Aromatic Alcohol Moiety Patents (Class 560/221)
  • Patent number: 6369262
    Abstract: Rigid-rod monomers and polymers are provided for use in applications such as rapid prototyping, composites and adhesives. The monomers can be photocured through the end groups and then thermally post cured through the acetylene groups. The result is a highly crosslinked polymer having an effective glass transition temperature well above 200° C.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: April 9, 2002
    Assignee: University of Dayton
    Inventors: Richard P. Chartoff, Jayprakash C. Bhatt, Tat H. Tong
  • Patent number: 6359170
    Abstract: Described are (alkyl,bromo)phenoxy alkyl(meth)acrylate monomers and polymers made therefrom.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: March 19, 2002
    Assignee: 3M Innovative Properties Company
    Inventor: David B. Olson
  • Patent number: 6268111
    Abstract: An oligomer is provided having tetraacrylate functionality as well as carboxylic acid functionality. The oligomer is useful as a photopolymerizable binder in photoresists for forming printed circuitry. Particular advantages of the oligomer are found in solder mask-forming compositions which must withstand the conditions of nickel/gold plating.
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: July 31, 2001
    Assignee: Rohm and Haas Company
    Inventors: Lincoln Eramo, Jr., Mitchell G. Male, Robert K. Barr, Daniel E. Lundy
  • Patent number: 6265132
    Abstract: The invention provides an oligomer having tetraacrylate functionality which provides enhanced flexibility to photoimageable compositions which function as photoresists. The enhanced flexibility is particularly advantageous in epoxy-containing, solder mask-forming photoimageable composition, as this flexibility provides improved performance in nickel/gold plating.
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: July 24, 2001
    Assignee: Rohm and Haas Company
    Inventors: Lincoln Eramo, Jr., Mitchell G. Male, Robert K. Barr
  • Patent number: 6255523
    Abstract: The present invention relates to powder coating compositions which can be cured at low temperatures. The powder coating composition of the invention include a unique combination of a branched oligoester polyol and uretdione crosslinking agent which when cured results in a coating binder with desirable hardness, flexibility, solvent resistance, corrosion resistance, weatherability and gloss.
    Type: Grant
    Filed: September 18, 1998
    Date of Patent: July 3, 2001
    Assignee: McWhorter Technologies, Inc.
    Inventors: Kamlesh Pai Panandiker, John Michael Bronk, Franklin Paul Spitler
  • Patent number: 6175037
    Abstract: An improved process for preparing acrylate esters, methacrylate esters, polyester acrylates or polyester methacrylates by reacting acrylic or methacrylic acid with a monohydroxy containing compound or a polyhydroxy containing compound in the presence of a catalyst and polymerization inhibitor in a reaction vessel, in the presence or absence of a solvent, under microwave energy as a heating source. Advantages of using microwave energy in place of conventional thermal heating include higher temperatures coupled with shorter residence times, reduced production costs, increased capacity, lower energy costs, effective use of raw materials, and solventless processing which is environmentally friendly.
    Type: Grant
    Filed: October 9, 1998
    Date of Patent: January 16, 2001
    Assignee: UCB, S.A.
