Using Metal-free H Acceptor Patents (Class 585/414)
  • Patent number: 9938206
    Abstract: A process for aromatizing hydrocarbons comprises: converting at least a portion of highly branched hydrocarbons in a feed stream into selectively convertible components, and aromatizing the selectively convertible components to produce an aromatization reactor effluent. The aromatization reactor effluent comprises an aromatic product. Converting at least the portion of the highly branched hydrocarbons into the selectively convertible components may include contacting the feed stream with an isomerization catalyst in an isomerization reaction system under isomerization reaction conditions; and isomerizing the portion of the highly branched hydrocarbons in the feed stream into the selectively convertible components.
    Type: Grant
    Filed: October 5, 2017
    Date of Patent: April 10, 2018
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Eric P. Weber, Tin-Tack Peter Cheung, Yu Su
  • Patent number: 9809510
    Abstract: A process for aromatizing hydrocarbons comprises: converting at least a portion of highly branched hydrocarbons in a feed stream into selectively convertible components, and aromatizing the selectively convertible components to produce an aromatization reactor effluent. The aromatization reactor effluent comprises an aromatic product. Converting at least the portion of the highly branched hydrocarbons into the selectively convertible components may include contacting the feed stream with an isomerization catalyst in an isomerization reaction system under isomerization reaction conditions; and isomerizing the portion of the highly branched hydrocarbons in the feed stream into the selectively convertible components.
    Type: Grant
    Filed: June 21, 2016
    Date of Patent: November 7, 2017
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Eric P. Weber, Tin-Tack Peter Cheung, Yu Su
  • Patent number: 9302954
    Abstract: The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.
    Type: Grant
    Filed: October 22, 2012
    Date of Patent: April 5, 2016
    Assignee: Rutgers, The State University of New Jersey
    Inventors: Alan Goldman, Ritu Ahuja, William Schinski
  • Publication number: 20130123552
    Abstract: The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.
    Type: Application
    Filed: October 22, 2012
    Publication date: May 16, 2013
    Inventors: Alan Goldman, Ritu Ahuja, William Schinski
  • Patent number: 8188327
    Abstract: This invention covers a process for dimerizing of isobutylene to Iso-octene and unique configuration is being disclosed, where the Feed is diluted to low level with recycle which has essentially no Iso-octene, dual catalyst system, new selectivator (IPA) and successive catalyst stages if needed to enhance the conversion. The process is very selective and provides higher isobutylene conversion. Additionally the invention also covers the hydrogenation of olefins to Paraffin, Iso-octene to Iso-octane product under moderate conditions and with dual or single catalyst system.
    Type: Grant
    Filed: February 1, 2010
    Date of Patent: May 29, 2012
    Inventor: Amarjit S. Bakshi
  • Patent number: 7273957
    Abstract: A process for the production of gasoline stocks wherein lower molecular weight olefins are first oligomerized and the oligomers then hydrogenated. In the first instance the oligomerization is carried out in a single pass fixed bed boiling point reactor. The oligomers are then hydrogenated in a distillation column reactor.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: September 25, 2007
    Assignee: Catalytic Distillation Technologies
    Inventors: Amarjit S. Bakshi, Mitchell E. Loescher, Nishit Sahay
  • Patent number: 6544408
    Abstract: Process for the production of aromatic compounds, such as reforming, that uses at least one fixed catalyst bed with a base of platinum and 0.08% rhenium. In said process, before moving onto the bed, the feedstock undergoes a heat exchange with the effluent that is obtained from the process, whereby the exchange is carried out with a pressure drop that is less than 1 bar and a temperature difference that is less than 70° C. The beds are preferably radial and those that are located at the top of the reactor are covered by a cloth layer. The process preferably uses at least two fixed catalyst beds, whereby the first bed (in the direction of circulation of the feedstock) has an Re/Pt ratio by weight that is greater than that of the second bed, and whereby the second catalyst preferably contains at least 0.08% of Re.
    Type: Grant
    Filed: March 13, 2000
    Date of Patent: April 8, 2003
    Assignee: Institut Francais du Petrole
    Inventor: Jean de Bonneville
  • Publication number: 20030004381
    Abstract: A process for selectively producing para-xylene from a feedstock enriched in C8 isoalkanes and/or isoalkenes is disclosed. The feed is contacted with Group VIII metal loaded molecular sieve catalyst of low acidity under dehydrocyclization conditions wherein the molecular sieve has a channel size ranging from about 5-8 Angstroms and a 10 to 12 membered ring structure containing at least two elements selected from the group consisting of Si, Al, P, Ge, Ga and Ti.
    Type: Application
    Filed: June 15, 2001
    Publication date: January 2, 2003
    Inventors: Xiaobing Feng, Thomas H. Colle, Gary D. Mohr
  • Patent number: 5877368
    Abstract: Disclosed is a method for producing aromatic hydrocarbons, which comprises contacting a light hydrocarbon feedstock comprising olefins and/or paraffins with a zeolite catalyst in a fixed-bed, adiabatic reactor containing a fixed catalyst bed comprised of the zeolite catalyst, to thereby effect a catalytic cyclization reaction of the light hydrocarbon feedstock, wherein the catalytic cyclization reaction is performed under conditions which satisfy the following requirements: (1) the zeolite catalyst has an initial stage-catalytic activity of 0.2 (sec.sup.-1) or more in terms of the initial stage, first-order reaction rate constant of the decomposition of n-hexane catalyzed by the zeolite catalyst; (2) the catalyst bed has a temperature of from 450.degree. C. to 650.degree. C.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: March 2, 1999
    Assignee: Sanyo Petrochemical Co., Ltd.
    Inventors: Kazuyoshi Kiyama, Takashi Tsunoda, Masatsugu Kawase
  • Patent number: 4246202
    Abstract: This invention provides a process for the production of cyclic hydrocarbons from light olefinic hydrocarbons which involves contacting n-octene feed with a Group VIII metal oxide catalyst in the presence of molecular oxygen at temperatures of 130.degree.-500.degree. C. and a pressure of 1-200 psi to yield vinylcyclohexene and ethylbenzene.The invention further provides a two step vapor phase process embodiment for converting n-octene feed to styrene via a vinylcyclohexene/ethylbenzene intermediate mixture. When nitrobenzene is employed as the oxidizing agent in place of molecular oxygen, aniline is obtained as an additional product.
    Type: Grant
    Filed: May 23, 1979
    Date of Patent: January 20, 1981
    Assignee: El Paso Products Company
    Inventor: John L. Cihonski
  • Patent number: 4210603
    Abstract: This invention provides a process for the production of cyclic hydrocarbons for light olefinic hydrocarbons which involves contacting n-butenes with a Group VIII metal oxide catalyst in the presence of molecular oxygen at temperatures of 130.degree.-500.degree. C. and a pressure of 1-200 psi to yield vinylcyclohexene and ethylbenzene with a selectivity of at least 80 weight percent.The invention further provides a two step vapor phase process embodiment for converting n-butenes to styrene via a vinylcyclohexene/ethylbenzene intermediate mixture. When nitrobenzene is employed as the oxidizing agent in place of molecular oxygen, aniline is obtained as an additional product.
    Type: Grant
    Filed: April 16, 1979
    Date of Patent: July 1, 1980
    Assignee: El Paso Products Company
    Inventor: John L. Cihonski