Of Carboxylic Acid Patents (Class 564/138)
  • Patent number: 5103056
    Abstract: Disclosed is a method for selective formation of amidoamines which comprises reacting a carboxylic acid group, such as, for example, a diacid or an aliphatic acid terminated amide with an aminopropylated disecondary amine which contains a secondary amine terminus in the same molecule at a temperature of about 150.degree. C. to about 260.degree.0 C.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: April 7, 1992
    Assignee: Texaco Chemical Company
    Inventors: George P. Speranza, Donald H. Champion
  • Patent number: 5091572
    Abstract: Liquid amine terminated polyamide addition products having an average molecular weight of about 3,000 to about 10,000 are prepared by the non-catalytic reaction of a dicarboxylic acid having a molecular weight within the range of about 130 to about 700 with a higher molecular weight polyoxypropylene diamine having an average molecular weight within the range of about 1,500 to about 6,000 and with a lower molecular weight polyoxypropylene diamine having an average molecular weight within the range of about 200 to about 700, the reaction conditions including a temperature within the range of about 150.degree. to about 280.degree. C., a pressure of about 0.1 to 20 atmospheres and a reaction time of about 2 to about 5 hours.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: February 25, 1992
    Assignee: Texaco Chemical Company
    Inventors: George P. Speranza, Wei-Yang Su
  • Patent number: 5085788
    Abstract: An oil soluble dispersant comprising the reaction products of:(1) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides, (ii) long chain hydrocarbon having a polyamine attached directly thereto, and (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyalkylene polyamine, said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2) at least one polyepoxide.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: February 4, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert D. Bundberg
  • Patent number: 5047573
    Abstract: Process for the production of peptides of general formula R.sup.1 CO--NHR.sup.2 (1), where R.sup.1 CO-is the carboxy component and R.sup.2 NH-is the amino component of a peptide building block. The process is characterized in that a carboxylic acid of general formula R.sup.1 COOH (II), where R.sup.1 CO- has the above meaning, is made to react with a carboxylic acid imide choloride of general formula (III), wherein X is a hydrogen atom, an alkyl group with a maximum of 4 carbon atoms, a fluorine atom, a cholorine atom or a nitro group, Y is a fluorine atom, a chlorine atom or a nitro group and Z has the same meaning as Y or is a hydrogen atom, and the diacylamine of general formula (IV), where R.sup.1, C, Y and Z have the above meaning, is bound to an amine of general formula R.sup.2 NH.sup.2 (V), where R.sup.2 NH- have the above-mentioned meaning.
    Type: Grant
    Filed: December 7, 1987
    Date of Patent: September 10, 1991
    Inventors: Hans Bradaczek, Wojciech Gruszecki, Maria Gruszecki
  • Patent number: 5045244
    Abstract: A process for the preparation of an amine complex of a metal halide which comprises reacting said metal with an amine hydrohalide. The process can be extended to the use of metals such as aluminum, magnesium, zinc, iron, and the like.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: September 3, 1991
    Assignee: Ethyl Corporation
    Inventor: Everett M. Marlett
  • Patent number: 4973750
    Abstract: A novel sequence of highly selective chemical reactions for conversion of 3-Aryl-2-propyn-1-ols into cis-1-Aryl-3-fluoro-1-propene and into D,L-(threo)-1-Aryl-2-acylamido-3-fluoro-1-propanols is disclosed. Preparation of D-(threo)-1-Aryl-2-acylamido-3-fluoro-1-propanol antibacterial agents including the D-(threo)-3-fluoro-3-deoxy derivatives of chloramphenicol and thiamphenicol is also disclosed.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: November 27, 1990
    Assignee: Schering Corporation
    Inventors: Tattanahali L. Nagabhushan, Stuart W. McCombie
  • Patent number: 4869728
    Abstract: A motor fuel composition which inhibits engine ORI comprises a mixture of hydrocarbons boiling in the range of 90.degree. F.-450.degree. F. and the reaction product of one or more substituted or unsubstituted aliphatic carboxylic acids, including acyl-containing aliphatic carboxylic acids, and a polyoxyalkylene diamine.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: September 26, 1989
    Assignee: Texaco Inc.