    Inventor: Harrell Emmett Tweedy
  • Patent number: 6127407
    Abstract: The present invention provides substituted 3,3-diphenyl indanone, indane and indole compounds, as well as analogues thereof, which are specific, potent and safe inhibitors of mammalian cell proliferation. The compounds can be used to inhibit mammalian cell proliferation in situ as a therapeutic approach towards the treatment or prevention of diseases characterized by abnormal cell proliferation, such as cancer.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: October 3, 2000
    Assignees: Ion Pharmaceuticals, Inc., President and Fellows of Harvard College, Children's Medical Center Corporation
    Inventors: Carlo Brugnara, Jose Halperin, Rudolf Fluckiger, Emile M. Bellott, Jr., Richard John Lombardy, John J. Clifford, Ying-Duo Gao, Reem M. Haidar, Eugene W. Kelleher, Adel M. Moussa, Yesh P. Sachdeva, Minghua Sun, Heather N. Taft
  • Patent number: 6049000
    Abstract: The invention relates to compounds with the general formula Y.sup.1 --A.sup.1 --M.sup.1 --A.sup.2 --Y.sup.2 whereinY.sup.1 and Y.sup.2 are different from each other and Y.sup.1 is an acrylate or methacrylate residue and Y.sup.2 is a vinyl ether, epoxy, or azide residue,A.sup.1 and A.sup.2 are identical or different residues with the general formula C.sub.n H.sub.2n in which n is a whole number from 0 to 20 and one or more methylene groups can be replaced by oxygen atoms, andM.sup.1 has the general formula --R.sup.1 --X.sup.1 --R.sup.2 --X.sup.2 --R.sup.3 --X.sup.3 --R.sup.4 -- whereinR.sup.1, R.sup.2, R.sup.3, and R.sup.4 are identical or different doubly bonded residues from the group --O--, --COO--, --CONH--, --CO--, --S--, --C.tbd.C--, --CH.dbd.CH--, --CH.dbd.N--, --CH.sub.2 --, --N.dbd.N--, and --N.dbd.N(O)--, and R.sup.2 --X.sup.2 --R.sup.3 can also be a C--C bond, andX.sup.1, X.sup.2, and X.sup.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: April 11, 2000
    Assignee: DaimlerChrysler AG
    Inventors: Peter Strohriegl, Katja Strelzyk, Andreas Stohr, Petra Grundig, Michael Gailberger, Fritz Dannenhauer, Anne Barth
  • Patent number: 6043272
    Abstract: The present invention provides substituted 3,3-diphenyl indanone, indane and indole compounds, as well as analogues thereof, which are specific, potent and safe inhibitors of mammalian cell proliferation. The compounds can be used to inhibit mammalian cell proliferation in situ as a therapeutic approach towards the treatment or prevention of diseases characterized by abnormal cell proliferation, such as cancer.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: March 28, 2000
    Assignees: Ion Pharmaceuticals, Inc., President and Fellows of Harvard College, Children's Medical Center Corporation
    Inventors: Carlo Brugnara, Jose Halperin, Rudolf Fluckiger, Emile M. Bellott, Jr., Richard John Lombardy, John J. Clifford, Ying-Duo Gao, Reem M. Haidar, Eugene W. Kelleher, Adel M. Moussa, Yesh P. Sachdeva, Minghua Sun, Heather N. Taft
  • Patent number: 6040470
    Abstract: There is provided a developer composition including at least one of sulfonyl compounds represented by formula (1) and at least one of sulfonyl compounds represented by formula 2: ##STR1## wherein X is H or lower alkyl, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 which may be the same or different, present H, halogen or lower alkyl and Y represents alkyl, benzenesulfonyl, benzoyl et al, A thermalsensitive recording medium having the above developer is of high sensitivity, less surface-blushing with lapse of time and is excellent in storage stability of a recorded image, particularly in heat resistance, humidity resistance and anti-plasticizer.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: March 21, 2000
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Shigeru Oda, Eiji Kawabata
  • Patent number: 6040473
    Abstract: A transesterification process for the preparation of (meth)acrylates wherein a (meth)acrylic acid ester is re-esterified in the presence of a re-esterification catalyst comprised of calcium hydroxide or calcium hydroxide in combination with lithium chloride.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: March 21, 2000
    Assignee: Roehm GmbH
    Inventors: Joachim Knebel, Werner Spalt
  • Patent number: 5998499
    Abstract: A liquid crystalline compound, a polymeric product formed by polymerization of the liquid crystalline compound, a dental composition including the liquid crystalline compound and method of using the dental composition. Polymerization of the liquid crystalline compound results in an low volume percent shrinkage and a high conversion to polymer. The composition of the invention is useful for dental adhesive, primer, cement, pit and fissure sealant and restorative.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: December 7, 1999
    Assignee: Dentsply G.m.b.H.
    Inventors: Joachim E. Klee, Holger Frey, Dirk Holter, Rolf Mulhaupt
  • Patent number: 5917084
    Abstract: A pine root (Deutero mycetes) fungal metabolite and analogs thereof having antifungal activity.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: June 29, 1999
    Assignee: Millennium Pharmaceuticals, Inc.
