Including Steps Of Distillation And Agent Addition Patents (Class 585/807)
-
Patent number: 10329498Abstract: A process is presented for the purification of an olefins feed stream to a benzene alkylation unit. The process removes heavy aromatics in an adsorbent system comprising at least two adsorbent units. The unit passes the olefins feed stream to a first adsorbent unit, while the second adsorbent unit is either in regeneration mode, or standby mode. The process switches the feed stream to the second adsorbent unit and displaces the fluid in the second adsorbent unit, while maintaining the flow of the purified feed stream to the benzene alkylation unit.Type: GrantFiled: October 30, 2018Date of Patent: June 25, 2019
-
Patent number: 10167241Abstract: A process is presented for the purification of an olefins feed stream to a benzene alkylation unit. The process removes heavy aromatics in a two adsorbent unit system. The unit passes the olefins feed stream to a first adsorbent unit, while the second adsorbent unit is either in regeneration mode, or standby mode. The process switches the feed stream to the second adsorbent unit and displaces the fluid in the second adsorbent unit, while maintaining the flow of the purified feed stream to the benzene alkylation unit.Type: GrantFiled: May 23, 2018Date of Patent: January 1, 2019
-
Publication number: 20150031930Abstract: The invention relates to a method of isolating cymene comprising the following steps: a) providing a solution comprising cymene and monoterpenes, b) adding sulphuric acid to the solution in a) such that the concentration of sulphuric acid in the solution is at least 0.5% (w/w), such as 1-25% (w/w), c) distilling the solution mixture from step b) such that a target chemical stream enriched in cymene is obtained and separated from a residual stream.Type: ApplicationFiled: February 14, 2013Publication date: January 29, 2015Inventors: Jörg Brücher, David Blomberg Saitton
-
Patent number: 8889943Abstract: The present invention relates to a method and system for recovering aromatics from a naphtha feedstock obtained from a crude petroleum, natural gas condensate, or petrochemical feedstock. The method and system comprise the steps of recovering an aromatics fraction from the feedstock prior to reforming.Type: GrantFiled: February 2, 2007Date of Patent: November 18, 2014Inventor: William George Rhodey
-
Patent number: 8673134Abstract: A method for the removal of nitrogen compounds from FCC feed or from catalytically cracked distillates including FCC cycle oils by using formaldehyde to selectively couple organic heterocyclic nitrogen species in the FCC feed or FCC distillate to form higher boiling coupling products out of the boiling range of FCC distillate. Removal of the nitrogenous compounds improves the operation of subsequent hydrodesulfurization steps needed for the distillate fraction to conform to low sulfur standards. The formaldehyde is preferably used in the form of paraformaldehyde. The reaction between the nitrogenous compounds in the cycle oil fraction with the formaldehyde is conveniently carried out in the cycle oil pumparound circuit of the FCC main column.Type: GrantFiled: October 20, 2010Date of Patent: March 18, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Stacey E. Siporin, David Thomas Ferrughelli, Steven S. Lowenthal, Randolph J. Smiley, Alan Roy Katritzky, Bruce R. Cook
-
Patent number: 8663461Abstract: Solvent regeneration to recover a polar hydrocarbon (HC) selective solvent substantially free of hydrocarbons (HCs) and other impurities from a solvent-rich stream containing selective solvent, heavy HCs, and polymeric materials (PMs) generated from reactions among thermally decomposed or oxidized solvent, heavy HCs, and additives is provided. A combination of displacement agent and associated co-displacement agent squeezes out the heavy HCs and PMs from the extractive solvent within a solvent clean-up zone. Simultaneously, a filter equipped with a magnetic field is positioned in a lean solvent circulation line to remove paramagnetic contaminants. The presence of the co-displacement agent significantly enhances the capability of the displacement agent in removing the heavy HCs and PMs from the extractive solvent.Type: GrantFiled: March 3, 2013Date of Patent: March 4, 2014Assignees: AMT International, Inc., CPC Corporation, TaiwanInventors: Fu-Ming Lee, Tzong-Bin Lin, Kuang-Yeu Wu, Jyh-Haur Hwang, Tsung-Min Chiu, Jeng-Cheng Lee, Han-Tjen Jan, Yuan-Fu Sun
-
Patent number: 8648227Abstract: The invention relates to a method for extracting styrene, having a polymerization quality, from pyrolysis benzol fractions containing styrene by means of extractive distillation. The pyrolysis benzol fraction is separated in a separating wall column in a C8-core fraction, a C7 fraction and a C9+-fraction, the obtained C8-core fraction is subjected to selective hydrogenation of the phenylacetylene C8H6 which it contains. Subsequently, the obtained C8-fraction undergoes extractive-distillative separation in a styrene fraction and a fraction which is low in styrene.Type: GrantFiled: May 24, 2006Date of Patent: February 11, 2014Assignee: Thyssenkrupp Uhde GmbHInventor: Helmut Gehrke
