/882)
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Publication number: 20130227797Abstract: The invention relates to the dyeing of human keratinous fibres, in particular the hair, using anionic direct dyes or acid dyes having a tetraalkylammonium counterion of formula (I) with Col(?)m. R1, R2, R3, R4, m, and n as defined in the description. A subject-matter of the invention is a dyeing composition comprising an anionic dye of formula (I) and a method for dyeing keratinous fibres, such as the hair, employing the said composition. A subject-matter of the invention is likewise novel dyes of formula (I) and their uses for the colouring of keratinous fibres. This composition makes it possible to obtain a chromatic, powerful and particularly persistent colouring on keratinous fibres.Type: ApplicationFiled: November 16, 2011Publication date: September 5, 2013Applicant: L'OREALInventor: Andrew Greaves
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Publication number: 20040167322Abstract: A chemical amplification type resist composition comprising a specific benzenesulfonyldiazomethane containing a long-chain alkoxyl group at the 2-position on benzene ring has many advantages including improved resolution, improved focus latitude, minimized line width variation or shape degradation even on long-term PED, minimized debris left after coating, development and peeling, and improved pattern profile after development and is thus suited for microfabrication.Type: ApplicationFiled: February 12, 2004Publication date: August 26, 2004Inventors: Youichi Ohsawa, Katsuhiro Kobayashi, Yoshitaka Yanagi, Kazunori Maeda
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Patent number: 5770708Abstract: A process for preparing aqueous preparations of azo dyes of the formula ##STR1## where R is hydrogen or C.sub.1 -C.sub.4 -alkyl andKat.sym. is the equivalent of a cation which derives from a tertiary amine of the ethanolamine or propanolamine series,by diazotization of an aniline of the formula ##STR2## with neopentylglycol dinitrite in an aqueous medium and coupling of the resulting reaction mixture with .beta.-naphthol in the presence of a water-miscible diluent and of an amine comprises using an amine comprising a tertiary amine of the ethanolamine or propanolamine series.Type: GrantFiled: May 27, 1997Date of Patent: June 23, 1998Assignee: BASF AktiengesellschaftInventor: Rudolf Bermes
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Patent number: 5243031Abstract: A process for the production of a monoazo lake coated with a water-insoluble metal salt of rosin, which comprises the steps of:(a) adjusting a mixed solution containing a monoazo dye having a water-soluble group and an alkali metal or ammonium salt of rosin to pH of 8 to 12, and adding an stoichiometeric amount of a metal salt of at least one metal for insolubilizing rosin selected from the group consisting of zinc, aluminum, copper and manganese to form a water-insoluble rosin metal salt, and(b) adjusting the resultant mixture containing the water-insoluble rosin metal salt to pH of 9 to 12 and adding a metal salt of at least one metal for forming a lake of a monoazo dye selected from the group consisting of calcium, barium and strontium to form a monoazo lake.Type: GrantFiled: January 6, 1992Date of Patent: September 7, 1993Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Hitoshi Sugamo, Nobuyuki Tomiya, Yusuke Watabe
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Patent number: 5144014Abstract: A monoazo lake which comprises a monoazo dye, a lake-forming metal and a water-insoluble metal salt of a rosin, and which is coated with the water-insoluble water salt of the rosin, the lake-forming metal being at least one metal selected from calcium, barium and strontium, the metal of the water-insoluble metal salt being at least one metal selected from zinc, aluminum, copper and manganese, and a process for the production of a monoazo lake coated with a water-insoluble metal salt of a rosin, which comprises carrying out the following steps (1) and (2) in the order of (1) to (2) or (2) to (1):(1) a step of forming a monoazo lake by forming a lake of a monoazo dye with a metal salt of at least one metal for formation of a lake of the monoazo dye selected from calcium, barium and strontium, and(2) a step of forming the water-insoluble metal salt of the rosin by insolubilizing the rosin with a metal salt of at least one metal for insolubilization of the rosin selected from zinc, aluminum, copper and manganese.Type: GrantFiled: August 8, 1990Date of Patent: September 1, 1992Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Hitoshi Sugamo, Nobuyuki Tomiya, Yusuke Watabe