    Inventor: Zhi-Dong Jiang
  • Patent number: 5916987
    Abstract: A sulfur-containing O-(meth)acrylate compound of the following formula (1) is useful as a starting material for a resin composition used in optical applications such as a lens; ##STR1## wherein R represents hydrogen atom or methyl group; 1 represents an integer from 1 to 3; B is ##STR2## n is 1 or 2, m is 1, 2 or 3 and A is selected from certain arylene, aralkylene, thioether, dithioether or thiopheneylene radicals.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: June 29, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Seiichi Kobayashi, Nobuya Kawauchi, Toshiyuki Suzuki, Masao Imai, Kenichi Fujii
  • Patent number: 5912383
    Abstract: A description is given of a stabilized aqueous solution of unsaturated quaternary ammonium salt(s) (I), having been obtained by reaction, in the presence of water, of N,N-dimethylaminoethyl (meth)acrylate (II) with a quaternizing agent (III), at least one stabilizing agent having been used in combination with the monomer (II). This aqueous solution contains at least one sequestering agent for metals chosen from diethylenetriaminepentaacetic acid, the pentasodium salt of diethylenetriaminepentaacetic acid, N-(hydroxyethyl)ethylenediaminetriacetic acid and the trisodium salt of N-(hydroxyethyl)ethylenediaminetriacetic acid. ##STR1## R.sup.1 =H or CH.sub.3 ; R=methyl or benzyl; X=Cl, Br or CH.sub.3 --SO.sub.4.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: June 15, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Alain Riondel, Robert Legros
  • Patent number: 5834621
    Abstract: A novel sulfur-containing compound represented by the general formula (I): ##STR1## wherein n is an integer from 0 to 2; R represents a hydrogen atom, a vinyl group, a methacryloyl group, a vinylbenzyl group, a glycidyl group, an acryloyl group or an allyl group; and the case where n is 0 and R is a hydrogen atom is excluded, and a method for preparing said sulfur-containing compound. The novel sulfur-containing compound of the present invention can be copolymerized with various copolymerizable compounds to yield excellent hardened products of high refractive index. The novel sulfur-containing compound of the present invention can therefore be used as a very useful monomer for the production of optical materials, paints, adhesives, sealants, etc. having excellent properties.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: November 10, 1998
    Assignee: Sumitomo Seika Chemicals Co., Ltd.
    Inventors: Katsumasa Yamamoto, Masahito Nakano, Michio Suzuki
  • Patent number: 5830835
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; (B) a non-allylic perfume alcohol ester; and (C) optionally, (1) a carboxylic acid salt of a tertiary amine and/or a tertiary amine ester; and (2) a nonionic softener; wherein, preferably, the Iodine Value of the total number of fatty acyl groups present in (A), (C)(1), and (C)(2) is from about 3 to about 60. These compositions exhibit good antistatic properties as well as improved delivery from a substrate.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: November 3, 1998
    Assignee: Procter & Gamble Company
    Inventors: John Cort Severns, Mark Robert Sivik, Frederick Anthony Hartman, Hugo Robert Germain Denutte, Jill Bonham Costa, Alex Haejoon Chung, Rafael Ortiz
  • Patent number: 5814378
    Abstract: The present invention provides a polymerizable compound represented by Formula (I): ##STR1## where X represents a hydrogen atom or a methyl group; 1 represents an integer in the range of 0 to 14; m represents 0 or 1; n represents 0 or 1; p represents an integer in the range of 0 to 6; and q represents an integer in the range of 0 to 9, wherein m is 0 under the condition 1=0, and 1 under the condition 1.noteq.0.
    Type: Grant
    Filed: July 11, 1996
    Date of Patent: September 29, 1998
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Noriaki Onishi, Nobuaki Yamada, Kenji Suzuki, Hoyo Mizobe, Masahiko Yoshida
  • Patent number: 5770760
    Abstract: Novel aqueous thickener or thixotropic polymers are prepared by the copolymerization of (A) about 15-60 weight percent of a C.sub.3 -C.sub.8 alpha, beta-ethylenically unsaturated carboxylic acid monomer, preferably acrylic or methacrylic acid or a mixture thereof with itaconic or fumaric acid, (B) about 15-80 weight percent of a nonionic copolymerizable C.sub.2 -C.sub.12 alpha, beta-ethylenically unsaturated monomer, preferably a monovinyl ester such as ethyl acrylate or a mixture thereof with styrene, acrylonitrile, vinyl chloride or vinyl acetate, and (C) about 1-30 weight percent of a new and novel nonionic ethylenically unsaturated nonionic biphillic monomer such as tristyrylpoly(ethyleneoxy).sub.x methyl acrylate, to provide a stable aqueous colloidal dispersion at an acid pH lower than about 5.0 but becoming an effective thickener for aqueous systems upon adjustment to a pH of about 5.5-10.5 or higher. These polymers adjusted to a pH of about 5.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: June 23, 1998
    Assignee: Rhodia Inc.