-
Publication number: 20140012058Abstract: Methods and systems for controlling the pressure of distillation columns, for example those operating under vacuum pressure and conventionally equipped with a steam ejector system, are described. Representative distillation columns are used in the separation of thermally unstable components, such as the physical solvent sulfolane, having relatively low volatility. Such columns are employed in aromatic hydrocarbon extraction processes for the recovery of purified C6-C8 aromatic hydrocarbons from a hydrocarbon feed stream (e.g., obtained from the catalytic reforming of naphtha).Type: ApplicationFiled: August 29, 2013Publication date: January 9, 2014Applicant: Uop LLCInventors: Bruce R. Beadle, Jason L. Noe, Sara A. Williams
-
Patent number: 8552245Abstract: This method includes the separation of an upstream partly condensed cracked gas stream in an intermediate separator (44B) in order to recover an intermediate liquid (136), and an intermediate cracked gas stream (138) and the introduction of the intermediate liquid (140) into an intermediate demethanization column (68). The method comprises the sampling of a portion of the intermediate liquid (136) and the expansion of at least one first fraction (194) obtained from the sampled portion (190). It comprises the putting of the first expanded fraction in a heat exchange relationship with the intermediate head stream (146) from the column (68) for at least partly condensing the intermediate head stream (146). The method includes the separation of the intermediate partly condensed head stream in a first reflux separator (76) in order to form a liquid stream (148) introduced into the intermediate column (68) and a combustible gas stream (150).Type: GrantFiled: March 28, 2011Date of Patent: October 8, 2013Assignee: Technip FranceInventors: Yvon Simon, Jean-Paul Laugier
-
Patent number: 8536397Abstract: A process for the separation of the aromatic compounds benzene, toluene and xylene from an aromatics-containing reformate gasoline and pyrolysis gasoline or a coke-oven light oil or an aromatics-containing refinery stream, in which the aromatics are separated by an extractive distillation uses a novel solvent combination made up of the compounds n,n?-diformyl piperazine or 2,2?-bis-(cyanoethyl)ether in a combination with n-formyl morpholine as a second solvent for extractive distillation so that the solvent combination obtained shows a higher selectivity with regard to the aromatics to be extracted so that a lower solvent load is required. The aromatics-containing feed mixture is first submitted to a pre-distillation so that the obtained fraction has a narrow boiling point range. This fraction is then submitted to an extractive distillation in a first column, in which an aromatics-lean head product of predominantly paraffinic hydrocarbons is obtained as well as an aromatics-enriched bottom product.Type: GrantFiled: August 5, 2008Date of Patent: September 17, 2013Assignee: UHDE GmbHInventors: Oliver Noll, Helmut Gehrke, Christian Luebbecke, Baerbel Kolbe
-
Publication number: 20130217945Abstract: Processes and systems for treating an aromatic feed comprising an aromatic component and nitrogen-containing impurities, as well as processes and systems for preparing a reaction product of an aromatic component from an aromatic feed comprising the aromatic component and nitrogen-containing impurities, are provided herein. In an embodiment, a process for treating an aromatic feed comprising an aromatic component and nitrogen-containing impurities includes adsorbing a portion of the nitrogen-containing impurities from the aromatic feed to produce a treated aromatic feed comprising the aromatic component and residual nitrogen-containing impurities. The treated aromatic feed and water are mixed to produce a hydrated aromatic feed.Type: ApplicationFiled: February 22, 2012Publication date: August 22, 2013Applicant: UOP LLCInventors: Chad A. Williams, Wugeng Liang, Patrick Jerome Bullen
-
Patent number: 8507745Abstract: Processes and systems for treating an aromatic feed comprising an aromatic component and nitrogen-containing impurities, as well as processes and systems for preparing a reaction product of an aromatic component from an aromatic feed comprising the aromatic component and nitrogen-containing impurities, are provided herein. In an embodiment, a process for treating an aromatic feed comprising an aromatic component and nitrogen-containing impurities includes adsorbing a portion of the nitrogen-containing impurities from the aromatic feed to produce a treated aromatic feed comprising the aromatic component and residual nitrogen-containing impurities. The treated aromatic feed and water are mixed to produce a hydrated aromatic feed.Type: GrantFiled: February 22, 2012Date of Patent: August 13, 2013Assignee: UOP LLCInventors: Chad A. Williams, Wugeng Liang, Patrick Jerome Bullen
-
