Abstract: A method for recombining and then solidifying groups of soil particles by utilizing changes in the status and properties of soil particles which comprises a combination (in an adhering state) between soil particles and groups polymers (humin) in an aqueous solution (solvent). By using specified solvents, the preliminary treatment of separating soil particles and polymers is initiated. Secondarily, each structure of groups of soil particles is observed microscopically as a metal complex, and the combining method is accomplished by utilizing substitution based on various reactions (i.e. SN, SE, and SEAr type reactions) along with electron transfer in a solvent made of specified solutes. The substitution includes the rock forming function through the substitution of the hydrogen atom within the hydroxyl group of clay minerals as molecular components and the dehydration and dissociation function resulted from the binding structure of oxygen molecule O−2 and Al+3 as components of aluminum oxide.

Abstract: A process for vitrifying waste material containing environmentally hazardous metals or metal compounds includes drying a waste material using a flash dryer, where the drying is carried out at a temperature low enough to prevent volatilization of hazardous metals and metal compounds contained in the waste material. Preferably, more than about 95% of the water is removed form the waste material. The dried waste material is transferred from the flash dryer into a melting vessel, melted, collected and cooled to form a vitrified mass of waste material. Gases produced during the process of the invention are filtered, treated, and released into the atmosphere.

Abstract: Method and apparatus for containing, transporting, and storing or disposing of radioactive machinery, including decommissioned nuclear reactor pressure vessels. An improved, economically-produced container is provided which allows easier handling and packaging of machinery within plants where the machinery has been installed, and which provides improved shock absorption and attenuation characteristics, especially when packaging is complete. A reactor pressure vessel or similar item is disconnected from the remainder of the plant and external fittings are trimmed as close to flush with item's exterior as practicable. A storage and containment canister, optionally cut into at least two sections to ease handling and packaging, is placed nearby. The pressure vessel head or any other low-radioactive items are removed, and insulation and other items removed from the outside of the item are placed inside the item's body.

Abstract: The present invention relates to apparatuses for processing homogeneous/heterogeneous radioactive wastes comprising ion-exchange reisns. A cooled discharge unit comprises a discharge pipe, a cooling jacket having a U-shaped form in cross section, a collector for feeding a coolant into the jacket, a discharge gate comprising a pipe, on one end of which a cone-shaped tip is positioned, on the other end a lid with an aperture. A cooled induction melter comprises a housing, side walls and bottom of which are made of metal pipes disposed with a gap therebetween and combined by a collector for supplying and discharging the coolant, an inductor positioned adaptable for displacement along the longitudinal axis of the melter and concentrically encompassing the side walls of the housing, the gaps between the pipes of which ensure transparency of the housing for an electromagnetic field of the inductor.

Abstract: Hydrocarbon contaminants in drill cuttings generated in an oil drilling operation are removed by mixing the drill cuttings with an agglomerant to produce a pre-treatment mixture; heating to vaporize the hydrocarbon contaminants under a condition in which vapor entrainable particles of the drill cuttings are agglomerated by the agglomerant, and caking of drill cuttings is inhibited; drill cuttings having a reduced content of the contaminant are removed, and vaporized hydrocarbons having a reduced content of vapor entrainable particles are recovered. In this way, the particulate content of vapors escaping from the drill cuttings is reduced.

Abstract: The invention provides a method for treating drill cuttings, preferably marine cuttings, preferably in situ, so that the cuttings can be discharged into the environment, preferably back into marine waters without causing oxygen depletion of marine sediment. In a preferred embodiment, the treatment emulsifies and then encapsulates free hydrocarbons in the marine cuttings.

Abstract: A detoxifying agent for use in disposal of noxious wastes that is conducted by solidifying them with cement, consisting essentially of an aqueous solution which comprises as main components (a) small-sized metal cations whose 6-coordination ionic radii are less than 100 pm, (b) medium-sized metal cations whose 6-coordination ionic radii are between 100 pm and 140 pm, and (c) large-sized metal cations whose 6-coordination ionic radii are in excess of 140 pm. This detoxifying agent can provide cement-solidified materials having high strength, substantially free from exudation of toxic substances such as heavy metals, PCBs and dioxins.