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Patent number: 5084106Abstract: A monoazo lake pigment of the formula (I): ##STR1## whose X-ray diffraction pattern shows a high diffraction intensity at a diffraction angle (2.theta..+-.0.2.degree.; Cu - K.sub..alpha.) of 4.9.degree., moderate diffraction intensities at 18.4.degree., 25.9.degree. and 26.8.degree. and relatively low diffraction intensities at 11.1.degree., 15.3.degree. and 21.2.degree., and printing ink, a paint and plastics in which the monoazo lake pigment is contained.Type: GrantFiled: December 23, 1987Date of Patent: January 28, 1992Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Nagatoshi Kobayashi, Hirohito Ando
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Patent number: 4918183Abstract: The invention relates to monoazo dyes of the formula ##STR1## wherein K is the radical of a coupling component of the benzene, naphthalene or heterocyclic series, and R is hydrogen, halogen, carboxy, a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkanoylamino, C.sub.1 -C.sub.6 alkylsulfonylamino, C.sub.1 -C.sub.6 alkylsulfonyl, phenyl(C.sub.1 -C.sub.4)alkylsulfonyl or naphthyl(C.sub.1 -C.sub.4)alkylsulfonyl or benzoyl radical, which radicals may be further substituted, or is a ##STR2## group, wherein each of R.sub.1 and R.sub.2 independently of the other is hydrogen or a C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl radical, which radicals may be further substituted, and wherein X is hydrogen, halogen or a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkanoylamino or C.sub.1 -C.sub.6 alkylsulfonylamino radical, which radicals may be further substituted.These dyes give dyeings of good light- and wetfastness properties on polyamide material.Type: GrantFiled: October 24, 1985Date of Patent: April 17, 1990Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter
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Patent number: 4906740Abstract: The present invention relates to monoazo dyes which dye polyamide material with good light- and wet-fastness and which have the formula ##STR1## in which K is the radical of an amino- or alkoxy-benzene, amino- or alkoxy-naphthalene, naphthol, aminonaphthol, pyrazolone, aminopyrazole, indole, naphthimidazole, diphenylamine, tetrahydroquinoline or acetoacetamide and can be further substituted, R is hydrogen, halogen, C.sub.1-6 -alkyl, trifluoromethyl, carboxyl or a --SO.sub.2 --C.sub.1-6 --alkyl, --SO.sub.2 --R.sub.1, ##STR2## --CO--R.sub.4 group, in which R.sub.1 is a substituted or unsubstituted phenyl- or naphthyl-C.sub.1-4 -alkyl radical, R.sub.2 and R.sub.3 independently of one another are hydrogen or a substituted or unsubstituted C.sub.1-6 -alkyl or C.sub.5-7 -cycloalkyl radical and R.sub.4 is a substituted or unsubstituted phenyl radical, and X is hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy or halogen, and in which R in formula (1) may not be hydrogen or chlorine if the radical --N.dbd.Type: GrantFiled: July 15, 1986Date of Patent: March 6, 1990Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter
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Patent number: 4719292Abstract: A novel crystallographic modification (.beta.-modification) of the pigment C. I. Pigment Red 53:1 is described and claimed which has characteristic reflection values in its X-ray diffraction pattern obtained by means of Cu-K.sub..alpha. radiation. This novel pigment form is obtained by reacting an aqueous solution of an alkali metal or ammonium salt of the formula 1 ##STR1## with the equivalent amount of a water-soluble barium salt in the presence of a compound of the formula 2 ##STR2## The modification is distinguished by a more yellowish-red shade as compared to the known .alpha.-modification.Type: GrantFiled: June 23, 1983Date of Patent: January 12, 1988Assignee: Hoechst AktiengesellschaftInventors: Franz Schui, Reinhold Deubel, Norbert Wester