    Inventor: Fred Robinson
  • Patent number: 5750213
    Abstract: A polymerizable compound represented by Formula (I): ##STR1## where X is a hydrogen atom or a methyl group; l and m are independently an integer of 0 to 14; Y is a single bond, --COO--, --OCO--, or --O--; n and p are independently an integer of 0 to 18; q and s are independently an integer of 0 or 1; and R.sup.A and R.sup.B are independently represented by Formula (II) or (III); ##STR2## provided that, when q=1, p.gtoreq.2; and when R.sup.A is represented by the Formula (II), R.sup.B is represented by the Formula (II).
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: May 12, 1998
    Assignees: Sharp Kabushiki Kaisha, Kanto Kagaku Kabushiki Kaisha
    Inventors: Noriaki Onishi, Nobuaki Yamada, Masahiko Yoshida, Hoyo Mizobe, Kenji Suzuki
  • Patent number: 5736747
    Abstract: Organic compounds having at least one ethylenically-unsaturated group are described, the organic compounds being suitable for use in coatable compositions as reactive diluents; compounds of the invention preferably have a divalent organic linking moiety devoid of reactive groups other than optional ethylenically-unsaturated groups, and a polar organic moiety and are particularly adept in solubilizing aminoplast resins having radiation-curable pendant groups.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: April 7, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ernest L. Thurber, Eric G. Larson, Alan R. Kirk, Gregg D. Dahlke
  • Patent number: 5728867
    Abstract: Carbonyloxy-substituted azulenesquaric acid dyes of the formula ##STR1## where L is C.sub.1 -C.sub.12 -alkylene which may be substituted by phenyl,R.sup.1 is C.sub.1 -C.sub.12 -alkyl, monounsaturated or polyunsaturated C.sub.3 -C.sub.12 -alkenyl, which may be phenyl-substituted, C.sub.3 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.7 -cycloalkenyl, substituted or unsubstituted phenyl, pyrrolyl, furanyl, thienyl or pyridyl andR.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently of the others hydrogen or substituted or unsubstituted C.sub.1 -C.sub.12 -alkyl,with the proviso that when R.sup.3 is hydrogen the positions of the substituents CH.sub.2 --L--O--CO--R.sup.1 and R.sup.4 on either or both azulene rings may also be interchanged with each other within an azulene ring, are useful in an optical recording medium.
    Type: Grant
    Filed: October 25, 1990
    Date of Patent: March 17, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Schmitt, Wolfgang Schrott, Peter Neumann, Sibylle Brosius, Klaus Dieter Schomann, Harald Kuppelmaier
  • Patent number: 5723066
    Abstract: An electrooptical system is disclosed in which a PDLC film is positioned between 2 electrode layers. The PDLC film contains a liquid crystal mixture forming microdroplets in an optically isotropic, transparent polymer matrix. The liquid crystal mixture comprises one or more compounds of formula I ##STR1## wherein R, A.sup.1, A.sup.2, Z.sup.1, Z.sup.2, X.sup.1, X.sup.2, Q, Y and n are as herein defined, and one or more reactive liquid crystalline compounds. The PDLC film exhibits improved switching times, especially at low temperatures.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 3, 1998
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: David Coates, Owain Llyr Parri, Simon Greenfield, Martin David Tillin, Mark John Goulding, Patrick Nolan
  • Patent number: 5709911
    Abstract: A polymerizable compound represented by Formula (I): ##STR1## where X is a hydrogen atom or a methyl group; Y and Z are independently a hydrogen atom or a fluorine atom; l is an integer of 0 to 14; m and n are independently an integer of 0 or 1; R is represented by Formula (II), (III), or (IV); and when m=1, l.gtoreq.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: January 20, 1998
    Assignees: Sharp Kabushiki Kaisha, Kanto Kagaku Kabushiki Kaisha
    Inventors: Noriaki Onishi, Nobuaki Yamada, Masahiko Yoshida, Hoyo Mizobe, Kenji Suzuki
  • Patent number: 5703272
    Abstract: A process for preparing a carboxylic acid ester which includes subjecting a carboxylic acid and an alcohol or a phenol to an esterification reaction in the presence of a silica-titania catalyst. The silica-titania catalyst is prepared by adding an acidic solution containing a silicon compound and a titanium compound dissolved therein to a solution of a basic compound to bring about co-precipitation, in which the acidic solution is a nitric acid-acidic solution or a sulfuric acid-acidic solution, a ratio of the amount (gram equivalent) of nitric acid or sulfuric acid to the amount (mol) of the silicon compound in the acidic solution is 0.5 to 50 and the amount of the titanium compound in the acidic solution is such that a ratio of titania (TiO.sub.2) in the silica-titania catalyst is 1 to 50% by weight.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 30, 1997
