Symmetrical Diaryl Hydrazines Patents (Class 564/311)
-
Patent number: 7399577Abstract: Compounds of the formula (I) or (II) wherein R1 is C1-C10haloalkylsulfonyl, halobenzenesulfonyl, C2- C10haloalkanoyl, halobenzoyl; R2 is halogen or C1-C10 haloalkyl; Arl is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl, or heteroaryl, all of which are optionally substituted; Ar?1 is for example phenylene, naphthylene, diphonylene, heteroarylene, oxydiphenylene, phenyleneD-D1-D-phenylene or —Ar?1-A1—Y1-A1—Ar?1—; wherein these radicals optionally are substituted; Ae?, is phenylene, naphthylene, anthracylene, phenanthrylene, or heteroarylene, all optionally substituted; A, is for example a direct bond, —0—, —S—, or —NR6—; Y, inter alia is C1-C18alkylene; X is halogen; D is for example —0—, —S— or —NR6—; D, inter alia is C1-C18alkylene; are particularly suitable as photolatent acids in ArF resist technology.Type: GrantFiled: February 9, 2004Date of Patent: July 15, 2008Assignee: Ciba Specialty Chemicals CorporationInventors: Hitoshi Yamato, Toshikage Asakura, Akira Matsumoto, Peter Murer, Tobias Hintermann
-
Publication number: 20070272894Abstract: Tetraaromatic diamine compounds having the general formula: are provided wherein a is 0-3; b, c and d independently are integers from 0-5, R1 and R2 together with the carbon atoms to which they are bonded are joined together to form a substituted or unsubstituted C3 to about C30 ring, saturated, partially unsaturated or fully unsaturated, optionally substituted with one or more heteroatoms, a is 0-3; b, c and d independently are integers from 0-5, R3, R4, R5 and R6 are independently hydrogen, a straight or branched C1-C30 alkyl or alkylene group optionally substituted with one or more substituents, a substituted or unsubstituted C3-C12 cycloalkyl, a substituted or unsubstituted C5-C25 aryl, a substituted or unsubstituted C6-C25 arylalkyl, a straight or branched C1-C30 alkoxy group optionally substituted with one or more substituents or two R4 substituents and/or two R5 substituents and/or two R6 substituents on adjacent carbon atoms of the aromatic ring associated therewith can be joined together to formType: ApplicationFiled: February 13, 2007Publication date: November 29, 2007Inventor: Qinggao Ma
-
Patent number: 6444848Abstract: Process for the preparation of symmetrical diacylhydrazines having general formula (I): R1—CO—NH—NH—CO—R1 wherein R1 represents a linear or branched C1-C18 alkyl group; a linear or branched C2-C8 alkoxyalkyl group; a C2-C8 cyanoalkyl group; a C5-C8 cycloalkyl group, said cycloalkyl group optionally containing a heteroatom selected from oxygen, nitrogen and sulfur; a C6-C18 aryl group; a C7C20 arylalkyl group or alkylaryl group, said arylalkyl or alkylaryl groups optionally substituted with one or more hydroxyl groups, or with one or more linear or branched C1-C8 alkoxyl groups; comprising: (a) reacting an ester of a carboxylic acid having general formula (II): R1—CO—OR2 wherein R1 has the same meanings defined above and R2 represents a linear or branched C1-C18 alkyl group, with hydrazine, in its pure or hydrated state, obtaining a monoacylhydrazine having general formula (III): R1—CO—NH—NH2; (b) reacting the monoacylhydrazine having general formulaType: GrantFiled: March 9, 2001Date of Patent: September 3, 2002Assignee: Great Lakes Chemical (Europe) GmbHInventors: Fabio Broussard, Carlo Neri, Flavio Somenzi
-
Publication number: 20020120149Abstract: A method for the inhibition of high affinity glycine transporters, compounds that inhibit these transporters; pharmaceutically active compositions comprising such compounds; and the use of such compounds either as above, or in formulations for the control or prevention of disease states in which glycine is involved are disclosed.Type: ApplicationFiled: September 7, 2001Publication date: August 29, 2002Inventors: Syed M. Ali, Kurt R. Brunden, Dario Doller, Brian Herbert, Jack B. Jiang, Amy Jordan
-
Patent number: 5948406Abstract: The present invention provides an immunogen, antibodies, kits and methods of using the same to measure diacyl hydrazine compounds. The methods are easy to use, inexpensive and provide suitable cross-activity and sensitivity to enable use under FIFRA guidelines.Type: GrantFiled: August 6, 1997Date of Patent: September 7, 1999Assignee: Rohm and Haas CompanyInventors: Stanley Stephen Stavinski, Shuguang Wu, James Douglas Thacker, Ellen Schalk Casale
