Abstract: A method for reacting a liquid phase chemical species includes the steps of providing liquid phase containing at least one liquid phase chemical species, providing a gas phase, and providing a reactor vessel for containing the liquid phase and the gas phase. The liquid phase and the gas phase are placed in the reactor vessel so as to form a liquid-gas interface between the liquid phase and the gas phase within the reactor vessel. A pulsed discharge cathode and anode are provided for creating a pulsed discharge electric field at the liquid-gas interface. A pulsed power input to the pulsed discharge cathode and anode is provided, thereby creating a plasma comprising ions at the liquid-gas interface. A secondary electric field is directed transverse to the liquid-gas interface, wherein the secondary electric field will drive ions from the gas phase into the liquid phase to react with the liquid phase species.

Abstract: This application relates to manufacturing of vacuum chambers of nuclear fusion reactors, and more particularly to a method, device and apparatus for machining grooves of poloidal segments of a vacuum chamber of a nuclear fusion reactor, and a computer-readable storage medium. The method includes: collecting three-dimensional (3D) point cloud data of surfaces of individual poloidal segments of the vacuum chamber; performing reverse model reconstruction, based on the three-dimensional point cloud data, to generate an actual 3D model to acquire a sectional view of the vacuum chamber; extracting a cross-reconstruction region between two adjacent poloidal segments; and calculating a target machining allowance of individual poloidal segments according to the cross-reconstruction region and a preset segment boundary to generate a machining strategy for the groove of individual poloidal segments.

Abstract: Systems and methods for plasma based synthesis of graphitic materials. The system includes a plasma forming zone configured to generate a plasma from radio-frequency radiation, an interface element configured to transmit the plasma from the plasma forming zone to a reaction zone, and the reaction zone configured to receive the plasma. The reaction zone is further configured to receive feedstock material comprising a carbon containing species, and convert the feedstock material to a product comprising the graphitic materials in presence of the plasma.

Abstract: A reactor system for reacting liquid phase chemical species in a liquid includes a reactor vessel for containing the liquid phase and a gas phase. The reactor vessel can have a gas injection port, a gas exit port, and a liquid-gas interface location within the reactor vessel. A pulsed discharge cathode and anode are provided for creating a pulsed discharge electric field at the liquid-gas interface location. A pulsed discharge power supply delivers a pulsed power input to the pulsed discharge cathode and anode, and thereby creates a plasma comprising ions at the liquid-gas interface location. A secondary electric field source is provided for directing a secondary electric field transverse to the liquid-gas interface. The secondary electric field will drive some of the ions from the gas phase into the liquid phase to react with the liquid phase chemical species. A method for reacting a liquid phase chemical species is also disclosed.

Abstract: A process for the simultaneous removal of iron and phosphate ions from a chlorinated hydrocarbon waste stream, such as a waste stream derived from a process for manufacturing 1,1,1,3,3-pentachloropropane (HCC-240fa) and/or 1,1,1,3-tetrachloropropane (HCC-250fb). The waste stream contains at least one of chlorinated hydrocarbons, tributyl phosphate (TBP) and/or triethyl phosphate (TEP), iron, FeCl2 and/or FeCl3, a TBP-FeCl2 complex and/or a TBP-FeCl3 complex, and a TEP-FeCl2 complex and/or a TEP-FeCl3 complex, and is subjected to thermal oxidation to generate a second, aqueous waste stream containing at least one of hydrogen chloride (HCl), FeCl3 and/or FeCl2, and H3PO4. The second waste stream is exposed to a base to generate a precipitate including at least one insoluble compound selected from the group consisting of FePO4, Fe(OH)3, and Ca3(PO4)2, and the precipitate is separated from the second waste stream to produce a liquid phase including only trace amounts of iron and phosphate ions.

