By Dehydrogenation Patents (Class 585/379)
  • Patent number: 4343724
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at hydrocarbon dehydrogenation conditions, with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component maintained in the elemental metallic state, and of an iron component. An example of the attenuated superactive nonacidic multimetallic catalytic composite disclosed herein is a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of an alkali or alkaline earth component, an iron component, and of a platinum group component which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: August 10, 1982
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4341664
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at hydrocarbon dehydrogenation conditions, with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component maintained in the elemental metallic state, and of a silver component. An example of the attenuated superactive nonacidic multimetallic catalytic composite disclosed herein is a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a silver component, an alkali or alkaline earth component and a platinum group component which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: July 27, 1982
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4320019
    Abstract: Reaction products prepared by reacting(a) interpolymers of ethylene, one or more C.sub.3 -C.sub.8 .alpha.-monoolefins, and one or more polyenes selected from non-conjugated dienes and trienes, with(b) one or more olefinic carboxylic acid acylating agents to form an acylating reaction intermediate which is further reacted with(c) an amine,are disclosed. These reaction products have been found useful as multi-functional additives to a variety of lubricating oils for enhancing their dispersancy as well as improving their viscosity-temperature relationship.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: March 16, 1982
    Assignee: The Lubrizol Corporation
    Inventor: Katsumi Hayashi
  • Patent number: 4289917
    Abstract: Alkali metal oxides of cis- and trans-2,6,6-trimethylbicyclo(3.1.1)-heptan-2-ol are surprisingly effective bases in organic reactions calling for the use of a strong base, especially those reactions wherein abstraction of a proton from attachment to a carbon atom is postulated to occur in the mechanism.
    Type: Grant
    Filed: August 17, 1979
    Date of Patent: September 15, 1981
    Assignee: SCM Corporation
    Inventors: Bernard J. Kane, Sean G. Traynor
  • Patent number: 4271323
    Abstract: Process for hydrogenating unsaturated compounds in the liquid phase in the presence of a soluble catalyst obtained by reacting an organometal derivative or a metal hydride with a synergistic mixture of (a) a compound of zinc, zirconium, manganese, molybdenum, or iron and (b) a nickel or cobalt compound.
    Type: Grant
    Filed: October 10, 1975
    Date of Patent: June 2, 1981
    Assignee: Institut Francais du Petrole
    Inventors: Daniel Durand, Gerard Hillion, Christian Lassau, Lucien Sajus
  • Patent number: 4235755
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a nonacidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, a lanthanide series component and an alkali or alkaline earth component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum group component, a cobalt component, a lanthanide series component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % lanthanide series metal and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.
    Type: Grant
    Filed: February 21, 1979
    Date of Patent: November 25, 1980
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4216346
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, and a zinc component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum group component, a cobalt component, a zinc component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % zinc and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: August 5, 1980
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4210769
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at hydrocarbon dehydrogenation conditions, with a novel superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component maintained in the elemental metallic state. An example of the superactive nonacidic multimetallic catalytic composite disclosed herein is a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of an alkali or alkaline earth component and of a platinum group component which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: July 1, 1980
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4197416
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a nonacidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a rhenium component, a cobalt component, a germanium component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 2 wt. % rhenium, about 0.1 to about 5 wt. % cobalt, about 0.001 to about 1 wt. % germanium and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.
    Type: Grant
    Filed: September 22, 1978
    Date of Patent: April 8, 1980
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4177218
    Abstract: A process for the catalytic dehydrogenation of a dehydrogenatable hydrocarbon is disclosed. The hydrocarbon is passed in contact with a germanium-promoted platinum group metal catalyst at dehydrogenation reaction conditions, said catalyst having been prepared by impregnating a porous high surface area carrier material with a non-aqueous solution of a platinum group metal and a halo-substituted germane containing less than about 4 halo substituents, and drying, calcining and reducing the impregnated carrier material.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: December 4, 1979
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4175031
    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state, and of an indium component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, indium component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt.% platinum group metal, about 0.01 to about 5 wt.% rhenium, about 0.01 to about 5% indium and about 0.1 to about 3.5 wt.% halogen.
    Type: Grant
    Filed: June 30, 1978
    Date of Patent: November 20, 1979
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4172853
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions including a hydrogen-rich and substantially water-free environment, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IVA metallic component, and a lanthanide series component with a porous carrier material. A specific example of the catalyst used in the disclosed hydrocarbon dehydrogenation method in a nonacidic catalytic composite comprising a combination of a platinum group component, a Group IVA metallic component, a lanthanide series component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IVA metal, about 0.1 to about 5 wt. % alkali metal or alkaline earth metal, and having an atomic ratio of lanthanide series metal to platinum group metal of about 0.1:1 to 1.25:1.
    Type: Grant
    Filed: June 22, 1978
    Date of Patent: October 30, 1979
    Assignee: UOP Inc.
    Inventor: George J. Antos