Nitrogen In Alcohol Moiety Patents (Class 560/196)
-
Patent number: 4324739Abstract: (Dimethylaminoalkyl)carboxylic and -carbamic acid esters and (dimethylaminoalkyl) ethers and ureas are compounds which are especially suitable for use as amine curing agents for polyepoxide compounds. They impart longer curing times to the curable mixtures and thus good processing properties, especially when the mixtures are used as adhesives. In addition, the mechanical properties are often improved. Further, these compounds afford advantages when used as curing agents on account of their low volatility.Type: GrantFiled: March 31, 1980Date of Patent: April 13, 1982Assignee: Ciba-Geigy CorporationInventors: Helmut Zondler, Roland Moser
-
Patent number: 4313889Abstract: Soft quaternary surface active agents having the formula: ##STR1## wherein ##STR2## represents a tertiary open chain or cyclic aliphatic amine; wherein ##STR3## represents an unsaturated amine; wherein R represents a member selected from the group consisting of a hydrogen atom, a C.sub.1 -C.sub.20 open chain or cyclo alkyl group, a C.sub.1 -C.sub.20 alkoxyalkyl group, a C.sub.1 -C.sub.20 acyloxyalkyl group, a C.sub.1 -C.sub.20 haloalkyl group, a C.sub.1 -C.sub.20 carboxyalkyl group, an aryl group, and a substituted aryl group, whose substituents are selected from the group consisting of a halogen atom, an O--C.sub.1 -C.sub.4 alkyl group, an O--C.sub.1 -C.sub.8 acyl group, a nitro group, a carboxyl group, and a carboethoxy group; wherein R.sub.1 represents a C.sub.9 -C.sub.22 straight or branched alkyl group, a --(CH.sub.2).sub.n -- ##STR4## wherein R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each selected from the group consisting of a hydrogen atom, a methyl group or an ethyl group, a C.sub.0 -C.sub.Type: GrantFiled: June 10, 1980Date of Patent: February 2, 1982Assignee: Merck & Co., Inc.Inventor: Nicolae S. Bodor
-
Patent number: 4310683Abstract: Sulfosuccinate diesters in which one carboxyl group of the sulfosuccinate is esterified with an ethoxylated or propoxylated non-tertiary monoamine, for instance, a C.sub.8 -C.sub.18 fatty amine, ethoxylated with 3 or 4 moles of ethylene oxide, to form a hydroxyl-containing tertiary amine, and in which the other carboxyl group of the sulfosuccinate is esterified with an .alpha.-monoepoxide such as propylene oxide, or higher .alpha.-monoepoxides, and method of preparation of such sulfosuccinate diesters. The said sulfosuccinate diesters have utility as surfactants, such as detergents and emulsifiers.Type: GrantFiled: June 15, 1979Date of Patent: January 12, 1982Assignee: Witco Chemical CorporationInventors: Kermit D. Longley, Anastasios J. Karalis
-
Patent number: 4293555Abstract: Disclosed are 6- and 6,6-disubstituted-2-substituted-oxapen-2-em-3-carboxylic acids of the following structure: ##STR1## wherein: R.sup.1 and R.sup.2 are independently selected from hydrogen, alkyl, alkoxyl, aralkyl, aryl, heterocyclyl and heterocyclylalkyl; R is selected from hydrogen, --OR, --SR, --NR.sub.2, alkyl, aryl, aralkyl, heterocyclyl, or heterocyclylalkyl. Such compounds and their pharmaceutically acceptable salt, and ester derivatives are useful as antibiotics. Also disclosed are processes for the preparation of such compounds, pharmaceutical compositions comprising such compounds and methods of treatment comprising administering such compounds and compositions when an antibiotic effect is indicated.Type: GrantFiled: October 10, 1979Date of Patent: October 6, 1981Assignee: Merck & Co., Inc.Inventors: Burton G. Christensen, Frank P. DiNinno
-
Patent number: 4228042Abstract: Novel, biodegradable cationic surface-active agents are disclosed. These compounds, when used in laundry detergent compositions together with selected nonionic surfactants, provide excellent removal of particulate and greasy/oily soils, as well as providing fabric softening, static control, and dye transfer inhibition benefits to the laundered fabrics.Type: GrantFiled: June 26, 1978Date of Patent: October 14, 1980Assignee: The Procter & Gamble CompanyInventor: James C. Letton
-
