Boron Containing Material Utilized Patents (Class 568/837)
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Publication number: 20150011797Abstract: The present invention relates to a process for the oxidation of cycloalkanes utilising a supported gold and palladium catalyst and the use of the supported gold and palladium catalyst for the oxidation of cycloalkanes. Also described is a process for the preparation of the supported catalyst.Type: ApplicationFiled: February 1, 2013Publication date: January 8, 2015Applicant: INVISTA NORTH AMERICA S.A R.L.Inventors: Keith Whiston, Xi Liu, Graham Hutchings
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Patent number: 7521582Abstract: The invention provides alkene fluoroalkanol and fluorinated polyol precursors to fluoroalkanol-substituted ?,?-unsaturated esters. The fluoroalkanol-substituted ?,?-unsaturated esters are olefins that can be readily polymerized to provide fluoroalkanol-substituted polymers useful in lithographic photoresist compositions. Also provided are methods for synthesizing the alkene fluoroalkanol and fluorinated polyol precursors.Type: GrantFiled: August 24, 2007Date of Patent: April 21, 2009Assignee: International Business Machines CorporationInventors: Gregory Breyta, Richard Anthony DiPietro, Daniel Joseph Dawson
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Patent number: 7442828Abstract: The invention provides alkene fluoroalkanol and fluorinated polyol precursors to fluoroalkanol-substituted ?,?-unsaturated esters. The fluoroalkanol-substituted ?,?-unsaturated esters are olefins that can be readily polymerized to provide fluoroalkanol-substituted polymers useful in lithographic photoresist compositions. Also provided are methods for synthesizing the alkene fluoroalkanol and fluorinated polyol precursors.Type: GrantFiled: August 24, 2007Date of Patent: October 28, 2008Assignee: International Business Machines CorporationInventors: Gregory Breyta, Richard Anthony DiPietro, Daniel Joseph Dawson
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Patent number: 5495054Abstract: A method for the enantioselective reduction of prochiral ketones using catalytic amounts of tetrahydroindeno[1,2-d][1,3,2] oxazaboroles of formula II is disclosed. ##STR1## The oxazaboroles can be generated in situ from the corresponding cis-1-amino-2-indanols or imino indanols (III) ##STR2## Novel compounds of formulas II and III are also disclosed.Type: GrantFiled: May 31, 1994Date of Patent: February 27, 1996Assignee: Sepracor, Inc.Inventors: Yun Gao, Yaping Hong, Charles M. Zepp
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Patent number: 5235117Abstract: For preparing at least one boric oxide in an anhydrous or hydrated form and of general formula B.sub.2 O.sub.3, xH.sub.2 O, in which x is a number from 0 to 3, a methyl borate hydrolyzate comprising boric oxide and methanol is introduced into a distillation column is introduced the product from, at least one compound (preferably a hydrocarbon such as, e.g., 2,3-dimethyl butane or 2-methyl pentane) forming a heteroazeotrope with methanol, said heteroazaeotrope having a boiling point below that of the azeotrope formed by methyl borate with methanol and at least one compound having a boiling point higher than that of methyl borate, said compound not forming an azeotrope with a boiling point below that of said heteroazeotrope and then at the head of the column said heteroazeotrope is recovered and at the bottom of the column a suspension containing at least one boric oxide.Type: GrantFiled: September 25, 1991Date of Patent: August 10, 1993Assignee: Institut Francais du PetroleInventors: Jacques Alagy, Christian Busson, Lionel Asselineau
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Patent number: 5137921Abstract: There is provided an inhibitory agent of an increase in blood sugar level, comprising conduritol A of the formula(I): ##STR1## or a derivative thereof, as an active component.Type: GrantFiled: July 26, 1991Date of Patent: August 11, 1992Assignee: Dai-Nippon Sugar Mfg. Co., Ltd.Inventors: Ituo Kensho, Fumio Yamashita, Toshikazu Nagai, Tadashi Fujimoto, Yoshihisa Nakano, Hideki Tukimura
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Patent number: 5107038Abstract: A process for the preparation of 4-tert-butyl-cyclohexanol, comprising the hydrogenation of 4-tert-butyl-phenol or of 4-tert-butyl-cyclohexanone in the presence of a catalytic system composed of rhodium on a Al.sub.2 O.sub.3, SiO.sub.2, TiO.sub.2, SiO.sub.2.Al.sub.2 O.sub.3 or charcoal support, in combination with HBF.sub.4 or BF.sub.3.[Y].sub.n wherein Y designates a R.sub.2 O group, R being a C.sub.1 to C.sub.6 lower alkyl radical, or a CH.sub.3 CO.sub.2 H, H.sub.3 PO.sub.4 or H.sub.2 O group and index n is equal to zero, 1 or 2.Type: GrantFiled: October 22, 1990Date of Patent: April 21, 1992Assignee: Firmenich SAInventor: Robert M. Weinstein
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Patent number: 4691053Abstract: A novel process for producing oxygen-containing organic compounds with high selectivity and good yield by oxidizing organic compounds under mild conditions is provided, which process comprises using as a catalyst for the oxidation, a complex (M.sub.m X.sub.n.L.sub.l) consisting of a transition metal compound (M.sub.m X.sub.n) and an organic phosphorous compound (L) as a ligand, wherein M represents a transition metal belonging to group I, group IV.about.VII or iron group in group VIII of the periodic table; X represents an anion such as a halogen; ligand L represents an organic phosphorous compound; and m and n mean a number of the atomic valence of said transition metal (ion) M and said anion X, respectively, and l means a number of said ligand.Type: GrantFiled: June 4, 1984Date of Patent: September 1, 1987Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Mutsuo Yamada, Yasuyuki Nishimura, Yoshijiro Arikawa, Takanori Kuwahara, Taiji Kamiguchi, Hirotoshi Tanimoto
