Preparing By Oxidation Patents (Class 568/910)
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Publication number: 20100089796Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.Type: ApplicationFiled: December 15, 2009Publication date: April 15, 2010Applicant: UOP LLCInventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
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Patent number: 7687669Abstract: A method for alkyl oxygenate (e.g., methanol) manufacture via partial oxidation of alkane (methane) uses an injectively-mixed backmixing reaction chamber in fluid communication with a tubular-flow reactor. Alkyl free radicals are induced in the backmixing reaction chamber prior to being fed through a flow-restriction baffle to the tubular-flow reactor. Injective intermixing of feed streams agitates the backmixing reaction chamber. In one embodiment, a variable position flow restriction baffle is axially moved to commensurately modify the backmixing reaction chamber and tubular-flow reactor volumes. In another embodiment, the tubular-flow reactor is quenched with a variable position quenching input. The method further provides for condensing the output stream from the reaction system in a condensing scrubber and also for recycling a portion of the scrubbed output stream to the reactor system.Type: GrantFiled: November 18, 2008Date of Patent: March 30, 2010Assignee: Gas Technologies LLCInventors: Nathan A. Pawlak, Robert W. Carr, Roger J. Grunch
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Patent number: 7642293Abstract: An apparatus and method of producing methanol includes reacting a heated hydrocarbon-containing gas and an oxygen-containing gas in a reactor; to provide a product stream comprising methanol; and transferring heat from the product stream to the hydrocarbon-containing gas to heat the hydrocarbon containing gas. After removing methanol and CO2 from the product stream, unprocessed hydrocarbons are mixed with the hydrocarbon containing gas fro reprocessing through the reactor.Type: GrantFiled: February 10, 2006Date of Patent: January 5, 2010Assignee: Gas Technologies LLCInventors: Nathan A Pawlak, Vladimir Ivanovich Vedeneev
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Publication number: 20090297424Abstract: The present invention relates to a continuous method for functionalizing a carbon nanotube, and more specifically, to a continuous method for functionalizing a carbon nanotube by feeding functional compounds having one or more functional group into a functionalizing reactor into which a carbon nanotube mixture including oxidizer is fed under a pressure of 50 to 400 atm and a temperature of 100 to 600° C. to a subcritical water or supercritical water condition of a pressure of 50 to 40 atm by using a continuously functionalizing apparatus to obtain the functionalized products, such that the functional group of the functional compound can be easily introduced to the carbon nanotube, thereby increasing the functionalized effect of the carbon nanotube and increasing the dispersibility accordingly.Type: ApplicationFiled: May 28, 2009Publication date: December 3, 2009Inventors: Jin Seo Lee, Joo Hee Han, Seung-Hoe Do, Seong Cheol Hong
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Publication number: 20090289227Abstract: The present invention is directed to a method for utilizing CO2 waste comprising recovering carbon dioxide from an industrial process that produces a waste stream comprising carbon dioxide in an amount greater than an amount of carbon dioxide present in starting materials for the industrial process. The method further includes producing hydrogen using a renewable energy resource and producing a hydrocarbon material utilizing the produced hydrogen and the recovered carbon dioxide.Type: ApplicationFiled: May 20, 2008Publication date: November 26, 2009Applicant: SIEMENS AKTIENGESELLSCHAFTInventor: Bruce W. Rising
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Patent number: 7615644Abstract: Aspects of the present invention relate to compositions and methods for the use of ionic liquids with dissolved metal compounds as catalysts for a variety of chemical reactions. Ionic liquids are salts that generally are liquids at room temperature, and are capable of dissolving a many types of compounds that are relatively insoluble in aqueous or organic solvent systems. Specifically, ionic liquids may dissolve metal compounds to produce homogeneous and heterogeneous organometallic catalysts. One industrially-important chemical reaction that may be catalyzed by metal-containing ionic liquid catalysts is the conversion of methane to methanol.Type: GrantFiled: September 16, 2005Date of Patent: November 10, 2009Assignee: California Institute of TechnologyInventors: Zaiwei Li, Yongchun Tang, Jihong Cheng
