Acylated Oxy In Acid Moiety Patents (Class 560/185)
  • Patent number: 4159991
    Abstract: .alpha.-Acyloxy-N,N'-diacylmalonamides of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, straight chain or branched alkyl radicals having from one to eleven carbon atoms, or hydrocarbon radicals with six to twelve carbon atoms and comprising at least one aromatic ring, are novel compounds prepared by the action of a mixture of carboxylic acids R.sub.3 COOH and R.sub.4 COOH upon an .alpha.-acyloxymalononitrile, R.sub.1 COO--C(CN).sub.2 --R.sub.2, in the presence of an acid catalyst and are useful as intermediates in organic synthesis and low temperature activators in bleaching or scouring compositions.
    Type: Grant
    Filed: August 22, 1977
    Date of Patent: July 3, 1979
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventors: Bernard Dubreux, Serve Y. Delavarenne, Jean-Pierre Schirmann
  • Patent number: 4159387
    Abstract: There are described new squaric acid esters, particularly mono-ortho esters, di-ortho esters, ortho ester anhydrides and ortho ester halides of squaric acid; a new process for producing these squaric acid esters; and a process for converting the squaric acid esters into squaric acid. It is possible by the new process to produce, with the use of readily obtainable starting products, the new squaric acid esters according to the invention in an economical manner and with good to very good yields; and the squaric acid esters can be converted under mild reaction conditions into squaric acid.
    Type: Grant
    Filed: November 23, 1977
    Date of Patent: June 26, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Daniel Bellus
  • Patent number: 4153804
    Abstract: A fluorinated vinyl ether having an ester group which has the formulaCF.sub.2 .dbd. CFOCF.sub.2 (CF(CF.sub.3)OCF.sub.2).sub.n-1 (Rf).sub.m CO.sub.2 Rwherein n represents an integer of 1 to 5; m represents 0 or 1; Rf represents a C.sub.1 -C.sub.10 bifunctional perfluoro group and R represents an alkyl group, is produced by reacting fluorinated acyl fluoride having an ester group which has the formulaFOC(CF(CF.sub.3)OCF.sub.2).sub.n (Rf).sub.m CO.sub.2 Rwith an alkali metal carbonate to produce an alkali metal salt of fluorinated carboxylic acid having an ester group which has the formulaMOOC(CF(CF.sub.3)OCF.sub.2).sub.n (Rf).sub.m CO.sub.2 Rwherein M represnts an alkali metal;And then, thermally decomposing the alkali metal salt of fluorinated carboxylic acid having an ester group.
    Type: Grant
    Filed: June 21, 1978
    Date of Patent: May 8, 1979
    Assignee: Asahi Glass Co. Ltd.
    Inventors: Masaaki Yamabe, Seiji Munekata, Shunichi Samejima
  • Patent number: 4139525
    Abstract: Flexible glycolic acid terpolymers useful in the preparation of hot-melt adhesives are prepared by heating glycolic acid, its esters, its homopolymers or mixtures thereof with a dihydroxyalkane and a dibasic acid.
    Type: Grant
    Filed: August 22, 1977
    Date of Patent: February 13, 1979
    Assignee: Chevron Research Company
    Inventor: Robert Bacskai
  • Patent number: 4138497
    Abstract: Compounds are provided having the structure ##STR1## wherein n is 1, 2 or 3, m is 0, 1 or 2, R.sub.1 R.sub.2, R.sub.3, R.sub.4 and R.sub.5 may be the same or different and can be hydrogen, lower alkyl, halo-lower alkyl, acyl, lower alkoxy-carbonyl ##STR2## amido ##STR3## or lower alkoxylakylene, X is a straight or branched bivalent aliphatic radical and Y is ##STR4## These compounds are useful in the treatment of hypertension.
    Type: Grant
    Filed: July 29, 1977
    Date of Patent: February 6, 1979
    Assignee: E. R. Squibb & Sons, Inc.
    Inventors: Frederic P. Hauck, Joseph E. Sundeen, Joyce Reid
  • Patent number: 4133794
    Abstract: Caprolactone modified polyesters, derived from an aliphatic diol, an aliphatic dicarboxylic acid or mixtures thereof, optionally with a proportion not exceeding 10 mole % of an aromatic dicarboxylic acid and terminated with an alcohol or monocarboxylic acid are good plasticizers for thermoplastic polymers especially polyvinyl chloride.
    Type: Grant
    Filed: August 6, 1975
    Date of Patent: January 9, 1979
    Assignee: Ciba-Geigy AG
    Inventor: Frank Lamb
  • Patent number: 4130532
    Abstract: Caprolactone modified polyesters derived from an aliphatic dihydroxy compound and a mixture of aliphatic dicarboxylic acids and a proportion above 10 mol % of the total acids used, of an aromatic dicarboxylic acid and terminated with an alcohol or monocarboxylic acid such that the molecular weight ranges from 500 to 1400 are good plasticizers for polymers, especially polyvinyl chloride.
