Abstract: Liquid Crystal compounds represented by the following formula are disclosed. ##STR1## wherein R and R' are independently selected from alkyl groups containing 1.about.20 carbon atoms; X is --O--, --O--CO--O-- or direct bond; A.sub.1 and A.sub.2 are independently cyclic groups (such as phenylene and biphenylene), said cyclic groups may be substituted with 1.about.4 fluorine, chlorine or bromine atoms, or 1 or 2 substituent groups selected from the group consisting of cyano, nitro and trifluoromethyl groups; Y is --CO--O--, --O--CO--, --C.tbd.C--, --CH.sub.2 O--, --OCH.sub.2 --, --CH.dbd.N--, --N.dbd.CH--, --N.dbd.N--, --CH.sub.2 S--, --SCH.sub.2 -- or direct bond; and * represents asymmetric atom providing optical activity.
Type:
Grant
Filed:
August 19, 1988
Date of Patent:
May 1, 1990
Assignees:
NEC Corporation, Sanyo Chemical Industries, Ltd.
Abstract: Sulphur-containing borate esters for use in lubricants appropriate to modern oil requirements with reduced or zero amounts of phosphorous and without the need for large amounts and/or expensive forms of antioxidant and additional anti-wear additives are of the formula: ##STR1## wherein each R is a hydrocarbyl group optionally substituted by one or more --XR" group, or the two R groups attached to one boron represent a group --(R'CH).sub.m --, x is 1 or 2, each n is from 1 to 6, each m is from 2 to 4 and each R' is hydrogen, and --XR" group, or a hydrocarbyl radical optionally substituted by one or more --XR" group, X is O, S or NR" and R" is hydrogen, a hydrocarbyl radical or a hydrocarbylcarbonyl group.
Abstract: 2-(4,3-Disubstituted phenyl)-5-alkyl-1,3,2-dioxaborinane derivatives of the general formula ##STR1## wherein A is --OR', --CN, ##STR2## X,Y being simultaneously or independently H, F, Cl, R, R' standing for an alkyl radical of a normal structure, comprising from 1 to 7 carbon atoms, as components for a liquid crystal material. A liquid crystal material comprises at least two components, of which one is a compound of said formula, taken in an amount of from 3 to 75 percent by mass.
Type:
Grant
Filed:
December 16, 1987
Date of Patent:
August 1, 1989
Assignee:
Nauchno-Issledovatelsky Institut Prikladnykh Fizicheskikh Problem Imeni A. N. Sevchenko
Inventors:
Vladimir S. Bezborodov, Oleg A. Grinkevich, Mikhail F. Grebenkin, Valery I. Lapanik, Anatoly A. Minko, Vitaly V. Rzhussky, Anatoly A. Muravsky, Vladimir F. Petrov, Alexandr V. Ivaschenko
Abstract: Sulfur containing diols are reacted with hydroxy boron compounds resulting in the formation of symmetrically balanced compounds which are useful as additives for lubricating oil compositions.
Abstract: Heterocyclic boron compounds of the formula IR.sup.1 --A.sup.1 --Z.sup.1 --A.sup.2 --R.sup.2 (I)can be used as components of liquid-crystal phases. A.sup.1 is --A--, --A.sup.4 --A--, or --A--A.sup.4 -- and A is ##STR1## .
Type:
Grant
Filed:
March 24, 1986
Date of Patent:
June 14, 1988
Assignee:
Merck Patent Gesellschaft mit beschrankter Haftung
Inventors:
Andreas Wachtler, Joachim Krause, Rudolf Eidenschink, Jurgen Eichler, Bernhard Scheuble
Abstract: Described are the aralkoxy, alkoxy, alkadienyloxy and alkenyloxy-1,3,2-dioxaborinane derivatives defined according to the genus: ##STR1## (wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different hydrogen, methyl and ethyl; and wherein R represents C.sub.6 straight chain alkenyloxy; C.sub.10 branched chain alkenyloxy; C.sub.12 aralkoxy; C.sub.12 branched chain alkoxy; or C.sub.10 branched chain alkadienyloxy) and uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, particularly drier-added fabric softener articles and perfumed polymers.
Abstract: A process is described in which catecholborane is produced by a reaction of a phenolic compound with a boron hydride in a solvent. Tris(catecholato)bisborane, i.e. the ester of boric acid and catechol, is reacted with an alkali metal-boron hydride in an aliphatic ether. A lithium halide is suitably used too, where sodium-boron hydride or potassium-boron hydride is employed. In a preferred embodiment, the reaction is carried out in conjunction with an activating grinding operation.
Abstract: In a process for hydroboronizing alkenes or alkynes with catecholborane (1,3,2-benzodioxaborolane) optionally in the presence of an added organic solvent the reaction is catalyzed by a complex compound having one of the formulas:(I) RhCl(CO).sub.x [E(C.sub.6 H.sub.5).sub.3 ].sub.3-x' wherein "E" is arsenic or phosphorous and "x" equals 0 or 1,(II) [RhCl(alkene).sub.2 ].sub.2'(III) [(C.sub.6 H.sub.5).sub.3 P].sub.3 3 Ru(CO)ClH or(IV) [(C.sub.6 H.sub.5).sub.3 P].sub.3 RuCl.sub.2,particularly suitable catalysts are, e.g. tris (triphenylphosphine)rhodium(I) chloride and bis(cyclooctadiene)rhodium(I) chloride.
Abstract: Esters of .alpha.,.alpha.-haloalkyl boronic acids are prepared by the addition of an alkali metal dialkylamide, or some other equivalent sterically hindered base to a mixture of a 1,1-dihaloalkane and a trialkyl borate in an organic solvent at a temperature between about -78.degree. C. and +25.degree. C. In one embodiment, diisopropyl (dichloromethyl)borate is formed by the addition of lithium diisopropylamide to a mixture of dichloromethane and triisopropyl borate in the presence of tetrahydrofuran as the solvent medium at a temperature between about -10.degree. C. and +10.degree. C.
Type:
Grant
Filed:
February 12, 1986
Date of Patent:
October 20, 1987
Assignee:
Washington State University Research Foundation, Inc.