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Publication number: 20090234121Abstract: The synthesis of discrete, air, protic, and thermally stable transition metal NNC complexes that catalyze the CH activation and functionalization of alkanes and arenes is disclosed. Methods for the selective conversion of methane to methanol or methyl esters in acidic and neutral media are disclosed.Type: ApplicationFiled: January 15, 2009Publication date: September 17, 2009Inventors: Roy A. Periana, William A. Goddard, III, Jonas Oxgaard, Kenneth Young
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Publication number: 20090203944Abstract: A catalyst for the oxidation of an alkane to an oxygenated hydrocarbon in the presence of oxygen as a first oxidant, comprising a redox active metal centre that can be present in an oxidised and in a reduced form, an acid, a second oxidant for oxidising the reduced form of the redox active metal centre, and a source of nitrous oxide.Type: ApplicationFiled: June 28, 2007Publication date: August 13, 2009Inventors: Zengjian An, Xinhe Bao, Xiuwen Han, Xiumei Liu, Xiulian Pan
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Publication number: 20090176895Abstract: Multi-tubular reactors for fluid processing incorporate reactor tubes containing thermally conductive monolithic catalyst structures with relative dimensions and thermal expansion characteristics effective to establish both a non-interfering or slidably interfering fit between the monolith structures and the reactor tubes at selected monolith mounting temperatures, and geometries at reactor operating temperatures such that the operating gaps between tubes and monoliths under the conditions of reactor operation do not exceed about 250 ?m over tube sections where high heat flux to or from the monoliths is required.Type: ApplicationFiled: March 16, 2009Publication date: July 9, 2009Inventors: Jeffrey M. Amsden, Gildas Boulc'h, Achim K. Heibel, Neil E. Partridge
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Publication number: 20090156867Abstract: The invention provides a process for the preparation of an alkylene glycol from an alkene. The gas composition from an alkylene oxide reactor is contacted with lean absorbent in an alkylene oxide absorber in the presence of one or more catalysts that promote carboxylation. The lean absorbent comprises at least 50 wt % alkylene carbonate and less than 10 wt % water and is supplied to the alkylene oxide absorber at a temperature greater than 60° C. Alkylene oxide reacts with carbon dioxide in the absorber, forming alkylene carbonate, and fat absorbent comprising alkylene carbonate is withdrawn from the absorber. A portion of the fat absorbent is supplied to one or more hydrolysis reactors, wherein alkylene carbonate reacts with water in the presence of one or more hydrolysis catalysts. The product stream from the hydrolysis reactor is dehydrated and purified.Type: ApplicationFiled: November 12, 2008Publication date: June 18, 2009Inventor: Eugene Marie Godfried Andre VAN KRUCHTEN
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Patent number: 7456327Abstract: A method for alkyl oxygenate (e.g., methanol) manufacture via partial oxidation of alkane (methane) uses an injectively-mixed backmixing reaction chamber in fluid communication with a tubular-flow reactor. Alkyl free radicals are induced in the backmixing reaction chamber prior to being fed through a flow-restriction baffle to the tubular-flow reactor. Injective intermixing of feed streams agitates the backmixing reaction chamber. In one embodiment, a variable position flow restriction baffle is axially moved to commensurately modify the backmixing reaction chamber and tubular-flow reactor volumes. In another embodiment, the tubular-flow reactor is quenched with a variable position quenching input. The method further provides for condensing the output stream from the reaction system in a condensing scrubber and also for recycling a portion of the scrubbed output stream to the reactor system.Type: GrantFiled: March 14, 2007Date of Patent: November 25, 2008Assignee: Gas Technologies, LLCInventors: Nathan A. Pawlak, Robert W. Carr, Roger J Grunch
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Patent number: 7365217Abstract: A process is disclosed for reacting an olefin, hydrogen, and oxygen in a reactor in the presence of an epoxidation catalyst comprising a transition metal zeolite and a noble metal to produce a product stream comprising an epoxide and an alkane. The alkane is separated and oxidized to at least one oxygenated product.Type: GrantFiled: January 25, 2006Date of Patent: April 29, 2008Assignee: Lyondell Chemical Technology, L.P.Inventor: Roger A. Grey