Abstract: A process of treating solid material flammable waste is provided in which dry fire retardant admixtures are used to intermix with the material waste so as to lower the burn rate and flammability characteristics of the material waste. The process, in turn, allows the waste to be accepted by an approved waste handling facility.

Abstract: The Advanced Vitrification System (AVS) Melting Process is a process for vitrification of waste in a disposable canister. In the process, waste is dropped into the disposable canister from the top. While the waste is being dropped into the disposable canister, radiant energy is added to the space above the waste in the canister, such that the temperature of the gaseous atmosphere above the waste is higher than the melting point of the waste. Since only the space above the waste in the canister is heated, the temperature of the melt decreases with increasing depth of the waste in the canister. The decreasing temperature permits a small surface melt volume to be maintained and solidified product to form with increasing depth. The process continues until the disposable canister is filled, then all heating is stopped and the disposable canister allowed to cool to ambient temperature.

Abstract: Glass produced on basis of a raw material in form of a mixture of mainly mineral-containing components comprising sludge from e.g. purification plants and waste products from the industry, and having a determined chemical composition adjusted on basis of knowledge of the chemical composition of the mineral-containing components forming part of the glass. The glass is produced from the raw material which after mineralization is pressed into briquettes that are hardened and subsequently melted in e.g. a blast furnace under oxygen supply, and where the melt is quenched and dried. Large amounts of waste products and waste substances that are normally deposited either treated or untreated can be reused and utilized at production of the glass.

Abstract: A fill material mix that includes coal processing wastes, at least one coal combustion by-product and a neutralizing/stabilizing by-product that may be the same as or different than the coal combustion by-product is mixed with water to form a mortar. The mortar can be placed in abandoned mines and other appropriate underground or surface locations as a fill material that is environmentally more benign that the individual components of the mix. The mortar cures rapidly to provide a surface that can support heavy equipment.

Abstract: The present invention relates to a vitrification process for a pulverulent material and an apparatus for implementing said process. The process consists in introducing the pulverulent material into the fusion area of a furnace via injection means, where it is melted by means of at least one plasma torch to obtain a melt, and where the melt is removed from the furnace via a casting zone, the material being introduced laterally into the fusion zone in a direction comprising a horizontal component, and the melt being removed from the furnace by overflowing via the said casting zone, more or less along said horizontal component and away from the means for injecting the material into the furnace, in relation to the fusion zone.

Abstract: An economical and efficient method for forming a waste containing monolith which meets applicable waste disposal laws, rules and regulations. Removable walls are attached to at least one side of the monolith, thereby forming an interior volume defined by the removable walls and at least one side of the monolith. Waste is placed within the interior volume, whereupon it is submerged in a flowable, curable, monolith forming material (typically concrete) by filling the interior volume with a monolith forming material, and allowing the monolith forming material to cure to a solidified state, thereby forming an expanded monolith integral with the existing monolith. The walls are then removed, thereby leaving the waste encased within said expanded monolith and allowing the removable walls to be reused for further expansion of the monolith.

Abstract: A canister containing spent fuel assemblies is contained in a body of a transportation cask. A top opening of a vessel body of the canister is closed by a lid welded to the vessel body. A ring-shaped elastic tube is provided between the inner surface of the upper end portion of the body and the outer surface of the upper end portion of the vessel body. The tube seals the gap between these surfaces to prevent a fluid from getting into the gap between the surfaces through the top opening of the body. An inspection space for the insertion of a tester for detecting the welding state of the lid is defined between the inner surface of the upper end portion of the body and the outer surface of the upper end portion of the vessel body.

Abstract: A radioactive substance decontamination method and apparatus which decontaminate the metal member contaminated by radioactive substance in a shorter period of time.

Abstract: A new method for combining elemental iron and other metals to form an inexpensive ceramic to stabilize arsenic, alkaline red mud wastes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast.