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Mariko Abe, Shuji Ebata, Takafumi Abe, Hirofumi Higuchi
  • Patent number: 5679834
    Abstract: A process for producing an acrylic acid ester or a methacrylic acid ester having a benzoic acid group from a benzoic acid derivative having a hydroxyalkyl group in the presence of an acid catalyst without using an azeotropic solvent with water having a strong toxicity and also without using acrylic acid chloride which has a strong tearing property, is hard to be handled and generates a by-product in the reaction. In the above process, the solvent for the benzoic acid derivative consists essentially of (meth)acrylic acid.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: October 21, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideyuki Nishikawa, Haruyoshi Gotou
  • Patent number: 5668102
    Abstract: The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced environmental impact.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: September 16, 1997
    Assignee: The Procter & Gamble Company
    Inventors: John Cort Severns, Mark Robert Sivik, Frederick Anthony Hartman, Hugo Robert Germain Denutte, Jill Bonham Costa, Alex Haejoon Chung, Rafael Ortiz
  • Patent number: 5663308
    Abstract: Organosilicon polymers, including crosslinked polymers and crosslinkable prepolymers, of cyclic polysiloxane, organic dyes, and, optionally, polyenes. The dyes include those with delocalized Pi electron systems linking electron donor groups and electron acceptor groups, and with at least two carbon-carbon double bond-containing pendant groups attached to at least two different sites from among the indicated delocalized Pi electron systems, donor groups, and acceptor groups.
    Type: Grant
    Filed: February 7, 1994
    Date of Patent: September 2, 1997
    Assignee: Hercules Incorporated
    Inventors: Wayne Michael Gibbons, Robert Paul Grasso, Michael Kevin O'Brien, Paul Joseph Shannon, Shao-Tang Sun
  • Patent number: 5663262
    Abstract: The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: September 2, 1997
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Shinsuke Shirakawa, Kazunori Kanda, Mitsuo Yamada, Kei Aoki, Satoshi Urano, Nobuaki Tomita
  • Patent number: 5629445
    Abstract: This invention relates to (meth)acrylates represented by formula (1): ##STR1## wherein, R.sub.1 and R.sub.2 are each independently H or CH.sub.3 and average value of n is 1-5; resin composite comprising (A) an urethane (meth)-acrylate and/or epoxy (meth)acrylate, (B) a (meth)-acrylate represented by formula (1) above, (C) an ethylenically unsaturated compound other than component (A) or (B), and (D) a photopolymerization initiator; and cured products of said resin composites. The cured products of said resin composites of this invention have high refractive index and are superior in mold release property, shape reproducibility, restorability, and scratch resistance and suited in particular for transmission type screens.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: May 13, 1997
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Kenji Nakayama, Katsunori Shimura, Minoru Yokoshima, Nobuo Taniguchi
  • Patent number: 5606104
    Abstract: In preparing an acyloxybenzenesulfonic acid or salts thereof by sulfonating the corresponding acyloxybenzene (1), the preparation process of the acyloxybenzenesulfonic acid wherein as an additive is added at least one selected from among carboxylic acids or esters thereof (2), alkyl phosphates (3), polyphosphoric acids (4), amides and like compounds (6), carbonic esters (7), and hydroxy compounds (8). By the process, acyloxybenzenesulfonic acid excellent in hue can be prepared on an industrial scale in an enhanced yield at enhanced selectivity and lowered cost as compared with the processes of the prior art.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: February 25, 1997
    Assignee: Kao Corporation
    Inventors: Yoshio Hatayama, Katsuhisa Inoue, Hiroshi Danjo, Kohshiro Sotoya
  • Patent number: 5578740
    Abstract: Epoxy-containing compounds which are essentially free of organic halides are prepared by (I) reacting an allyl derivative of an active hydrogen-containing compound with (II) a peroxygen-containing compound. The epoxy-containing compounds are useful in coatings, castings, laminates etc.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: November 26, 1996
    Assignee: The Dow Chemical Company
    Inventors: Andrew T. Au, J. Lowell Nafziger
  • Patent number: 5567838
    Abstract: The present invention relates to a new method of making the dimethacrylate ester of alkoxylated bisphenol-A via transesterification with methyl methacrylate. This transesterification reaction proceeds at low temperatures and is driven by the removal of methanol as a methanol/saturated hydrocarbon azeotrope. The lower temperature reaction advantageously inhibits polyerization of the feed ester. The reaction is catalyzed by potassium based catalysts.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 22, 1996