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Patent number: 7361794Abstract: In a method of converting alkanes to their corresponding alcohols and ethers a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal bromide in the first zone to provide bromine; bromine reacts with the alkane in the second zone to form alkyl bromide; and the alkyl bromide reacts with metal oxide in the third zone to form the corresponding alcohol and/or ether. Metal bromide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal bromide is recycled from the third zone to the first zone.Type: GrantFiled: February 19, 2003Date of Patent: April 22, 2008Assignee: GRT, Inc.Inventor: Philip Grosso
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Patent number: 7291755Abstract: The present invention relates to a method for producing an alcohol and/or a ketone from a corresponding alkene(s) in a gas phase in the presence of water vapor by the use of an oxide catalyst. According to the present invention, there is provided a method for producing an alcohol and/or a ketone by bringing a starting material containing an alkene(s), as a gas phase into contact with an oxide catalyst in the presence of water vapor to carry out the reaction, wherein the oxide catalyst satisfies the following requirements: (a) it comprises an oxide(s) of molybdenum and/or tin, and (b) the amount of carbonaceous substances accumulated on the oxide catalyst is controlled to be within a range of 0.1 to 10% by mass, during the reaction.Type: GrantFiled: December 25, 2003Date of Patent: November 6, 2007Assignee: Asahi Kasei Chemicals CorporationInventors: Takashi Tsunoda, Kenji Akagishi, Atusi Watanabe
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Patent number: 7276622Abstract: It is provided that a method for producing an oxygen-containing compound, characterized in that an olefin compound having a carbon-carbon double bond which is bonded to a methyl or methylene group is reacted with an organic hydroperoxide in the presence of an ionic liquid and a selenium compound.Type: GrantFiled: March 23, 2004Date of Patent: October 2, 2007Assignee: Sumitomo Chemical Company, LimitedInventor: Koji Hagiya
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Publication number: 20070149833Abstract: A process for the production of methanol from methane has been developed. The process involves reacting methane with an oxidant such as oxygen or a peroxide in the presence of a catalyst and a solvent in a reaction zone to produce an effluent stream comprising a methanol product. The effluent stream is next separated into a gaseous stream comprising unreacted methane and carbon dioxide and a liquid stream comprising the methanol product and solvent. Next the gaseous stream is further separated to provide a methane stream which is recycled to the reaction zone. Finally, a methanol stream is isolated and a solvent stream is recycled to the reaction zone.Type: ApplicationFiled: November 17, 2006Publication date: June 28, 2007Inventors: Timothy A. Brandvold, Joseph A. Kocal
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Publication number: 20070149832Abstract: A process for converting methane to methanol using a homogeneous catalyst has been developed. The catalyst is a metal compound having an empirical formula of MxXm where M is a metal such as Pd, Cu, Co, and Mn, X is an anion such as acetate, trifluoroacetate, sulfate, propionate, “m” is the oxidation state of M, and “x” is the anion valence of X. Generally the process involves contacting a gas stream containing methane with the homogeneous catalyst and an oxidant such as hydrogen peroxide at oxidation conditions to produce methyl trifluoroacetate. Finally, the methyl trifluoroacetate is hydrolyzed to give a methanol product stream.Type: ApplicationFiled: November 17, 2006Publication date: June 28, 2007Inventors: Wensheng Chen, Timothy A. Brandvold, Maureen L. Bricker, Joseph A. Kocal, Joel T. Walenga
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Patent number: 7214837Abstract: The present invention provides a process for the production of a mixture of alcohols and ketones by the liquid phase oxidation of higher alkanes using a catalyst system consisting of transition group metal such as palladium and support such as alumina, silica, carbon, preferably carbon in the presence of alkyl hydroperoxide as oxygen carrier, under stirring conditions at a temperature range of 10°–120° C. and at atmospheric pressure in a stirred glass reactor for a period of 1–30 h. The present invention produces a mixture of alcohols and ketones with high selectivity (preferably 60–90%) along with other byproducts such as diketones and acids.Type: GrantFiled: October 29, 2004Date of Patent: May 8, 2007Assignee: Council of Scientific and Industrial ResearchInventors: Raj Madhukar Deshpande, Vilas Hari Rane, Raghunath Vitthal Chaudhari