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Patent number: 4322558Abstract: The oxidation product of cyclohexane with an oxygen-containing gas in presence of a boron compound is, after hydrolysis and separation of boric acid, deperoxidized with a heavy metal catalyst, especially a chromium salt.Type: GrantFiled: December 5, 1977Date of Patent: March 30, 1982Assignee: Imperial Chemical Industries LimitedInventor: John F. Risebury
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Patent number: 4298750Abstract: The novel borane-1,4-thioxane is synthesized by adding the calculated quantity of diborane to 1,4-thioxane. It is a stable liquid at 25.degree. C. The neat liquid is approximately 8.0 M in borane. The product, in spite of the additional oxygen atom in the ring, exhibits the desirable hydroborating and reducing action of borane-methyl sulfide. However, it possesses a major advantage over the latter in that the donor component, 1,4-thioxane, in contrast to methyl sulfide, is readily soluble in water and can be washed out of typical reaction mixtures. This greatly facilitates the synthetic applications of borane-1,4-thioxane over borane-methyl sulfide.Type: GrantFiled: February 19, 1980Date of Patent: November 3, 1981Assignee: Aldrich-Boranes, Inc.Inventor: Herbert C. Brown
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Patent number: 4285820Abstract: A process for the treatment of a waste liquid containing boron compounds and organic compounds, such as resulting from the oxidation of paraffins with oxygen in the presence of boron compounds, includes combusting the waste liquid in a furnace at a temperature higher than 1000.degree. C. in the presence of a large amount of steam. The combustion gas may be introduced into a heat recovery zone, preferably a boiler, to recover the heat thereof and then into a contacting vessel to bring same into contact with water and to recover the boron components contained in the gas. Since substantially all the boron components contained in the combustion gas are present in the form of gaseous metaboric acid, there is caused no deposition of boron oxide onto the interior walls of the combustion furnace or gas passages in the boiler.Type: GrantFiled: December 11, 1979Date of Patent: August 25, 1981Assignee: Nittetu Chemical Engineering Ltd.Inventor: Mikio Akune
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Patent number: 4271317Abstract: The invention relates to alkylborane complexes with aromatic amines of the formula: ##STR1## in which R.sup.1 and R.sup.2 are the same or different (1-4C)-alkyl radicals, or together with the adjacent nitrogen atom are morpholino, piperidino or pyrrolidino radicals; R.sup.3 and R.sup.4 are independently selected from hydrogen, (1-4C)-alkyl, (1-4C)-alkoxy, di-(1-4C)-alkylamino, morpholino, piperidino and pyrrolidino; thexyl stands for 1,1,2-trimethylpropyl; and n is the integer 1 when R.sup.3 and R.sup.4 are other than nitrogen containing radicals, or the integer 1 or 2 when one of R.sup.3 and R.sup.4 is a nitrogen containing radical, or the integer 1, 2 or 3 when both R.sup.3 and R.sup.4 are nitrogen containing radicals.The complexes are more stable than thexylborane tetrahydrofuran complex, but are sufficiently reactive to be valuable as hydroborating and reducing agents.Type: GrantFiled: October 31, 1979Date of Patent: June 2, 1981Assignee: Imperial Chemical Industries LimitedInventors: Andrew Pelter, David J. Ryder
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Patent number: 4263448Abstract: An oxidizable hydrocarbon is oxidized in a reaction zone at elevated temperature in the presence of a liquid reaction medium by introducing the hydrocarbon and a feed stream containing molecular oxygen to the reaction zone under conditions sufficient to oxidize at least a portion of the hydrocarbon; withdrawing at least a portion of the liquid reaction medium from the reaction zone; passing at least a portion of the withdrawn liquid reaction medium to an oxygen injection zone located external to the reaction zone; contacting the liquid in said oxygen-injection zone with a gas stream containing molecular oxygen under conditions sufficient to form a two-phase gas/liquid mixture; and passing said two-phase gas/liquid mixture to the reaction zone as the feed of molecular oxygen thereto.Type: GrantFiled: March 30, 1979Date of Patent: April 21, 1981Assignee: Halcon Research and Development Corp.Inventor: James Leacock
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Patent number: 4183904Abstract: A method for the recovery of boron compounds from waste streams containing boric acid and combustible organic materials in water by incineration of the combustible organic materials and dehydration of the boric acid to boric oxide. Quenching of the boric oxide, depending upon temperature and water content, yields orthoboric and/or metaboric acids in vapor phase and polyboric acid in liquid phase which is cooled along with the products of the combustion of the organic materials and, in the presence of water, converted to a mixture of boric acids in solid and liquid phase leaving the products of combustion in vapor phase. The mixture of boric acids is then separated from the products of combustion.Type: GrantFiled: October 3, 1977Date of Patent: January 15, 1980Assignee: Monsanto CompanyInventor: Oscar A. Meyer