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Patent number: 4625018Abstract: Novel red azo pigment--fortified latex compositions for use in printing inks. The novel pigment compositions have superior burn-out resistance and color strength. The novel pigment compositions are made by coupling orthanilic acid derivatives (including optionally, disulfonated amine derivatives) with B-napthal precipitating the metal salts and mixing with fortified latex dispersions. The fortified latex dispersion comprises a dispersed polymer phase in a dissolved polymer phase. The dispersed polymer is preferably a high molecular weight copolymer while the soluble polymer is preferably a low molecular weight acrylic copolymer containing carboxyl group functionality. The novel pigment compositions have superior color strength.Type: GrantFiled: August 26, 1985Date of Patent: November 25, 1986Assignee: Inmont CorporationInventor: Byron G. Hays
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Patent number: 4602084Abstract: Monoazo dyes of the formula ##STR1## in which K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series, and R is a ##STR2## --CO--R.sub.2 or --SO.sub.2 --O--R.sub.2 group in which R.sub.1 is hydrogen or C.sub.1-4 -alkyl and R.sub.2 is a substituted or unsubstituted monosulfo-C.sub.1-12 -alkyl radical, a substituted or unsubstituted monosulfophenyl, disulfophenyl, monosulfonaphthyl or disulfonaphthyl radical, and X and Y, independently of each other, are hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, halogen, C.sub.2-6 -alkanoylamino, C.sub.1-5 -alkylsulfonylamino or a substituted or unsubstituted phenyl or phenoxy radical, produce dyeings on polyamide material which have good light and wet fastness properties.Type: GrantFiled: July 8, 1983Date of Patent: July 22, 1986Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter
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Patent number: 4567252Abstract: Azo dyestuff of the formula ##STR1## wherein X is secondary amino or tertiary amino moiety, useful for dyeing and printing hydrophobic fiber materials to produce a deep orange color having excellent fastness properties and also useful for coloring organic solvents, mineral oil products, waxes, plastics and surface coatings.Type: GrantFiled: May 6, 1983Date of Patent: January 28, 1986Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Horst Tappe, Albert Bode, Manfred Hahnke, Kurt Roth
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Patent number: 4560744Abstract: Compounds which in the form of the free acids correspond to the formula ##STR1## where A is a radical of a diazo component or of an amine,B is a radical of a coupling component or of an aldehyde,R.sup.1 is chlorine or bromine,R.sup.2 is methoxy or ethoxy,X is .dbd.N-- or .dbd.CH--,Y is --O-- or --COO-- andZ is --O-- or --NH--,are dyes which are very suitable for dyeing nylons and natural polyamides.Type: GrantFiled: March 6, 1981Date of Patent: December 24, 1985Assignee: BASF AktiengesellschaftInventors: Hans Baumann, Klaus Grychtol
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Patent number: 4530724Abstract: The color of azo pigments derived from 2-hydroxynaphthalene-3-carboxylic acid or its salts are improved by the coupling reaction of a diazonium compound of an aromatic aminosulfonic acid with a coupling component which is a mixture of (1) 2-hydroxynaphthalene-3-carboxylic acid or its salt, (2) .beta.-naphthol or its salt, and (3) a phenolic by-product having a molecular weight of about 300 and containing about 1 equivalent of phenolic hydroxy groups. The phenolic by-product can be obtained by evaporating .beta.-naphthol from a tarry substance formed as a by-product during the reaction of an alkali .beta.-naphtholate with carbon dioxide, extracting the residue with an alkali and precipitating the soluble matter with an acid. The color or tone of the azo pigment is stabilized by the use of the coupling component.Type: GrantFiled: September 1, 1982Date of Patent: July 23, 1985Assignee: Kabushiki Kaisha Ueno Seiyaku Uno KenkyujoInventors: Ryuzo Ueno, Hiroaki Tsuchiya, Shigeru Itoh