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Patent number: 7208642Abstract: A production process and a catalyst are provided, which can be less decreased in activity of the catalyst even when CO2, water and the like are present in the starting material and/or the reaction system, and which can produce a formic ester or a methanol at a low temperature and a low pressure. The present invention relates to a process for producing methanol, comprising reacting carbon monoxide with an alcohol in the presence of an alkali metal-type catalyst, and/or an alkaline earth metal-type catalyst to produce a formic ester, wherein a hydrogenolysis catalyst of formic ester and hydrogen are allowed to be present together in the reaction system to hydrogenate the produced formic ester and thereby obtain a methanol.Type: GrantFiled: February 23, 2001Date of Patent: April 24, 2007Assignee: Nippon Steel CorporationInventors: Kaoru Fujimoto, Noritatsu Tsubaki, Kenichiro Fujimoto
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Patent number: 7179843Abstract: Production of methanol includes supplying into a reactor a hydrocarbon-containing gas, supplying into the reactor an oxygen-containing as gas, carrying out in the reactor an oxidation of the heated hydrocarbon-containing gas by oxygen of the oxygen-containing gas, and supplying into the reactor a cold hydrocarbon-containing gas to be mixed directly with a mixture of the heated hydrocarbon-containing gas and the oxygen-containing gas at a later stage of the reaction to produce also formaldehyde.Type: GrantFiled: July 29, 2004Date of Patent: February 20, 2007Assignee: Gas Technologies LLCInventors: Oleg Vitalievich Bichkov, Yury Budansky, Alexander Leonidovich Tots, Vladimir Ivanovich Vedeneev
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Patent number: 7161050Abstract: A reactant selected from the group consisting of alkanes, alkenes, alkynes, dienes, and aromatics is reacted with a halide selected from the group including chlorine, bromine, and iodine to form a first reaction product. The first reaction product is reacted with a solid oxidizer to form a product selected from the group including olefins, alcohols, ethers, and aldehydes, and spent oxidizer. The spent oxidizer is oxidized to form the original solid oxidizer and the second reactant which are recycled.Type: GrantFiled: August 19, 2003Date of Patent: January 9, 2007Assignees: GRT, Inc., The Regents of the University of CaliforniaInventors: Jeffrey H. Sherman, Eric W. McFarland, Michael J. Weiss, Ivan Marc Lorkovic, Leroy E. Laverman, Shouli Sun, Dieter J. Schaefer, Galen Stucky, Peter Ford
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Patent number: 7161048Abstract: Methanol is produced from bacterially oxidized waste methane by reaction with Pd+2, Cu+2, air, and molten phthalic anhydride in an entrained oxidizer generating half ester of methyl phthalate which is reaction distilled to produce methanol and recycle phthalic anhydride containing the Pd+2, Cu+2 phthalate catalyst.Type: GrantFiled: May 11, 2006Date of Patent: January 9, 2007Assignee: Rinnovi, L.L.C.Inventors: Carol Knox, legal representative, Walter R. Knox, deceased
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Patent number: 7084307Abstract: A palladium complex catalyzed process for the oxidation of linear alkanes is proposed which employs molecular oxygen as the oxidant to produce secondary alcohols and ketones in high selectivity, the said catalyst is a single entity and does not requires the use of any co-catalyst or solvent.Type: GrantFiled: December 23, 2004Date of Patent: August 1, 2006Assignee: Council of Scientific and Industrial ResearchInventors: Raj M. Deshpande, Makarand M. Diwakar, Raghunath Vitthal Chaudhari
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Patent number: 7057081Abstract: Methods are disclosed for converting propane and higher alkanes to their corresponding alcohols through a multi-step process with olefin as an intermediate. Methods are also disclosed for facilitating the transportation, purification or other treatment of propylene and higher olefins using a chemical conversion to the corresponding alcohol and reconversion to olefin. Methods are also disclosed for converting propane and higher alkanes to olefins using the corresponding alcohol as a temporary intermediate to minimize purification, transportation and/or other treatment costs.Type: GrantFiled: May 9, 2003Date of Patent: June 6, 2006Assignee: ConocoPhillips CompanyInventors: Joe D. Allison, Steven R. McDonald