Abstract: The invention provides a method and apparatus for creating plasma particles and applying the plasma particles to a liquid. Liquid feedstock (e.g., water and/or hydrocarbons mixed with biomass) is pumped through a pipeline; the single-phase stream is then transformed into a biphasic liquid-and-gas stream inside a chamber. The transformation is achieved by transitioning the stream from a high pressure zone to a lower-pressure zone. The pressure drop may occur when the stream further passes through a device for atomizing liquid. Inside the chamber, an electric field is generated with an intensity level that exceeds the threshold of breakdown voltage of the biphasic medium leading to a generation of a plasma state. Furthermore, the invention provides an energy-efficient highly adaptable and versatile method and apparatus for sanitizing water using plasma particles to inactivate biological agents contaminating water.

Abstract: The present invention relates to a process for the treatment of hazardous waste, the process comprising: (i) providing a hazardous waste; (ii) providing a further waste; (iii) plasma treating the hazardous waste in a first plasma treatment unit, (iv) gasifying the further waste in a gasification unit to produce an offgas and a char material; and (v) plasma treating the offgas, and optionally the char material, in a second plasma treatment unit to produce a syngas, (vi) optionally treating the syngas in a gas cleaning plant, wherein the first plasma treatment unit is arranged to plasma treat at least some of the solid by-products from the gasification unit and/or the second plasma treatment unit and/or the gas cleaning plant.

Abstract: The waste disposal system disclosed herein includes a chamber operated at high ampere and low voltage, the chamber configured to inject smoke on a stream of free radicals. In one implementation, the stream of free radicals is generated from a plasma igniter and the smoke is generated from waste products, such as hospital waste products.

Abstract: A melting furnace includes a waste inlet formed on a first side wall of the plasma melting furnace to feed waste therein, an exhaust gas outlet formed on a second side wall facing the first side wall and located diagonally to a direction orthogonal to the first side wall having the waste inlet to discharge the exhaust gas generated in the plasma melting furnace, and a plasma torch mounted on a third side wall for heating inside of the plasma melting furnace at a position nearer to the second side wall than the first side wall so as to inject a plasma into the exhaust gas.

Abstract: Methods and apparatus for treating an exhaust gas in a foreline of a substrate processing system are provided herein. In some embodiments, an apparatus for treating an exhaust gas in a foreline of a substrate processing system includes a plasma source coupled to a foreline of a process chamber, a reagent source coupled to the foreline upstream of the plasma source, and a foreline gas injection kit coupled to the foreline to controllably deliver a gas to the foreline, wherein the foreline injection kit includes a pressure regulator to set a foreline gas delivery pressure setpoint, and a first pressure gauge coupled to monitor a delivery pressure of the gas upstream of the foreline.

Abstract: A two step process for the destruction of a precursor material using a steam plasma in a three zone reactor wherein the precursor material is hydrolyzed as a first step in the high temperature zone of the reactor, followed by a second step of medium temperature oxidation of the reactant stream in the combustion zone of the reactor where combustion oxygen or air is injected and immediate quenching of the resulting gas stream to avoid the formation of unwanted by-products. A related apparatus includes a non transferred direct current steam plasma torch, an externally cooled three zone steam plasma reactor means for introducing the precursor material into the plasma plume of the plasma torch, means for introducing the combustion air or oxygen into the combustion zone, means for exiting the reactant mixture from the reactor and means for quenching the reactant mixture located at the exit end of the reactor.

Abstract: A process and related apparatus for the treatment of hazardous waste and an initially separate waste stream, the process comprising gasifying the waste stream in a gasification unit to produce an offgas and a char material; and plasma treating the offgas, and optionally the char material, in a plasma treatment unit to produce a syngas; and blending hazardous waste with the waste stream at a point in the process determined by the relative chemical and/or physical properties of the hazardous waste and the waste stream.

Abstract: The present invention provides a method for the treatment of waste comprising one or more hazardous organic components, the method comprising plasma treating a waste in a plasma treatment unit; wherein the waste comprises: (i) a soil and/or aggregate material; and (ii) an oil component; and wherein, before plasma treating the waste, the waste comprises one or more hazardous organic components and from 5 to 50% water by weight of the waste.

