Distillation Patents (Class 62/620)
  • Patent number: 11885562
    Abstract: In a method for separating argon by cryogenic distillation, in which a flow containing argon, oxygen and nitrogen and being more rich in argon than the air is sent to a distillation column, and an argon-rich gas flow is withdrawn at the top of the column, a portion of the argon-rich gas flow is mixed with beads to form a gas mixture containing beads, the beads being capable of adsorbing oxygen in the presence of argon at the column operating temperatures; the portion of the argon-rich gas flow mixed with the beads is condensed and then sent to the top of the column; and a bottom liquid containing beads is withdrawn from the column and treated to remove the beads, the beads removed being regenerated to remove the adsorbed oxygen and being again mixed with the argon-rich gas flow.
    Type: Grant
    Filed: March 3, 2021
    Date of Patent: January 30, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Nicolas Kofman, David Bednarski, Bernard Saulnier, Guillaume Cardon, Mikael Wattiau
  • Patent number: 11715849
    Abstract: Disclosed herein are improved methods and devices for recycling lithium cathodes from batteries using a Soxhlet extractor.
    Type: Grant
    Filed: November 2, 2020
    Date of Patent: August 1, 2023
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Kyusung Park, Anthony Keiran Burrell
  • Patent number: 11692772
    Abstract: A method to recover hydrocarbonfractions from refineries gas streams involves a pre-cooled heat refinery fuel gas stream mixed with a pre-cooled and expanded supply of natural gas stream in an inline mixer to condense and recover at least C3+ fractions upstream of a fractionator. The temperature of the gas stream entering the fractionator may be monitored downstream of the in-line mixer. The pre-cooled stream of high pressure natural gas is sufficiently cooled by flowing through a gas expander that, when mixed with the pre-cooled refinery fuel gas, the resulting temperature causes condensation of heavier hydrocarbon fractions before entering the fractionator. A further cooled, pressure expanded natural gas reflux stream is temperature controlled to maintain fractionator overhead temperature. The fractionator bottoms temperature may be controlled by a circulating reboiler stream.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: July 4, 2023
    Assignees: 1304338 Alberta Ltd., 1304342 Alberta Ltd.
    Inventors: Jose Lourenco, Mackenzie Millar
  • Patent number: 11680747
    Abstract: In a process for the combined production of a) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or b) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, a still liquor is extracted from a scrubbing column and sent to a stripping column, a still liquor is extracted from the stripping column and sent to a separating column for carbon monoxide and methane and a cooling fluid is used at a pressure greater than that of the head of the separating column for cooling at least one fluid extracted at an intermediate level from the scrubbing column.
    Type: Grant
    Filed: November 16, 2017
    Date of Patent: June 20, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Jean Billy, Axelle Gaertner, Antoine Hernandez, Jean-Marc Tsevery, Marie-Pascal Victor
  • Patent number: 11643378
    Abstract: A process and apparatus reboil a propylene splitter bottoms by heat exchange and/or a deethanizer bottoms stream with a compressed propylene splitter overhead stream. Use of single splitter compressor and operation of the propane-propylene splitter column at lower pressure are enabled, whereas conventionally two splitter compressors and higher splitter pressure were necessary to provide a propylene product stream and a propane recycle stream of equivalent quality.
    Type: Grant
    Filed: February 11, 2022
    Date of Patent: May 9, 2023
    Inventors: Xin X Zhu, Stephen T. King, Glen John Pomorski, Joseph Edward Zimmerman
  • Patent number: 11607643
    Abstract: A system includes a purification unit configured to process a vapor stream including sulfur dioxide. The purification unit includes an inlet configured to allow the vapor stream to enter the purification unit. The purification unit includes a steam coil configured to circulate steam and provide a source of heat. The purification unit includes a packed bed. The purification unit includes a tray configured to accumulate sulfur. The purification unit includes an absorber section configured to remove at least a portion of the sulfur dioxide from the vapor stream. The purification unit includes an outlet configured to allow an effluent with a lower sulfur dioxide content than the vapor stream to exit the purification unit. The system includes a sulfur tank including a vent line in fluid communication with the inlet. The vent line is configured to allow vapor to flow from the sulfur tank to the purification unit.
    Type: Grant
    Filed: March 7, 2022
    Date of Patent: March 21, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Subindas M. Mohandas, Saeed A. Salah
  • Patent number: 11585598
    Abstract: A method for improved operation of a natural gas liquids stabilizer column, particularly a small-scale, is provided.