    Type: Grant
    Filed: March 7, 1977
    Date of Patent: December 19, 1978
    Assignee: Ciba-Geigy AG
    Inventor: Frank Lamb
  • Patent number: 4129721
    Abstract: A-40104 antibiotic complex, comprising active factors A, B, C, and D, produced by submerged aerobic fermentation of Clitopilus pseudo-pinsitus. Individual factors, A, B, and C have been isolated. A-40104 factor C is the known antibiotic pleuromutilin. A-40104 factors A and B are novel antibiotics related to pleuromutilin. A-40104 factor A, the major new factor, is the D-xylose acetal derivative of pleuromutilin. A-40104 factors A and B, their 19,20-dihydro derivatives and the per(C.sub.2 -C.sub.6)alkanoyl derivatives of factors A and B and of their 19,20-dihydro derivatives are active against gram-positive and gram-negative bacteria, anaerobic bacteria, and Mycoplasma.
    Type: Grant
    Filed: December 8, 1977
    Date of Patent: December 12, 1978
    Assignee: Eli Lilly and Company
    Inventors: Karl H. Michel, Calvin E. Higgens
  • Patent number: 4128575
    Abstract: Glycolic acid or the esters thereof are prepared by reacting paraformaldehyde or trioxane or a mixture thereof with formic acid or a formic acid ester in the liquid phase at a temperature of from 70.degree. to 200.degree. C in the presence of a strongly acidic catalyst.
    Type: Grant
    Filed: November 14, 1977
    Date of Patent: December 5, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst I. Leupold, Hans-Jurgen Arpe
  • Patent number: 4122097
    Abstract: The present specification provides novel intermediates and novel processes for the synthesis of various side chain and skeletal analogs of Thromboxane B.sub.2 (11.beta.-homo-11a-oxa-PGF.sub.2.alpha.). These analogs are particularly and especially useful as reproductive cycle control agents.
    Type: Grant
    Filed: September 6, 1977
    Date of Patent: October 24, 1978
    Assignee: The Upjohn Company
    Inventor: William P. Schneider
  • Patent number: 4097678
    Abstract: 3.alpha.-Hydroxy and 3.alpha.-acyloxy- .DELTA..sup.9(11) -5.alpha.-D-homo-20-ketopregnenes of the formula ##STR1## wherein R is hydrogen or acyl, R.sub.1 is hydrogen or methyl and R.sub.2 is methyl or ethyl, are produced by esterifying a corresponding 3.beta.-hydroxy-5.alpha.-20-keto pregnane of the formula ##STR2## wherein R.sub.1 and R.sub.2 have the values given above, with m-iodo-benzoic acid with inversion of the 3.beta.-oxy group to a 3.alpha.-oxy group; chlorinating the thus-produced 3.alpha.-m-iodobenzoyl ester with dichloroiodobenzene under irradiation; and treating the reaction product with a dehydrohalogenating silver salt. Optionally thereafter, the 3.alpha.-iodobenzoyl group is split off in a conventional manner to produce the corresponding 3.alpha.-hydroxy steroid and optionally the thus-produced 3.alpha.-hydroxy steroid is esterified to produce a desired 3-ester thereof.
    Type: Grant
    Filed: June 8, 1976
    Date of Patent: June 27, 1978
    Assignee: Schering Aktiengesellschaft
    Inventors: Ulrich Kerb, Rudolf Wiechert, Otto Engelfried
  • Patent number: 4078148
    Abstract: Polyether ester polymers of tetrahydrofuran and .gamma.-butyrolactone or hexamethyleneoxide and .gamma.-butyrolactone. The polymers are prepared by contacting the mentioned monomers in the presence a fluoride or chloride of antimony or a chloride of tin or titanium. The polymers can be used as components in the preparation of polyurethanes.
    Type: Grant
    Filed: October 10, 1973
    Date of Patent: March 7, 1978
    Assignee: Dynamit Nobel Aktiengesellschaft
    Inventors: Norbert Vollkommer, Hermann Richtzenhain, Gerhard Bier, Manfred Gorlitz
  • Patent number: 4062887
    Abstract: Energy-absorbing interlayers and glass laminates prepared therefrom for use as automobile windshields and other safety glass applications are disclosed. The interlayers are made from a poly(lactone-urethane) in which the molecular weight and structure of the lactone moiety is carefully controlled so as to get optimum energy-absorbing and optical properties.
    Type: Grant
    Filed: December 11, 1975
    Date of Patent: December 13, 1977
    Assignee: PPG Industries, Inc.
    Inventors: Wen-Hsuan Chang, Vernon G. Ammons