    Assignee: Aristech Chemical Corporation
    Inventors: Joseph Pugach, Jeffrey S. Salek, John E. Aiken
  • Patent number: 5562847
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; and (B) an ester of an alcohol perfume wherein the ester has at least one free carboxylic acid. The ester has the general formula: ##STR1## wherein R is selected from the group consisting of substituted or unsubstituted C.sub.1-C.sub.30 straight, branched or cyclic alkyl, alkenyl, alkynyl, alkylaryl, aryl group; or ring containing a heteroatom, R' is a perfume alcohol with a boiling point at 760 mm Hg of less than about 300 .degree. C.; and m and n are independently an integer of 1 or greater.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: October 8, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Scott W. Waite, John C. Severns, Mark R. Sivik, Frederick A. Hartman
  • Patent number: 5559088
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; (B) a non-allylic perfume alcohol ester; and (C) optionally, (1) a carboxylic acid salt of a tertiary amine and/or a tertiary amine ester; and (2) a nonionic softener; wherein, preferably, the Iodine Value of the total number of fatty acyl groups present in (A), (C)(1), and (C)(2) is from about 3 to about 60. These compositions exhibit good antistatic properties as well as improved delivery from a substrate.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: September 24, 1996
    Assignee: The Proctor & Gamble Company
    Inventors: John C. Severns, Mark R. Sivik, Frederick A. Hartman, Hugo R. G. Denutte, Jill B. Costa, Alex H. Chung
  • Patent number: 5534188
    Abstract: An acetylene derivative represented by general formula (I): ##STR1## wherein R.sup.1 is saturated or unsaturated alkyl group having 3-20 carbon atoms, R.sup.2 is saturated or unsaturated alkyl group having 1-20 carbon atoms which may optionally be substituted by halogen atom or alkoxyalkyl group having 2-20 carbon atoms, A and B represent phenylene group or the like or taken as --A--B-- represent naphthalene group or the like, m and s are each 0 or 1, n is integer of 1-6, and * means asymmetric carbon atom; a process for producing said acetylene derivative, a liquid crystal composition using the same as active ingredient, and a liquid crystal element using said composition.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: July 9, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masayoshi Minai, Takayuki Higashii, Shoji Toda, Naoyuki Takano, Kayoko Ueda, Koichi Fujisawa
  • Patent number: 5531910
    Abstract: The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced enviromental impact.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: July 2, 1996
    Assignee: The Procter & Gamble Company
    Inventors: John C. Severns, Mark R. Sivik, Frederick A. Hartman, Hugo R. G. Denutte, Jill B. Costa, Alex H. Chung
  • Patent number: 5523152
    Abstract: Organic compounds having at least one ethylenically-unsaturated group are described, the organic compounds being suitable for use in coatable compositions as reactive diluents; compounds of the invention preferably have a divalent organic linking moiety devoid of reactive groups other than optional ethylenically-unsaturated groups, and a polar organic moiety and are particularly adept in solubilizing aminoplast resins having radiation-curable pendant groups.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: June 4, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ernest L. Thurber, Eric G. Larson, Alan R. Kirk, Gregg D. Dahlke
  • Patent number: 5510402
    Abstract: The novel compounds of the formula I ##STR1## in which n is an integer from the range from 4 to 8 and m is an integer from the range from 1 to 4,A is the aliphatic, aromatic, araliphatic or heterocyclic radical of a monobasic to tetrabasic carboxylic acid, andR.sup.1 and R.sup.1', independently of one another, are C.sub.1 -C.sub.24 alkyl or C.sub.5 -C.sub.8 cycloalkyl, are suitable for stabilizing organic material against thermal, oxidative or actinic degradation.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: April 23, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul Dubs, Rita Pitteloud
  • Patent number: 5506279
    Abstract: The invention provides novel acrylamide functional disubstituted acetyl aryl ketones and a process for their preparation in high yields uncontaminated by difunctional material. The invention further provides photocrosslinkable compositions comprising one or more ethylenically-unsaturated monomers and as photoinitiator the acrylamide functional disubstituted acetyl aryl ketone of the invention. The compositions are useful for the preparation of films and coatings, particularly pressure-sensitive adhesive coatings.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: April 9, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gaddam N. Babu, Greggory S. Bennett, Kejian Chen, Steven M. Heilmann, Howell K. Smith, II, Louis E. Winslow