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Patent number: 7019182Abstract: Gas phase hydrocarbons resulting from the operation of offshore petroleum wells are converted into corresponding liquid products which are mixed with liquid phased hydrocarbons resulting from operation of the offshore petroleum well for delivery therewith.Type: GrantFiled: October 4, 2004Date of Patent: March 28, 2006Assignee: GRT, Inc.Inventor: Philip Grosso
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Patent number: 7019175Abstract: The invention provides a process for the catalytic oxidation of an alkane, which comprises contacting the alkane with a source of oxygen in the presence of a catalyst comprising a compound of the formula (2) where R1 and R2 independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, or R1 and R2 may together form a double bond or an aromatic or non-aromatic ring; Y represents an oxygen atom or a sulfur atom; X represents an oxygen atom or a hydroxyl group; m denotes an integer of 0 to 4; and n denotes an integer of 1 to 3. Compounds in accordance with formula (2) possess good catalytic properties, such that when they are employed in a process in accordance with the present invention, they are capable of activating a source of oxygen and promoting the oxidation of an alkane at mild reaction temperatures.Type: GrantFiled: May 30, 2002Date of Patent: March 28, 2006Assignee: Imperial Chemical Industries PLCInventors: Xavier Baucherel, Roger Arthur Sheldon
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Patent number: 6960693Abstract: The present invention relates to an oxidation reaction catalyzed by a reaction controlled phase-transfer catalyst having the general formula of [R1R2R3R4N]xHy[A] or QmMO3(L). The catalysts themselves are not soluble in the reaction medium, but can form an active species that is soluble in the reaction medium under the action of one of the reactants. The active species can in turn react selectively with another reactant. When one of the reactants is completely consumed, the catalyst will separated out from the reacting system and can be recovered by means of simple separation method. The recovered catalyst can be recycled with comparable efficiency as that of the original catalyst. The separation of said catalyst is similar to that of heterogeneous catalyst while said catalyst will completely exhibit the characteristics of homogeneous catalyst during the reaction.Type: GrantFiled: November 29, 2001Date of Patent: November 1, 2005Assignees: China Petroleum & Chemical Corporation, Dalian Institute of Chemical Physics the Chinese Academy of SciencesInventors: Zuwei Xi, Yu Sun, Kunlan Li, Ning Zhou
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Patent number: 6924401Abstract: An apparatus and method for converting methane to methanol by partial oxidation comprises a source of methane, a source of oxygen, and a capillary tube having an outflow end and an inflow end communicating with the sources of methane and oxygen. An anode is positioned proximate to but spaced from the capillary tube. A voltage source negatively biases the capillary tube relative to the anode. A plasma jet flows from the outflow end of the capillary tube. The methane partially oxidizes into methanol in a reaction zone in the plasma jet. A collector receives the methanol in the plasma jet for subsequent condensation, separation and purification.Type: GrantFiled: August 21, 2003Date of Patent: August 2, 2005Assignee: California Institute of TechnologyInventors: Konstantinos P. Giapis, R. Mohan Sankaran, Sean McHugh
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Patent number: 6919472Abstract: A catalyst composition for the selective conversion of an alkane to an unsaturated carboxylic acid having the general formula: MoVaNbbAgcMdOx wherein optional element M may be one or more selected from aluminum, copper, lithium, sodium, potassium, rubidium, cesium, gallium, phosphorus, iron, rhenium, cobalt, chromium, manganese, arsenic, indium, thallium, bismuth, germanium, tin, cerium or lanthanum; a is 0.05 to 0.99, b is 0.01 to 0.99, c is 0.01 to 0.99, d is 0 to 0.5 and x is determined by the valence requirements of the other components of the catalyst composition. This catalyst is prepared by co-precipitation of compounds of molybdenum, vanadium, niobium, silver and M to form a mixed metal oxide catalyst. This catalyst can be used for the selective conversion of an alkane to an unsaturated carboxylic acid in a one-step process or the ammoxidation of alkanes and olefins.Type: GrantFiled: December 20, 2002Date of Patent: July 19, 2005Assignee: Saudi Basic Industries CorporationInventors: Paulette N. Hazin, Paul E. Ellis, Jr.
