Abstract: A sliding member which has low sliding resistance, can prevent the leakage of a liquid, has low dust emission properties and low leachability, and can be manufactured in a simple manner; and a method for manufacturing the sliding member. The sliding member includes an elastic molded body which is coated with a coating layer composition containing an amino-modified silicone compound having a silanol group and/or an alkoxysilyl group and also having an amino-containing group in a side chain. The method for manufacturing the sliding member includes the steps of: preparing the coating layer composition containing the amino-modified silicone compound having the silanol group and/or the alkoxysilyl group and also having the amino-containing group in a side chain; applying the coating layer composition to the elastic molded body; and coating the elastic molded body with the coating layer composition.

Abstract: An active material for organic image sensors, where the active material is a squaraine-based active material or a thiophene-based active material. A photoelectric conversion layer containing the active material, which is a squaraine-based active material or a thiophene-based active material. An organic image sensor containing the photoelectric conversion layer containing the active material.

Abstract: Urea-functional organopolysiloxanes containing units of the formula RnSiO(4-n)/2??(I), where R is a radical R1 or a radical —OR2 or a radical Q, Q is a urea-functional radical of the formula —R5—[NR4—R6—]xNR4R3??(II), where the radicals R4 are identical or different and are each a radical R4? or a radical Ru, where R4? is hydrogen or a monovalent C1-C6-hydrocarbon radical where Ru is radical of the formula —C(?O)—NH2, and where at least one urea-functional radical Q having a radical Ru is present per molecule are prepared by reacting amino-functional organopolysiloxanes comprising units of the formula R?nSiO(4-n)/2??(IV), where A is an amino-functional radical of the formula —R5—[NR4?—R6—]xNR4?R3??(V), with the proviso that at least one amino-functional radical A is present per molecule in the organopolysiloxanes made up of units of the formula (III), with ortho-substituted aryl carbamates of the formula R7—Ar—O—C(?O)—NH2??(VI), where Ar is an ortho-substituted aryl radical.

Abstract: A polymeric film includes a polymer matrix having at least one of a discrete RSNO adduct or a polymeric RSNO adduct associated therewith, by: covalent attachment to the polymer matrix; dispersion within the polymer matrix; or both, with the at least one of the discrete RSNO adduct or the polymeric RSNO adduct capable of releasing nitric oxide (NO). The polymer matrix is a polyurethane polymer matrix, a silicone rubber polymer matrix, or a copolymer matrix of polyurethane and silicone rubber. The polymeric film is to exhibit stability under dry conditions at 37° C. and prolonged and controllable NO release rates, when exposed to moisture or light capable of photolyzing an RSNO bond, for a predetermined amount of time from the at least one of the discrete RSNO adduct or the polymeric RSNO adduct.

Abstract: The present application relates to a novel liquid crystal compound and a use thereof. The novel liquid crystal compounds of the present application can exhibit a smectic A phase over a wide temperature range. The novel liquid crystal compounds of the present application can be usefully used in the technical fields to which smectic A liquid crystals can be applied, for example, bistable devices.

Abstract: The present invention relates to a rubber modifier, a conjugated diene-based polymer including a functional group derived from the modifier, and a method for preparing a modified and conjugated diene-based polymer using the modifier. The modifier is used as the modifier of a conjugated diene-based polymer and combined with a conjugated diene-based polymer chain to easily introduce a functional group having affinity with a filler. Accordingly, a modified and conjugated diene-based polymer prepared using a compound of the rubber modifier may have excellent affinity with a filler, and as a result, molded articles (for example, tires) manufactured from a rubber composition including the polymer may have excellent tensile strength, abrasion resistance, and wet traction.

Abstract: The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.

Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ?N—R5, ?N—N(R5)(R5?) or ?N—O—R5, R5 and R5? independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

Abstract: A golf club head includes a face; a body, the body defining an interior and an exterior; the face and the body together defining a center of gravity, the center of gravity being proximate the face; a coefficient of restitution feature defined in the body; wherein the coefficient of restitution feature defines a gap in the body. A golf club head includes a face and a golf club body; the face and the golf club body defining a center of gravity, the center of gravity defined a distance, ?z, from a ground plane as measured along a z-axis, the center of gravity defined a distance, CGy, from the center face along the y-axis.