Patent number: 8471087Abstract: Disclosed is a process for separating an acidic contaminant and light hydrocarbon of a light hydrocarbon feed having a large contaminating acidic contaminant content. Among other features, the process uses a combination of distillation and membrane separation arranged in a unique way to yield a high-purity light hydrocarbon product and a high-purity acidic contaminant product.Type: GrantFiled: May 17, 2010Date of Patent: June 25, 2013Assignee: Shell Oil CompanyInventors: Zaida Diaz, Shu Shu, Paul Jason Williams
-
Patent number: 8395002Abstract: A process for recovering benzene, the process including: feeding hydrogen and a hydrocarbon fraction comprising benzene, components lighter than benzene, components heavier than benzene, and diolefins to a catalytic distillation reactor system comprising at least one reaction zone comprising a hydrogenation catalyst; concurrently in the catalytic distillation reactor system: contacting the diolefins and hydrogen in the presence of the hydrogenation catalyst to selectively hydrogenate at least a portion of the diolefins; and fractionating the hydrocarbon fraction to form a fraction comprising benzene and other C6 hydrocarbons, and a heavies fraction comprising C7+ hydrocarbons; recovering the heavies fraction from the first catalytic distillation reactor system as a bottoms fraction; and withdrawing the fraction comprising benzene and other C6 hydrocarbons from the catalytic distillation reactor system as a benzene concentrate fraction.Type: GrantFiled: March 9, 2010Date of Patent: March 12, 2013Assignee: Catalytic Distillation TechnologiesInventors: Martinus J. Almering, Purvis K. Ho, Mitchell E. Loescher, Montri Vichailak
-
Patent number: 8362313Abstract: In various embodiments, the present disclosure describes processes and systems for recovery of styrene from a styrene-rich feedstock. The processes and systems maintain performance of an extractive solvent used in the styrene recovery. In general, the processes include introducing a styrene-rich feedstock to an extractive distillation column, removing a styrene-rich stream from the extractive distillation column, introducing the styrene-rich stream to a solvent recovery column, removing a styrene-lean stream from the solvent recovery column, separating and treating a portion of the styrene-lean stream to form a treated extractive solvent and recycling the treated extractive solvent. In some embodiments, the treating process also includes steam stripping. Styrene-recovery systems including an extractive distillation column, a solvent recovery column, a solvent treatment apparatus having at least one equilibrium stage and a continuous circulation loop connecting these components are also disclosed herein.Type: GrantFiled: February 1, 2010Date of Patent: January 29, 2013Assignee: GTC Technology, LPInventors: Zhong Yi Ding, Weihua Jin, Andrei Cimpeanu, Amy Sealey
-
Patent number: 8193405Abstract: Disclosed is a process for integrating a butene dimerization process with a metathesis process to remove isobutene from the feed stream to the metathesis reactor. The isobutene is preferentially dimerized in the dimerization process to leave n-butenes for metathesis with ethylene. An upstream selective hydrogenation process also isomerizes 1-butenes to 2-butenes which is the preferred butene reagent in the metathesis process. A common fractionator column for the dimerization and hydrogenation processes is also described.Type: GrantFiled: September 2, 2009Date of Patent: June 5, 2012Assignee: UOP LLCInventors: Steven L. Krupa, Jill M. Meister
-
Patent number: 8178061Abstract: Processes and systems are disclosed that relate to the removal of impurities and separation the light olefins from an MTO product vapor stream. Specifically, the processes and systems relate to recovery of light olefins during regeneration of an adsorber in an oxygenate removal unit. Processes and systems for recovering light olefins during regeneration of an adsorber in an oxygenate removal unit can include recycling residual effluent stream to an upstream operation unit upstream of the oxygenate removal unit. Processes and systems for recovering light olefins during regeneration of an adsorber in an oxygenate removal unit can also include recycling residual effluent gas produced by depressurizing residual effluent in the first adsorber, as well as preferably venting an effluent gas from the first adsorber to a compressor upstream of the oxygenate removal unit.Type: GrantFiled: January 21, 2011Date of Patent: May 15, 2012Assignee: UOP LLCInventor: Jason T. Corradi
-
Patent number: 8124824Abstract: A system and method for the use of super critical CO2 as a carrying or suspension agent for transport of extracted or processed hydrocarbons. The super critical state CO2 is then co-mingled with the extracted or processed hydrocarbons and transported in the co-mingled state to a delivery point. At the delivery point, the super critical state CO2 is allowed to return to its gaseous state allowing the separation of the hydrocarbons therefrom. The hydrocarbons may be processed and the gaseous CO2 returned to its super critical state for future transport, use in EOR, or geologically sequestered.Type: GrantFiled: April 17, 2009Date of Patent: February 28, 2012Inventor: Michael J. Hirl
-
