Carbon To Carbon Unsaturation Containing Patents (Class 568/843)
  • Patent number: 4751245
    Abstract: N-(6,6-dimethyl-2-hepten-4-ynyl)-1-naphthalenemethanamine derivatives are provided having the general formula ##STR1## wherein R.sub.1 is methoxy, iminomethyl or 1-iminoethyl and R.sub.2 and R.sub.3 are each hydrogen; or R.sub.1 is methyl and one of R.sub.2 and R.sub.3 is hydrogen and the other is halogen.The above compounds as well as acid-addition salts thereof are useful as antifungal agents.
    Type: Grant
    Filed: June 25, 1986
    Date of Patent: June 14, 1988
    Assignee: E. R. Squibb & Sons, Inc.
    Inventors: Gregory S. Bisacchi, Robert Zahler
  • Patent number: 4604480
    Abstract: A method for the preparation of a first sulfone compound of the formula: ##STR1## wherein R.sub.a is ##STR2## where R.sub.b is Br and R.sub.c is H except that R.sub.b and R.sub.c together may be an electron pair when R.sub.6 is a radical of the formula: ##STR3## wherein X.sub.1 is independently chlorine, bromine or iodine and R.sub.1 and R.sub.2 are independently at each occurrence hydrogen or, substituted or unsubstituted, phenyl or alkyl where the substituents are halogen or alkoxy or additional --SO.sub.2 Br groups; provided that, each carbon atom of R.sub.1 or R.sub.2 which contains --SO.sub.2 Br also contains an X.sub.1 group and wherein R.sub.3 through R.sub.9 are independently --OZ,--C.sub.6 M.sub.5,--Z,--SiZ.sub.3 or --X.sub.2, where Z is hydrogen or substituted or unsubstituted phenyl, alkyl, alkenyl or alkynyl; X.sub.2 is chlorine, bromine, iodine or fluorine; M is independently at each occurrence Z or X.sub.2 ; R.sub.3 and R.sub.4 may together be an electron pair; two or more of R.sub.3, R.sub.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: August 5, 1986
    Assignee: The Research Foundation of State University of New York
    Inventors: Eric Block, Mohammad Aslam
  • Patent number: 4578396
    Abstract: Hydroxyalkinyl-azolyl derivatives of the formula ##STR1## in which A is a nitrogen atom or the CH group,R is optionally substituted alkyl, cycloalkyl or phenyl,R.sup.1 is hydrogen, alkyl, alkenyl, alkinyl, or optionally substituted benzyl,R.sup.2 is hydrogen or methyl, andX is hydrogen, bromine or iodine,or addition products thereof with acids or metal salts exhibit fungicidal activity. Some intermediates therefor are also new.
    Type: Grant
    Filed: May 27, 1983
    Date of Patent: March 25, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Jager, Klaus Bockmann, Karl H. Buchel, Wilhelm Brandes, Paul-Ernst Frohberger, Hans Scheinpflug
  • Patent number: 4564717
    Abstract: A fluorine-containing olefin of the formula: CF.sub.2 .dbd.CF(CF.sub.2).sub.m (CH.sub.2).sub.n OH wherein m is 0 or an integer of 1 to 10 and n is an integer of 1 to 4, which is copolymerizable with various ethylenically unsaturated compounds and provide fluorine-containing copolymers useful as raw materials for room temperature curing paints, fluorine-containing rubbers and the like.
    Type: Grant
    Filed: September 21, 1984
    Date of Patent: January 14, 1986
    Assignee: Daikin Kogyo Co., Ltd.
    Inventors: Akira Ohmori, Nobuyuki Tomihashi, Hiroshi Inukai, Yoshiki Shimizu
  • Patent number: 4558148
    Abstract: There are described fluorinated allylic compounds as expressed by the following general formula ##STR1## wherein R.sub.f is a fluorinated aliphatic group and R is a group expressed by a general formula ##STR2## wherein R.sup.1 is an aliphatic or aromatic hydrocarbon group and R.sup.2 and R.sup.3 are the same group or different groups as selected among hydrogen atom, aliphatic and aromatic hydrocarbon groups, and heterocyclic groups. Further, a process of preparing fluorinated allylic compounds is described which includes a process step wherein a silane metal halide as expressed by a general formula(R.sup.1).sub.3 SiCH.sub.2 MX,wherein R.sup.1 is either an aliphatic or aromatic hydrocarbon group, M is an element that belongs to the group IIa, IIIb, or VIIb of the periodic table, and X is a halogen atom, is reacted with a fluorinated carboxylic acid ester as expressed by a general formulaR.sub.f COOR',wherein R.sub.