    Type: Grant
    Filed: December 18, 2020
    Date of Patent: February 21, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Oriane Farges, Michael A. Turney, Pierre Costa De Beauregard
  • Patent number: 11578915
    Abstract: A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream which is divided into first and second streams. The first stream is cooled, expanded to lower pressure, and supplied to a fractionation tower. The second stream is cooled and separated into vapor and liquid streams. The vapor stream is divided into two portions. A first portion is cooled, expanded to tower pressure, and supplied to the tower at an upper mid-column feed position. The second portion and the liquid stream are expanded to tower pressure and supplied to the tower. After heating, compressing, and cooling, a portion of the tower overhead vapor is cooled, expanded, and supplied to the tower at the top feed position. The quantities and temperatures of the feeds to the tower maintain the overhead temperature of the tower whereby the major portion of the desired components is recovered.
    Type: Grant
    Filed: March 11, 2020
    Date of Patent: February 14, 2023
    Assignee: UOP LLC
    Inventors: J. Ascencio Anguiano, John D. Wilkinson, Hank M. Hudson
  • Patent number: 11566501
    Abstract: A natural gas conditioning system for conditioning unconditioned natural gas for use in a gas lift system at a wellbore comprises a series of coolers to receive and cool unconditioned natural gas, and a high-pressure, three-phase separator. The separator receives cooled unconditioned natural gas from the coolers and results in separate flows of conditioned lift gas, waste water and hydro-carbon liquids. The conditioned lift gas can be directed to a first heat exchanger, and the hydro-carbon liquids can be directed to a second heat exchanger. A chiller can be coupled to a third heat exchanger. All the components can be carried by a skid.
    Type: Grant
    Filed: June 25, 2020
    Date of Patent: January 31, 2023
    Assignee: Moneyhun Equipment Sales & Service Co., Inc.
    Inventors: David Moneyhun, Bernie Claydon
  • Patent number: 11473837
    Abstract: A design is provided to convert a gas subcooled process plant to a recycle split vapor process for recovering ethane and propane from natural gas. When in operation, the recovery of ethane and propane can exceed 97 to 99 wt. % of the stream being processed. A second smaller demethanizer column is added to the gas subcooled process plant as well as the addition of several cryogenic pumps.
    Type: Grant
    Filed: July 9, 2019
    Date of Patent: October 18, 2022
    Assignee: UOP LLC
    Inventors: David M. Thom, Jeffrey R. Garrison, David Farr
  • Patent number: 11408678
    Abstract: The claimed invention provides a method and an apparatus for separating hydrocarbons, wherein the method and the apparatus are used for separating a hydrocarbon having 3 or more carbon atoms including at least propane (hereinafter sometimes called “C3+ NGL”. NGL: Natural Gas Liquid) from liquefied natural gas (LNG).
    Type: Grant
    Filed: October 23, 2018
    Date of Patent: August 9, 2022
    Assignee: TOYO ENGINEERING CORPORATION
    Inventors: Yasuyuki Yamamori, Xiaoxue Zhang
  • Patent number: 11365933
    Abstract: A LNG liquefaction plant includes a propane recovery unit including an inlet for a feed gas, a first outlet for a LPG, and a second outlet for an ethane-rich feed gas, an ethane recovery unit including an inlet coupled to the second outlet for the ethane-rich feed gas, a first outlet for an ethane liquid, and a second outlet for a methane-rich feed gas, and a LNG liquefaction unit including an inlet coupled to the second outlet for the methane-rich feed gas, a refrigerant to cool the methane-rich feed gas, and an outlet for a LNG. The LNG plant may also include a stripper, an absorber, and a separator configured to separate the feed gas into a stripper liquid and an absorber vapor. The stripper liquid can be converted to an overhead stream used as a reflux stream to the absorber.
    Type: Grant
    Filed: April 22, 2019
    Date of Patent: June 21, 2022
    Assignee: FLUOR TECHNOLOGIES CORPORATION
    Inventors: John Mak, Jacob Thomas, Curt Graham
  • Patent number: 11015865
    Abstract: A system and method for producing an NGL product stream in either an ethane retention or rejection mode. Rejection modes include (a) two heat exchange stages between a feed stream and first separator bottoms stream and cooling a side stream withdrawn from a fractionation tower through heat exchange with both the fractionation tower and second separator overhead streams; or (b) warming the first separator bottoms stream and fractionation overhead stream through heat exchange with the side stream prior to heat exchange with the feed stream, to achieve 4-15% ethane recovery and 97%+ propane recovery. In ethane retention mode, a portion of the feed stream and portions of a first separator overhead and bottoms streams are separately cooled through heat exchange with other process streams, including the entireties of a recycled residue gas and fractionation column overhead streams, resulting in around 99% ethane and around 100% propane recovery.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: May 25, 2021
    Assignee: BCCK Holding Company
    Inventor: Rayburn C. Butts
  • Patent number: 11015866
    Abstract: Process for the combined production of a mixture of hydrogen and nitrogen, and of carbon monoxide by cryogenic distillation and cryogenic scrubbing, wherein a methane-rich liquid is introduced at a first intermediate level of a scrubbing column as first scrubbing liquid and at least one nitrogen-rich liquid is introduced at a level higher than the first level of the scrubbing column as second scrubbing liquid and a mixture of hydrogen and nitrogen is drawn off as overhead gas from the scrubbing column.