Abstract: The present invention relates to a plasma process and appropriate equipment well adapted for eliminating toxic or hazardous organic compounds, such as petroleum, oils, pesticides, herbicides and various hydrocarbons, orginitated from petrochemical spills or inappropriate discard/handling, from different materials, such assail, sludges; the process and appropriate equipment can also be used to remove the hydrocarbons contained in the sludge formed at the bottom of petroleum storage tanks. The plasma process, with the appropriate equipment, object of the invention, has the following advantages as compared to the other processes used to treat similar materials: removal of the contaminants to less than 0.1% in weight of the soil or sludge; continuous operation; possibility of recovering the contaminants when desired; high energy efficiency of the process; and insignificant amount of gases to be treated.

Abstract: The method for converting harmful polychlorinated biphenyl (PCB) oil into a resource includes chemical decomposition treatment, pelletizing treatment and thermal decomposition treatment. The chemical decomposition treatment uses a decomposing agent including calcium oxide powder coated with a vegetable oil and quartz porphyry powder, causes a decomposing action of CaO and far-infrared rays emitted from quartz porphyry, to act onto polychlorinated biphenyl oil, and decomposes the polychlorinated biphenyl oil into powder including a metal salt. The pelletizing treatment hardens the powder into pellets. The thermal decomposition treatment melts the pellets and glass cullet at a temperature above the thermal decomposition temperature of the PCBs for molten integration of the pellets and glass cullet as slag. The slag is cooled and the solid substance can be widely used as various types of construction materials and agricultural materials.

Abstract: A method is disclosed for the degradation of persistent contaminants in soil. The method provides the combination of a stabilizing reagent and a degradative reagent where both are admixed into a contaminated soil site for the reduction of permeability at the site and the chemical degradation of the contaminant over time.

Abstract: A process of making vitrified waste in a crucible and inserting the crucible and vitrified waste into an outer container after vitrification. The outer container is then sealed.

Abstract: A process for vitrifying waste material containing environmentally hazardous metals or metal compounds includes drying a waste material using a flash dryer, where the drying is carried out at a temperature low enough to prevent volatilization of hazardous metals and metal compounds contained in the waste material. Preferably, more than about 95% of the water is removed form the waste material. The dried waste material is transferred from the flash dryer into a melting vessel, melted, collected and cooled to form a vitrified mass of waste material. Gases produced during the process of the invention are filtered, treated, and released into the atmosphere.

Abstract: The AVS Melting Process is a process for vitrification of waste in a disposable canister. In the process, waste is dropped into the disposable canister from the top. While the waste is being dropped into the disposable canister, radiant energy is added to the space above the waste in the canister, such that the temperature of the gaseous atmosphere above the waste is higher than the melting point of the waste. Since only the space above the waste in the canister is heated, the temperature of the melt decreases with increasing depth of the waste in the canister. The decreasing temperature permits a small surface melt volume to be maintained and solidified product to form with increasing depth. The process continues until the disposable canister is filled, then all heating is stopped and the disposable canister allowed to cool to ambient temperature.

Abstract: Solidification of liquid radioactive waste, and other hazardous wastes, is accomplished by the method of the invention by incorporating the waste into a porous glass crystalline molded block. The porous block is first loaded with the liquid waste and then dehydrated and exposed to thermal treatment at 50-1,000° C. The porous glass crystalline molded block consists of glass crystalline hollow microspheres separated from fly ash (cenospheres), resulting from incineration of fossil plant coals. In a preferred embodiment, the porous glass crystalline blocks are formed from perforated cenospheres of grain size −400+50, wherein the selected cenospheres are consolidated into the porous molded block with a binder, such as liquid silicate glass. The porous blocks are then subjected to repeated cycles of saturating with liquid waste, and drying, and after the last cycle the blocks are subjected to calcination to transform the dried salts to more stable oxides.

Abstract: The invention involves a process for containment of industrial wastes, particularly nuclear wastes, in apatite ceramics. This process involves preparing a homogeneous mixture of powders which can form an apatite matrix, introducing the waste into this mixture, compacting it under a pressure of 100 to 500 MPa at room temperature, and subjecting it to hydrothermal processing at low temperature (100 to 500° C.) in the presence of water in a sealed chamber.

