By Condensive Ring Expansion, E.g., "olefin Dismutation", Etc. Patents (Class 585/364)
  • Patent number: 7838711
    Abstract: The invention relates to a process for carrying out metathesis reactions, wherein the process is carried out continuously and a ruthenium-containing catalyst is used.
    Type: Grant
    Filed: July 7, 2005
    Date of Patent: November 23, 2010
    Assignee: Boehringer Ingelheim International GmbH
    Inventors: Thomas Herweck, Albrecht Jacobi, Thomas Nicola, Michael Wiese
  • Patent number: 7151199
    Abstract: Hydrocarbon or oxygenate conversion process in which a feedstock is contacted with a non zeolitic molecular sieve which has been treated to remove most, if not all, of the halogen contained in the catalyst. The halogen may be removed by one of several methods. One method includes heating the catalyst in a low moisture environment, followed by contacting the heated catalyst with air and/or steam. Another method includes steam-treating the catalyst at a temperature from 400° C. to 1000° C. The hydrocarbon or oxygenate conversion processes include the conversion of oxygenates to olefins, the conversion of oxygenates and ammonia to alkylamines, the conversion of oxygenates and aromatic compounds to alkylated aromatic compounds, cracking and dewaxing.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: December 19, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Luc Roger Marc Martens, Stephen N. Vaughn, Albert Edward Schweizer, John K. Pierce, Shun Chong Fung
  • Patent number: 6639116
    Abstract: Novel condensation reactions used to produce 1,3-cyclohexadiene. Such a compound is an important precursor in the manufacture of high performance plastics, as one example, are provided. In the past, the production methods for such 1,3-cyclohexadiene required very complex reactions involving numerous process steps. Such a method has proven costly, difficult to properly monitor and control, and less than reliable to provide even low amounts of such a precursor compound. The inventive production methods thus permit a reduction in complexity and cost, and, with a single reaction step, facilitate quality measurements as to the product purity itself.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: October 28, 2003
    Assignee: Millken & Company
    Inventors: John G. Lever, Kenneth Wagner, John C. Sworen
  • Patent number: 4822937
    Abstract: A process for the production of isobutylbenzenes in particular, isobutylbenzene itself, is provided. The process is in two stages and comprises (1) reacting a vinylcyclohexane with an isoolefin of formula (R)(R.sup.1)C.dbd.C(CH.sub.3).sub.2 in the presence of a dismutation catalyst to produce an isobutenylcyclohexene and (2) contacting the isobutenylcyclohexene with a dehydroisomerisation catalyst to produce an isobutylbenzene. Examples of vinylcyclohexenes which can be used include 4-vinylcyclohexene and styrene.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: April 18, 1989
    Assignee: BP Chemicals Limited
    Inventors: Derek K. MacAlpine, Malcolm J. Lawrenson
  • Patent number: 4777309
    Abstract: A continuous process for producing 5-vinyl-2-norbornene, useful as the raw material of 5-ethylidene-2-norbornene used as a termonomer for EPDM, from a mixture of cyclopentadiene and butadiene or from a mixture of cyclopentadiene and dicyclopentadiene and butadiene by the Diels-Alder reaction which process comprises adding from 10 to 10,000 ppm of N,N-diethylhydroxylamine or 4-oxo-2,2,6,6-tetramethylpiperidine-1-oxyl relative to the total weight of cyclopentadiene and butadiene or of a mixture of cyclopentadiene and dicyclopentadiene and butadiene, continuously introducing the resulting mixture into a pressure reaction vessel, allowing them to react in the absence of any gas phase portion within the said pressure reaction vessel, and continuously withdrawing the reaction product.
    Type: Grant
    Filed: September 29, 1987
    Date of Patent: October 11, 1988
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazuo Kimura, Masahiro Usui, Fujio Masuko
  • Patent number: 4668836
    Abstract: A process for producing cycloalkadienes in liquid phase by metathesis reaction of cycloalkenes in the presence of a carrier catalyst based on Re.sub.2 O.sub.7 /Al.sub.2 O.sub.3. The cycloalkenes in the form of 0.01 to 0.05 molar solutions are contacted with the carrier catalyst in a fixed bed arrangement with contact times of 10 to 100 seconds.
    Type: Grant
    Filed: October 24, 1985
    Date of Patent: May 26, 1987
    Assignee: Consortium fur Elektrochemische Industrie GmbH
    Inventors: Hans-J/u/ rgen Eberle, Franz-Heinrich Kreuzer, Norbert Zeitler
  • Patent number: 4508930
    Abstract: There is disclosed a process for the conversion of terpenes to limonene which comprises contacting at least one terpene, selected from the group comprised of mono- and bi-cyclic unsaturated hydrocarbons having the formula C.sub.10 H.sub.16 with an alkali metal sulfide catalyst on a support at a temperature of 300.degree. to 450.degree. C.
    Type: Grant
    Filed: July 20, 1984
    Date of Patent: April 2, 1985
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson G. Wideman, Lynn A. Bente
  • Patent number: 4431855
    Abstract: In an olefin disproportionation reaction, the formation of undesirable polymer is inhibited by the inclusion of a small amount of carbon monoxide in the feed.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: February 14, 1984
    Assignee: Phillips Petroleum Company
    Inventors: Robert E. Reusser, Donald G. Kuper
  • Patent number: 4180524
    Abstract: Double bond isomerization and disproportionation of olefins is obtained by contact with a catalyst in a single-stage composition containing a support, uranium, and at least one of tungsten, molybdenum, or rhenium.
    Type: Grant
    Filed: February 16, 1978
    Date of Patent: December 25, 1979
    Assignee: Phillips Petroleum Company
    Inventors: Robert E. Reusser, William B. Hughes