Abstract: An adsorptive separation method capable of effectively separating the desired component from a mixture containing the same at a high purity and a high recovery ratio, and easily coping with scale-up of the apparatus is disclosed.
Abstract: Normal paraffins are separated from a gas oil-containing hydrocarbon vapor feed stream having 16 to 25 carbon atoms per molecule in a constant pressure process employing a molecular sieve adsorbent and n-hexane for purging and for dilution of gas oil-containing feedstock. Cocurrent purge effluent is used to provide a source of such n-hexane diluent, thereby reducing the equipment size and energy consumption for processing of the n-hexane purge recycle stream and increasing adsorbent utilization or the efficiency of the adsorption process.
Abstract: Normal paraffins are separated from a gas oil-containing hydrocarbon vapor feed stream having 16 to 25 carbon atoms per molecule in a constant pressure process employing a molecular sieve adsorbent and n-hexane for purging and for dilution of gas oil-containing feedstocks. Countercurrent purge effluent is used to provide a source of such n-hexane diluent, thereby effecting a savings in the amount of energy necessary to process the purge recycle stream and the size of the equipment used therefor.
Abstract: The invention concerns a process for the removal of catalyst residues from a gas by contacting the gas with particulate mineral oxides. The process of the invention may be applied to the removal of coordination catalyst residues from .alpha.-olefins recycled from a polymerization reactor. The process is particularly useful in the removal of alkylaluminium halides and hydrogen halides, such as diethylaluminium chloride and hydrogen chloride, from .alpha.-olefins such as propylene. The process offers the advantages of being able to be operated under anhydrous conditions, and combining high efficiency in the removal of low levels of catalyst residues with a high capacity for the catalyst residues.
Type:
Grant
Filed:
July 22, 1980
Date of Patent:
July 6, 1982
Assignees:
ICI Australia Limited, Commonwealth Scientific and Industrial Research Organization
Abstract: A process for purifying isoprene produced by catalytic decomposition of dimethyldioxane from carbonyl compounds and cyclopentadiene which involves passing isoprene at a temperature of 40.degree. to 70.degree. C. through a bed of a solid product such as an anion exchange resin or alkali (the latter may be used with or without an inert carrier), followed by subjecting the isoprene to close fractionation performed with at least 50 theoretical plates and at a reflux ratio of at least 3. The process of the present invention enables practically complete purification of isoprene from carbonyl compounds and cyclopentadiene. The purified isoprene, when used as a monomer in the production of stereospecific isoprene rubber, results in high-quality products; and reduces by a factor of 2-3 the Ziegler catalyst consumption in the isoprene rubber synthesis.
Type:
Grant
Filed:
November 21, 1977
Date of Patent:
November 4, 1980
Inventors:
Alexandr G. Liakumovich, Boris I. Pantukh, Tatyana M. Lesteva
Abstract: A hydrocarbon mixture is fed to a system of adsorbents in a plug flow so as to form at least one displacement boundary in the system to accumulate the composition in the vicinity of the boundary. The process is simple to operate and suitable for separation of a hydrocarbon mixture containing components with similar physical and chemical properties such as a mixture of hydrocarbon isomers.