Patent number: 7994378Abstract: This invention presents a process of butadiene-1,3 extraction. The process consists of the procedure of 1st extractive fractionation, 2nd extractive fractionation, distillation and alkyne fractionation. This invention can improve the yield and capacity of butadiene extraction unit by adding an alkyne fractionator to the existing butadiene extraction unit and appropriately adjusting the process condition of 1st and 2nd extractive fractionators. This invention can decrease the energy and material consumption per unit of butadiene-1,3, which greatly improved the economic profit. The investment on various scales of butadiene extraction units for adding alkyne fractionator is almost same. Further more, the profit is in direct proportion with the scale of a plant and output is in several to some dozens of folds to investment. After the implementation of this invention, the discharge of vinyl acetylene offgas can be reduced by around 3400 tons per year, which mitigate the pollution on environment and save energy.Type: GrantFiled: March 4, 2009Date of Patent: August 9, 2011Inventors: Minghua Wang, Duoshan Zhao, Meng Wang
-
Patent number: 7956231Abstract: To decrease capital costs of crack gas treatment of the olefin plant, a method for separation of olefins reduces the units for catalytic hydrogenation. In the method, olefins having three carbon atoms are separated from olefins having four carbon atoms. Crude gas is precompressed (1), precooled and dried (2), and passed into a C3/C4 separation stage (6) comprising a C4 absorber, operating at full crude gas pressure, and a depropanizer, operated at a pressure of 8 to 12 bar. In the C3/C4 separation stage, the olefins are separated into a fraction having at most three carbon atoms (C3?), and a fraction having at least four carbon atoms (C4+). The fraction having at most three carbon atoms is completely compressed (1) and passed to the catalytic hydrogenation (4); the fraction having at least four carbon atoms is passed out for further processing (7).Type: GrantFiled: March 6, 2007Date of Patent: June 7, 2011Assignee: Linde AktiengesellschaftInventor: Tuat Pham Duc
-
Patent number: 7923591Abstract: Method and device for manufacturing at least one low olefin from an oxygenate-containing first reaction mixture (11) through conversion by a catalyst (20) to an olefin and paraffin-containing second reaction mixture (21) where the second reaction mixture (21) is flowed through a separation system (300), in which one at least one low olefin-containing first product stream (31) and at least one paraffin-enriched fraction (321) is extracted and where the remaining product stream (322) is at least partially recirculated to the catalyst (20).Type: GrantFiled: October 27, 2005Date of Patent: April 12, 2011Assignee: Lurgi AGInventors: Gerhard Birke, Harald Koempel, Waldemar Liebner, Hermann Bach
-
Patent number: 7897827Abstract: Processes and systems are disclosed that relate to the removal of impurities and separation the light olefins from an MTO product vapor stream. Specifically, the processes and systems relate to recovery of light olefins during regeneration of an adsorber in an oxygenate removal unit. Processes and systems for recovering light olefins during regeneration of an adsorber in an oxygenate removal unit can include recycling residual effluent stream to an upstream operation unit upstream of the oxygenate removal unit. Processes and systems for recovering light olefins during regeneration of an adsorber in an oxygenate removal unit can also include recycling residual effluent gas produced by depressurizing residual effluent in the first adsorber, as well as preferably venting an effluent gas from the first adsorber to a compressor upstream of the oxygenate removal unit.Type: GrantFiled: December 11, 2007Date of Patent: March 1, 2011Assignee: UOP LLCInventor: Jason T. Corradi
-
Patent number: 7709693Abstract: A method for optimizing the production of nitration grade toluene from a solvent extraction process that produces an aromatic rich extract and a saturate rich raffinate, comprising adding an effective amount of the raffinate back to the extract.Type: GrantFiled: October 1, 2007Date of Patent: May 4, 2010Assignee: Equistar Chemicals, LPInventors: Benjamin F. Gaeth, Reynaldo E. Vera
-
Patent number: 7687677Abstract: A processing scheme and arrangement for enhanced olefin production involves recovering thermal energy from a reactor effluent stream resulting from the dehydrogenation of a dehydrogenatable hydrocarbon. The process involves contacting the reactor effluent stream with a circulating fluid stream in a first contact cooling zone to produce a product stream and to form a heated circulating fluid stream. Thermal energy is recovered from the heated circulating fluid stream via indirect heat exchange with a first process stream in a first heat exchange zone to form a cooled circulating fluid stream. The cooled circulating fluid stream can be subsequently cooled and at least a first portion thereof returned to the first contact cooling zone.Type: GrantFiled: September 29, 2006Date of Patent: March 30, 2010Assignee: UOP LLCInventors: Dennis E. O'Brien, Joseph E. Zimmermann, Douglas G. Stewart
-