    Type: Grant
    Filed: May 24, 2017
    Date of Patent: May 25, 2021
    Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Bertrand Demolliens
  • Patent number: 10989078
    Abstract: Recovering heat from a Natural Gas Liquid (NGL) fractionation plant via a waste heat recovery heat exchanger network including heating a buffer fluid in a heat exchanger with a stream from the NGL fractionation plant and discharging the heated buffer fluid to an integrated triple cycle system. Generating cooling capacity for the NGL fractionation plant via the integrated triple cycle system with heat from the buffer fluid.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: April 27, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Mahmoud Bahy Mahmoud Noureldin, Akram Hamed Mohamed Kamel
  • Patent number: 10480354
    Abstract: Certain aspects of natural gas liquid fractionation plant waste heat conversion to simultaneous power and potable water using Kalina Cycle and modified multi-effect-distillation system can be implemented as a system. The system includes a waste heat recovery heat exchanger network coupled to multiple heat sources of a Natural Gas Liquid (NGL) fractionation plant. The heat exchanger network is configured to transfer at least a portion of heat generated at the multiple heat sources to a first buffer fluid and a second buffer fluid flowed through the first heat exchanger network. The system includes a first sub-system configured to generate power. The first sub-system is thermally coupled to the waste heat recovery heat exchanger. The system includes a second sub-system configured to generate potable water from brackish water. The second sub-system is thermally coupled to the waste heat recovery heat exchanger.
    Type: Grant
    Filed: December 14, 2017
    Date of Patent: November 19, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Mahmoud Bahy Mahmoud Noureldin, Akram Hamed Mohamed Kamel
  • Patent number: 10267457
    Abstract: An apparatus, system and method for capture, utilization and sendout of latent heat in boil off gas (“BOG”) onboard a cryogenic storage vessel is described. A liquefied gas vessel comprises a cryogenic cargo tank onboard a liquefied gas vessel, the cargo tank comprising a liquefied gas and a BOG, a latent heat exchanger fluidly coupled to a stream of the liquefied gas and a stream of the BOG, wherein the latent heat exchanger transfers a heat between the BOG stream and the liquefied gas stream to produce a condensed BOG, means for combining the condensed BOG and the liquefied gas stream to obtain a combined stream, the means for combining the condensed BOG and the liquefied gas stream fluidly coupled to the latent heat exchanger, and a liquefied gas regasifier onboard the vessel and fluidly coupled to the combined stream, wherein the liquefied gas regasifier regasifies the combined stream.
    Type: Grant
    Filed: September 26, 2014
    Date of Patent: April 23, 2019
    Assignee: Excelerate Energy Limited Partnership
    Inventors: Kenneth D. Nelson, Graeme David Trotter, Alan B. Nierenberg, Kenneth Hugh McGeachie
  • Patent number: 10227273
    Abstract: A process and an apparatus are disclosed for a compact processing assembly to remove C5 and heavier hydrocarbon components from a hydrocarbon gas stream. The hydrocarbon gas stream is expanded to lower pressure and supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a residual vapor stream and a condensed stream. The condensed stream is supplied to the absorbing means at its top feed point. A distillation liquid stream is collected from the lower region of the mass transfer means and directed into a second heat and mass transfer means inside the processing assembly to heat it and strip out its volatile components.
    Type: Grant
    Filed: August 28, 2017
    Date of Patent: March 12, 2019
    Assignees: Ortloff Engineers, Ltd., S.M.E. Products, LP
    Inventors: Scott A. Miller, John D. Wilkinson, Joe T. Lynch, Hank M. Hudson, Kyle T. Cuellar, Andrew F. Johnke, W. Larry Lewis
  • Patent number: 10132562
    Abstract: In a process for the cryogenic separation of a methane-rich feed stream containing between 3 and 35% of oxygen and also nitrogen, the feed stream is cooled in order to produce a cooled stream, at least one portion of the cooled stream is sent to a distillation column, a bottom stream is withdrawn from the distillation column, the bottom stream being enriched in methane compared to the feed stream, a stream enriched in oxygen compared to the feed stream is withdrawn from the distillation column, and a nitrogen-rich stream is sent to the column.
