Upstream Operation Patents (Class 62/644)
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Patent number: 11092292Abstract: In a method for reheating an atmospheric vaporizer, a cryogenic liquid is vaporized by heat exchange with ambient air in the atmospheric vaporizer and to reheat the vaporizer, a gas is sent thereto at a temperature of at least 0° C., this gas originating from a cryogenic distillation air separation unit.Type: GrantFiled: February 21, 2020Date of Patent: August 17, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Marc Peyron, Fabrice Rivoal, Lian-Ming Sun
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Patent number: 10964436Abstract: A system for injecting hydrogen into Boiling Water Reactor (BWR) reactor support systems in operation during reactor startup and/or shutdown. The system the hydrogen injection system includes at least one hydrogen source, flow control equipment, and pressure control equipment. The pressure control equipment being configured to regulate a pressure of a hydrogen flow between the at least one hydrogen source and the at least one first BWR support system based upon an operating pressure of the at least one first BWR support system.Type: GrantFiled: January 3, 2019Date of Patent: March 30, 2021Assignee: GE-Hitachi Nuclear Energy Americas LLCInventors: John C Whittaker, Angelo Foz Gonzaga, Paul Y Shu, Luong C Tran
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Patent number: 10690408Abstract: A method and device to variably obtain argon by means of low-temperature separation. Feed air is cooled in a main heat exchanger and then conducted into a distillation column system with a high-pressure column and a low-pressure column. Argon is obtained using a crud argon column and a purified argon column. A purified liquid argon product flow is generated from an argon-enriched flow from the low-pressure column. In a first operating mode, a first quantity of purified argon product is discharged, and in a second operating mode, a reduced quantity of purified argon product is discharged. In the second operating mode, a gaseous argon return flow is drawn from the crude argon column or the purified argon column and heated in a separate passage of the main heat exchanger.Type: GrantFiled: September 23, 2015Date of Patent: June 23, 2020Assignee: LINDE AKTIENGESELLSCHAFTInventor: Stefan Lochner
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Patent number: 10684071Abstract: An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall and radially spaced therefrom to define an annulus column region as the space between the first annular column wall and the second annular column wall. An interior core column region is also defined by the interior space of the second annular column wall. The present annular divided wall column further includes a plurality of packing elements, plurality of trays or a heat exchange device disposed within the interior core column region; and a plurality of packing elements disposed within the annulus column region.Type: GrantFiled: July 23, 2018Date of Patent: June 16, 2020Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Kirk F. Larson, Paul W. Belanger, Steven C. Brown, John P. Ricotta, Guang X. Chen, Richard D. Lenz
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Patent number: 10605410Abstract: In a method for reheating an atmospheric vaporizer, a cryogenic liquid is vaporized by heat exchange with ambient air in the atmospheric vaporizer and to reheat the vaporizer, a gas is sent thereto at a temperature of at least 0° C., this gas originating from a cryogenic distillation air separation unit.Type: GrantFiled: January 4, 2018Date of Patent: March 31, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Marc Peyron, Fabrice Rivoal, Lian-Ming Sun
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Patent number: 10578356Abstract: An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.Type: GrantFiled: July 23, 2018Date of Patent: March 3, 2020Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Kevin J. Saboda, Paul W. Belanger, Richard D. Lenz, Kirk F. Larson, Steven C. Brown, John P. Ricotta, Guang X. Chen, Jeremy D. Faust
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Patent number: 10578355Abstract: An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.Type: GrantFiled: July 23, 2018Date of Patent: March 3, 2020Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Kevin J. Saboda, Paul W. Belanger, Richard D. Lenz, Kirk F. Larson, Steven C. Brown, John P. Ricotta, Guang X. Chen, Jeremy D. Faust
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Patent number: 10578357Abstract: An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.Type: GrantFiled: July 23, 2018Date of Patent: March 3, 2020Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Kevin J. Saboda, Paul W. Belanger, Richard D. Lenz, Kirk F. Larson, Steven C. Brown, John P. Ricotta, Guang X. Chen, Jeremy D. Faust