Patent number: 7556717Abstract: A process for fractionating a starting mixture of two or more components by extractive distillation using a selective solvent in a dividing wall column aligned in the longitudinal direction of the column and extending to the upper end of the column and dividing the column interior into a first region, a second region, and a lower combined column region. The starting mixture is fed into the first region, a first top stream is taken off from the first region, and a second top stream is taken off from the second region, each stream having a prescribed specification. The selective solvent is introduced in the upper part of the first region and/or in the upper part of the second region, and solvent flow into the first region and/or solvent flow into the second region are set so that each of the prescribed specifications for the top streams are met.Type: GrantFiled: December 11, 2003Date of Patent: July 7, 2009Assignee: BASF AktiengesellschaftInventor: Bernd Heida
-
Publication number: 20090069618Abstract: In an isomerization process where the isomerization effluent (114) is fractionated in a deisohexanizer (116) to provide a lower boiling fraction (122) containing dimethylbutanes, a higher boiling fraction containing methylpentanes and a bottoms stream (120) containing normal hexane and heavies, the bottoms stream is contacted with a selective permeation membrane (124) to provide a normal hexane-containing permeate (128) suitable for recycle to the isomerization. The energy consumption of the deisohexanizer (116) can be reduced without adversely affecting the octane rating of the overhead (122).Type: ApplicationFiled: September 7, 2007Publication date: March 12, 2009Inventor: Lynn H. Rice
-
Publication number: 20080161627Abstract: Aromatic by-products are sorbed from mono-olefin-containing feedstocks of olefins having from about 6 to 22 carbon atoms per molecule that contain aromatic by-products having from 7 to 22 carbon atoms per molecule. A benzene-containing regenerant displaces and desorbs the aromatic by-products from the sorbent and a regeneration effluent is provided. The regeneration effluent is treated in a regeneration effluent distillation system to provide a benzene-rich stream and an aromatic by-products-containing stream. The latter is subjected to benzene-forming conditions and recycled to the regeneration effluent distillation system where benzene is recovered.Type: ApplicationFiled: March 12, 2008Publication date: July 3, 2008Inventors: Bryan K Glover, Andrea G. Bozzano, Antoine Negiz
-
Patent number: 7348466Abstract: In a method for the solvent extraction of butadiene from a mixture of hydrocarbons having four carbon atoms per molecule, which method inherently produces tars, the extraction process is operated with a tar loading level, relative to the solvent employed, of no more than about 1.6 wt. %.Type: GrantFiled: April 13, 2005Date of Patent: March 25, 2008Assignee: Equistar Chemicals, LPInventors: Joseph P. Bridges, Solon B. Williams, Byron B. Unterbrink
-
Patent number: 7094937Abstract: Disclosed are compositions comprising C26H30 hexamantane, referred to herein as peri-condensed hexamantane, fully condensed hexamantane, and cyclohexamantane. These enriched cyclohexamantane compositions comprise at least 5 percent by weight cyclohexamantane based upon the total weight of the composition.Type: GrantFiled: December 12, 2001Date of Patent: August 22, 2006Assignee: Chevron U.S.A. Inc.Inventors: Jeremy E. Dahl, Robert M. Carlson
-
Patent number: 6960279Abstract: Disclosed is the observation that 7-aryl-quinone methides and 4-tert-butylcatechol, when used in combination in a vinyl aromatic monomer to inhibit polymerization,do not inhibit polymerization to the same extend as each would if used separately. Stated another way, a phenomenon has been observed that when these two compounds are used together, they can, to a large extent, render each other unable to inhibit polymerization in a vinyl aromatic monomer. Also disclosed are methods of preventing adverse results of this interaction when undesired and a method of using this interaction to prepare a reactive vinyl aromatic monomer having a concentration of 4-tert-butylcatechol that would otherwise inhibit polymerization. The invention is disclosed to be useful with the production and storage of any vinyl aromatic monomer and is disclosed to be particularly useful with the production and storage of styrene monomer.Type: GrantFiled: May 6, 2002Date of Patent: November 1, 2005Assignee: Fina Technology, Inc.Inventor: James T. Merrill
-
Patent number: 6838587Abstract: This invention is directed to a method of removing acetaldehyde, CO2 and/or water from an ethylene and/or propylene containing stream. In this invention, acetaldehyde and C4+ olefins are substantially removed from the ethylene and/or propylene containing stream. The stream is then acid gas treated. The ethylene and/or propylene streams which are separated and recovered according to this invention can be further processed, for example, to make polymers such as polyethylene and polypropylene.Type: GrantFiled: April 19, 2002Date of Patent: January 4, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventors: James R. Lattner, David R. Lumgair, Jr.