-
Patent number: 5808154Abstract: A process for the production of an aromatic hydrazo compound, which comprises catalytically reducing an aromatic nitro compound with hydrogen in an alkali metal hydroxide aqueous solution and a hydrogen-donating solvent in the presence of a noble metal catalyst and a quinoid compound cocatalyst at a high temperature under a high pressure, the hydrogen-donating solvent being a cyclic hydrocarbon in which hydrogen atoms are attached to its basic skeleton having 1 to 4 aromatic rings and at least one unsaturated carbon-carbon bond remains.Type: GrantFiled: July 27, 1992Date of Patent: September 15, 1998Assignee: Toyo Ink Manufacturing Co., Ltd.Inventor: Hitoshi Maki
-
Patent number: 5789139Abstract: A hydrazide compound represented by the following formula (I), and a silver halide photographic photonsensitive material comprising the hydrazide compound:A--(B).sub.b (I)wherein A represents a heterocyclic group, a condensed polycyclic aromatic group or a group formed by connecting at least two aromatic groups to each other, B represents a group represented by the following formula (I-B) or (II-B), and b represents an integer from 2 to 6;--L.sub.1 --Ar.sub.1 --NHNH--G.sub.1 --R.sub.1 (I-B)--L.sub.3 --Ar.sub.3 --L.sub.2 --Ar.sub.2 --NHNH --G.sub.2 --R.sub.2(II-B)wherein each of G.sub.1 and G.sub.2 represents a carbonyl group, an oxalyl group, a sulfonyl group or a phosphoryl group; each of R.sub.1 and R.sub.2 represents a hydrogen atom or a blocking group; each of Ar.sub.1, Ar.sub.2 and Ar.sub.3 represents an aromatic group or an aromatic heterocyclic group; and each of L.sub.1, L.sub.2 and L.sub.3 represents a linkage group.Type: GrantFiled: December 27, 1996Date of Patent: August 4, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe, Koji Kawato
-
Patent number: 5747542Abstract: Compounds of the formula ##STR1## where the symbols have the meaning described in the application, have retinoid-like or retinoid antagonist-like biological activity.Type: GrantFiled: June 21, 1996Date of Patent: May 5, 1998Assignee: AllerganInventors: Vidyasagar Vuligonda, Alan T. Johnson, Richard L. Beard, Min Teng, Tae K. Song, Harold N. Wong, Roshantha A. Chandraratna
-
Patent number: 5652239Abstract: The present invention relates to pyridazino[4,5-b]indoles, and pharmaceutically useful salts thereof, which are excitatory amino acid antagonists and which are useful when such antagonism is desired such as in the treatment of neurological disorders. The invention further provides pharmaceutical compositions containing pyridazino[4,5-b]indoles as active ingredient, and methods for the treatment of neurological disorders.Type: GrantFiled: October 19, 1995Date of Patent: July 29, 1997Assignee: Imperial Chemical CompanyInventors: Thomas Michael Bare, James Franklin Resch, Paul Francis Jackson
-
Patent number: 5530028Abstract: Insecticidal compounds having the formula N-(2-R.sup.a -3-R.sup.b -4-R.sup.h -benzoyl)-N'-(2-R.sup.c -3-R.sup.d -4-R.sup.e -5-R.sup.f -benzoyl)-N'-R.sup.g -hydrazine wherein R.sup.a is a halo or lower alkyl; R.sup. b is lower alkoxy, optionally substituted with halo (preferably fluoro); R.sup.c is selected from hydrogen, halo, lower alkyl, lower alkoxy, lower alkoxy lower alkyl, and nitro; R.sup.d, R.sup.e and R.sup.f are each independently selected from hydrogen, bromo, chloro, fluoro, lower alkyl, lower alkoxy, and lower alkoxy lower alkyl; R.sub.g is a (C.sub.4 -C.sub.6)alkyl; R.sup.h is hydrogen, lower alkoxy, lower alkyl, or when taken together with R.sup.b is methylenedioxy (--OCH.sub.2 O--), 1,2-ethylenedioxy (--OCH.sub.2 CH.sub.2 O--), 1,2-ethyleneoxy (--CH.sub.2 CH.sub.2 O--) or 1,3-propyleneoxy (--CH.sub.2 CH.sub.2 CH.sub.2 O--) wherein an oxo atom is located at the R.sup.b position; and the substituents R.sup.c and R.sup.d, or R.sup.d and R.sup.e, or R.sup.e and R.sup.Type: GrantFiled: September 29, 1993Date of Patent: June 25, 1996Assignee: Rohm and Haas CompanyInventors: Zev Lidert, Dat P. Le, Robert E. Hormann, Thomas R. Opie
-
