Benzene Ring Bonded Directly To Ring Nitrogen Of The Five-membered Hetero Ring (e.g., N-phenylmaleimide, Etc.) Patents (Class 548/549)
  • Patent number: 4812577
    Abstract: A mercuric maleimide is utilized as a pharmaceutical kit for preparing radiohalogenated maleimides.
    Type: Grant
    Filed: February 12, 1988
    Date of Patent: March 14, 1989
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Prem C. Srivastava
  • Patent number: 4812579
    Abstract: A process for producing N-substituted maleimides which comprises heating maleic anhydride and an aromatic or aliphatic amine, or maleic acid monoamides obtained from them, in the presence of an ion exchange resin in an organic solvent to effect cyclodehydration.
    Type: Grant
    Filed: October 13, 1987
    Date of Patent: March 14, 1989
    Assignee: Nitto Chemical Industry Co., Ltd.
    Inventors: Shunichi Doi, Yasuyuki Takayanagi
  • Patent number: 4804400
    Abstract: Novel derivatives of N-phenylmaleic acid imide and N-phenylsuccinimide have good pre- and post-emergence selective herbicidal properties and they influence plant growth. The compounds correspond to the formula I ##STR1## in which .vertline.: represent a single or double bond,R.sup.1 represents hydrogen or fluorine,R.sup.2 represents halogen,Y represents C.sub.1 -C.sub.8 -alkyl,Z represents hydrogen or C.sub.1 -C.sub.8 -alkyl, andA represents hydrogen or a group ##STR2## wherein R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 represent customary organic radicals and X represents oxygen, sulphur, SO, SO.sub.2, NH, alkylimino or alkenylimino.
    Type: Grant
    Filed: September 3, 1987
    Date of Patent: February 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Moser, Georg Pissiotas, Hans-Georg Brunner, Beat Bohner, Marcus Baumann
  • Patent number: 4788295
    Abstract: Novel N-(meth)allyloxyphenylmaleimides are prepolymerized with at least one bis-imide and formulated, together with at least one imidazole compound, into thermosetting compositions useful for the production of a wide variety of shaped articles having improved mechanical properties.
    Type: Grant
    Filed: July 1, 1986
    Date of Patent: November 29, 1988
    Assignee: Rhone-Poulenc Specialites Chimiques
    Inventor: Michel Rakoutz, deceased
  • Patent number: 4786738
    Abstract: A method for the production of maleimides, which comprises subjecting maleinamic acids to ring-closure imidation in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst at a temperature in the range of 120.degree. to 250.degree. C. while removing the formed water in the form of an azeotrope with said organic solvent and thereafter purifying the produced maleimides.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: November 22, 1988
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuichi Kita, Kentaro Sakamoto, Masao Baba, Atsushi Okubo
  • Patent number: 4780546
    Abstract: A method for the production of maleimides, which comprises subjecting maleinamic acids to ring-closure imidation in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst at a temperature in the range of 120.degree. C. to 250.degree. C. while removing the formed water in the form of an azeotrope with said organic solvent and thereafter purifying the produced maleimides.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: October 25, 1988
    Assignee: Nippon Shokubai Kagaku Kogyo Co. Ltd.
    Inventors: Yuichi Kita, Kentaro Sakamoto, Masao Baba, Atsushi Okubo
  • Patent number: 4777237
    Abstract: Novel, heat-stable imido polymers, well adopted, e.g., as coating or molding resins, comprise the polymerizates of (a) at least one N,N'-bismaleimide, (b) at least one diprimary diamine, and (c) at least one N-(meth)-allyloxyphenylmaleimide.
    Type: Grant
    Filed: November 13, 1986
    Date of Patent: October 11, 1988
    Assignee: Rhone-Poulenc Specialities Chimiques
    Inventors: Rene Dien, Michel Rakoutz
  • Patent number: 4735792
    Abstract: A radiopharmaceutical for antibody labeling comprising an iodophenyl maleimide that attaches thiol sites of proteins thereby maintaining bioreactivity largely located at the nitrogen sites.