Abstract: Described herein are precursors and methods for forming silicon-containing films. In one aspect, there is provided a precursor of Formula I: wherein R1 is selected from linear or branched C3 to C10 alkyl group, linear or branched C3 to C10 alkenyl group, linear or branched C3 to C10 alkynyl group, C1 to C6 dialkylamino group, electron withdrawing group, and C6 to C10 aryl group; R2 is selected from hydrogen, linear or branched C1 to C10 alkyl group, linear or branched C3 to C6 alkenyl group, linear or branched C3 to C6 alkynyl group, C1 to C6 dialkylamino group, C6 to C10 aryl group, linear or branched C1 to C6 fluorinated alkyl group, electron withdrawing group, and C4 to C10 aryl group; optionally wherein R1 and R2 are linked together to form ring selected from substituted or unsubstituted aromatic ring or substituted or unsubstituted aliphatic ring; and n=1 or 2.

Abstract: Described herein are precursors and methods for forming silicon-containing films. In one aspect, there is provided a precursor of Formula I: wherein R1 is selected from linear or branched C3 to C10 alkyl group, linear or branched C3 to C10 alkenyl group, linear or branched C3 to C10 alkynyl group, C1 to C6 dialkylamino group, electron withdrawing group, and C6 to C10 aryl group; R2 is selected from hydrogen, linear or branched C1 to C10 alkyl group, linear or branched C3 to C6 alkenyl group, linear or branched C3 to C6 alkynyl group, C1 to C6 dialkylamino group, C6 to C10 aryl group, linear or branched C1 to C6 fluorinated alkyl group, electron withdrawing group, and C4 to C10 aryl group; optionally wherein R1 and R2 are linked together to form ring selected from substituted or unsubstituted aromatic ring or substituted or unsubstituted aliphatic ring; and n=1 or 2.

Abstract: A stain-treated substrate comprising an extremely thin coating for stain protection. The stain-treated substrate includes substrate material and the extremely thin coating include a molecular layer of organosilane 3-(trimethoxysilyl) propyldimethyl octadecyl ammonium chloride covalently bonded to the surface of the substrate material. The substrate material can include a wide variety of materials including tile, ceramic, glass, stone and marble and can optionally be used in conjunction with a grout mixture including a diluted organosilane mixture.

Abstract: Provided is an alkoxysilyl-vinylene group-containing silicon compound represented by the following general formula (1): wherein each of R1 and R2 independently represents a monovalent hydrocarbon group having 1 to 20 carbon atoms; R represents a monovalent hydrocarbon group having an organic functional group(s) and 1 to 30 carbon atoms; and n represents an integer of 1 to 3. The alkoxy groups in the novel organic silicon compound of the invention have a dramatically improved hydrolyzability. Further, a high adhesion or adhesiveness; and a fast adhesiveness can be exhibited by adding the novel organic silicon compound to a room temperature curable organopolysiloxane.

Abstract: The present invention discloses a process for preparing a functionalized choline chloride ionic liquid as defined in formula (I), and thereof use in an electrochemical energy storage device, as an electrolyte solution or an additive for a lithium ion battery and a supercapacitor. The ionic liquid electrolyte material has better biocompatibility, flame retardance, high ionic conductivity, low viscosity, and wide electrochemical window. wherein R1 is selected from the group consisting of: (CH2?CH—(CH2)n)—, CN(CH2)n—, or R23Si—; R2 is selected from CH3—(CH2)m—, n is an integer selected from 1 to 3, m is an integer selected from 0 to 2; or one of R2 is (CH3)3Si—O—. Anion A in Formula I is selected from the group consisting of: Cl?, Br?, I?, BF4?, NO3?, SO42?, CF3COO?, CF3SO3?, (CF3SO2)2N?, PF6?, BF2C2O4?, or B(C2O4)2?.

Abstract: A coating for an article may be made by applying a powder of a polyhemiaminal (PHA) polymer material to the article in a particulate form and then converting the PHA polymer material to a polyhexahydrotriazine (PHT) polymer material and fusing the particles into a monolithic coating by applying heat to the particles. The method generally includes forming a dilute reaction mixture comprising a formaldehyde reactant, a solvent, a primary aromatic diamine, and heating the reaction mixture to a temperature of between about 20° C. and about 120° C. for a short time to form a polymer. A particulate solid is precipitated by adding an excess volume of a non-solvent to the mixture. The powder may be applied to an article and then heated to fuse the powder into a coating and convert the PHA to PHT.

Abstract: The invention relates to a polysiloxane compound comprising specific siloxane units, curable dental materials comprising one or more than one polysiloxane compound according to the invention, cured dental materials obtainable from the curable dental materials according to the invention, a method for preparation of polysiloxane compounds according to the invention, a method for preparing curable polysiloxane compounds according to the invention and a method for preparing cured dental materials according to the invention.

Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X=N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X=N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.

Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X?N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X?N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.

Abstract: An organosilicon compound having a hydrolyzable silyl group and a catechol group in the molecule is novel. When modified by surface treatment with an adhesive composition comprising the organosilicon compound, various inorganic materials such as glass and metals become tightly adherent to epoxy and other resins.

Abstract: A composition of matter that has surfactant properties in aqueous solutions. The presence of a large number of silanols on the molecules of these compositions creates a solubility or disperseability of these molecules in aqueous solutions that is not obtainable from the quaternary salt monomers. The compositions also have adhesive properties when cured with or without functional organic materials.

Abstract: (Dimethylvinylgermoxy)heptasubstituted silsesquioxanes of the formula 1, in which the substituents R are equal to one another and represent: a linear or branched C2 to C8 alkyl group; a cyclopentyl or cyclohexyl group; a phenyl group; and the method of their synthesis.

Abstract: This invention relates to the use of certain amine promoters in processes for surface-treating colloidal silica nanoparticles with selected aromatic aminosilanes, aromatic aminoalkylsilanes, and secondary and tertiary aliphatic aminosilanes. This process provides surface-modified nanoparticle colloidal silica without causing the silica nanoparticles to gel, agglomerate, or aggregate.

Abstract: An electronic device comprising a structured organic film with an added functionality comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

Abstract: A method of preparing an aminoalkylalkoxysilane, the method comprising reacting a haloalkylalkoxysilane with ammonia in a high pressure reactor for an amount of time sufficient to consume from 20 to 99.99% (w/w) of the haloalkylalkoxysilane and form an aminoalkylalkoxysilane; venting ammonia from the reactor to give a mixture comprising the aminoalkylalkoxysilane, unreacted haloalkylalkoxysilane, and an ammonium halide; and treating the mixture with a primary amine to form an N-substituted aminoalkylalkoxysilane.

Abstract: A liquid ejection head includes a member having a liquid ejection port, wherein a surface of the member on which the ejection port is open is formed by a curing reaction of a siloxane compound having a first group and a second group. The first group has a fluorine atom. The second group has at least one selected from the group consisting of a hydroxy group, a carboxy group, a carbonyl group, and a polyether structure.

Abstract: T-aminoalkyl-functional organopolysiloxanes with defined viscosity can be reproducibly prepared without gelling by condensing an organopolysiloxane containing at least two Si-bonded hydroxyl groups with an aminoalkyltrialkoxysilane in the presence of an organic compound bearing one or more hydroxyl groups.

Abstract: The invention relates to a method for producing amino-functional polyorganosiloxanes, wherein (A) organosiloxanes which contain Si—OH groups are reacted with (B) at least stoichiometric quantities of mono-alkoxy (amino-alkyl) silanes, with respect to the Si—OH groups, (C) in the presence of at least one acid as a catalyst.

Abstract: A method of making amino-mercapto functional organopolysiloxanes is disclosed by reacting (A) a dialkoxydialkylsilane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.

Abstract: A modified polysiloxane compound is represented by following Formula (1), in which R1 to R9 represent hydrocarbon groups selected from linear alkyl groups having 1 to 20 carbon atoms, branched chain alkyl groups having 3 to 6 carbon atoms, and cyclic alkyl groups having 3 to 6 carbon atoms; p and q represent average numbers of siloxane units indicated in parentheses, where p is a number of 1 or more and q is a number of 2 or more; and “A” represents a group selected from a group represented by following Formula (2), a group represented by following Formula (3), and hydrogen atom. The modified polysiloxane compound has at least a siloxane unit wherein “A” is the group represented by following Formula (2), and a siloxane unit wherein “A” is the group represented by following Formula (3).

Abstract: Disclosed is a method for producing a compound having an amino group and/or a hydroxyl group from a substrate compound having an atomic group containing CO or CS by eliminating such atomic group. The substrate compound, having an atomic group containing CO or CS (for example, an amide, a carbamate, or the like), is allowed to react with a compound expressed by formula (I) below, at a temperature of 120° C. or lower, preferably in the presence of an ammonium salt, to eliminate such atomic group containing CO or CS. In formula (I) A may not be present, and in a case where A is present, A represents an alkyl group having 1 to 6 carbon atoms. H2N-A—NH2 (I) - - -.