Patent number: 5489711Abstract: An oligomer from diarylamines is disclosed which has desirable antioxidant properties in lubricating oils which contain synthetic ester lubricants. The oligomer is desirable for use at higher temperatures where it has less volatility than simple diarylamines. The oligomer has substantial portions of monosubstituted diphenylamine repeat units which result in linear oligomers. Di and polysubstituted diphenylamines may optionally be present as repeat units. These di and polysubstituted diphenylamines generally react as monofunctional reactants in oligomerization and tend to reduce the number of repeat units in the average oligomer.Type: GrantFiled: December 20, 1994Date of Patent: February 6, 1996Assignee: The B. F. Goodrich CompanyInventor: John T. Lai
-
Patent number: 5206437Abstract: The present invention relates to novel calixarene derivatives having an inclusion activity which are useful for selective transportation of various metal ions, possess a biological activity and a redox activity, and are not only capable of forming conductive or photoconductive electron transfer complexes but also have strong ability of forming complexes and absorbing UV rays. The present invention also relates to intermediates of calixarene derivatives as well as processes for production thereof.Type: GrantFiled: October 2, 1990Date of Patent: April 27, 1993Inventor: Yutaka Morita
-
Patent number: 5104910Abstract: Described herein is an isocyanate-reactive compound containing at least one linkage of the formula:--X--X--wherein X is independently in each occurrence --NR--, --S--, or --O--; R is independently in each occurrence hydrogen, C.sub.1-10 alkyl, aryl, or arylene; and at least one N, S, or O atom of the above formula is bonded to an aryl or arylene group. Also disclosed are isocyanate-reactive compositions containing the above compound and flexible polyurethane foams prepared therefrom.Type: GrantFiled: January 3, 1991Date of Patent: April 14, 1992Assignee: The Dow Chemical CompanyInventors: Robert B. Turner, Ralph D. Priester, Jr., Stephen R. Burkes
-
Patent number: 4841009Abstract: Described herein are novel substantially linear monomeric compositions which can be polymerized with one or more difunctional monomers to give novel polymeric compositions having liquid crystal properties. This invention is also directed to a process for preparation of the novel substantially linear monomeric compositions.Type: GrantFiled: July 5, 1985Date of Patent: June 20, 1989Assignee: Amoco CorporationInventor: Donald R. Kelsey
-
Patent number: 4550207Abstract: The reduction of azoxybenzene, azobenzenes and mixtures of azoxybenzenes and azobenzene to the hydrazobenzenes is possible under mild conditions, with high yields and without any great excess of reducing agents in the presence of raney-nickel and compounds which have an alkaline action with hydrogen or hydrazine hydrate.Type: GrantFiled: March 4, 1977Date of Patent: October 29, 1985Assignee: Bayer AktiengesellschaftInventors: Gunter Stephan, Karl Heinz Schundehutte
-
Patent number: 4375559Abstract: A process is disclosed for the catalytic hydrogenation of nitro-alkylbenzenes to hydrazo-alkylbenzenes wherein the reaction is conducted in a two phase solution wherein one phase constitutes an aqueous alkaline base and a second organic phase constitutes a solvent mixture having a first solvent component which is a solvent for the starting reactant and the alkaline base and a second solvent component which lowers the solvent mixture dielectric constant below 25 and which solvent component is a solvent for the reaction product.Type: GrantFiled: July 15, 1982Date of Patent: March 1, 1983Assignee: Air Products and Chemicals, Inc.Inventor: Charles G. Coe
-
Patent number: 4258059Abstract: Compounds of the formula ##STR1## wherein: Ar and Ar' are independently alicyclic aryl or heterocyclic aryl groups;R.sub.1 is a substituent replacing a hydrogen on the ring and is independently hydroxy, alkyl, alkoxy, halogen, nitro, amino, monoalkyl-amino, dialkyl-amino, sulfhydryl, alkylmercapto, sulfonamido, carboxy, carbalkoxy, or trihalomethyl;n is an integer from 0 to 5 inclusive;R.sub.2 and R.sub.3 are independently hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, phenyl, or cycloalkyl-alkyl; andR.sub.4 and R.sub.5 are independently halogen or trihalomethyl, with the proviso that when both Ar and Ar' are phenyl and n is 0, both R.sub.2 and R.sub.3 are not hydrogen.Type: GrantFiled: June 21, 1979Date of Patent: March 24, 1981Assignee: USV Pharmaceutical CorporationInventors: Joseph Auerbach, Martin L. Kantor