Abstract: A method for converting renewable energy source electricity and a hydrocarbon feedstock into a liquid fuel by providing a source of renewable electrical energy in communication with a synthesis gas generation unit and an air separation unit is described. Oxygen from the air separation unit and a hydrocarbon feedstock is provided to the synthesis gas generation unit, thereby causing partial oxidation reactions in the synthesis gas generation unit in a process that converts the hydrocarbon feedstock into synthesis gas. The synthesis gas is then converted into a liquid fuel.

Abstract: A method and system for treating emissions includes charging particles in an exhaust stream, producing one or more radicals, and oxidizing at least a portion of the charged particles with at least a portion of the produced radicals. At least a portion of the charged particles in the exhaust stream are then attracted on at least one attraction surface which is one of oppositely charged from the charged particles and grounded. The attracted particles are oxidized with another portion of the one or more produced radicals to self regenerate the at least one attraction surface. Downstream from where the attracted particles are oxidized, at least a portion of one or more first compounds in the exhaust stream are converted to one or more second compounds downstream from the attracting. Additionally, at least a portion of any remaining charged particles are oxidized into one or more gases.

Abstract: Disclosed are a method and an apparatus for processing an exhaust gas, which enable to suppress decrease of pH and increase of ORP of a mixture of an aqueous solution of a reducing agent and an aqueous alkali solution circulated within a wet reactor comprising a reduction reaction region and an oxidation reaction region. The method and apparatus enable to prevent deterioration of the mixed aqueous solution, and can be continuously operated for a long time. Specifically, the ORP and pH of the mixed aqueous solution of the aqueous solution of a reducing agent and the aqueous alkali solution to be circulated within the wet reactor are measured, and a fresh aqueous solution of a reducing agent and a fresh aqueous alkali solution are supplied, if necessary, into a reservoir unit arranged in the lower part of the wet reactor so that the ORP and pH of the mixed aqueous solution are kept within predetermined ranges.

Abstract: A waste transformation and destruction apparatus includes a natural gas ignition system, a silica material bed, a heat transfer device, and a system for collecting plasma produced energy. A reaction formed by heat from ignition, carbon from the waste material, supercritical water, —OH radicals, and muons released from the silica bed transform the waste into a fuel. This fuel is more efficiently consumed by the complete combustion process resulting in near total elimination of the waste, increased energy production, and virtually no emissions.

Abstract: The present invention relates to a process for the treatment of hazardous waste, the process comprising: (i) providing a hazardous waste; (ii) providing a further waste; (iii) plasma treating the hazardous waste in a first plasma treatment unit, (iv) gasifying the further waste in a gasification unit to produce an offgas and a char material; and (v) plasma treating the offgas, and optionally the char material, in a second plasma treatment unit to produce a syngas, (vi) optionally treating the syngas in a gas cleaning plant, wherein the first plasma treatment unit is arranged to plasma treat at least some of the solid by-products from the gasification unit and/or the second plasma treatment unit and/or the gas cleaning plant.

Abstract: A process for the treatment of waste, the process comprising either a gasification step or a pyrolysis step to produce an offgas and a non-airborne, solid char material; followed by a plasma treatment step. An associated apparatus having a plasma treatment unit which is separate from the gasification unit or pyrolysis unit.

Abstract: A two step process for the destruction of a precursor material using a steam plasma in a three zone reactor wherein the precursor material is hydrolyzed as a first step in the high temperature zone of the reactor, followed by a second step of medium temperature oxidation of the reactant stream in the combustion zone of the reactor where combustion oxygen or air is injected and immediate quenching of the resulting gas stream to avoid the formation of unwanted by-products. A related apparatus includes a non transferred direct current steam plasma torch, an externally cooled three zone steam plasma reactor means for introducing the precursor material into the plasma plume of the plasma torch, means for introducing the combustion air or oxygen into the combustion zone, means for exiting the reactant mixture from the reactor and means for quenching the reactant mixture located at the exit end of the reactor.