Abstract: Industrial combustion facilities are integrated with greenhouse gas-solidifying fertilizer production reactions so that CO2, CO, NOx, and SOx emissions can be converted prior to emission into carbonate-containing fertilizers, mainly NH4HCO3 and/or (NH2)2CO, plus a small fraction of NH4NO3 and (NH4)2SO4. The invention enhances sequestration of CO2 into soil and the earth subsurface, reduces N03− contamination of surface and groundwater, and stimulates photosynthetic fixation of CO2 from the atmosphere. The method for converting CO2, CO, NOx, and SOx emissions into fertilizers includes the step of collecting these materials from the emissions of industrial combustion facilities such as fossil fuel-powered energy sources and transporting the emissions to a reactor. In the reactor, the CO2, CO, N2, SOx, and/or NOx are converted into carbonate-containing fertilizers using H2, CH4, or NH3.

Abstract: The present invention provides a method and an apparatus for treating boron-containing waste, which prevent clogging of a waste liquid line, achieve an increase in feeding of a waste liquid to a dryer, make in-drum mixing feasible, and increase the strength of a cement solidification product. A method for treating a boron-containing waste liquid comprises the step of adding an alkali metal element compound and an alkali earth metal element compound to the boron-containing waste liquid, and the step of then drying and powdering the boron-containing waste liquid, wherein the temperature of the boron-containing waste liquid during a period from addition of either the alkali metal element compound or the alkali earth metal element compound until the drying and powdering is maintained at not lower than the precipitation temperature of a compound containing boron and an alkali metal and a compound containing boron and an alkali earth metal.

Abstract: Building bricks and tiles are made by mixing 60% to 75% clay, 20% to 40% sludge and 1% to 10% sand, all percentages being by weight of the total composition. This process utilizes industrial waste products to provide building materials which are lighter and stronger than conventional materials.

Abstract: This invention discloses a method for the co-solidification of low-level radioactive wet wastes of BWR nuclear power plants, including concentrate waste, spent ion exchange resins and sludge wastes etc., with very high volume efficiency. In this invention, for promoting the stability of the solidified waste, sodium sulfate in the concentrate solution is converted to sodium hydroxide and barium sulfate by reacting with barium hydroxide. The conversion product barium sulfate possessing high density and stability is insoluble and used as a fine aggregate material in the solidified waste. Sodium hydroxide is used to stabilize ion exchange resins and to form a highly water-durable solidified waste form with silicates and phosphates in the solidification agent mixture. The solidification agent used in this invention is a formulated powder mixture completely made from inorganic materials. Therefore, there is no aging problem of the solidified waste.

Abstract: A method of encapsulating hazardous waste materials including heavy metals such as arsenic, mercury, nickel and chromium residues, as well as radioactive materials. The method involves adding the hazardous waste material to a settable composition, forming a slurry, and allowing the slurry to set to encapsulate the waste material. The settable composition is a powdered flowable cement composition containing calcium carbonate and a caustic magnesium oxide. Tests conducted on the encapsulated material indicate that virtually none of the hazardous waste material is leached out of the set composition which has a concrete-like appearance.

Abstract: A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

Abstract: An apparatus and process for producing a homogeneous analytical sample from a heterogenous feedstock by: providing the mixed feedstock, reducing the temperature of the feedstock to a temperature below a critical temperature, reducing the size of the feedstock components, blending the reduced size feedstock to form a homogeneous mixture; and obtaining a representative sample of the homogeneous mixture. The size reduction and blending steps are performed at temperatures below the critical temperature in order to retain organic compounds in the form of solvents, oils, or liquids that may be adsorbed onto or absorbed into the solid components of the mixture, while also improving the efficiency of the size reduction. Preferably, the critical temperature is less than 77 K (−196° C.). Further, with the process of this invention the representative sample may be maintained below the critical temperature until being analyzed.

Abstract: A process for improving waste vitrification in a disposable canister. In the process, chunks of frit are combined with waste and then added to the disposable canister. The waste and frit are then heated to melt the frit and waste. The melted mixture is then cooled to form a vitrified product in the module.