    Type: Grant
    Filed: February 8, 2012
    Date of Patent: November 20, 2018
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Golo Zick
  • Patent number: 10099168
    Abstract: Water-saturated desiccant in a dehydration unit, having previously been used to dehydrate natural gas, is regenerated in a closed loop process using liquid petroleum gas (LPG). LPG is pumped from a storage tank, vaporized and superheated. The superheated LPG gas enters the dehydration unit such that the hot gas passes over the desiccant thereby regenerating the desiccant. An overhead stream from the dehydration unit passes to a condenser where the temperature of the hot gas from the dehydration unit is dropped to form a fluid stream containing LPG, water and non-condensable gases. The fluid stream passes to a three phase separator for separating the fluid stream into a gas stream, a water stream, and a liquid stream containing LPG which is then returned to the storage tank for reuse in the closed loop process.
    Type: Grant
    Filed: March 7, 2017
    Date of Patent: October 16, 2018
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Saham Sam Tafreshi, Piyush Balkrishna Shah, Kamalkumar Ishwar Gursahani, Craig Charles Manion
  • Patent number: 10088228
    Abstract: The apparatus for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant refrigeration cycle loop incorporating heavy hydrocarbons, as well as a distillation column to remove constituents lighter than ethane.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: October 2, 2018
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Michael A. Turney, Yasser Jebbari
  • Patent number: 10006701
    Abstract: A method for operating a natural gas liquids processing (NGL) system, the system being selectively configured in either an ethane rejection configuration or an ethane recovery configuration, the method comprising, when the NGL system is in the ethane rejection configuration, collecting a reboiler bottom stream that, in the ethane rejection configuration, includes ethane in an amount of less than 5% by volume, and when the NGL system is in the ethane recovery configuration, collecting a reboiler bottom stream that, in the ethane recovery configuration, includes ethane in an amount of at least about 30% by volume.
    Type: Grant
    Filed: January 5, 2016
    Date of Patent: June 26, 2018
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Patent number: 9964352
    Abstract: Embodiments described herein provide methods and systems for separating a mixed ethane and CO2. A method described includes generating a liquid stream including ethane and CO2. The liquid stream is flashed to form an ethane vapor stream and solid CO2. The solid CO2 is accumulated in an accumulation vessel and the gas is removed from the top of the accumulation vessel.
    Type: Grant
    Filed: March 8, 2013
    Date of Patent: May 8, 2018
    Assignee: ExxonMobil Upstream Research Company
    Inventor: Russell H. Oelfke
  • Patent number: 9909803
    Abstract: A process and apparatus for separating a feed containing hydrogen, carbon monoxide, methane, and optionally nitrogen to form a product gas having a desired H2:CO molar ratio and optionally a hydrogen product gas and a carbon monoxide product gas. The feed is partially condensed to form a hydrogen-enriched vapor fraction and a carbon monoxide-enriched liquid fraction. The hydrogen-enriched vapor fraction and carbon monoxide-enriched liquid fraction are combined in a regulated manner to form an admixture, which is cryogenically separated to form the product mixture having the desired H2:CO molar ratio.
    Type: Grant
    Filed: January 18, 2016
    Date of Patent: March 6, 2018
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Brian Alfred McNeil, Andrew Weaver, David Graham Winter
  • Patent number: 9908060
    Abstract: A distillation apparatus of the present invention includes high-pressure column 1 corresponding to a region above a heat exchanging section located at a lowermost part of a region including a trayed section or a packed bed section, which is used as a rectifying section; and low-pressure column 2 that is located above as seen from high-pressure column 1, which integrates a region including a trayed section or a packed bed section which is used as a stripping section, with rectifying section corresponding portion 2g that corresponds to a region locating below the heat exchanging section located at the lowermost part in the rectifying section. Rectifying section corresponding portion 2g is located on top 2c of the stripping section in low-pressure column 2 so that rectifying section corresponding portion 2g continues to the stripping section.