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Patent number: 9574821Abstract: A system and method for separating air in an air separation plant is provided. The disclosed systems and methods divert a portion of the compressed, purified air stream to a bypass system configured to selectively produce a higher pressure compressed output stream or a lower pressure compressed output stream. The higher pressure and/or lower pressure compressed output streams are cooled in a main heat exchanger by indirect heat transfer with a plurality of product streams from the air separation plant and then rectified in the distillation column system. A second portion of the compressed, purified air stream is partially cooled in the main heat exchanger and expanding in a turbo-expander to produce power and an exhaust stream which is directed to the distillation column system of the air separation plant where it imparts additional refrigeration generated by the expansion of the compressed air stream in the turbo-expander.Type: GrantFiled: June 2, 2014Date of Patent: February 21, 2017Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Jeremiah J. Rauch, Sophia J. Dowd, Andrew M. Warta, Catherine B. Sarigiannis, Wei Zhang
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Publication number: 20150114037Abstract: A method and apparatus for separating air in which an oxygen-rich liquid stream is pumped and then heated within a heat exchanger to produce an oxygen product through indirect heat exchange with first and second boosted pressure air streams. The first boosted pressure air stream is cold compressed at an intermediate temperature of the heat exchanger, reintroduced into the heat exchanger at a warmer temperature and then fully cooled and liquefied. The second boosted pressure air stream, after having been partially cooled, is expanded to produce an exhaust stream that is in turn introduced into a lower pressure column producing the oxygen-rich liquid. The second boosted pressure air stream is partially cooled to a temperature no greater than the intermediate temperature at which the cold compression occurs so that both the first and second boosted pressure air streams are able to take part in the heating of the oxygen-rich stream.Type: ApplicationFiled: October 25, 2013Publication date: April 30, 2015Inventor: Neil M. Prosser
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Patent number: 8997520Abstract: A method of producing at least one air gas using cryogenic distillation is provided. The expanded streams coming from the two turbines are combined and then split into two fractions. The first fraction is sent to the medium-pressure column of the system in gaseous form, whereas the second fraction is returned to the cold end of the heat exchange line. At a temperature T4 below ?100° C. and above T2, the second fraction is sent to a turbine where it expands up to a temperature T5, forming an air stream. This air stream is then warmed in the heat exchange line before being discharged into the atmosphere, so that the distillation is not disturbed. A liquid product is withdrawn from the column system as final product. The sole liquid product from the apparatus is liquid oxygen, but of course other products may be produced.Type: GrantFiled: February 26, 2008Date of Patent: April 7, 2015Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alain Guillard, Patrick Le Bot, Xavier Pontone
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Patent number: 8820115Abstract: A method and apparatus for producing an oxygen product in which air is separated in an installation including air separation units having higher and lower pressure columns. A pumped liquid stream generated within the installation, that can be a pumped liquid oxygen stream, is warmed within a main heat exchanger through indirect heat exchange with a compressed air stream to produce a liquid air stream. An impure oxygen stream is rectified within an auxiliary column to produce an oxygen containing stream that is introduced into the lower pressure column of each of the air separation units and intermediate liquid streams, composed of the liquid air stream or another air-like stream, reflux the lower pressure columns and the auxiliary column and optionally the higher pressure column of each of the air separation units.Type: GrantFiled: December 10, 2009Date of Patent: September 2, 2014Assignee: Praxair Technology, Inc.Inventors: Henry Edward Howard, Richard John Jibb
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Publication number: 20140223960Abstract: The invention relates to a method and device for generating two purified partial air streams under different pressures. A total air stream (1) is compressed to a first total air pressure. The compressed total air stream (5) is cooled with cooling water under the first total air pressure by way of heat exchange (4, 6). The heat exchange with cooling water for cooling the total air stream (5) is carried out as a direct heat exchange in a first direct contact cooler (6), at least in part. The cooled total air stream (9) is divided into a first partial air stream (10) and a second partial air stream (11). The first partial air stream (10) is purified in a first purification device (18) under the first total air pressure, generating the first purified partial air stream (19). The second partial air stream (11) is re-compressed to a higher pressure (12), which is higher than the first total air pressure.Type: ApplicationFiled: September 20, 2012Publication date: August 14, 2014Applicant: LINDE AKTIENGESELLSCHAFTInventors: Alexander Alekseev, Dimitri Goloubev