Abstract: A waste treatment process includes containing a reactant metal alloy (210) in a reactant alloy container (202) substantially isolated from oxygen gas. The reactant metal alloy includes at least one chemically active alkaline metal and at least one radiation absorbing metal. After heating the reactant alloy (210) in the reactant alloy container (202) to a desired operating temperature, a waste material including radioactive isotopes to be alloyed is introduced into the molten alloy, preferably below the surface of the alloy. Non-radioactive compounds in the waste material react with metals in the reactant alloy (210) to produce useful halogen salts and other materials. The metal radioactive isotopes in the waste material are alloyed with the alkaline metal and radiation absorbing metals to create a storage product for long term storage.

Abstract: In a glass melter, a precious metal insert is used to protect a gas bubbler from corrosion at the orifice of the bubbler through which gas is injected into the melt. The use of a precious refractory metal insert at the bubbler orifice prevents the attack of molten glass on the bubbler. The precious metal is chosen from the refractory group of metals and the platinum group of metals. Preferably the precious metal from the platinum group is platinum or one of its alloys or one of ruthenium, rhodium, palladium, osmium and iridium. The precious metal from the refractory group is preferably chromium.

Abstract: A method of restoring wetlands is provided, by separating drill cuttings from drilling fluid, mixing the cuttings with a stabilization medium, and then filling a desired position in the marshland or wetlands with the reconstituted material.

Abstract: A one-step method and compositions for stabilization of heavy metals, acid gas removal and pH control in hazardous and toxic solid, semi-solid, liquid and/or gaseous matrices using a mixture of reactive agents in a single product, for the broader purpose of enhancing environmental pollution control, prevention and remediation are described. The product contains sulfonated calcium aluminum magnesium phosphate. This material may be used alone or in combination with magnesium sulfite and/or hydroboracite.

Abstract: A phosphate mineral based reactive barrier system. Phosphate minerals are known to be sinks for heavy metal contaminants. The reactive barrier prevents the release of contaminants from waste materials, sediments or dredged materials via reaction with the contaminants at the interface between the barrier and the waste material, sediments or dredged material. The barrier is comprised of a phosphate mineral material where the form of the phosphate mineral is variable but primarily insoluble. This barrier is placed below, around, and/or on top of the contaminated materials such that the contaminated materials are completely enveloped, capped, or contained by a grout curtain. The barrier can be in a (i) slurry form, (ii) blended matrix form with other inorganic agents, or (iii) composite form with a geotextile or geofabric. These methods of construction can be used singly or jointly. In some cases, pH control may be used to optimize the chemical reactions within the barrier system.

Abstract: A method of filling a canister with vitrified waste starting with a waste, such as high-level radioactive waste, that is cooler than its melting point. Waste is added incrementally to a canister forming a column of waste capable of being separated into an upper zone and a lower zone. The minimum height of the column is defined such that the waste in the lower zone can be dried and melted while maintaining the waste in the upper zone below its melting point. The maximum height of the column is such that the upper zone remains porous enough to permit evolved gases from the lower zone to flow through the upper zone and out of the canister. Heat is applied to the waste in the lower zone to first dry then to raise and maintain its temperature to a target temperature above the melting point of the waste.

Abstract: A method for selecting an emulsifier for isolating free hydrocarbons in a given drilling system and a method of using the emulsifiers to treat drill cuttings to isolate free hydrocarbons, including bitumen.

Abstract: The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods.

Abstract: A process for improving waste vitrification in a disposable canister. In the process, chunks of frit are combined with waste and then added to the disposable canister. The waste and frit are then heated to melt the frit and waste. The melted mixture is then cooled to form a vitrified product in the module.

Abstract: A process for treating thickened phosphatic clay suspensions, waste clay and phosphogypsum produced in the processing of phosphate ore by water beneficiation and chemical processing, the thickened phosphatic clay suspension having a solid content of from about 4 to about 40 percent by weight, includes mixing a sufficient amount of deflocculating agent with a thickened phosphatic clay suspension to cause deflocculation of the suspension to an extent sufficient to reduce the viscosity thereof to a value enabling the deflocculated suspension to be readily pumped from one location to another, the deflocculating agent comprising an alkali compound of a phosphorus oxide. The deflocculated suspension of reduced viscosity is pumped from one location to another and separated into a clay suspension and a phosphatic mineral and sand suspension.

