Benzene Ring Bonded Directly To Ring Nitrogen Of The Five-membered Hetero Ring (e.g., N-phenylmaleimide, Etc.) Patents (Class 548/549)
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Patent number: 4812577Abstract: A mercuric maleimide is utilized as a pharmaceutical kit for preparing radiohalogenated maleimides.Type: GrantFiled: February 12, 1988Date of Patent: March 14, 1989Assignee: The United States of America as represented by the United States Department of EnergyInventor: Prem C. Srivastava
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Patent number: 4812579Abstract: A process for producing N-substituted maleimides which comprises heating maleic anhydride and an aromatic or aliphatic amine, or maleic acid monoamides obtained from them, in the presence of an ion exchange resin in an organic solvent to effect cyclodehydration.Type: GrantFiled: October 13, 1987Date of Patent: March 14, 1989Assignee: Nitto Chemical Industry Co., Ltd.Inventors: Shunichi Doi, Yasuyuki Takayanagi
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Patent number: 4804400Abstract: Novel derivatives of N-phenylmaleic acid imide and N-phenylsuccinimide have good pre- and post-emergence selective herbicidal properties and they influence plant growth. The compounds correspond to the formula I ##STR1## in which .vertline.: represent a single or double bond,R.sup.1 represents hydrogen or fluorine,R.sup.2 represents halogen,Y represents C.sub.1 -C.sub.8 -alkyl,Z represents hydrogen or C.sub.1 -C.sub.8 -alkyl, andA represents hydrogen or a group ##STR2## wherein R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 represent customary organic radicals and X represents oxygen, sulphur, SO, SO.sub.2, NH, alkylimino or alkenylimino.Type: GrantFiled: September 3, 1987Date of Patent: February 14, 1989Assignee: Ciba-Geigy CorporationInventors: Hans Moser, Georg Pissiotas, Hans-Georg Brunner, Beat Bohner, Marcus Baumann
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Patent number: 4788295Abstract: Novel N-(meth)allyloxyphenylmaleimides are prepolymerized with at least one bis-imide and formulated, together with at least one imidazole compound, into thermosetting compositions useful for the production of a wide variety of shaped articles having improved mechanical properties.Type: GrantFiled: July 1, 1986Date of Patent: November 29, 1988Assignee: Rhone-Poulenc Specialites ChimiquesInventor: Michel Rakoutz, deceased
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Patent number: 4786738Abstract: A method for the production of maleimides, which comprises subjecting maleinamic acids to ring-closure imidation in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst at a temperature in the range of 120.degree. to 250.degree. C. while removing the formed water in the form of an azeotrope with said organic solvent and thereafter purifying the produced maleimides.Type: GrantFiled: October 27, 1986Date of Patent: November 22, 1988Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Yuichi Kita, Kentaro Sakamoto, Masao Baba, Atsushi Okubo
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Patent number: 4780546Abstract: A method for the production of maleimides, which comprises subjecting maleinamic acids to ring-closure imidation in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst at a temperature in the range of 120.degree. C. to 250.degree. C. while removing the formed water in the form of an azeotrope with said organic solvent and thereafter purifying the produced maleimides.Type: GrantFiled: October 27, 1986Date of Patent: October 25, 1988Assignee: Nippon Shokubai Kagaku Kogyo Co. Ltd.Inventors: Yuichi Kita, Kentaro Sakamoto, Masao Baba, Atsushi Okubo
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Patent number: 4777237Abstract: Novel, heat-stable imido polymers, well adopted, e.g., as coating or molding resins, comprise the polymerizates of (a) at least one N,N'-bismaleimide, (b) at least one diprimary diamine, and (c) at least one N-(meth)-allyloxyphenylmaleimide.Type: GrantFiled: November 13, 1986Date of Patent: October 11, 1988Assignee: Rhone-Poulenc Specialities ChimiquesInventors: Rene Dien, Michel Rakoutz
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Patent number: 4735792Abstract: A radiopharmaceutical for antibody labeling comprising an iodophenyl maleimide that attaches thiol sites of proteins thereby maintaining bioreactivity largely located at the nitrogen sites.Type: GrantFiled: April 28, 1987Date of Patent: April 5, 1988Assignee: The United States of America as represented by the United States Department of EnergyInventor: Prem C. Srivastava