-
Publication number: 20040019247Abstract: Styrene is recovered continuously from a styrene-containing mixture by distillation of the mixture in a cascade of n distillation columns, whereType: ApplicationFiled: September 5, 2003Publication date: January 29, 2004Applicant: BASF AktiengesellschaftInventors: Konrad Mitulla, Heinz Friedrich Sutoris
-
Patent number: 6664433Abstract: This invention provides a process for purifying to a high degree of purity aromatic hydrocarbons containing impurities which are difficult to separate by distillation such as sulfur compounds and nitrogen compounds. The process of this invention for purifying aromatic hydrocarbons comprises treating crude aromatic hydrocarbons with a formaldehyde or with a formaldehyde and a phenol in the presence of an acid catalyst to form oligomers, distilling or evaporating the reaction mixture thereby separating the unreacted aromatic hydrocarbons from the oligomers, and crystallizing or washing with an organic solvent the separated aromatic hydrocarbons. In case the target hydrocarbon is naphthalene, it is possible to prepare naphthalene which has a purity of 99.9999 wt % or more, emits little odor, and can be readily flavored by perfumes. Naphthalene of this quality is used to prepare an insecticide of excellent fragrance.Type: GrantFiled: October 15, 2001Date of Patent: December 16, 2003Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Toshihide Senzaki, Takahiro Imamura, Takeshi Takayama, Katsuhide Noguchi
-
Publication number: 20030199721Abstract: Disclosed is a method of removing dimethyl ether from an ethylene and/or propylene containing stream. Dimethyl ether is removed at a low pressure, preferably in a distillation column. The low pressure separation has the benefit of providing a relatively low temperature separation, while allowing for recovery of a highly concentrated ethylene and/or propylene stream.Type: ApplicationFiled: April 18, 2002Publication date: October 23, 2003Inventors: Zhong Y. Ding, James R. Lattner, Cor F. Van Egmond, Jeffrey L. Brinen, Michael Peter Nicoletti
-
Publication number: 20030199722Abstract: This invention is directed to a method of removing acetaldehyde, CO2 and/or water from an ethylene and/or propylene containing stream. In this invention, acetaldehyde and C4+ olefins are substantially removed from the ethylene and/or propylene containing stream. The stream is then acid gas treated. The ethylene and/or propylene streams which are separated and recovered according to this invention can be further processed, for example, to make polymers such as polyethylene and polypropylene.Type: ApplicationFiled: April 19, 2002Publication date: October 23, 2003Inventors: James R. Lattner, David R. Lumgair
-
Patent number: 6565742Abstract: An improved process for the recovery of aromatic compounds from a mixture containing aromatic and non-aromatic compounds and method for retrofitting existing equipment for the same is provided. The improved process comprises the steps of recovering aromatic compounds via parallel operation of a hybrid extractive distillation/liquid-liquid extractor operation and variations thereof. Methods of quickly and economically retrofitting existing recovery process equipment for use with the improved aromatic recovery process are also disclosed.Type: GrantFiled: December 30, 1997Date of Patent: May 20, 2003Assignee: GTC Technology Inc.Inventors: Joseph C. Gentry, Fu-Ming Lee
-
Publication number: 20030069459Abstract: The present invention relates to an integrated process for the production of high purity 2,6-dimethylnaphthalene starting from hydrocarbon mixtures containing naphthalene and/or isomers of methylnaphthalene and/or isomers of dimethylnaphthalene and/or isomers of polymethylnaphthalene, and from an alkylating agent, preferably methanol, reacted in the presence of a methylated benzene solvent or mixture of various methylated benzene solvents, preferably selected from toluene, xylene and trimethylbenzene, and a catalyst consisting of ZSM-12 zeolite and an inorganic ligand.Type: ApplicationFiled: June 6, 2002Publication date: April 10, 2003Applicant: ENI S.p.A.Inventors: Gianni Girotti, Giuseppe Terzoni, Oscar Cappellazzo, Renzo Bignazzi, Giannino Pazzuconi
-
Patent number: 6545192Abstract: A process for separating and isolating olefins from saturated hydrocarbons, preferably in a Fischer Tropsch stream, by adducting the olefins with a linear polyaromatic compound and separating the adducts from the remainder, which comprises saturated hydrocarbons.Type: GrantFiled: May 11, 1999Date of Patent: April 8, 2003Assignee: Shell Oil CompanyInventors: Lynn Henry Slaugh, Laurent Alain Fenouil, Howard Lam-Ho Fong
-