    Type: Grant
    Filed: March 7, 2013
    Date of Patent: March 6, 2018
    Assignee: Toyo Engineering Corporation
    Inventors: Toshihiro Wakabayashi, Takato Nakao
  • Patent number: 9903646
    Abstract: The apparatus for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant refrigeration cycle loop incorporating heavy hydrocarbons, as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The main heat exchanger is configured to cool the first fraction before heading to the distillation column for separation therein. An expansion device expands the second fraction to produce a two phase fluid, which is separated in a gas/liquid separator, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Michael A. Turney, Paul Terrien, Yasser Jebbari
  • Patent number: 9903645
    Abstract: The process for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant loop incorporating heavy hydrocarbons (butane, and/or pentane), as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The first fraction is cooled in the main heat exchanger and introduced to the distillation column. The second fraction is expanded to produce a two phase fluid, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Michael A. Turney, Paul Terrien, Yasser Jebbari
  • Patent number: 9896394
    Abstract: A propane dehydrogenation and propylene purification process in which a stream comprising propylene, propane, and methyl acetylene and propadiene (MAPD) is mixed with a hydrogen stream then reacted in at least three distinct reaction zones in a hydrogenation reactor system where MAPD is hydrogenated by a high-selectivity hydrogenation catalyst in a first reaction zone, and a second and a third reaction zones each have a low-selectivity hydrogenation catalyst to remove unreacted hydrogen. The outlet stream leaving the hydrogenation reactor system is MAPD-free and can be fed to a splitter column, which now mainly serves to separate propylene from propane. Various embodiments of reaction zone arrangements in a single or multiple reactors are also provided.
    Type: Grant
    Filed: April 21, 2016
    Date of Patent: February 20, 2018
    Assignee: National Industrialization Company
    Inventor: Pablo Rafael Arocha
  • Patent number: 9816752
    Abstract: A system and method for removing nitrogen and producing a high pressure methane product stream from natural gas feed streams having wide variations in nitrogen and methane content are disclosed. Optional add-on systems may be incorporated into the nitrogen and methane separation to produce an NGL sales stream to reduce excess hydrocarbons in the nitrogen vent stream, or to recover helium. The system and method of the invention are particularly suitable for use with feed streams in excess of 50 MMSCFD and up to 300 MMSCFD and containing up to 100 ppm carbon dioxide. Typical power requirements for compressing the methane product stream to produce a suitably high pressure stream for sale are reduced according to the systems and methods of the invention.
    Type: Grant
    Filed: July 22, 2015
    Date of Patent: November 14, 2017
    Assignee: Butts Properties, Ltd.
    Inventor: Rayburn C. Butts
  • Patent number: 9790147
    Abstract: A process and an apparatus are disclosed for a compact processing assembly to fractionate lighter components from mixed hydrocarbon streams. The hydrocarbon stream is supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a volatile stream and a condensed stream. The condensed stream is supplied to the absorbing means as its top feed. A distillation liquid stream is collected from the lower region of the mass transfer means and heated in a second heat and mass transfer means inside the processing assembly to strip out its volatile components, forming a relatively less volatile stream and a vaporized stream. The vaporized stream is supplied to the mass transfer means as its bottom feed.
    Type: Grant
    Filed: August 18, 2014
    Date of Patent: October 17, 2017
    Assignees: Ortloff Engineers, Ltd., S.M.E. Products, LP
    Inventors: Joe T Lynch, John D. Wilkinson, Scott A. Miller, Hank M. Hudson, Kyle T. Cuellar, Andrew F. Johnke, W. Larry Lewis
  • Patent number: 9746233
    Abstract: In a process for the separation of a gas rich in carbon dioxide and containing at least one component lighter than carbon dioxide, the feed gas rich in carbon dioxide is cooled in a first heat exchanger, partially condensed and separated to form a gaseous portion and a liquid, sending the liquid portion to the top of a distillation column, removing a liquid stream richer in carbon dioxide than the feed gas from the bottom of the distillation column, removing a gaseous stream less rich in carbon dioxide than the feed gas from the top of the distillation column and warming the gaseous stream in the first heat exchanger, sending the gaseous portion to a shell and tube heat exchanger having tubes in a bath of triple point carbon dioxide, in which it condenses at least partially to form a liquid fraction, sending the liquid fraction to the top of the distillation column, vaporizing a liquid stream from the bottom of the distillation column outside or within the distillation column to form a gas which is subsequent
    Type: Grant
    Filed: July 8, 2013
    Date of Patent: August 29, 2017
    Assignee: L'Air Liquide Socieété Anonyme Pour l'Étude Et l'Exploitation Des Procedes Georges Clause
    Inventors: Alain Briglia, Arthur Darde, Paul Terrien
  • Patent number: 9638462
    Abstract: The method according to the invention comprises the separation of a feed stream (16) into a first fraction (60) and a second fraction (62) and the injection of at least part of the second fraction (62) into a second dynamic expansion turbine (46) to form a second expanded fraction (80). It comprises the cooling of the second expanded fraction (80) through heat exchange with at least part of the first headstream (84) coming from a first column (28) and the formation of a second feed stream (82) of the first column (28) from the second cooled expanded fraction.
