Hydroxymethyl Group Containing Patents (Class 568/764)
  • Patent number: 4245126
    Abstract: Mixtures of 2- and 4-hydroxybenzyl alcohol with high contents of 4-hydroxybenzyl alcohol are obtained by a process comprising reacting phenol with paraformaldehyde in the presence of a compound which exhibits two or more tertiary nitrogen atoms per molecule and a pK.sub.a value of .gtoreq.6.5 (measured at 20.degree. C. in water).
    Type: Grant
    Filed: August 30, 1979
    Date of Patent: January 13, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Fiege, Karlfried Wedemeyer, Kurt Bauer, Reiner Molleken
  • Patent number: 4238629
    Abstract: Mixtures of 2- and 4-hydroxybenzyl alcohol with high contents of 4-hydroxybenzyl alcohol are obtained by a process comprising reacting phenol and paraformaldehyde in the presence of a strongly basic catalyst and a polyalkylene polyether.
    Type: Grant
    Filed: August 30, 1979
    Date of Patent: December 9, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt Bauer, Reiner Molleken, Karlfried Wedemeyer, Helmut Fiege
  • Patent number: 4208331
    Abstract: Synthesis of optically active vitamin E from 2-methyl-5-oxotetrahydro-2-furoic acid including intermediates in this synthesis.
    Type: Grant
    Filed: January 29, 1979
    Date of Patent: June 17, 1980
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Noal Cohen, Gabriel Saucy
  • Patent number: 4205188
    Abstract: A process is provided for the production of hydroxybenzyl alcohols, comprising condensing phenol with formaldehyde in an alkaline solution to form a mixture of ortho- and para-hydroxymethyl phenols, and solvent extracting unreacted phenol from the resulting alkaline hydroxybenzyl alcohol condensate solution. The phenol-reduced hydroxybenzyl alcohol condensate solution is particularly suited for treatment with excess caustic and subsequent oxidation of the resulting aqueous solution of ortho- and para-hydroxybenzyl alcohols-sodium salt to yield the corresponding ortho- and para-hydroxybenzaldehydes-sodium salt.
    Type: Grant
    Filed: September 8, 1978
    Date of Patent: May 27, 1980
    Assignee: The Dow Chemical Company
    Inventors: Wayne C. Muench, Thad S. Hormel, Pamela M. Kirchhoff, Lanny A. Robbins
  • Patent number: 4192959
    Abstract: A process for the preparation of pure 2-hydroxybenzyl alcohol, pure 4-hydroxybenzyl alcohol or a mixture of both hydroxybenzyl alcohols by reacting phenol and formaldehyde in the presence of a basic catalyst and subjecting the resulting reaction mixture to an at least 2-stage countercurrent extraction in a solvent system of water/organic solvent which is water-immiscible or water-miscible only to a limited extent.
    Type: Grant
    Filed: June 14, 1978
    Date of Patent: March 11, 1980
    Assignee: Haarmann & Reimer
    Inventors: Kurt Bauer, Alfred Krempel, Reiner Molleken, Karlfried Wedemeyer, Helmut Fiege
  • Patent number: 4113740
    Abstract: Synthesis of optically active vitamin E from 2-methyl-5-oxotetrahydro-2-furoic acid including intermediates in this synthesis.
    Type: Grant
    Filed: May 17, 1977
    Date of Patent: September 12, 1978
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Noal Cohen, Gabriel Saucy
  • Patent number: 4111960
    Abstract: Substituted dioxolanes are provided having the formula ##STR1## wherein R.sup.1 and R.sup.2 are H or a phenyl group substituted with up to 5 substituents of lower alkyl or nitro, with the proviso that at least one of F.sup.1 and R.sup.2 is a phenyl group having an orthonitro substituent; and R.sup.3 and R.sup.4 are each H or lower alkyl. These dioxolanes, as well as appropriate dioxanes, are used to intercalate a polyoxymethylene polymer to make such a polymer having thermally stable but photochemically sensitive and degradable random linkages ##STR2## in the chain where n is 0 or 1, R.sup.3 and R.sup.4 are H or lower alkyl and at least one of R.sup.1 and R.sup.2 is a phenyl group with an orthonitro substituent. By exposing a film of the polymer to light through a transparency followed by heating or a heated treatment with base, a relief image of the copy on the transparency is obtained.
    Type: Grant
    Filed: June 29, 1976
    Date of Patent: September 5, 1978
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Donnie Joe Sam