    Inventor: Rodney L. Sung
  • Patent number: 4798687
    Abstract: Compounds are provided of the following general structure: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from hydrogen or methyl and A is amino, C.sub.1 -C.sub.4 monoalkylamino, C.sub.2 -C.sub.8 dialkylamino, cyclopropylamino, 1-pyrrolidinyl, 1-piperidinyl or 4-morpholinyl. They are useful for providing sedative and antiepileptic activity.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: January 17, 1989
    Assignee: Pennwalt Corporation
    Inventors: Ronald C. Griffith, James J. Napier
  • Patent number: 4682982
    Abstract: N-higher alk(en)yl neoalkanamides are new compounds which unlike many other amides, are oily at washing temperatures, in the 10.degree. to 90.degree. C. range, and are capable of being adsorbed from wash and rinse waters by fibrous materials, such as laundry of synthetic, e.g., polyester, fabrics, which laundry is susceptible to being electrostatically charged, and decrease any electrostatic charge or inhibit accumulation thereof on such materials. Such neoalkanamides, e.g., N-coco-alkyl neodecanamide, can be incorporated in detergent compositions and in compositions for addition to laundry rinse waters, and in some instances it may be desirable for bentonite powder or agglomerate to also be included in such compositions to contribute fabric softening and other useful physical properties. Washing and rinsing operations are described in which N-higher alk(en)yl neoalkanamide is present in the waters, with and without supplementing small proportions of quaternary ammonium salt.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: July 28, 1987
    Assignee: Colgate-Palmolive Company
    Inventors: Robert J. Steltenkamp, Michael A. Camara
  • Patent number: 4675442
    Abstract: What is disclosed is a method for making an amide of acrylic acid or of methacrylic acid by the reaction of an alkyl ester of acrylic acid or of methacrylic acid with an amine at a temperature between 50.degree. C. and 180.degree. C., whereby the reaction with the amine is carried out in the presence of a catalytic amount of a compound of a metal of Group IVB of the periodic table of the elements or of a compound of lead, zinc, or tantalum.
    Type: Grant
    Filed: March 6, 1985
    Date of Patent: June 23, 1987
    Assignee: Rohm GmbH
    Inventors: Siegmund Besecke, Guenter Schroeder
  • Patent number: 4658036
    Abstract: A process is disclosed for preparation of invert emulsifiers useful for oil-base drilling muds. The emulsifiers are prepared by reacting at least one tall oil fatty acid with acrylic acid, maleic anhydride or fumaric acid. The product of this reaction is substantially reacted with diethylene triamine, and at least one tall oil fatty acid to give the invert emulsifier.
    Type: Grant
    Filed: October 3, 1985
    Date of Patent: April 14, 1987
    Assignee: Westvaco Corporation
    Inventor: Peter Schilling
  • Patent number: 4655972
    Abstract: Carbonamides are prepared from carboxylic acids and ammonia in the presence of a catalytic amount of a hydrated oxide.Preferably a hydrated titanium-, zirconium- or tin oxide in an amount between 0.05 to 10% by weight is used. The hydrated oxide contains at least 4% of water.
    Type: Grant
    Filed: July 3, 1984
    Date of Patent: April 7, 1987
    Assignee: Internationale Octrooi Maatschappij "Octropa" B.V.
    Inventors: Teunis Eikelboom, John A. Rand, Pieter M. van Dijk
  • Patent number: 4640787
    Abstract: Certain branched chain amines and carboxylic derivatives thereof are useful additives for lubricants and fuels.
    Type: Grant
    Filed: June 22, 1984
    Date of Patent: February 3, 1987
    Assignee: Phillips Petroleum Company
    Inventor: Alexander D. Schuettenberg
  • Patent number: 4582933
    Abstract: This invention describes a process for the production of N-(tert-aminoalkyl)acrylamides by the reaction of acrylic acid with a suitable tertiary aminoalkylamine at a temperature of 150.degree.-230.degree. C. The aminoalkylamine and acrylic acid are reacted in equimolar quantities, preferably in the presence of an acidic or a basic catalyst.
    Type: Grant
    Filed: March 17, 1983
    Date of Patent: April 15, 1986
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Richard Mertens, Kurt Dahmen
  • Patent number: 4564695
    Abstract: An N.sup..alpha. -protected-N.sup.G -protected-arginyl-p-nitro-anilide with high purity can be produced in high yield by reacting an N.sup..alpha. -protected-N.sup.G -protected-arginine with p-nitroaniline in pyridine in the presence of a condensing agent.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: January 14, 1986
    Assignee: Nitto Boseki Co., Ltd.