  • Patent number: 5502242
    Abstract: The present invention provides a propiolate ester compound represented by the formula I: ##STR1## wherein R.sub.1 represents a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.4 alkyl group or a C.sub.1 -C.sub.4 alkoxy group or alkoxy group;m denotes an integer of 1 to 5;Y represents --CH.sub.2 CH.sub.2 CH.sub.2 --, --OCH.sub.2 -- or --CH.sub.2 O--;Z represents a C.sub.2 -C.sub.6 alkylene group which may be substituted with a C.sub.1 -C.sub.4 alkyl group; andR.sub.1 may be the same or different, when m is an integer of larger than 1.The invention also provides an acaricide containing the same as an active ingredient and an acaricidal method.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: March 26, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Akira Shuto, Hirosi Kisida, Yoji Takada, Takao Ishiwatari
  • Patent number: 5488137
    Abstract: An electrophotographic photoconductor is composed of a substrate and a photoconductive layer formed thereon. The photoconductive layer is composed of a polymer including an acrylic acid ester moiety of formula (I) as repeat unit: ##STR1## wherein R.sup.1 represents hydrogen or a methyl group; R.sup.2, R.sup.3, and R.sup.4 each represent an alkyl group having 1 to 4 carbon atoms, a benzyl group, a phenyl group, a phenoxyl group, chlorine or bromine; n is an integer of 1 to 4; m is 0 or 1; and k is 0 or 1.The polymer and the monomer from which the polymer is prepared are synthesized.
    Type: Grant
    Filed: March 22, 1994
    Date of Patent: January 30, 1996
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Tamura, Toshio Fukagai, Naoshi Mishima, Masaomi Sasaki
  • Patent number: 5453452
    Abstract: This invention relates to (meth)acrylates represented by formula (1): ##STR1## wherein, R.sub.1 and R.sub.2 are each independently H or CH.sub.3 and average value of n is 1-5; resin composite comprising (A) an urethane (meth)acrylate and/or epoxy (meth)acrylate, (B) a (meth)acrylate represented by formula (1) above, (C) an ethylenically unsaturated compound other than component (A) or (B), and (D) a photopolymerization initiator; and cured products of said resin composites. The cured products of said resin composites of this invention have high refractive index and are superior in mold release property, shape reproducibility, restorability, and scratch resistance and suited in particular for transmission type screens.
    Type: Grant
    Filed: December 16, 1993
    Date of Patent: September 26, 1995
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Kenji Nakayama, Katsunori Shimura, Minoru Yokoshima, Nobuo Taniguchi
  • Patent number: 5440060
    Abstract: The demands on the properties of pigments, in particular in the areas of emulsion paints and printing inks, which are continuously becoming more specific made it necessary to develop selective and environmentally safe dispersing and emulsifying agents and coupling auxiliaries.The compounds according to the invention are alkoxylation products prepared from fatty amine dialkylenediamines which, if desired, are linked to give recurring structural units by means of esterification with dicarboxylic acids and in which, preferably, the hydroxyl end groups of these fatty amine alkylenediamine alkoxylates have been esterified with fatty acids, aromatic carboxylic acids and/or resin acids and any hydroxyl groups still present have been converted to the corresponding mono-ester-containing anionic radicals by means of dicarboxylic acids and sulfites.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: August 8, 1995
    Assignee: Hoechst AG
    Inventors: Heinz Uhrig, Albert Munkel
  • Patent number: 5342985
    Abstract: The invention relates to a process for the metathesis of olefins which comprises reacting an olefin of the formula YCZ.dbd.CZ--(CX.sub.2).sub.n R.sup.2 (II) whereinn is an integer from 1 to 28,X represents H or F,Y represents H or alkyl having from 1 to 10 carbon atoms andZ represents H or a non-aromatic hydrocarbon group having from 1 to 6 carbon atoms and R.sup.2 represents H, alkyl, halogen, COOR.sup.3 or OR.sup.4, wherein R.sup.3 and R.sup.4 represent alkyl having from 1 to 15 carbon atoms or phenyl which is unsubstituted or contains from 1 to 3 substituents or wherein R.sup.4 is trialkylsilyl R.sup.5 Si, wherein R.sup.5 represents alkyl having from 1 to 5 carbon atoms, at a catalyst comprising an oxidic carrier charged with a rhenium compound as defined hereinbefore.
