Abstract: 2-Alkylidene-1,3-dioxolanes and 2-(1-alkylalkylidene)-1,3-dioxolanes are employed as acid acceptors in methylchloroform, trichloroethylene or mixtures thereof. The preferred acid acceptor is 2-methylene-1,3-dioxolane.In another aspect of the invention, aliphatic aldehyde hydrazone is employed to stabilize 2-alkylidene-1,3-dioxolane and 2-(1-alkylalkylidene)-1,3-dioxolane. The preferred aliphatic aldehyde hydrazone is acetaldehyde dimethylhydrazone.
Abstract: A nitroalkane-free inhibitor system for methylchloroform has been formulated which contains dioxane, an alkylene oxide, and 3-butyn-1-ol. The stabilizer amounts to about 4 to 6% by volume of the stabilized methylchloroform composition. The stabilized composition is useful in vapor degreasing applications when it additionally contains an alkyl nitrate.
Abstract: A stabilized methylchloroform solvent useful in degreasing operations in which the alkylene oxide stabilizer component normally employed is replaced by a tricyclic or quadricyclic compound containing a fused cyclopropane ring.