    Type: Grant
    Filed: January 6, 2012
    Date of Patent: May 2, 2017
    Assignee: Technip France
    Inventors: Julie Gouriou, Vanessa Gahier, Sandra Thiebault, Loic Barthe
  • Patent number: 9423175
    Abstract: A natural gas liquids plant uses a demethanizer and a deethanizer in a two-column or single column configuration that can be used for ethane recovery and ethane rejection. During ethane recovery, 95% ethane recovery and 99% propane recovery are achieved, while during ethane rejection the sales gas Wobbe Index requirement is maintained while maintaining 95% propane recovery. A residue gas recycle exchanger is most preferably configured to use the demethanizer overhead product to either cool a portion of the residue gas and a portion of the feed gas during ethane recovery, or to cool a portion of the feed gas using two distinct heat transfer areas to produce a feed gas reflux at significantly lower temperature.
    Type: Grant
    Filed: March 13, 2014
    Date of Patent: August 23, 2016
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Patent number: 9389015
    Abstract: Described herein is a method for separating C2+-hydrocarbons or C3+-hydrocarbons from a hydrocarbon-rich fraction is described, whereby the separation is carried out in a rectification fractionation. The rectification fractionation is provided with at least three heating circuits via which intermediate fractions are drawn off from rectification fractionation, partially evaporated and fed back again to rectification fractionation. In the method, removal of the intermediate fraction circulating in the heating circuit located at the highest temperature level is at least temporarily interrupted. During this interruption, a partial stream of a bottom fraction from the rectification fractionation is partially evaporated against an external medium and is fed as a bottom heating to the rectification fractionation.
    Type: Grant
    Filed: September 3, 2013
    Date of Patent: July 12, 2016
    Assignee: LINDE AKTIENGESELLSCHAFT
    Inventors: Rainer Sapper, Jurgen Witte
  • Patent number: 9278295
    Abstract: A distillation apparatus includes a rectifying column, a stripping column, a first pipe that communicates a column top of the stripping column with a column bottom of the rectifying column, and a compressor configured to compress vapor from the stripping column and then to feed the compressed vapor to the rectifying column. The distillation apparatus further includes a heat exchanger located at a predetermined stage of the rectifying column, a liquid withdrawal unit located at a predetermined stage of the stripping column and configured to withdraw a part of liquid from the predetermined stage to an outside of the column, a second pipe that introduces the liquid from the liquid withdrawal unit to the heat exchanger, and a third pipe that introduces fluids introduced through the second pipe to the heat exchanger and then discharged out of the heat exchanger to a stage directly below the liquid withdrawal unit.
    Type: Grant
    Filed: February 20, 2013
    Date of Patent: March 8, 2016
    Assignee: TOYO ENGINEERING CORPORATION
    Inventors: Toshihiro Wakabayashi, Takato Nakao
  • Patent number: 9266034
    Abstract: A distillation apparatus includes a rectifying column, a stripping column located above seen from the rectifying column, a liquid sump unit located at a predetermined stage of the stripping column and configured to hold liquid that has flowed downward, a heat exchanger located in the liquid sump unit, a second pipe for introducing vapor in the rectifying column to the heat exchanger of the stripping column, and a third pipe for introducing fluids flowing out from the heat exchanger of the stripping column to the rectifying column. Further, a flare line having lower pressure than pressure in the rectifying column is connected to a downstream side of the third pipe. The distillation apparatus can switch a first flow toward an inside of the rectifying column through the third pipe to a second flow branching from the third pipe toward a pipe at a lower pressure side.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: February 23, 2016
    Assignee: TOYO ENGINEERING CORPORATION
    Inventors: Toshihiro Wakabayashi, Takato Nakao
  • Patent number: 9239186
    Abstract: Provided is a method for operating a fuel supply system for a marine structure. The fuel supply system includes a BOG compression unit configured to receive and compress BOG generated in a storage tank, a reliquefaction apparatus configured to receive and liquefy the BOG compressed by the BOG compression unit, a high-pressure pump configured to compress the liquefied BOG generated by the reliquefaction apparatus, and a high-pressure gasifier configured to gasify the liquefied BOG compressed by the high-pressure pump. The fuel supply system includes a recondenser installed at an upstream side of the high-pressure pump, and the recondenser recondenses a portion or all of the generated BOG by using liquefied gas supplied from the storage tank. During a ballast voyage process, all of the BOG is supplied to and recondensed by the recondenser, and an operation of the reliquefaction apparatus is interrupted.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: January 19, 2016
    Assignee: DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD.