Abstract: A method for decontaminating bioaerosol with high concentrations of bacterial, viral, spore and other airborne microorganisms or biologic contaminants, in flight at high flow rates. A plasma screen created across the flow of air contaminated with airborne biologic agents renders contaminants non-culturable within millisecond. The technology may cooperate with heating, ventilation, and air conditioning (HVAC) systems. It may be particularly beneficial in preventing bioterrorism and the spread of toxic or infectious agents, containing airborne pandemic threats such as avian flu, sterilizing spaces such as hospitals, pharmaceutical plants and manufacturing facilities, treating exhaust ventilation streams, minimizing biological environmental pollutants in industrial settings, improving general air quality, and preventing sick building syndrome.

Abstract: A method and device for chemical destruction of at least one feed comprising at least one organic compound are provided. The device comprises at least one inductive plasma torch, means for introducing at least one plasma-forming gas into the torch, optionally when the plasma gas(es) comprise(s) no or little oxygen, means for bringing oxygen gas into the plasma or into the vicinity of the plasma, means for introducing the feed into the torch, a reaction enclosure capable of allowing thermal destruction of the gases flowing from the torch, a device allowing mixing of the gases flowing out of the reaction enclosure to be carried out, means for introducing air and/or oxygen gas into the mixing device, a device allowing recombination by cooling of at least one portion of the gases from the mixing device, the torch, the reaction enclosure, the mixing device and the recombination device being in fluidic communication.

Abstract: A process for the treatment of waste, the process comprising either a gasification step or a pyrolysis step to produce an offgas and a non-airborne, solid char material; followed by a plasma treatment step. An associated apparatus having a plasma treatment unit which is separate from the gasification unit or pyrolysis unit.

Abstract: An apparatus for synergistically combining a plasma with a comminution means such as a fluid kinetic energy mill (jet mill), preferably in a single reactor and/or in a single process step is provided by the present invention. Within the apparatus of the invention potential energy is converted into kinetic energy and subsequently into angular momentum by means of wave energy, for comminuting, reacting and separation of feed materials. Methods of use of the apparatus in the practice of various processes are also provided by the present invention.

Abstract: The present invention relates to a method for treating spent pot liner material (SPL) containing carbon and/or an inorganic material, the method comprising: providing a plasma furnace having first and second electrodes for generating plasma and a crucible having a non-electrically conductive inner surface, heating the SPL material in the crucible in the presence of a flux material and an oxidant by passing an arc between the first and second electrodes via the SPL material to form a molten slag material and convert at least some of the carbon in the SPL material to CO and/or CO2 and/or incorporate at least some of the inorganic material into the molten slag material.

Abstract: An apparatus subjects fluid waste to waves from an RF plasma. This allows continuous production of “activated water” characterized by cluster sizes below about 4 molecules per cluster, water having pH below 4 or above 10, or water having ORP of less than ?350 mV or more than +800 mV. The basic frequency of the plasma is preferably between 0.44 MHz and 40.68 MHz, and the plasma is preferably modulated at a frequency between 10 kHz and 34 kHz. Flow rates typically range from 20 1/hr to about 2000 1 hr.

Abstract: The invention relates to a device and a process for the destruction of toxic or hazardous chemical products using inductively coupled plasma. These products may occur in liquid, gaseous or powder form and belong to the family of organic or halogenated organic compounds.

Abstract: An electrode includes an elongated conductive metal support and a layer of carbon fibers supported by, and in electrical contact with, the elongated conductive metal support such that ends of fibers of the layer of carbon fibers extend beyond the conductive metal support.

Abstract: The present invention pertains to a process and an device for plasma fusion inertizing of toxic materials, consisting of a melting vessel having an internal volume defined by walls. At least one non-transferred arc plasma source intended to generate a lance of plasma is inclined toward the lower part of the melting vessel and propagated along an axis of propagation situated outside of the vertical plane containing the normal to the wall at the point of intersection of said propagation axis with said wall so as to agitate the melting bath. The melting vessel is in fluid communication with the upstream part of a refining and pouring vessel and consists of an opening to which a non-transferred arc plasma source is connected, said source being mounted so as to emit a plasma lance to strike the refining bath directly in said upstream part.