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Patent number: 6849767Abstract: A method of hydroborating an alkene or alkyne, or reducing an organic functionality, oxidizing primary and secondary alcohols using a fluorous borane-sulfide is disclosed. The method includes regeneration and recycling the fluorous borane-sulfide.Type: GrantFiled: July 24, 2003Date of Patent: February 1, 2005Assignee: The Board of Trustees of the University of IllinoisInventors: David C. Crich, Santhosh Neelamkavil
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Publication number: 20040260126Abstract: The present invention is a re-usable and stable supported catalyst comprising a support, an anchoring agent, and a metal complex of a substantially enantiomerically pure phosphine-aminophosphine ligand. The resulting catalyst is useful for asymmetric catalytic reactions, such as asymmetric hydrogenation reactions. Also included are methods for preparing the supported catalyst and its use for asymmetric reactions.Type: ApplicationFiled: June 7, 2004Publication date: December 23, 2004Inventors: Robert Leo Augustine, Setrak Kavork Tanielyan, Clementine Reyes, Neil Warren Boaz
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Publication number: 20040249086Abstract: The present invention is a method for oxyfunctionalizing, that is, introducing oxygen functionality to, a polyolefin such as polypropylene and poly(ethylene-alt-propylene). The polyolefin is contacted with an oxygen source such as a persulfate and catalytic amounts of a metal porphyrin complex under mild conditions to yield an oxyfunctionalized polymer that has a polydispersity that is very similar to that of the starting polymer.Type: ApplicationFiled: April 26, 2004Publication date: December 9, 2004Inventors: Nicole K. Boaen, Marc A. Hillmyer, Stephen F. Hahn
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Publication number: 20040249197Abstract: The invention relates to a method for catalytically oxidizing unsaturated hydrocarbons to form oxidation products, and to the production of saturated alcohols, ketones, aldehydes or carboxylic acids by subsequently hydrogenating the oxidation product. A compound of formula (I) is used as a catalyst during oxidizing in which: R1, R2═H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 carbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 signify identical or different radicals or R1 and R2 can be coupled to one another via a covalent bond, with Q1, Q2=the same or different, C, CH, N; X, Z═C, S or CH2; Y═O or OH; k=0, 1 or 2; 1=0, 1 or 2; m=1 to 100 in the presence of a radical initiator. Peroxy compounds or azo compounds can be used as radical initiators. Preferred substrates are cyclic aliphatic or aromatic compounds.Type: ApplicationFiled: June 25, 2004Publication date: December 9, 2004Inventors: Adolf Kuhnle, Carsten Jost, Roger Arthur Sheldon, Sandrine M.M. Chatel, Isabella W.C.E. Arends
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Publication number: 20040242941Abstract: A process for the preparation of a catalyst which comprises activating a catalyst precursor comprising a cobalt compound and a support with a gas comprising at least 5 mol % of a hydrocarbon.Type: ApplicationFiled: December 23, 2003Publication date: December 2, 2004Inventors: Malcolm Leslie Hodder Green, Tiancun Xiao
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Publication number: 20040225164Abstract: Methods are disclosed for converting ethane to ethanol through a multi-step process with ethylene as an intermediate. Methods are also disclosed for facilitating the transportation, purification or other treatment of ethylene using a chemical conversion to ethanol and reconversion to ethylene. Methods are also disclosed for converting ethane to ethylene using ethanol as a temporary intermediate to minimize purification, transportation and/or other treatment costs.Type: ApplicationFiled: May 9, 2003Publication date: November 11, 2004Applicant: ConocoPhillips CompanyInventors: Joe D. Allison, Timothy J. Eggeman, Steven R. McDonald, Kent A. Pennybaker
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Publication number: 20040186325Abstract: The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprisesType: ApplicationFiled: January 29, 2004Publication date: September 23, 2004Applicant: BASF AktiengesellschaftInventors: Heiko Maas, Michael Roper, Marc Walter, Ralf Schulz, Jurgen Tropsch, Hans-Ulrich Jager, Peter Schwab, Michael Schulz
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Publication number: 20040171861Abstract: Vanadium antimony oxide catalysts useful for the selective oxidation and ammoxidation of paraffins, olefins, and aromatic compounds are manufactured in a process comprising (i) forming a catalyst precursor slurry comprising a vanadium containing compound and an antimony containing compound in a liquid solvent medium which comprises an organic solvent, and (ii) recovering a vanadium antimony oxide from the slurry by drying the slurry in order to remove water and organic solvent.Type: ApplicationFiled: March 5, 2004Publication date: September 2, 2004Inventor: James F. Brazdil
