Purification Or Recovery Patents (Class 534/887)
  • Patent number: 4609726
    Abstract: Compounds of the general formula I ##STR1## where R is hydrogen or C.sub.1 -C.sub.6 -alkyl and X is chlorine or bromine, with the proviso that X is only bromine when R is H, possess pigment properties and are distinguished by high color strength, brilliance and very good fastness properties.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: September 2, 1986
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhard Kemper, Egon Liedek
  • Patent number: 4607096
    Abstract: Azo pigments are obtained by diazotizing a diazotizable aromatic amine without solubilizing groups in anhydrous dipolar aprotic water-miscible solvents with the stoichiometric amount or a small excess of nitrosylsulfuric acid or nitrosyl chloride, coupling the diazonium compound so obtained with a coupling component and isolating the pigment obtained in usual manner. This process is carried out in homogeneous solution and yields azo pigments the advantageous properties of which cannot be achieved by other methods, for example, the excellent purity, grain softness, narrow range of particle size distribution, excellent dispersibility in plastic materials and color lacquers, high gloss and excellent opacity in color lacquers.
    Type: Grant
    Filed: November 4, 1982
    Date of Patent: August 19, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Josef Landler, Klaus Hunger, Erhard Worfel
  • Patent number: 4605734
    Abstract: A compound, useful as an anti-cancer drug or agent, having the formula: ##STR1## where X represents hydroxyl, amino or alkylamino, Y represents one member selected from ##STR2## or alkylated derivatives thereof, and Z represents hydrogen or one of the basic groups of Y, an acid addition salt of the said compound, a nitrogen oxide derivative of the said compound in the case where it contains a ring nitrogen atom or atoms.
    Type: Grant
    Filed: September 25, 1984
    Date of Patent: August 12, 1986
    Inventor: Douglas Shortridge
  • Patent number: 4589921
    Abstract: The invention relates to a process for improving the application properties of Pigment Yellow 13. The crude pigment is heated in an aqueous suspension to temperatures above 100.degree. C. Pigment Yellow 13 thus obtained is particularly suitable for replacing lead-containing chrome yellow pigments of comparable shade.
    Type: Grant
    Filed: June 10, 1985
    Date of Patent: May 20, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Hunger, Wolfgang Rieper
  • Patent number: 4562248
    Abstract: Azo dyes having the general formula ##STR1## in which each of X, Y and Z are independently selected from H and a variety of substituents, preferably provided that at least one of X and Y is a substituent selected, for example, from --CN, halogen, alkyl, and alkylsulfonyl, and C is the residue of a phenol, naphthol, indole, imidazothiazole, pyrazolone, thiazole, isothiazole or pyrazole type disperse dye coupling component. These dyes which are unexpectedly non-phototropic produce yellow to orange shades on hydrophobic fibers and exhibit improvements in one or more properties such as dyeability, dye exhaustion rate, light fastness, nonblooming, pH stability, build, fastness to ozone and nitrogen oxide, crock and wash fastness, migration, transfer, and pH stability on polyester, polyamide and other fibers including cellulose ester.
    Type: Grant
    Filed: November 25, 1983
    Date of Patent: December 31, 1985
    Assignee: Eastman Kodak Company
    Inventors: Max A. Weaver, Jean C. Fleischer
  • Patent number: 4560747
    Abstract: A process for producing granulates of water-soluble dyes by means of fluidized bed granulation, wherein there is added a granulating auxiliary having a softening point or softening range between 30.degree. and 150.degree. C. and consisting of(a) at least one compound of the formula IA--(CH.sub.2 CH.sub.2 O).sub.n --H (I)in which A is the group R--O-- or ##STR1## wherein R is an aliphatic or alicyclic hydrocarbon radical having 8 to 22 carbon atoms, R' is an aliphatic hydrocarbon radical having 8 to 22 carbon atoms, and n is 10 to 200, preferably 20 to 150, or(b) a mixture of a compound of the formula II ##STR2## in which m is 50 to 500, and x is 3 to 5, with a compound of the formula IIIR.sub.1 --NH--CO--NH--R.sub.1 (III),in which each R.sub.1 independently of the other is hydrogen or methyl, or(c) a mixture of a compound of the formula I with at least one compound of the formula II or III.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: December 24, 1985
    Assignee: Ciba Geigy Corporation
    Inventors: Beat Bruttel, Hansjorg Schneider, Werner H. Dorfel
  • Patent number: 4560746
    Abstract: The disodium salt of 1-[(6-methoxy-4-sulfo-3-methylphenyl)azo]-2-naphthol-6-sulfonic acid (FD and C Red 40), the disodium salt of 1-[(4-sulfophenyl)azo]-2-naphthol-6-sulfonic acid (FD and C Yellow 6), the trisodium salt of 1-[1-(4-sulfonaphthyl)azo]-2-naphthol-3,6-disulfonic acid (FD and C Red 2), the disodium salt of 2-[1-(4-sulfonaphthyl)azo]-1-naphthol-4-sulfonic acid (Carmoisine) and the sodium salt of 2-(2-quinolyl)-1,3-indanedione-sulfonic acid (D and C Yellow 10) are prepared and purified in high yield and in a high state of purity by subjecting their aqueous reaction mixtures to ultrafiltration through a membrane of such structure and under such conditions that the impurities are separated from the reaction mixtures, and the products are concentrated in high purity concentrates from which the products can be isolated directly by evaporation of the solvent.
    Type: Grant
    Filed: November 30, 1984
    Date of Patent: December 24, 1985
    Assignee: The Hilton-Davis Chemical Co.
