Abstract: The present invention relates to compounds containing organofluorochlorophosphate anions, the preparation thereof and the use thereof, in particular as ionic liquids.
Type:
Grant
Filed:
December 7, 2007
Date of Patent:
July 3, 2012
Assignee:
Merck Patent GmbH
Inventors:
Nikolai Ignatyev, German Bissky, Helge Willner
Abstract: An ionic liquid of the formula K+A? wherein K+ and A? are as defined herein, are suitable for use in electrochemical cells and capacitors. These ionic liquids can also be used in catalysis, as inert solvents, and as hydraulic liquids.
Type:
Grant
Filed:
June 11, 2001
Date of Patent:
December 26, 2006
Assignee:
Merck GmbH
Inventors:
Michael Schmidt, Udo Heider, Winfried Geissler, Nikolai Ignatyev, Volker Hilarius
Abstract: Halogenated phosphines are produced by reacting a secondary phosphine with a quaternary phosphonium halide, in a solvent/carrier for the reactants.
Type:
Grant
Filed:
February 27, 2002
Date of Patent:
March 15, 2005
Assignee:
Rhodia Consumer Specialties Limited
Inventors:
Gordon Findlay Docherty, Floryan De Campo
Abstract: Benzene phosphorus dichloride can be prepared by the reaction of benzene and phosphorus trichloride in the presence of a catalytically effective amount of a Friedel-Crafts catalyst, such as aluminum trichloride or ferric trichloride, at elevated temperature, such as from about 200.degree. C. to about 250.degree. C., and superatmospheric pressure, such as no less than the vapor pressure of the components at the chosen reaction temperature, to insure a liquid reaction medium.
Abstract: A manufacturing method for an alkyldihalogenophosphine uses an alkyl halide and a trihalide of phosphorus as starting materials. A reaction product which is formed by an FC reaction is reduced by yellow phosphorus in the presence of iodine, whereby an alkyldihalogenophosphine is manufactured. A high-purity alkyldihalogenophosphine can be manufactured with a high yield by using an excess amount of a trihalide of phosphorus, which can act as a reaction solvent.