    Inventors: Katsumasa Kuroiwa, Shuichi Nakatsuyama, Takeshi Nagasawa
  • Patent number: 4426325
    Abstract: To prepare compounds containing carboxylic acid amide groups, in particular peptides, there are reacted compounds containing a carboxy group, in the presence of dialkylphosphinic acid anhydrides with compounds containing a free amino group.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: January 17, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Wissmann, Hans-Jerg Kleiner
  • Patent number: 4419255
    Abstract: Lubricating oil characterized by improved friction reduction contains friction reducing amounts of a keto amide prepared by the reaction of an amine and an unsaturated cyclic keto acid bearing pendant alkyl groups.
    Type: Grant
    Filed: February 1, 1982
    Date of Patent: December 6, 1983
    Assignee: Texaco Inc.
    Inventors: Benjamin J. Kaufman, Robert A. Sawicki, Stephen A. Levine
  • Patent number: 4418211
    Abstract: A process is disclosed for selectively making trans-cyclohexane-1,4-diisocyanate, trans-cyclohexane-1,4-diamine, a trans-cyclohexane-1,4-diurethane, a transcyclohexane-1,4-diurea and trans-cyclohexane-1,4-disulphonyl urea by reacting ammonia with a mixture of cis and trans cyclohexane-1,4-dicarboxylic acid, a lower alkyl ester, a glycol ester, an oligomeric ester or a polyester to make a solid trans-dicarboxylic acid diamide in a first step. The diamide is chlorinated to form trans-cyclohexane-1,4-dicarboxylic acid-bis-N-chloramide.
    Type: Grant
    Filed: December 11, 1980
    Date of Patent: November 29, 1983
    Assignee: Akzona Incorporated
    Inventors: Hans Zengel, Manfred Bergfeld
  • Patent number: 4379928
    Abstract: Alkyl amides have been synthesized from cyclic anhydrides, carboxyl acids and their esters by contacting them with an amine carbamic acid salt.
    Type: Grant
    Filed: March 4, 1981
    Date of Patent: April 12, 1983
    Assignee: Union Carbide Corporation
    Inventor: Spyros Theodoropulos
  • Patent number: 4331592
    Abstract: What is disclosed is a method of making a carboxylic acid amide, including a peptide, by reacting a compound having a free amino group with a compound having a free carboxy group in the presence of an anhydride of an alkane-phosphonic acid.
    Type: Grant
    Filed: January 16, 1980
    Date of Patent: May 25, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Wissmann, Hans-Jerg Kleiner
  • Patent number: 4329462
    Abstract: Carboxylic amides can be produced simply and in good yield by reacting primary alcohols with at least one compound selected from ammonia, primary amines, and secondary amines, in the presence of a molecular oxygen-containing gas and a palladium or platinum catalyst under oxidative conditions.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: May 11, 1982
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Nobuhiro Tamura, Yohei Fukuoka, Joji Nishikido, Setsuo Yamamatsu, Yoshio Suzuki
  • Patent number: 4288609
    Abstract: Compounds having the general formula: ##STR1## in which: Ad is 1-adamantyl (C.sub.10 H.sub.15) radicalA is oxygen atom or --NH--(imino) groupR is --CH.sub.3 (methyl) group or --C.sub.2 H.sub.5 (ethyl) groupR' is a linear aliphatic chain containing from 10 to 12 atoms of carbonX.sup.- is a halide ion.The halide may be chlorine or bromine. The compounds exhibit an antibacterial, antimould and antiprotozoic activity and may be formulated as pharmaceutical and cosmetic preparations or used as preservatives for food products.
    Type: Grant
    Filed: December 4, 1979
    Date of Patent: September 8, 1981
    Assignee: Rotta Research Laboratorium S.p.A.
    Inventors: Luigi Rovati, Francesco Makovec, Paolo Senin
  • Patent number: 4286105
    Abstract: An inexpensive and nonhazardous process for the preparation of an amide wherein an organic acid reacting with an aryl amine to form an intermediate hydroxy aryl amide and then dehydrating the hydroxy aryl amide to form a .alpha., .beta. unsaturated amide.
    Type: Grant
    Filed: November 9, 1979
    Date of Patent: August 25, 1981
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Dane K. Parker