    Type: Grant
    Filed: April 28, 1987
    Date of Patent: April 5, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Prem C. Srivastava
  • Patent number: 4736056
    Abstract: This invention relates to a process for preparing a malonic acid derivative compound of formula (i) depicted herein in high yield and high purity by reacting a malonic acid derivative compound of formula (ii) depicted herein with an alkylating agent of formula (iii) depicted herein in the presence of a solvent and a base.
    Type: Grant
    Filed: December 15, 1986
    Date of Patent: April 5, 1988
    Inventors: Oliver W. Smith, Russell J. Outcalt
  • Patent number: 4705866
    Abstract: A process for the preparation of N-brominated or N-chlorinated phenylmaleimide by reacting maleic anhydride and a brominated or chlorinated aniline compound at temperatures of from about 100.degree. C. to about 210.degree. C. in the presence of tin containing catalyst compound and optionally an inert solvent.
    Type: Grant
    Filed: December 26, 1985
    Date of Patent: November 10, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Robert G. Gastinger
  • Patent number: 4683276
    Abstract: Thermoset products are prepared by polymerizing (A) at least one thermosettable compound which contains both a maleimide group and a cyanate group such as 3-(2,5-dihydro-2,5-dioxo-1H-pyrrol-1-yl)phenyl cyanate and optionally (B) at least one of (1) at least one aromatic polycyanate such as bisphenol A dicyanate; (2) at least one polymaleimide such as N,N'-(methylenedi-p-phenylene)bismaleimide; (3) at least one material having an average of more than one vicinal epoxide group per molecule such as a diglycidyl ether of bisphenol A; (4) at least one polymerizable ethylenically unsaturated material such as styrene; or (5) a mixture of any two or more of components 1-4 in any combination.
    Type: Grant
    Filed: October 1, 1985
    Date of Patent: July 28, 1987
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4659840
    Abstract: Provided is a method for preparing diaryl iodonium salts represented by the formula:[Ar.sub.1 --I.sup..sym. --Ar.sub.2 ]HSO.sub.4.sup..crclbar.wherein Ar.sub.1 and Ar.sub.2 respectively are an aryl group which may be substituted with an electron donor group and which may be the same or different which comprises subjecting a compound represented by the formula Ar.sub.1 --H wherein Ar.sub.1 is as defined above and a compound Ar.sub.2 --I wherein Ar.sub.2 is as defined above to a coupling reaction in a sulfuric acid solution containing an oxidizing agent and diluted with a diluting agent to a concentration of 85% by weight or less at a reaction temperature in the range from -20.degree. to +35.degree. C.
    Type: Grant
    Filed: March 8, 1984
    Date of Patent: April 21, 1987
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Isoo Shimizu, Yasuo Matsumura, Yoshihisa Inomata
  • Patent number: 4638078
    Abstract: The invention is a compound which comprises an amido alkenoic acid or a water-soluble salt thereof and and arylcyclobutene moiety, wherein the cyclobutene moiety is fused to the aryl radical, and wherein the amide nitrogen is connected to the aryl radical of the arylcyclobutenyl moiety by a direct bond or a bridging member.
    Type: Grant
    Filed: April 25, 1985
    Date of Patent: January 20, 1987
    Assignee: The Dow Chemical Company
    Inventor: Robert A. Kirchhoff
  • Patent number: 4599430
    Abstract: A process is provided for the nitrogenation of hydrocarbons, resulting in the production of cyclic imides and nitriles from hydrocarbons contacted with molecular oxygen and a nitrogenating agent, including ammonia or primary amines, in the presence of an oxidation catalyst containing variable valency metal oxides, in the vapor phase at elevated temperature.
    Type: Grant
    Filed: February 2, 1984
    Date of Patent: July 8, 1986
    Assignee: The Standard Oil Company
    Inventors: Ernest C. Milberger, Eunice K. T. Wong
  • Patent number: 4552890
    Abstract: A method of combatting fungi which comprises applying to fungi or a fungus habitat a fungicidally effective amount of at least one maleic acid N-aralkyl-imide of the formula ##STR1## in which X is hydrogen or halogen,Hal is halogen, andm is 2,3 or 4.Those compounds are new in whichHal is chlorine or bromine, andX is hydrogen or bromine if m is 2, orX is chlorine if m is 4.