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Patent number: 4736056Abstract: This invention relates to a process for preparing a malonic acid derivative compound of formula (i) depicted herein in high yield and high purity by reacting a malonic acid derivative compound of formula (ii) depicted herein with an alkylating agent of formula (iii) depicted herein in the presence of a solvent and a base.Type: GrantFiled: December 15, 1986Date of Patent: April 5, 1988Inventors: Oliver W. Smith, Russell J. Outcalt
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Patent number: 4705866Abstract: A process for the preparation of N-brominated or N-chlorinated phenylmaleimide by reacting maleic anhydride and a brominated or chlorinated aniline compound at temperatures of from about 100.degree. C. to about 210.degree. C. in the presence of tin containing catalyst compound and optionally an inert solvent.Type: GrantFiled: December 26, 1985Date of Patent: November 10, 1987Assignee: Atlantic Richfield CompanyInventor: Robert G. Gastinger
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Patent number: 4683276Abstract: Thermoset products are prepared by polymerizing (A) at least one thermosettable compound which contains both a maleimide group and a cyanate group such as 3-(2,5-dihydro-2,5-dioxo-1H-pyrrol-1-yl)phenyl cyanate and optionally (B) at least one of (1) at least one aromatic polycyanate such as bisphenol A dicyanate; (2) at least one polymaleimide such as N,N'-(methylenedi-p-phenylene)bismaleimide; (3) at least one material having an average of more than one vicinal epoxide group per molecule such as a diglycidyl ether of bisphenol A; (4) at least one polymerizable ethylenically unsaturated material such as styrene; or (5) a mixture of any two or more of components 1-4 in any combination.Type: GrantFiled: October 1, 1985Date of Patent: July 28, 1987Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4659840Abstract: Provided is a method for preparing diaryl iodonium salts represented by the formula:[Ar.sub.1 --I.sup..sym. --Ar.sub.2 ]HSO.sub.4.sup..crclbar.wherein Ar.sub.1 and Ar.sub.2 respectively are an aryl group which may be substituted with an electron donor group and which may be the same or different which comprises subjecting a compound represented by the formula Ar.sub.1 --H wherein Ar.sub.1 is as defined above and a compound Ar.sub.2 --I wherein Ar.sub.2 is as defined above to a coupling reaction in a sulfuric acid solution containing an oxidizing agent and diluted with a diluting agent to a concentration of 85% by weight or less at a reaction temperature in the range from -20.degree. to +35.degree. C.Type: GrantFiled: March 8, 1984Date of Patent: April 21, 1987Assignee: Nippon Petrochemicals Co., Ltd.Inventors: Isoo Shimizu, Yasuo Matsumura, Yoshihisa Inomata
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Patent number: 4638078Abstract: The invention is a compound which comprises an amido alkenoic acid or a water-soluble salt thereof and and arylcyclobutene moiety, wherein the cyclobutene moiety is fused to the aryl radical, and wherein the amide nitrogen is connected to the aryl radical of the arylcyclobutenyl moiety by a direct bond or a bridging member.Type: GrantFiled: April 25, 1985Date of Patent: January 20, 1987Assignee: The Dow Chemical CompanyInventor: Robert A. Kirchhoff
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Patent number: 4599430Abstract: A process is provided for the nitrogenation of hydrocarbons, resulting in the production of cyclic imides and nitriles from hydrocarbons contacted with molecular oxygen and a nitrogenating agent, including ammonia or primary amines, in the presence of an oxidation catalyst containing variable valency metal oxides, in the vapor phase at elevated temperature.Type: GrantFiled: February 2, 1984Date of Patent: July 8, 1986Assignee: The Standard Oil CompanyInventors: Ernest C. Milberger, Eunice K. T. Wong
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Patent number: 4552890Abstract: A method of combatting fungi which comprises applying to fungi or a fungus habitat a fungicidally effective amount of at least one maleic acid N-aralkyl-imide of the formula ##STR1## in which X is hydrogen or halogen,Hal is halogen, andm is 2,3 or 4.Those compounds are new in whichHal is chlorine or bromine, andX is hydrogen or bromine if m is 2, orX is chlorine if m is 4.Type: GrantFiled: February 8, 1984Date of Patent: November 12, 1985Assignee: Bayer AktiengesellschaftInventors: Gerhard Marzolph, Heinz U. Blank, Paul Reinecke, Wilhelm Brandes, Gerd Hanssler