    Type: Grant
    Filed: July 30, 1984
    Date of Patent: December 10, 1985
    Assignee: Daikin Industries Ltd.
    Inventors: Nobuo Ishikawa, Tomoya Kitazume
  • Patent number: 4532020
    Abstract: A process for preparing a .beta.-(fluoroalkyl or fluoroalkenyl)-.beta.-hydroxyalkyne represented by the formula ##STR1## wherein R.sub.f represents a fluoroalkyl or fluoroalkenyl group and R represents an aliphatic or aromatic group, comprising reacting an alkyne represented by the formulaR--C.tbd.CH (II)wherein R is the same as defined above with a fluorine containing aldehyde represented by the formulaR.sub.f CHO (III)wherein R.sub.f is the same as defined above in the presence of catalyst under ultrasonic irradiation.A process for preparing an .alpha.-(fluoroalkyl or fluoroalkenyl)allyl alcohol represented by the formula ##STR2## wherein R.sub.f represents a fluoroalkyl or fluoroalkenyl group, R represents an aliphatic or aromatic group and R' represents a hydrogen atom or an aliphatic group, comprising (1) reacting a .beta.-(fluoroalkyl or fluoroalkenyl)-.beta.-hydroxyalkyne represented by the formula ##STR3## wherein R.sub.
    Type: Grant
    Filed: March 7, 1984
    Date of Patent: July 30, 1985
    Assignee: Daikin Kogyo Co., Ltd.
    Inventors: Nobuo Ishikawa, Tomoya Kitazume
  • Patent number: 4455441
    Abstract: Alpha - fluoro - omega - hydroxy straight chain hydrocarbons are utilized to form attractant termiticidal compositions which are safe and economical for the combatting of termites and related pests.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: June 19, 1984
    Assignee: Research Foundation of State University of New York
    Inventor: Glenn D. Prestwich
  • Patent number: 4385185
    Abstract: Compounds of the general formula I: ##STR1## wherein R.sub.1 and R.sub.2 are equal or different alkyl-, alkoxyalkyl-, or aryl groups, or together form a ring; R.sub.3 is an allyl or benzyl radical; and R.sub.4 and R.sub.5 represent hydrogen, alkyl, alkoxyalkyl, alkenyl or further compounds of the formula II: ##STR2## wherein R.sub.1, R.sub.2, R.sub.4 and R.sub.5 have the meaning indicated above and R.sub.6 stands for hydrogen or methyl or to compounds which are modified by the addition of hydrogen to at least one olefinic or carbonylic double bond of compounds of the general formula I or II. The invention also relates to a process for preparing the new compounds. The compounds of the general formula II are obtained by thermal treatment of a selection of compounds of formula I, for which R.sub.3 stands for the allyl or methallyl radical. The compounds according to the invention are used as fragrant and flavoring substances.
    Type: Grant
    Filed: March 20, 1981
    Date of Patent: May 24, 1983
    Assignee: Consortium fur Elektrochemische Industrie GmbH
    Inventors: Helmut Gebauer, Walter Hafner
  • Patent number: 4183948
    Abstract: A compound of formula: ##STR1## wherein one of R.sup.1 and R.sup.2 represents a group of formula:W(CF.sub.2).sub.m -where W represents an atom of hydrogen, fluorine or chlorine and m has the value one or two, and the other of R.sup.1 and R.sup.2 represents an atom of fluorine, chlorine or bromine or a group of formula: ##STR2## where each of X, Y and Z independently represents an atom of hydrogen, fluorine or chlorine, and R.sup.3 represents an atom of hydrogen, or the cyano or ethynyl group. The compounds are useful against insect or acarine pests.
    Type: Grant
    Filed: January 16, 1978
    Date of Patent: January 15, 1980
    Assignee: Imperial Chemical Industries Limited
    Inventor: Roger K. Huff
  • Patent number: 4113968
    Abstract: When 1-halogeno-3-alkene-2-ol is reacted with an ortho-carboxylic ester and/or a ketene acetal, a .gamma.-halogeno-.delta.-unsaturated-carboxylic ester is obtained as a main reaction product. When this intermediate is treated with a basic substance, a substituted cyclopropane-carboxylic ester is formed. This ester can be used as an insecticide or an agricultural chemical as it is or after the alcohol residue of the ester has been converted to other alcohol residue.
    Type: Grant
    Filed: September 26, 1975
    Date of Patent: September 12, 1978
    Assignee: Kuraray Co., Ltd.
    Inventors: Fumio Mori, Yoshiaki Omura, Takashi Nishida, Kazuo Itoi