Abstract: The invention provides a method for treating marine cuttings, preferably in situ, so that the cuttings can be discharged back into marine waters without causing oxygen depletion of marine sediment. In a preferred embodiment, the treatment emulsifies and then encapsulates free hydrocarbons in the marine cuttings.

Abstract: A device for improving waste vitrification in a disposable canister, the process for using the device, and the process for making the device. The disposable canister, also known as a module, has outer and inner containers with thermal insulation therebetween. The device includes an inner container of graphite having a layer of pyrographite on its external wall. The outer container is typically made of stainless steel. The inner container is heated, typically by induction, to melt the frit and waste. The melted mixture is then cooled to form a vitrified product in the module. The fabrication of the pyrographite coating on the inner container involves heating the container to about 1500 degrees centigrade in a methane atmosphere, then cooling the container to ambient temperature.

Abstract: A method using retardant to inhibit solidification of slurried fly ash particles that were collected on a collection surface. The slurried particles are transported in a pipeline to a collection or disposal site during or after the addition of the retardant to the slurry. The retardant can be a dispersant, a deflocculant, a scale inhibitor or a sequestering agent such as a phosphate, organic phosphate, polymer, and mixtures thereof.

Abstract: The AVS invention provides for an apparatus and process for its practice involving the vitrification of waste materials, such as nuclear waste, inside a disposable canister. The preferred embodiment of the process includes a canister having outer and inner containers with thermal insulation therebetween. Solid frit sections are placed inside the inner container to create one or more regions for receiving waste. The waste is then loaded into the regions. The inner canister is heated to melt the frit and waste and mix them once molten. The melted mixture is then cooled to form a vitrified product in the module. In an alternative process, chunks of frit are mixed with waste and loaded into the empty canister. The mixture is then melted and cooled inside the disposal canister.

Abstract: The current invention provides methods for stabilizing wastes, preparing construction materials and stabilizing soils using compositions including hexametaphosphate, with or without other additives. More particularly, one method of the invention discloses a process for treating a variety of materials including solid and liquid-containing wastes, including for example, common debris or hazardous, radioactive or toxic waste. This method involves combining a waste material with hexametaphosphate, and in some cases other additives. The resulting amended waste may also be compacted. Another method involves use of hexametaphosphate compositions to prepare construction materials. This method involves combining hexametaphosphate with a starting material such as soil, soil-containing compositions, mine tailings, mill tailings and combinations thereof. The resulting mixture is then compacted.

Abstract: A pumpable ceramic composition is provided comprising an inorganic oxide, potassium phosphate, and an oxide coating material. Also provided is a method for preparing pumpable ceramic-based waste forms comprising selecting inorganic oxides based on solubility, surface area and morphology criteria; mixing the selected oxides with phosphate solution and waste to form a first mixture; combining an additive to the first mixture to create a second mixture; adding water to the second mixture to create a reactive mixture; homogenizing the reactive mixture; and allowing the reactive mixture to cure.

Abstract: A process for solidifying and stabilizing waste, the process comprising (a) combining bagasse and a liquid medium having a pH below about 4 or above about 10 to form a mixture, (b) heating the mixture, (c) separating the mixture into solid matter and filtrate and washing the solid matter with a liquid in which sugar is soluble, (d) substituting the solid matter for the bagasse in (a) and repeating steps (a) through (c) until the filtrate is substantially colorless under ambient light conditions, thereby producing washed solid matter, (e) combining at least a portion of the washed solid matter with at least (1) the waste, (2) water, and (3) a cement, so as to form a cement slurry, and (f) curing the cement slurry. Cementitious products formed by processes of this invention.

Abstract: Recycling liquid waste and rendering particulate substances suitable for handling, transportation, or use. More specifically, preferred embodiments provide methods for recycling waste liquids such as latex paint by using them as an agglomeration agent to increase the particle size for particulate substances such as ash, dust, powders, sands, sludge, and fines.