Patent number: 4194052Abstract: A sulfonic acid salt of an acyloxyalkylamine is prepared by reaction of an organic acid or amino-acid with a sulfonic acid salt of an alkanolamine. Isocyanates are prepared therefrom by reaction with phosgene.Type: GrantFiled: May 1, 1969Date of Patent: March 18, 1980Assignee: Rohm and Haas CompanyInventors: Sheldon N. Lewis, Jerome F. Levy
-
Patent number: 4185485Abstract: An emulsifiable concentrate for use in metal processing, especially in can forming, comprises an ester prepared from a polyalkenylsuccinic acid or anhydride, and a hydroxyl-containing amine. It is critical to the invention with respect to can forming that the acid or anhydride contain, in addition to its basic carbon length, a chain derived from an olefin having from 16 to 28 carbon atoms.Type: GrantFiled: June 30, 1978Date of Patent: January 29, 1980Assignee: Mobil Oil CorporationInventors: John W. Schick, Robert H. Davis, Harry J. Andress
-
Patent number: 4176232Abstract: A sulfonic acid salt of an acyloxyalkylamine is prepared by reaction of an organic acid or amino-acid with a sulfonic acid salt of an alkanolamine. Isocyanates are prepared therefrom by reaction with phosgene.Type: GrantFiled: June 27, 1968Date of Patent: November 27, 1979Assignee: Rohm and Haas CompanyInventors: Sheldon N. Lewis, Jerome F. Levy
-
Patent number: 4165432Abstract: Compounds containing peroxy linkages connecting similar polyol ester constituents are described. These peroxy di-ester polyols are prepared by the direct esterification of peroxy diacids with polyols, in the presence of a strong mineral acid catalyst. The peroxy di-ester polyol products function as free radical initiators and grafting bases in the graft copolymerization of unsaturated monomers with polyols. These graft copolymers are useful in the formulation of polyurethanes.Type: GrantFiled: October 18, 1977Date of Patent: August 21, 1979Assignee: Olin CorporationInventors: Frank J. Preston, Theodore C. Kraus, Kiran B. Chandalia
-
Patent number: 4145559Abstract: Esters of 4-substituted 2-methyleneglutaric acids are prepared by reacting an ester of acrylic acid with an ester of an .alpha.-substituted acrylic acid, such as an ester of methacrylic acid, in the presence of a tertiary organic phosphine, an organic phosphorus triamide, an organic phosphonous diamide, or an organic phosphinous amide.Type: GrantFiled: November 6, 1974Date of Patent: March 20, 1979Assignee: Rohm and Haas CompanyInventors: Joseph W. Nemec, Richard B. Wuchter
-
Patent number: 4137245Abstract: Nitrogenous condensation products and hydrolysis products thereof are provided wherein the condensate of a fatty acid and diamine is reacted with an unsaturated dicarboxylic acid or a partial ester thereof; optionally the product of such a reaction or a similar product obtained from an unsaturated monocarboxylic acid is further reacted with a halocarboxylic acid. The unhydrolyzed products can be formulated as imidazolines.Type: GrantFiled: May 19, 1977Date of Patent: January 30, 1979Assignee: The Miranol Chemical Company, Inc.Inventor: Arvid Christiansen
-
Patent number: 4115169Abstract: Bis-ketimine esters of the general formula ##STR1## wherein, for example, R and R.sup.1 are alkyl groups,X is alkylene, andY is the non-carboxyl moiety of a dicarboxylic acid, are disclosed. Said compound is mixed with an acid polymeric anhydride to form an ambient moisture-curable adhesive composition.Type: GrantFiled: January 6, 1977Date of Patent: September 19, 1978Assignee: Rohm and Haas CompanyInventors: William D. Emmons, Samuel S. Kim, Donald A. Winey
-
Patent number: 4094796Abstract: There is disclosed a compound having the following structural formula: ##STR1## WHEREIN X, Y, and Z each being selected from the group consisting of ##STR2## wherein one of R.sub.1 and R.sub.2 is hydrogen and the other is an alkyl group having from 1 to 6 carbon atoms with the alkyl to hydrogen mole ratio being less than 0.4 and X being an integer of at least 1 and R.sub.3 is a diradical selected for the group consisting ofR.sub.3 is a diradical of either:(a) 1 to 6 methylene groups(b) a diradical of: --CH.dbd.CH--(c) a diradical of: ##STR3## where R.sub.1, R.sub.Type: GrantFiled: June 7, 1977Date of Patent: June 13, 1978Assignee: Biax-Fiberfilm CorporationInventor: Eckhard C. A. Schwarz