    Inventors: Seung Kyo Jung, Je Heon Jung, Jung Han Lee, Hyun Jun Shin, Sung Jun Lee, Dong Kyu Choi
  • Patent number: 9021832
    Abstract: A process and an apparatus are disclosed for recovering ethane, ethylene, and heavier hydrocarbon components from a hydrocarbon gas stream. The stream is cooled, expanded to lower pressure, and supplied to a first fractionation tower at a mid-column feed position. A distillation liquid stream is withdrawn from the first fractionation tower below the feed position of the expanded stream, heated, and directed into a second fractionation tower that produces an overhead vapor stream and a bottom liquid stream. The overhead vapor stream is cooled to condense it, with a portion of the condensed stream directed to the second fractionation tower as its top feed and the remainder directed to the first fractionation tower at a lower column feed position. The bottom liquid stream from the second fractionation tower is cooled and directed to the first fractionation tower as its top feed.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: May 5, 2015
    Assignee: Ortloff Engineers, Ltd.
    Inventors: Michael C. Pierce, John D. Wilkinson, Hank M. Hudson
  • Patent number: 9021831
    Abstract: A process and an apparatus are disclosed for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbon components from a hydrocarbon gas stream in a compact processing assembly. The gas stream is cooled and divided into first and second streams. The first stream is further cooled to condense substantially all of it and is thereafter expanded to lower pressure and supplied as the top feed to an absorbing means inside the processing assembly. The second stream is also expanded to lower pressure and supplied as the bottom feed to the absorbing means. A distillation vapor stream is collected from the upper region of the absorbing means and directed into one or more heat exchange means inside the processing assembly to heat it while cooling the gas stream and the first stream.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: May 5, 2015
    Assignees: Ortloff Engineers, Ltd., S.M.E. Products LP
    Inventors: Andrew F. Johnke, Larry Lewis, John D. Wilkinson, Joe T. Lynch, Hank M. Hudson, Kyle T. Cuellar
  • Publication number: 20150114035
    Abstract: In a process for the cryogenic separation of a feed mixture of at least carbon monoxide, hydrogen and methane, the feed mixture is separated in a methane wash column fed by a liquid methane stream at the top of the methane wash column to produce a gas enriched in hydrogen, a liquid stream from the bottom of the methane wash column is treated to produce a mixture of carbon monoxide and methane, the mixture of carbon monoxide and methane is separated in a separation column to produce a gas enriched in carbon monoxide and a liquid methane flow at least part of which forms a purge stream, the purge stream being varied to take account of load variations.
    Type: Application
    Filed: April 29, 2013
    Publication date: April 30, 2015
    Inventors: Alain Briglia, Emmanuelle Brocheriou, Pascal Marty, Bhadri Prasad
  • Patent number: 9016088
    Abstract: A system and method for removing nitrogen and producing liquefied natural gas (“LNG”) from methane without the need for external refrigeration. The invention also relates to a system and method for removing nitrogen from methane and for producing liquefied nitrogen in addition to LNG. The system and method of the invention are particularly suitable for use in recovering and processing comparatively small volumes of methane from coal mines or from flash gas captured at an LNG loading site.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: April 28, 2015
    Assignee: Butts Propertties, Ltd.
    Inventor: Rayburn C. Butts
  • Patent number: 9003829
    Abstract: The invention relates to a method for the separation of a hydrocarbon-rich, nitrogen-containing feed fraction (1, 101), preferably natural gas, wherein the feed fraction (1, 101) is at least in part liquefied (E1, E2) and divided by rectification (T1) into a nitrogen-enriched fraction (14, 110) and a hydrocarbon-rich, nitrogen-depleted fraction (11, 111) and wherein, in the upper region of the rectification (T1), a nitrogen-enriched stream (14) is taken off, cooled (E3) and applied (20) at least in part to the rectification (T1) as reflux and/or the nitrogen-enriched fraction (110) is cooled and partially condensed (E3), applied at least in part to the rectification (T1) as reflux (115) and the remaining stream (116) of the nitrogen-enriched fraction (110) is subjected to a double-column process (T3).
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: April 14, 2015
    Assignee: Linde Aktiengesellschaft
    Inventors: Heinz Bauer, Martin Gwinner, Daniel Garthe
  • Patent number: 8997519
    Abstract: A method and device for the cryogenic separation of a methane-rich flow is provided.
    Type: Grant
    Filed: June 6, 2008
    Date of Patent: April 7, 2015
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Pierre Briend
  • Publication number: 20150073195
    Abstract: A process and an apparatus are disclosed for a compact processing assembly to fractionate lighter components from mixed hydrocarbon streams. The hydrocarbon stream is supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a volatile stream and a condensed stream. The condensed stream is supplied to the absorbing means as its top feed. A distillation liquid stream is collected from the lower region of the mass transfer means and heated in a second heat and mass transfer means inside the processing assembly to strip out its volatile components, forming a relatively less volatile stream and a vaporized stream. The vaporized stream is supplied to the mass transfer means as its bottom feed.