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Patent number: 4500719Abstract: Disclosed are novel alkenylphenylmaleimide derivatives having the general formula ##STR1## where R is an alkenyl radical of from 3 to 12 carbon atoms, R' is a hydrogen atom, a halogen atom, or a straight-chain or branched alkyl radical of from 1 to 4 carbon atoms, and n is a whole number of from 1 to 4, and linear dimers thereof as well as a process for the preparation of such maleimide compounds.Type: GrantFiled: August 13, 1982Date of Patent: February 19, 1985Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
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Patent number: 4460783Abstract: An ether imide of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and D are as defined in the specification produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid can give a composition together with one or more unsaturated polyesters, epoxy compounds, amines, and the like to give shaped articles excellent in flexibility and heat resistance.Type: GrantFiled: January 19, 1981Date of Patent: July 17, 1984Assignee: Hitachi, Ltd.Inventors: Akio Nishikawa, Masashi Shitara, Susumu Era, Toshiaki Fukushima, Hiroshi Suzuki, Hisashi Kohkame
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Patent number: 4455315Abstract: A 2,3-dichloro-N-difluoromethoxyphenylmaleimide of the formula (I): ##STR1## is useful as an agricultural and horticultural fungicide, particularly for fruit trees.Type: GrantFiled: November 6, 1981Date of Patent: June 19, 1984Assignee: Showa Denko Kabushiki KaishaInventors: Kazuhiro Kojima, Haruaki Ito, Hiroshi Kubo
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Patent number: 4439229Abstract: Compounds of the formula: ##STR1## wherein A is O or S, halo is chloro, bromo or fluoro; X' is --CH.sub.2 --, O or S; X is hydrogen or halo; R.sup.1 and R.sup.2 are the same or different radicals selected from hydrogen or lower alkyl; and Z can be a variety of substituents and agronomically acceptable salts, esters and amides as well as other heterocyclic benzenes are disclosed as selective herbicides.Type: GrantFiled: May 6, 1982Date of Patent: March 27, 1984Assignee: Rohm and Haas CompanyInventor: Colin Swithenbank
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Patent number: 4400521Abstract: Maleimide compounds represented by the general formula (I) ##STR1## where R and R' are a hydrogen atom, a halogen atom, or an alkyl radical of from 1 to 4 carbon atoms, and n and n' are a whole number of from 1 to 4; and a process for the preparation of the maleimide compounds, in which a maleamic acid represented by the general formula (II) ##STR2## where R and R' are a hydrogen atom, a halogen atom, or an alkyl radical of from 1 to 4 carbon atoms, and n and n' are a whole number of from 1 to 4, is contacted with a dehydrating agent in an organic solvent.Type: GrantFiled: October 29, 1980Date of Patent: August 23, 1983Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
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Patent number: 4376206Abstract: Disclosed are novel alkenylphenylmaleimide derivatives having the general formula ##STR1## where R is an alkenyl radical of from 3 to 12 carbon atoms, R' is a hydrogen atom, a halogen atom, or a straight-chain or branched alkyl radical of from 1 to 4 carbon atoms, and n is a whole number of from 1 to 4, and linear dimers thereof as well as a process for the preparation of such maleimide compounds.Type: GrantFiled: March 19, 1980Date of Patent: March 8, 1983Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
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Patent number: 4329556Abstract: The invention relates to new arylsulfonylazides as well as the use of these compounds. The new compounds are characterized by the general formula: ##STR1## where R=aryl; x=1 or 2; and R.sup.1 and R.sup.2 are selected from H, CH.sub.3 and Cl and may be the same or different, with the provision that CH.sub.3 and Cl are not present side by side. The compounds according to the invention are suitable as photoinitiators in the preparation of relief structures by phototechniques from olefinically unsaturated polymers, as well as cross-link enhancing agents in the radical-wise cross linking of thermoplastic polymers.Type: GrantFiled: May 9, 1980Date of Patent: May 11, 1982Assignee: Siemens AktiengesellschaftInventors: Roland Rubner, Eberhard Kuhn, Hellmut Ahne