    Inventors: Robert W. J. Rebhahn, Wayne L. Cook
  • Patent number: 4560745
    Abstract: A process for the preparation of dyes which contain sulfonic acid groups and have a low electrolyte content, wherein an aqueous solution or suspension, which may or may not contain inorganic salts, of the dye containing sulfonic acid groups is(a) mixed with an amount, equivalent to the said dye, of a non-emulsifying, water-insoluble amine of a total of 12 to 40 carbon atoms, which forms, with the said dye, a salt which is sufficiently lipophilic for it to separate spontaneously from the aqueous phase,(b) the pH is brought to <5 with an acid and the batch is mixed thoroughly,(c) the two resulting phases of different density are separated, and(d) the phase which consists of the lipophilic ammonium salt of the dye is mixed, with or without prior washing with water, with a water-soluble base whose sulfonate salt is to be prepared, and with water, the resulting phases are separated, and the salt is left in the aqueous solution or is isolated therefrom.
    Type: Grant
    Filed: May 12, 1981
    Date of Patent: December 24, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Volkmar Weberndoerfer, Friedrich Brunnmueller, Manfred Eisert, Rudolf Bermes
  • Patent number: 4556706
    Abstract: Dyes of formula ##STR1## wherein D is the radical of a formazane dye of formula ##STR2## X is a group which is capable of complex formation, Z is a --NH.sub.2 group, a substituted or unsubstituted aliphatic or aromatic amino group, n is 1 or 2 and m is an integer from 2 to 5, and the benzene rings A, B and C can contain further substituents in addition to the --SO.sub.
    Type: Grant
    Filed: April 28, 1980
    Date of Patent: December 3, 1985
    Assignee: Ciba Geigy Corporation
    Inventors: Gert Hegar, Herbert Seiler
  • Patent number: 4541831
    Abstract: Described is a process for the production of substantially dustless water-soluble dye or optical brightener compositions, which process comprises mixing a dry, solid inorganic salt, heated to at least 50.degree. C., with a mixture of at least one dye or optical brightener, an adhesive as e.g. sorbitol, a dust binding surface active agent and further additives. Such compositions are negligibly dusty to dustfree, and retain these properties even after storage for months, particularly in the case where spray-dried material is used.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: September 17, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Walter Gunther, Kurt Hintermayr
  • Patent number: 4536569
    Abstract: A compound of the formula, ##STR1## wherein R.sup.1 is methyl or ethyl, R.sup.2 and R.sup.3 are each C.sub.5 -- or C.sub.6 --alkyl, and Z is chlorine for use as a blue disperse dye of hydrophobic fibers, either alone or as a mixed dye in combination with anthraquinone; the compound combines low cost relative to anthraquinone with superior stability in the dye bath and excellent dyeability; mixed dyes retain anthraquinone-imparted brilliance of color, have good color fastness, dyeability and reproducibility characteristics, and maintain low cost.
    Type: Grant
    Filed: March 26, 1981
    Date of Patent: August 20, 1985
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kiyoyasu Hashimoto, Kenji Yoshinaga, Yoshio Mori, Junzaburo Seino, Hirohito Kenmochi, Katsunobu Sato
  • Patent number: 4535151
    Abstract: A process for the wet granulation of organic pigment is disclosed which consists in treating under vigorous agitation an aqueous suspension of pigment with acetic anhydride, propionic anhydride or a mixture thereof. Acetic anhydride is used preferentially. After hydrolysis of the anhydride, besides the granules, an aqueous solution of acid or its corresponding salt, directly saleable or re-usable in the chemical industry, is recovered whereby problems related to the recovery of organic solvents are avoided.
    Type: Grant
    Filed: May 16, 1984
    Date of Patent: August 13, 1985
    Assignee: I.C.I. Francolor S.A.
    Inventor: Pierre L. E. Fournier
  • Patent number: 4528367
    Abstract: A method of preparing 3,3'-azo-bis-(6-hydroxy benzoic acid) of formula I ##STR1## and salts thereof in at least 98% purity for treating inflammatory intestinal diseases. According to the invention a compound II ##STR2## is diazotized, and the diazonium salt obtained is coupled with a compound III ##STR3## The formed intermediate IV, which is also comprised by the invention, ##STR4## is hydrolized in alkaline medium to form the compound I. R.sub.1, R.sub.2 and R.sub.3 signify lower alkyl, R.sub.2 also possibly substituted phenyl.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: July 9, 1985
    Assignee: Pharmacia AB
    Inventors: Karl H. Agback, Alf S. Nygren
  • Patent number: 4507471
    Abstract: Trisazo compounds having the following general formula I: ##STR1## are useful as charge carrier generating materials for electrophotographic elements. Multilayer electrophotographic elements having a charge carrier generating layer containing these compounds as charge carrier generators and having a separate charge transport layer containing a charge transport material are particularly excellent in sensitivity in the 780-800 nm wavelength region.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: March 26, 1985
    Assignee: Ricoh Company, Ltd.
    Inventor: Masafumi Ohta
  • Patent number: 4504416
    Abstract: When diazotizing a p-amino-benzoic acid anilide, the anilide nucleus of which is substituted in its paraposition by carbamoyl, acetamino or chloro and coupling it onto 5-acetoacetylamino-benzimidazolone-(2) monoazo pigments are obtained having a high fastness to light, solvents, overlacquering and bleeding and a very high heat resistance.
    Type: Grant
    Filed: April 21, 1981
    Date of Patent: March 12, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Hunger, Manfred Pesenacker