    Type: Grant
    Filed: February 8, 1984
    Date of Patent: November 12, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Marzolph, Heinz U. Blank, Paul Reinecke, Wilhelm Brandes, Gerd Hanssler
  • Patent number: 4500719
    Abstract: Disclosed are novel alkenylphenylmaleimide derivatives having the general formula ##STR1## where R is an alkenyl radical of from 3 to 12 carbon atoms, R' is a hydrogen atom, a halogen atom, or a straight-chain or branched alkyl radical of from 1 to 4 carbon atoms, and n is a whole number of from 1 to 4, and linear dimers thereof as well as a process for the preparation of such maleimide compounds.
    Type: Grant
    Filed: August 13, 1982
    Date of Patent: February 19, 1985
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
  • Patent number: 4460783
    Abstract: An ether imide of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and D are as defined in the specification produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid can give a composition together with one or more unsaturated polyesters, epoxy compounds, amines, and the like to give shaped articles excellent in flexibility and heat resistance.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: July 17, 1984
    Assignee: Hitachi, Ltd.
    Inventors: Akio Nishikawa, Masashi Shitara, Susumu Era, Toshiaki Fukushima, Hiroshi Suzuki, Hisashi Kohkame
  • Patent number: 4455315
    Abstract: A 2,3-dichloro-N-difluoromethoxyphenylmaleimide of the formula (I): ##STR1## is useful as an agricultural and horticultural fungicide, particularly for fruit trees.
    Type: Grant
    Filed: November 6, 1981
    Date of Patent: June 19, 1984
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Kazuhiro Kojima, Haruaki Ito, Hiroshi Kubo
  • Patent number: 4439229
    Abstract: Compounds of the formula: ##STR1## wherein A is O or S, halo is chloro, bromo or fluoro; X' is --CH.sub.2 --, O or S; X is hydrogen or halo; R.sup.1 and R.sup.2 are the same or different radicals selected from hydrogen or lower alkyl; and Z can be a variety of substituents and agronomically acceptable salts, esters and amides as well as other heterocyclic benzenes are disclosed as selective herbicides.
    Type: Grant
    Filed: May 6, 1982
    Date of Patent: March 27, 1984
    Assignee: Rohm and Haas Company
    Inventor: Colin Swithenbank
  • Patent number: 4400521
    Abstract: Maleimide compounds represented by the general formula (I) ##STR1## where R and R' are a hydrogen atom, a halogen atom, or an alkyl radical of from 1 to 4 carbon atoms, and n and n' are a whole number of from 1 to 4; and a process for the preparation of the maleimide compounds, in which a maleamic acid represented by the general formula (II) ##STR2## where R and R' are a hydrogen atom, a halogen atom, or an alkyl radical of from 1 to 4 carbon atoms, and n and n' are a whole number of from 1 to 4, is contacted with a dehydrating agent in an organic solvent.
    Type: Grant
    Filed: October 29, 1980
    Date of Patent: August 23, 1983
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
  • Patent number: 4376206
    Abstract: Disclosed are novel alkenylphenylmaleimide derivatives having the general formula ##STR1## where R is an alkenyl radical of from 3 to 12 carbon atoms, R' is a hydrogen atom, a halogen atom, or a straight-chain or branched alkyl radical of from 1 to 4 carbon atoms, and n is a whole number of from 1 to 4, and linear dimers thereof as well as a process for the preparation of such maleimide compounds.
    Type: Grant
    Filed: March 19, 1980
    Date of Patent: March 8, 1983
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
  • Patent number: 4329556
    Abstract: The invention relates to new arylsulfonylazides as well as the use of these compounds. The new compounds are characterized by the general formula: ##STR1## where R=aryl; x=1 or 2; and R.sup.1 and R.sup.2 are selected from H, CH.sub.3 and Cl and may be the same or different, with the provision that CH.sub.3 and Cl are not present side by side. The compounds according to the invention are suitable as photoinitiators in the preparation of relief structures by phototechniques from olefinically unsaturated polymers, as well as cross-link enhancing agents in the radical-wise cross linking of thermoplastic polymers.
    Type: Grant
    Filed: May 9, 1980
    Date of Patent: May 11, 1982
    Assignee: Siemens Aktiengesellschaft
    Inventors: Roland Rubner, Eberhard Kuhn, Hellmut Ahne