Abstract: This invention relates to hydrolysable silanes useful in the modification of elastomers, and as coupling agents for diene elastomer compositions containing a filler. In particular the invention relates to novel hydrolysable silanes containing a piperazine ring and an ether or thioether linkage.

Abstract: Disclosed herein is a surface-modified inorganic filler including an alkyl group and an amine group sequentially introduced on a surface thereof, wherein the alkyl group and the amine group are introduced on the surface of the inorganic filler in a weight ratio between the alkyl group and the amine group of 0.5:9.5 to 4:6. An epoxy resin composition including the surface-treated inorganic filler according to the present invention may have low dielectric loss rate and low coefficient of thermal expansion properties.

Abstract: Described are single-walled metal oxide nanotubes having a plurality of organic functional units or moieties bonded generally in a covalent manner to the inner wall of the single-walled nanotubes. Functionalization of the single-walled metal oxide nanotubes is performed in a single-step during synthesis of the nanotubes. The organic functional units are found dispersed throughout the length of the inner wall and not sterically hindered or contained at only the mouth or ends of the single-walled metal oxide nanotubes.

Abstract: A method for treating filler material includes contacting the filler material with a silane which, upon hydrolysis, produces substantially no significant amount of volatile organic compound and/or the hydrolyzate of the silane to provide a treated filler which can then be incorporated into a matrix to provide a composite body.

Abstract: The invention relates to a composition and to a method for the production thereof, comprising quaternary amino-functional organosilicon compounds, in particular in the form of oligomers and polymers, which can be present ranging from partially hydrolyzed form to completely hydrolyzed form, and which are in particular soluble in water, have a low VOC content, and to the use thereof.

Abstract: The invention relates to a method (a) for producing aminoorganyltriorganylsilanes of the general formula (1) R?3-nR1nSi—R2—NR3R4 (1), a method (b) for producing cyclic aminosilanes of the general formula (4), and a method (III) for producing silylorganoamines of the general formula (7) R013-tR11tSi—R12—NR13—R14—SiR023-sR15s (7), wherein amines are reacted with halogen organylsilanes, wherein R?, R1, R2, R3, R4, R, R5, R6, R01, R02, R11, R12, R13, R14, R15, n, and s have the meanings specified in claims 1 to 3, wherein after the reaction, the ammonium halides of the amines produced as by-products are released by adding a base (B) to the reaction mixture, the amines are removed from the reaction mixture by distillation, two liquid phases are formed by further adding base (B) to the reaction mixture, wherein the one phase contains at least 90 wt % of the hydrohalide of the base (B) and said phase is separated.

Abstract: Provided are a modifying agent obtained by subjecting a silicon-containing compound having a protected primary amino group and at least two hydrolyzable groups to complete condensation, a method of producing a modified conjugated diene-based polymer, a modified conjugated diene-based polymer obtained by the production method, a rubber composition using the polymer, and a pneumatic tire. The modified conjugated diene-based polymer has excellent low heat generating property and abrasion resistance, and the rubber composition is obtained by using the modified conjugated diene-based polymer and the pneumatic tire is obtained by using the rubber composition.

Abstract: Described herein are heterocyclic organic compounds of following formulae: More specifically, described herein are fused heterocyclic naphthalene compounds, polymers based on fused heterocyclic naphthalene compounds, methods for making these compounds, and uses thereof. The compounds described have improved polymerization and stability properties that allow for improved material processibility for use as organic semiconductors (OSCs).

Abstract: In a conductive film forming method using photo sintering, a conductive film having low electric resistance is easily formed. The conductive film forming method is a method in which a conductive film is formed using photo sintering. This method includes the steps of forming a layer made of a sintering promoter on a substrate, forming a liquid film made of a copper particulate dispersion on the layer of the sintering promoter, drying the liquid film to form a copper particulate layer, and subjecting the copper particulate layer to photo sintering. The sintering promoter is a compound which removes copper oxide from metallic copper. Thereby, the sintering promoter removes a surface oxide film of copper particulates in photo sintering.

Abstract: Disclosed herein are inventive branched blocky cationic organopolysiloxanes and consumer product compositions comprising such organopolysiloxanes. Such compositions can deposit effectively onto target substrates to deliver consumer-desired benefits such as conditioning, anti-wrinkle, softness, and anti-static.

Abstract: An amine-based compound is represented by Formula 1: An organic light-emitting diode includes a first electrode, a second electrode, and an organic layer between the first electrode and the second electrode. The organic layer includes an emission layer and the amine-based compound represented by Formula 1. The OLED including the amine-based compound represented by Formula 1 has good color purity, low driving voltage, high efficiency, high brightness, and/or a long lifetime.