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Publication number: 20040171893Abstract: A method of increasing the lifetime of a hydro-oxidation catalyst comprising, preferably, gold, silver, or mixtures thereof, and optionally one or more promoters, on a titanium-containing support, such as a titanosilicate or titanium dispersed on silica. The method of the invention involves contacting the catalyst support with a hydroxy-functionalized organosilicon compound, a carboxy-functionalized organosilicon compound, or a mixture of hydroxy- and carboxy-functionalized organosilicon compounds, such as, sodium methyl siliconate or (2-carboxypropyl)tetramethyldisiloxane. The contacting is preferably conducted during deposition of the catalytic metal(s) and optional promoters(s) onto the support. A catalyst composition and hydro-oxidation process utilizing the silicon-treated catalyst support are also claimed.Type: ApplicationFiled: January 21, 2004Publication date: September 2, 2004Inventors: David G. Barton, Robert G Bowman, George E Hartwell, Howard W Clark, Alexander Kuperman
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Patent number: 6781020Abstract: A water soluble bactericide is obtained by ozone-oxidizing glycerin. Specifically, a 0.1 to 20% glycerin aqueous solution and gas phase ozone obtained by ozonizing oxygen through contact between oxygen and a silent discharge field, are brought into gas-liquid contact with each other, thereby to ozone-oxdize glycerin. Alternatively, a 0.1 to 20% glycerin aqueous solution is electrolyzed, thereby to produce ozone directly in the glycerin aqueous solution.Type: GrantFiled: August 8, 2002Date of Patent: August 24, 2004Assignee: VMC Co., Ltd.Inventors: Akihiko Shiba, Kiyoko Shiba, Gotaro Shiota, Yoshiaki Maruyama
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Publication number: 20040133037Abstract: A process for preparing branched olefins comprising 0.5% or less quaternary aliphatic carbon atoms, which process comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.7 and the branching comprising methyl and optionally ethyl branches, and which isoparaffinic composition may be obtained by hydrocracking and hydroisomerization of a paraffinic wax; a method of using olefins for making an anionic surfactant, a nonionic surfactant or a cationic surfactant, in particular a surfactant sulfate or sulfonate, comprising converting the branched olefins into the surfactant; and an anionic surfactant, a nonionic surfactant or a cationic surfactant which is obtainable by the method of use.Type: ApplicationFiled: December 17, 2003Publication date: July 8, 2004Inventors: Laurent Alain Michel Fenouil, Brendan Dermot Murray, Paul Marie Ayoub
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Publication number: 20040116752Abstract: An apparatus and method for converting methane to methanol by partial oxidation comprises a source of methane, a source of oxygen, and a capillary tube having an outflow end and an inflow end communicating with the sources of methane and oxygen. An anode is positioned proximate to but spaced from the capillary tube. A voltage source negatively biases the capillary tube relative to the anode. A plasma jet flows from the outflow end of the capillary tube. The methane partially oxidizes into methanol in a reaction zone in the plasma jet. A collector receives the methanol in the plasma jet for subsequent condensation, separation and purification.Type: ApplicationFiled: August 21, 2003Publication date: June 17, 2004Inventors: Konstantinos P. Giapis, R. Mohan Sankaran, Sean McHugh
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Publication number: 20040014985Abstract: A method separates a reaction product from an imide compound catalyst represented by Formula (1) or an altered derivative thereof in a reaction mixture obtained as a result of a reaction in the presence of the imide compound catalyst by performing an extraction process using two organic solvents separable from each other to thereby separate the reaction product into one organic solvent layer and the imide compound catalyst or an altered derivative thereof into the other organic solvent layer, respectively: 1Type: ApplicationFiled: May 1, 2003Publication date: January 22, 2004Inventor: Michihiro Sugahara
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Publication number: 20040006246Abstract: A reactant selected from the group consisting of alkanes, alkenes, alkynes, dienes, and aromatics is reacted with a halide selected from the group including chlorine, bromine, and iodine to form a first reaction product. The first reaction product is reacted with a solid oxidizer to form a product selected from the group including olefins, alcohols, ethers, and aldehydes, and spent oxidizer. The spent oxidizer is oxidized to form the original solid oxidizer and the second reactant which are recycled.Type: ApplicationFiled: August 19, 2003Publication date: January 8, 2004Inventors: Jeffrey H. Sherman, Eric W. McFarland, Michael J. Weiss, Ivan Marc Lorkovic, Leroy E. Laverman, Shouli Sun, Dieter J. Schaefer, Galen Stucky, Peter Ford