-
Patent number: 4076949Abstract: A process for the preparation of oxalate esters by reacting an alcohol with a mixture of carbon monoxide and oxygen in the presence of a catalytic mixture of:(a) a palladium, rhodium, platinum, copper, or cadmium metal salt compound or mixture thereof,(b) an aliphatic, cycloaliphatic, aromatic or heterocyclic amine or ammonia,(c) a copper (I), copper (II), iron (II) or iron (III) oxidant salt compound, and(d) an ammonium or substituted ammonium salt compound or acid with a counterion other than a halide.Alternatively a ligand or coordination complex compound of the metal salt compound may be employed.Type: GrantFiled: May 9, 1977Date of Patent: February 28, 1978Assignee: Atlantic Richfield CompanyInventor: Lee R. Zehner
-
Patent number: 4069388Abstract: A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of an alkoxycycloalkene with carbon monoxide, an alcohol and oxygen or an oxygen-containing gas in the presence of a metal salt catalyst and an amine base. In addition, a catalytic amount of particular metal oxidizing salts is employed along with a catalytic amount of an acid or an amine salt compound. Alternatively various counterions and ligands of the metal salt catalysts may be employed.Type: GrantFiled: October 22, 1976Date of Patent: January 17, 1978Assignee: Atlantic Richfield CompanyInventor: Lee R. Zehner
-
Patent number: 4069384Abstract: Carboxyl terminated polymers prepared by reacting a cyclic anhydride with a liquid polymeric hydroxyl terminated polymer selected from polyethers, polydienes, and copolymers of the dienes with styrene or acrylonitrile in the presence of a catalyst selected from quaternary ammonium salts and from halogen acid salts of amines. The carboxyl terminated polymers can be used as flexibilizers in epoxy resins.Type: GrantFiled: November 8, 1974Date of Patent: January 17, 1978Assignee: The Goodyear Tire & Rubber CompanyInventor: Glen E. Meyer
-
Patent number: 4065490Abstract: A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of an enol ether with carbon monoxide, an alcohol and oxygen-containing gas in the presence of a metal salt catalyst and an amine base. In addition, a catalytic amount of particular metal oxidizing salts is employed along with a catalytic amount of an acid or an amine salt compound. Alternatively various counterions and ligands of the metal salt catalysts may be employed.Type: GrantFiled: March 22, 1976Date of Patent: December 27, 1977Assignee: Atlantic Richfield CompanyInventor: Lee R. Zehner
-
Patent number: 4065627Abstract: High molecular weight radiation curable ester-diethers, ester-monoethers and their diisocyanate derivatives.Type: GrantFiled: September 27, 1976Date of Patent: December 27, 1977Assignee: General Mills Chemicals, Inc.Inventor: Stuart A. Harrison
-
Patent number: 4059610Abstract: Isocyanic acid derivatives are prepared by reacting an organic halogen compound with an alkali cyanate in N,N-disubstituted organic acid amides, N,N-disubstituted sulfonic acid amides, sulfoxides, sulfones or macrocyclic polyethers, at 70.degree. to 200.degree. C, in the presence of organic polyhalogen compounds selected from compounds having dihalogenomethyl group, dihalogenomethylene group, or trihalogenomethyl group and tetrahalogenomethane, in an amount in the range of from 1 to 20 weight percent based on the weight of said organic halogen compounds.Type: GrantFiled: May 14, 1976Date of Patent: November 22, 1977Assignee: Kao Soap Co., Ltd.Inventors: Susumu Handa, Yoshiaki Tanaka, Atsushi Nishibata, Sadashi Ueda, Yoshiaki Inamoto, Masahiro Saito, Fumio Tanimoto, Hisao Kitano
-
Patent number: RE30530Abstract: Novel polymerizable monomers which are ethylenically unsaturated esters of the formula: ##STR1## wherein R.sub.4 comprises a polymerizable ethylenic double bond. Homopolymers and copolymers of the monomers are disclosed and in one embodiment provide water-dispersible film-forming polymer which may be electrophoretically deposited on a conducting substrate.Type: GrantFiled: August 25, 1978Date of Patent: February 24, 1981Assignee: Dulux Australia Ltd.Inventor: John J. Hopwood