Abstract: The present invention is related to silicon nanoparticles, a pharmaceutical composition comprising silicon nanoparticles, a method for synthesis of the silicon nanoparticles and their use for in vivo diagnostics, visualization of drug delivery or staining of cells, biological processes or pathways. The silicon nanoparticles are characterised that they comprise a silicon core of a size of 1 to 10 nm and are terminated with allylamine or poly(allylamine) comprising up to 10 allylamine groups.

Abstract: A compound represented by the formula (I) [R1 to R3 represent an alkyl group, an alkenyl group, and the like; n represents 0 or 1; R4 represents an amino group or —(CX2)m—COOH (m represents 0 to 3, and X represents hydrogen atom); R5 represents —(CY2)p—COOR6 (p represents an 0 to 3, Y represents hydrogen atom, and R6 represents hydrogen atom or an alkyl group)], or a salt thereof.

Abstract: The invention provides a silicon-containing bianthracene derivative, a production process and use thereof, and an organic electroluminescent device. The invention belongs to the technical field of organic electroluminescence, and can give a blue light-emitting material being able to form a dense film. The silicon-containing bianthracene derivative has a molecular structure of the following general formula, wherein R group represents an aryl group having a carbon atom number of 6-14, an aromatic heterocyclic group having a carbon atom number of 8-18, a fused-ring aromatic group having a carbon atom number of 9-15, a fluorenyl group, or a triarylamino group. The silicon-containing bianthracene derivative mentioned in the invention can be used in an organic electroluminescent device.

Abstract: Polybranched organic/inorganic hybrid polymer and method for its manufacture. The hybrid polymer has the form of an inorganic core carrying organic branches. The core is first prepared by controlled hydrolysis and condensation of a silane with a structure: X—B—Si(—Y)3 in which X?NR1 R2, while R1, R2 are chosen among hydrogen, alkyl and aryl, or R1, R2 are chosen among condensation products, addition products of one or more type of chemical substances such as acids, alcohols, phenols, amines, aldehydes or epoxides. B is a linkage group chosen among alkylene and arylene which may include oxygen, nitrogen, sulphur, phosphorous, silicon and boron. Y is chosen among hydrolyzable residues such as alkoxy, carboxyl, and halogen. The organic branches are developed by substituting N—H hydrogen atoms in the X—B group by reactions that are typical for primary and secondary amines, and/or by adding an acid that causes an addition to the N atoms of the X—B group in the core.

Abstract: Provided are benzofluorene-based compounds according to the following Formula 1 and an organic light-emitting diode including the same:

Abstract: The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, and wherein the general symbols are as defined in claim 1. These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.

Abstract: The present disclosure invention relates to novel secondary aminosilanes, a method for producing same, and the use thereof. The secondary aminosilanes can be produced from readily available reactants in a simple manner. The secondary aminosilanes are characterized for example by a low viscosity and are well suited for producing silane-functional polymers that have a low viscosity, fast curing, and good thermal stability.

Abstract: Polybranched organic/inorganic hybrid polymer and method for its manufacture. The hybrid polymer has the form of an inorganic core carrying organic branches. The core is first prepared by controlled hydrolysis and condensation of a silane with a structure: X—B—Si(—Y)3 in which X?NR1R2, while R1, R2 are chosen among hydrogen, alkyl and aryl, or R1, R2 are chosen among condensation products, addition products of one or more type of chemical substances such as acids, alcohols, phenols, amines, aldehydes or epoxides. B is a linkage group chosen among alkylene and arylene which may include oxygen, nitrogen, sulphur, phosphorous, silicon and boron. Y is chosen among hydrolyzable residues such as alkoxy, carboxyl, and halogen. The organic branches are developed by substituting N—H hydrogen atoms in the X—B group by reactions that are typical for primary and secondary amines, and/or by adding an acid that causes an addition to the N atoms of the X—B group in the core.

Abstract: The present invention is capable of providing a light emitting device with excellent device lifetime while maintaining low driving voltage and good color purity by using a benzofluorene compound which is substituted with a diaryl amino group having a naphthyl and a phenyl or a heteroaryl and which is represented by general formula (1) as a material for luminescent layers of an organic electroluminescent device, for example. (In the formula, Ar is a phenyl, a heteroaryl, etc., R1 and R2 are fluorine or a substituted silyl, etc., n1 and n2 are an integer of 0-5, and R3 is an alkyl, etc.