Abstract: Apparatus, process and article for treating an aqueous solution containing a chemical contaminant. The process includes contacting an aqueous solution containing a chemical contaminant with an aggregate composition comprising an insoluble rare earth-containing compound to form a solution depleted of chemical contaminants. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from a cerium carbonate, cerium oxalate and/or a cerium salt. The aggregate composition can include more than 10.01% by weight of the insoluble rare earth-containing compound, and in a particular embodiment consists essentially of one or more cerium oxides, and optionally a binder and/or flow aid. Although intended for a variety of fluid treatment applications, such applications specifically include removing or detoxifying chemical contaminants in water.

Abstract: A method for decontaminating bioaerosol with high concentrations of bacterial, viral, spore and other airborne microorganisms or biologic contaminants, in flight at high flow rates. A plasma screen created across the flow of air contaminated with airborne biologic agents renders contaminants non-culturable within millisecond. The technology may cooperate with heating, ventilation, and air conditioning (HVAC) systems. It may be particularly beneficial in preventing bioterrorism and the spread of toxic or infectious agents, containing airborne pandemic threats such as avian flu, sterilizing spaces such as hospitals, pharmaceutical plants and manufacturing facilities, treating exhaust ventilation streams, minimizing biological environmental pollutants in industrial settings, improving general air quality, and preventing sick building syndrome.

Abstract: The present invention relates to a method for treating spent pot liner material (SPL) containing carbon and/or an inorganic material, the method comprising: providing a plasma furnace having first and second electrodes for generating plasma and a crucible having a non-electrically conductive inner surface, heating the SPL material in the crucible in the presence of a flux material and an oxidant by passing an arc between the first and second electrodes via the SPL material to form a molten slag material and convert at least some of the carbon in the SPL material to CO and/or CO2 and/or incorporate at least some of the inorganic material into the molten slag material.

Abstract: The invention is a system and method for neutralizing fluid chemical waste products that result from a chemical production process and are collected from the production line. The invention comprises a pyrolysis/reaction chamber into which the fluid chemical waste is pumped through an atomizer. The jet of small droplets of liquid waste that is formed by the atomizer effectively contacts the plasma stream created by a plasma torch. When the droplets contact the plasma stream the molecules of the waste from which the droplets are composed are dissociated into atoms and/or ions. These atoms and ions move out of the immediate region of the plasma stream and recombine to form a mixture of product gases which exits the chamber. The product gases then enter a post-pyrolysis subsystem, which is designed to neutralize and/or collect the components comprising the mixture of product gases.

Abstract: Disclosed are a hybrid reactor, method, and device for improved nuclear fusion reactors to provide sufficient flux of fast neutrons with sufficient energy to transmutate transuranic wastes from nuclear fission and to be used in improved nuclear fuel cycles so as to effectively reduce the amount radio-toxicity, and the risks and costs of the disposal of nuclear waste, thereby reducing the cost of nuclear energy and increasing its acceptability as an energy source. This abstract is intended for use as a scanning tool only and is not intended to be limiting.

Abstract: The invention is related to an apparatus made of microwave plasma burner for a large-volume elimination of toxic airborne chemical and biological warfare agents. The apparatus can purify the interior air of large volume in an isolated space such as buildings, public transportation systems, and military vehicles contaminated with chemical and biological warfare agents. The apparatus consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber for elimination and burnout of toxic airborne warfare agents in large quantities. Hydrocarbon fuel in gaseous or liquid state injected into the microwave plasma torch evaporates instantaneously, generating a large volume of plasma flame in the reaction chamber where the oxidation mechanism eliminates the chemical and biological warfare agents that pass through the reaction chamber. The apparatus can also purify air contaminated with volatile organic compounds and eliminate soot from diesel engines.