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Patent number: 6664430Abstract: The present invention provides a catalyst for preparing a fluorine-containing alcohol compound, the catalyst having at least one component selected from elements in Group 1B, Group 2B, Group 6A, Group 7A and Group 8 of the periodic table, ions of these elements, oxides containing these elements, hydroxides containing these elements and salts containing these elements, said component being supported on at least one complex oxide selected from Si—Al complex oxides, Al—P complex oxides and Si—Al—P complex oxides; and a method for preparing a fluorine-containing alcohol compound, the method comprising reacting a halogenated fluorine compound with water in the presence of the catalyst. According to the present invention, a fluorine-containing alcohol compound can be prepared at a relatively low reaction temperature and in a high yield.Type: GrantFiled: November 13, 2001Date of Patent: December 16, 2003Assignee: Daikin Industries, Ltd.Inventors: Jun Miki, Hirokazu Aoyama
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Publication number: 20030212283Abstract: A process of activating a fresh catalyst or regenerating a deactivated catalyst which is used in a hydro-oxidation process, preferably, the hydro-oxidation of an olefin in the presence of oxygen and hydrogen to an olefin oxide. The hydro-oxidation catalyst preferably comprises at least one metal selected from gold, silver, the platinum group metals, the lanthanide metals, and combinations thereof, incorporated onto a titanium- , vanadium- , or zirconium-containing support more preferably, a titanium-containing support, such as titanium oxide or a titanosilicate. The activation or regeneration process involves contacting the fresh catalyst or the deactivated catalyst with ozone.Type: ApplicationFiled: September 30, 2002Publication date: November 13, 2003Inventors: Deborah H. Parker, Robert G. Bowman, Howard W. Clark, George E. Hartwell, Alex Kuperman
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Publication number: 20030191327Abstract: Process for the preparation of alkylene oxide which process comprises contacting organic hydroperoxide and alkene with a heterogeneous epoxidation catalyst and withdrawing a product stream comprising alkylene oxide and an alcohol as reaction products, in which process fresh catalyst is contacted with feed having a higher molar ratio of alkene to organic hydroperoxide than the molar ratio of normal operation.Type: ApplicationFiled: March 21, 2003Publication date: October 9, 2003Inventors: Johannes Folkert Postma, Alexander Jan Van Der Veen
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Publication number: 20030149313Abstract: A process for making a selectively branched alcohol composition contacting a lower olefin feed comprising linear olefins having at least 3 carbon atoms and a concentration of phosphorous-containing compounds with a sorbent comprising a metal or metal oxide on a support, thereby substantially reducing the concentration of phosphorous-containing compounds and producing a purified lower olefin feed. The purified lower olefin feed is skeletally isomerized and then treated to selectively hydrogenate dienes before hydroformylation to produce selectively branched alcohols.Type: ApplicationFiled: August 9, 2002Publication date: August 7, 2003Inventors: Brendan Dermot Murray, Paul Benjerman Himelfarb, Zaida Diaz, David Michael Singleton
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Publication number: 20030125589Abstract: In a method of converting alkanes to their corresponding alcohols and ethers a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal bromide in the first zone to provide bromine; bromine reacts with the alkane in the second zone to form alkyl bromide; and the alkyl bromide reacts with metal oxide in the third zone to form the corresponding alcohol and/or ether. Metal bromide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal bromide is recycled from the third zone to the first zone.Type: ApplicationFiled: February 19, 2003Publication date: July 3, 2003Applicant: GRT, Inc.Inventor: Philip Grosso
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Publication number: 20030120121Abstract: A reactant selected from the group consisting of alkanes, alkenes, and aromatics is reacted with a metal halide to form the halide of the reactant and reduced metal. The reduced metal is oxidized to form metal oxide. The metal oxide is reacted with the halide of the reactant to produce the alcohol and/or the ether corresponding to the reactant and the original metal halide which is recycled.Type: ApplicationFiled: February 12, 2003Publication date: June 26, 2003Applicant: GRT, Inc.Inventors: Jeffrey H. Sherman, Eric McFarland
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Patent number: 6573414Abstract: A process for preparing C9-alcohols comprises a) providing a C4-hydrocarbon stream comprising butene and butane; b) subjecting the C4-hydrocarbon stream to oligomerization over an olefin oligomerization catalyst and fractionating the resulting reaction mixture to give an octene-containing stream and a butene-depleted C4-hydrocarbon stream; c) subjecting the butene-depleted C4-hydrocarbon stream to steam reforming or partial oxidation to give carbon monoxide and hydrogen; d) hydroformylating the octene-containing stream by means of carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to form C9-aldehydes, where the carbon monoxide used and/or the hydrogen used originate at least in part from step c); and e) catalytically hydrogenating the C9-aldehydes by means of hydrogen.Type: GrantFiled: July 18, 2002Date of Patent: June 3, 2003Assignee: BASF AktiengesellschaftInventors: Michael Richard McAtee, Rocco Paciello, Michael-Dieter Ulbrich