    Type: Grant
    Filed: August 20, 1990
    Date of Patent: August 30, 1994
    Assignee: Hoechst AG
    Inventors: Wolfgang A. Herrmann, Werner Wagner, Ursula Volkhardt
  • Patent number: 5334749
    Abstract: A polymerizable phenol compound represented by the formula (I): ##STR1## wherein X represents a hydrogen atom, an alkyl group, a halogen atom, an alkylsulfonyl group, a hydroxyl group or a substituted or unsubstituted phenyl group; Y represents a hydrogen atom, a hydroxyl group, an alkoxy-carbonyl group, a halogen atom, an alkyl group, an alkyl-sulfonyl group, an alkoxy group, an alkanoyloxy group, an acryloyloxy group or a methacryloyloxy group; Z represents --COO--, --O--, --SO.sub.2 -- or --SO.sub.2 NH--; R represents a divalent linkage group having an --O--, --S--, --SO.sub.2 --, --CO--, --NH--, or a cyclic structure; and P represents an acryloyloxy group or a methacryloyloxy group.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: August 2, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuuichi Fukushige, Ken Iwakura, Masato Satomura
  • Patent number: 5326901
    Abstract: Novel 2-(2,2-difluorocyclopropyl)-acetic acid derivatives of formula I ##STR1## wherein A is oxygen or --NR.sub.1 --,B is C.sub.2 -C.sub.6 alkylene,D is oxygen, sulfur or --O--CH.sub.2 --,E is phenyl; phenyl substituted by from one to three substituents selected from the group halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 haloalkyl and C.sub.1 -C.sub.4 alkoxy; a five-membered aromatic heterocycle having from one to three hetero atoms selected from the group nitrogen, oxygen and sulfur, a five-membered aromatic heterocycle having from one to three hetero atoms selected from the group nitrogen, oxygen and sulfur that is substituted by one or two substituents selected from the group halogen, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.3 -haloalkyl; a six-membered aromatic heterocycle having from one to three nitrogen atoms; or a six-membered aromatic heterocycle having from one to three nitrogen atoms that is substituted by one or two substituents selected from the group halogen, C.sub.1 -C.sub.4 alkyl and C.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: July 5, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Manfred Boger
  • Patent number: 5326902
    Abstract: Oxyalkyne compounds corresponding to the formula I ##STR1## in which the substituent Y in the meta- or para-position is R.sup.1 represents CH.sub.3 or NH.sub.2, R.sup.2 represents H or CH.sub.3, R.sup.3 represents H, C.sub.1-3 -alkyl or COCH.sub.3, and Ar represents an aromatic residue selected from the group ##STR2## with the proviso that the substituents R.sup.4, R.sup.5 and R.sup.6 are the same or different and each substituent represents H, F, Cl, Br, C.sub.1-6 -alkyl, CF.sub.3 or C.sub.1-6 -alkoxy, and R.sup.7 represents H, F, Cl, Br, C.sub.1-3 -alkyl or CF.sub.3,in the form of their racemates or mixtures of diastereoisomers or in optically active form, which are suitable active ingredients in pharmaceutical compositions.
    Type: Grant
    Filed: March 24, 1993
    Date of Patent: July 5, 1994
    Assignee: Gruenenthal GmbH
    Inventors: Ulrich Seipp, Werner Vollenberg, Werner Englberger, Cornelia Geist, Michael Haurand
  • Patent number: 5292927
    Abstract: A highly fluorinated benzene compound is reacted with acryloyl chloride to ield a fluorinated liquid product which is used to impregnate a reinforcing structure. Upon impregnation, the liquid material is polymerized at about 55.degree.C. to produce a reinforced polymeric structure, which can be a circuit board. The polymer has dielectric constant of about 2.1, which is very low compared to the polymers used presently.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: March 8, 1994
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: James R. Griffith, Henry S. W. Hu
  • Patent number: 5288912
    Abstract: Disclosed is a process for the preparation of alkali metal diarylphosphide compounds wherein at least one of the aryl radicals is substituted with an alkyl group. Also disclosed is the preparation of alkyl(diaryl)phosphine compounds which are obtained by the reaction of the alkali metal diarylphosphide compounds with alkyl halide alkylating agents.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: February 22, 1994
    Assignee: Eastman Kodak Company
    Inventor: Thomas J. Devon