Abstract: A molecularly imprinted polymer and production process therefor and a process for selective treatment of poorly degradable and/or toxic compounds in liquids using the molecularly imprinted polymers. Such polymers and processes are required for selective removal and/or degradation of biological, poorly degradable pollutants or toxic compounds, for example from wastewaters. Consequently, a molecularly imprinted polymer suitable for the selective treatment of at least one poorly degradable and/or toxic compound is provided having a polymeric network which is made up of monomers and has cavities of predetermined size, wherein the cavities are arranged at predetermined spacings and have specific binding sites and/or patterns for the poorly degradable and/or toxic compounds.

Abstract: A process for the treatment of waste, the process comprising: (i) either (a) a gasification step comprising treating the waste in a gasification unit in the presence of oxygen and steam to produce an offgas and a char, or (b) a pyrolysis step comprising treating the waste in a pyrolysis unit to produce an offgas and a char; and (ii) a plasma treatment step comprising subjecting the offgas and the char to a plasma treatment in a plasma treatment unit in the presence of oxygen and, optionally, steam.

Abstract: A method for gasification of carbonic materials using CO2 is disclosed where materials having at least some carbon content are subjected to a high-temperature environment, for example, inside a reactor vessel in which a plasma are a plasma torch or the like is energized. CO2 is injected into such an environment in a substantially stoichiometric amount with respect to the amount of carbon within the carbonic components.

Abstract: Process for combustion and vitrification of waste in which at least one oxygen plasma jet is associated with a continuous melting device by high frequency direct induction. The crucible is composed of a continuous external shell and a sole plate, both cooled by a liquid circulating in internal channels. The inductor is placed below the sole plate. There is a gravity drain valve at the bottom or on the side.

Abstract: A recycling system for a waste converting apparatus collects residues from a post-processing means and re-introduces the residues into the apparatus such that the residues are exposed to the high temperature zone thereof.

Abstract: A system and method for the removal of metals such as mercury from a gas stream. The method involves contacting a gas stream containing the target metals with reactive chemical species generated in a plasma device. The metal to be removed is chemically converted into forms enabling capture in either conventional particulate removal devices or in a wet scrubber for the capture of a soluble chemical species.

Abstract: There are disclosed various processes, apparatuses and systems for treating a halogen-containing gas such as F2 that involve generating a plasma in order to reduce chemically the halogen-containing gas into products that are more environmentally manageable. According to a particular embodiment, a reducing agent is mixed with the halogen-containing gas to produce a feed gas mixture and a non-thermal plasma is generated in the feed gas mixture in the presence of liquid water. According to another embodiment, a vaporized portion of a liquid reducing agent is mixed with the halogen-containing gas to produce a reaction mixture and a non-thermal plasma is generated in the reaction gas mixture to reduce the halogen-containing gas.

Abstract: A method of using high temperature plasma to disintegrate waste containing titanyl phthalocyanine (TiOPc) comprises heating a mixture of titanyl phthalocyanine (TiOPc), a vitrifying material and optionally selected waste soil to a temperature of 1,220° C. to 10,000° C. until the mixture becomes a molten lava. The plasma breaks down the titanyl phthalocyanine and encapsulates the benign products in the lava that is chemically very stable. Since the titanyl phthalocyanine (TiOPc) is disintegrated completely in the process, the titanyl phtbalocyanine (TiOPc) no longer represents a threat to the environmental.

Abstract: A feed system for loading waste into a fuel gas generator system where the feed system is made of a walled container wherein the outer container back has an outer back hole and the inner container back has an inner back hole, and wherein the holes are aligned and a piston penetrates the holes, wherein the piston is connected to a plate moveably disposed in the container, wherein the piston is connected to sealable opening locks to apply pressure and retract the plate to a position against the back thereby providing a loading chamber to insert waste, a second piston connected to the door retracts the door for loading waste, at least one inert gas injector mounted to the container for flooding the loading chamber with inert gas, a liquid cooling system disposed in the walls of the container, and a controller for operating the locks, doors and sealable opening.