    Type: Application
    Filed: August 18, 2014
    Publication date: March 12, 2015
    Inventors: Joe T. Lynch, John D. Wilkinson, Scott A. Miller, Hank M. Hudson, Kyle T. Cuellar, Andrew F. Johnke, W. Larry Lewis
  • Publication number: 20150073194
    Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the expanded first stream is heated to form a vapor fraction and a liquid fraction. The vapor fraction is combined with the tower overhead vapor, directed to a heat and mass transfer means inside a processing assembly, and cooled and partially condensed by the expanded first stream to form a residual vapor stream and a condensed stream. The condensed stream is combined with the liquid fraction and supplied to the tower at its top feed point.
    Type: Application
    Filed: August 18, 2014
    Publication date: March 12, 2015
    Inventors: Hank M. Hudson, John D. Wilkinson, Joe T. Lynch, Scott A. Miller, Kyle T. Cuellar, Andrew F. Johnke, W. Larry Lewis
  • Publication number: 20150052941
    Abstract: Fractionation systems utilizing a single rectifying column with a stripping column housed in the same vessel and having a uniform diameter are described. Methods of separating feed streams using the fractionation systems are also described.
    Type: Application
    Filed: September 30, 2013
    Publication date: February 26, 2015
    Applicant: UOP LLC
    Inventors: Stephen T. King, Steven Kozup, Xin X. Zhu
  • Publication number: 20150052940
    Abstract: Fractionation systems utilizing a rectifying column with a stripping column are described. The liquid from the rectifying column bottoms is sent to the first tray of the stripping column, while the overhead stream from the stripping column is sent to the bottom of the rectifying column. Processes for separating feed streams are also described.
    Type: Application
    Filed: September 30, 2013
    Publication date: February 26, 2015
    Applicant: UOP LLC
    Inventors: Stephen T. King, Steven Lankton, Xin X. Zhu
  • Publication number: 20150047391
    Abstract: A system and process for separating ethane and propane from a feed stream comprising dehydrated liquefied petroleum gas is disclosed. A distillation column operates at a lower pressure and temperature than conventional distillation columns. High purity liquid propane exits the bottom of the distillation column and is flashed through a cooling control valve becoming a two-phase stream with the vapor entering a heat pump compressor. The high or increased temperature compressed propane stream exiting the heat pump compressor is directed into the distillation column to drive the separation of the ethane and propane, allowing the elimination of a reboiler from the system and process.
    Type: Application
    Filed: August 13, 2014
    Publication date: February 19, 2015
    Applicant: S & B ENGINEERS AND CONSTRUCTORS, LTD.
    Inventors: Guy S. Suffridge, Sean C. Gattis, Marshall J. Fullwood
  • Patent number: 8955354
    Abstract: Methods and systems are provided for treating hydrogen sulfide rich sour gas through a series of fractionation columns. The processes disclosed herein and the variations thereof provide optimized processes for the removal of hydrogen sulfide from sour gas through the introduction of innovative azeotrope breakers, novel configurations of process equipment, and optimized operating conditions. Advantages of certain embodiments of the present invention include reduced equipment requirements, improved process efficiencies, reduced operating costs, and reduced capital costs. Other advantages include better process suitability to certain environmental conditions such as the arctic cold when compared to conventional amine treatment processes.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: February 17, 2015
    Assignee: ConocoPhillips Company
    Inventors: Shawn S. Huang, Douglas Elliot, Jame Yao, Wei Yan, Naushad A. Kassamali, Mark S. Elkins
  • Patent number: 8956428
    Abstract: A process for treating offshore natural gas includes processing the natural gas on an off-shore processing facility by, (i) liquefying and fractionating the natural gas to generate a liquefied natural gas stream and a higher hydrocarbon stream, (ii) vaporizing at least a portion of the higher hydrocarbon stream, (iii) passing the vaporized higher hydrocarbon stream and steam over a steam reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon oxides and hydrogen, (iv) passing the reformed gas mixture over a methanation catalyst to generate a methane rich gas, and (v) combining the methane-rich gas with the natural gas prior to the liquefaction step.
    Type: Grant
    Filed: June 15, 2009
    Date of Patent: February 17, 2015
    Assignee: Johnson Matthey PLC
    Inventors: Peter John Herbert Carnell, Ginny Yuen Che Ng