Patent number: 6483000Abstract: The invention relates to a process for the recovery as a feedstock of an alpha-olefin from a mixture containing mainly hydrocarbon compounds, such as is obtained by Fischer-Tropsch-synthesis after an at least crude separation of components boiling higher and/or lower than the alpha-olefin, wherein tertiary olefins of the mixture, after superstoichiometrical addition of a low alcohol, are subjected to catalytic etherification and a stream derived by etherification is fed jointly with the alpha-olefin and the ethers produced and other high boiling reaction products to a distillative separation of components boiling higher than the olefin.Type: GrantFiled: May 3, 2001Date of Patent: November 19, 2002Assignee: Sasol Technology (Pty) LTDInventor: Hans Becker
-
Patent number: 6395953Abstract: Processes for producing a purified conjugated diene comprise feeding a petroleum fraction containing the conjugated diene to an extractive distillation column, feeding an extraction solvent to the extractive distillation column, and extractive-distilling the conjugated diene from the petroleum fraction containing the conjugated diene in the extractive distillation column. The extraction solvent comprises an amide compound, and a heterocyclic aldehyde, aromatic nitro compound or aromatic aldehyde is contained in the extraction solvent within a range of 0.01 to 10 wt. % based on the weight of the extractive solvent. An oxygen concentration in a gas phase of a distillate discharged from the top of the extraction distillation column is controlled to 10 ppm or lower.Type: GrantFiled: August 24, 1999Date of Patent: May 28, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Takaki Koga, Nobumasa Shimomura, Masanobu Kanauchi
-
Patent number: 6348136Abstract: The present invention is directed to an apparatus and method for the distillation of a readily polymerizable vinyl aromatic compound employing a polymerization inhibitor. The vinyl aromatic compound is subjected to distillation in at least one fractionation column having at least one reboiler for maintaining the bottoms of said column at a proper temperature. The reboiler includes a heating section and a vapor phase section. The bottoms fraction from the fractionation column is cycled to the reboiler and subjected to heat to vaporize at least a portion of the bottoms fraction to form a vapor phase in the vapor section, A slip stream of the bottoms fraction is introduced to the vapor phase section of the reboiler. The slipstream contains polymerization inhibitor that had been added to the process at the fractionation column. The invention reduces fouling at the reboilers. The slipstream is optionally introduced to the reboiler using one or more spray nozzles.Type: GrantFiled: February 29, 2000Date of Patent: February 19, 2002Assignee: Fina Technology, Inc.Inventors: Marcus E. Ledoux, Kelli E. Prince, Adrian M. Jacobsen, Larry P. Braud, Jr.
-
Patent number: 5972172Abstract: 1,2,4-Trimethylbenzene is difficult to separate from 1,2,3-trimethylbenzene by conventional distillation or rectification because of the proximity of their boiling points. 1,2,4-trimethylbenzene can be readily separated from 1,2,3-trimethylbenzene by extractive distillation. Effective agents are 3-nitrotoluene, m-cresol and sulfolane.Type: GrantFiled: December 23, 1996Date of Patent: October 26, 1999Inventor: Lloyd Berg
-
Patent number: 5942655Abstract: A process for the removal of trace quantities of polynuclear aromatic compounds from the vapor effluent of a hydrocarbon dehydrogenation zone containing normally gaseous olefinic hydrocarbons, trace mononuclear aromatic compounds and trace polynuclear aromatic compounds by contacting the vapor effluent of a hydrocarbon dehydrogenation zone with a lean liquid absorption stream comprising at least one alkylated mononuclear aromatic compound to absorb at least a portion of the trace mononuclear aromatic compounds and the trace polynuclear aromatic compounds to produce a rich liquid absorption stream and a gaseous olefin-containing hydrocarbon stream having a reduced concentration of mononuclear aromatic compounds and polynuclear aromatic compounds. The rich liquid absorption stream is separated to produce a stream rich in mononuclear aromatic compounds, a stream rich in alkylated mononuclear aromatic compounds and a stream comprising polynuclear aromatic compounds.Type: GrantFiled: September 9, 1997Date of Patent: August 24, 1999Assignee: UOP LLCInventor: Bryan K. Glover
-
Patent number: 5877385Abstract: Disclosed is a process for recovering styrene from a feedstock containing at least styrene, ethylbenzene, and one or more aromatic or non-aromatic hydrocarbon compounds which includes separating said feedstock into a first stream relatively more concentrated in styrene than said feedstock and a second stream relatively more concentrated in ethylbenzene than said feedstock, recovering styrene from said first stream to produce a styrene product stream, dehydrogenating the ethylbenzene of said second stream to produce additional styrene, and recovering said additional styrene. The feedstock may be separated into said first and second streams by a process selected from the class consisting of extractive distillation, azeotropic distillation, distillation, liquid-liquid extraction, chemical complex formation, membrane separation, and combinations thereof, and the additional styrene may be recovered by recycling it into said feedstock.Type: GrantFiled: September 26, 1996Date of Patent: March 2, 1999Assignee: HFM International, Inc.Inventors: Fu-Ming Lee, Stephen G. Norwood, Joseph C. Gentry
-
Patent number: 5849982Abstract: An extractive distillation process for separating at least one substituted unsaturated aromatic from a pyrolysis gasoline mixture, containing said aromatic and at least one close-boiling aromatic or non-aromatic hydrocarbon, employing a two part extractive solvent, the first part selected from propylene carbonate, sulfolane (tetramethylene sulfone), methyl carbitol, 1-methyl-2-pyrrolidinone, 2-pyrrolidinone and mixtures thereof, and the second portion consisting of water.Type: GrantFiled: October 29, 1997Date of Patent: December 15, 1998Assignee: HFM International, Inc.Inventors: Fu-Ming Lee, Joseph C. Gentry, Randi Wright Wytcherley
-
Patent number: 5763714Abstract: A mixed aromatic stream is hydrotreated to remove olefins and fractionated to separate C.sub.9 + heavies in a distillation column reactor and the C.sub.8 and lighter material is fed to a selective adsorption unit where the para-xylene is removed. The para-xylene depleted raffinate therefrom may be subjected to isomerization to form additional para-xylene. The effluent from the isomerization can be fed to the distillation column reactor for hydrogenation of any olefins formed during the isomerization or directly to the adsorption unit.Type: GrantFiled: January 8, 1997Date of Patent: June 9, 1998Assignee: Catalytic Distillation TechnologiesInventors: Thomas P. Hickey, Dennis Hearn, Hugh M. Putman
-
Patent number: 5723026Abstract: The production of high purity benzene and high purity toluene is obtained by utilizing the initial gas separating column for the treatment of the aromatic containing starting material as a separating column for separating a benzene rich from a toluene rich component. The benzene rich component is subject directly to distillation while the toluene is subject to predistillation to separate high boiling components and only then to extractive distillation is distilled to separate the high purity benzene from the high purity toluene.Type: GrantFiled: August 18, 1995Date of Patent: March 3, 1998Assignee: Krupp Koppers GmbHInventors: Martin Leisse, Hans-Jurgen Vollmer, Uwe Ranke
-
Patent number: 5672804Abstract: A process for the removal of trace quantities of polynuclear aromatic compounds from the vapor effluent of a hydrocarbon dehydrogenation zone containing normally gaseous olefinic hydrocarbons, trace mononuclear aromatic compounds and trace polynuclear aromatic compounds by cooling the vapor effluent to condense at least a portion thereof, up to five weight percent, by introducing the resulting cooled stream into a vapor-liquid separator to produce a vapor stream containing normally gaseous olefinic hydrocarbons and having a reduced concentration of polynuclear aromatic compounds and a liquid stream containing mononuclear and polynuclear aromatic compounds and by recovering the vapor stream comprising normally gaseous olefinic hydrocarbons having a reduced concentration of polynuclear aromatic compounds.Type: GrantFiled: July 17, 1995Date of Patent: September 30, 1997Assignee: UOPInventor: Bryan K. Glover
-
Patent number: 5663337Abstract: The present invention relates to benzoquinazoline thymidylate synthase inhibitors, processes for preparing them and pharmaceutical formulations containing them.Type: GrantFiled: May 25, 1995Date of Patent: September 2, 1997Assignee: Glaxo Wellcome Inc.Inventors: William Pendergast, Scott Howard Dickerson
-
Patent number: 5630914Abstract: A method for decontaminating a liquid of a contaminant having a vapor pressure which is higher than the vapor pressure of the liquid. A contaminated liquid is directed through an inclined conduit. A gas is directed into the inclined conduit, whereby the gas contacts the liquid and transports the contaminant, which has volatilized in the inclined conduit, out of the inclined conduit, thereby decontaminating the liquid. The liquid is discharged from the inclined conduit.Type: GrantFiled: June 7, 1995Date of Patent: May 20, 1997Assignee: Pharm-Eco Laboratories, Inc.Inventors: Yesh P. Sachdeva, Richard L. Gabriel