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Patent number: 8776546Abstract: An air distillation unit comprises an air distillation column (10) suitable for producing a nominal flow of gaseous nitrogen, the top of said column being connected to a liquid nitrogen source (8), and operates by carrying out the following steps: a flow of compressed, cooled and purified air is sent to an exchanger (11) and then to the column, a flow of gaseous nitrogen is withdrawn from the column, the level of liquid at the bottom of the column is controlled; and injection liquid (20), sent from the source to the column, is no longer sent if the required production reduces to at most the nominal production. Application to the separation of air by cryogenic distillation.Type: GrantFiled: June 19, 2007Date of Patent: July 15, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Benoit Davidian, Pierre Bodelin
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Patent number: 8769985Abstract: A compressed air stream is cooled in an exchanger to form a compressed cooled air stream. The stream is then cryogenically compressed in a first compressor to form a first pressurized gas stream. The first pressurized gas stream is further cooled in the exchanger, cryogenically compressed in a second compressor, and then it is cooled and partially liquefied. The cooled and partially liquefied product is then fed to a system of distillation columns. A liquid product is removed from the system of distillation columns. This product is then pressurized, vaporized and warmed in the exchanger to yield pressurized gaseous product.Type: GrantFiled: July 12, 2005Date of Patent: July 8, 2014Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procédés Georges ClaudeInventors: Jean-Renaud Brugerolle, Bao Ha
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Patent number: 8739557Abstract: A system and method according to which ice is automatically disposed in respective bags and the bags of ice are distributed and stacked within a temperature-controlled storage unit, such as an ice merchandiser.Type: GrantFiled: October 28, 2010Date of Patent: June 3, 2014Assignee: Reddy Ice CorporationInventor: Mark C. Metzger
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Patent number: 8726691Abstract: The present invention relates to an air separation apparatus and method in which a pumped liquid oxygen stream is heated within a heat exchanger through indirect heat exchange with compressed air to produce an oxygen product. The liquid oxygen stream is pressurized in a range above about 55 bar(a) and no greater than about 150 bar(a) and is a supercritical fluid after having been heated within the heat exchanger. The air is compressed to an air pressure that is a function of the oxygen pressure that will result in a minimum power being expended in the compression of the air. The heat exchanger can be a brazed fin heat exchanger fabricated from aluminum in which the fins located in heat exchange passages have an undulating configuration to increase the flow path length and induce flow separation and thereby increase the heat transfer coefficient within the heat exchanger.Type: GrantFiled: July 23, 2010Date of Patent: May 20, 2014Assignee: Praxair Technology, Inc.Inventors: Richard John Jibb, Maulik R. Shelat, Lyda Zambrano
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Patent number: 8713964Abstract: The invention relates to a cryogenic distillation apparatus for a gas mixture, including a purification apparatus for purifying a gas mixture in a system with a plurality of adsorbant bottles, a column system, a capacity, means for feeding a cryogenic liquid to the capacity, means for feeding a vaporized liquid from the capacity to a column of the system, a vaporizer in the capacity for vaporizing the contained liquid; means for feeding a calorigenic gas to the vaporizer, and means for drawing a liquid from the capacity.Type: GrantFiled: December 18, 2007Date of Patent: May 6, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Nerve Le Bihan, Jean-Marc Peyron
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Patent number: 8695377Abstract: A process for producing a gaseous component of air under pressure by cryogenic separation is provided.Type: GrantFiled: August 10, 2007Date of Patent: April 15, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Frédéric Bachelier, Shao-Hua Sun
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Patent number: 8640496Abstract: Air separation method in which air is separated within cryogenic rectification processes conducted in first and second cryogenic air separation plants. The first cryogenic air separation plant is designed to produce an oxygen-rich product stream and the second cryogenic air separation plant is designed to produce an impure oxygen vapor stream. At least part of the impure oxygen vapor stream is introduced into a lower pressure column of the first cryogenic air separation plant and oxygen contained in such stream along with air separated within the first air separation plant is used in producing the oxygen-rich product stream.Type: GrantFiled: August 21, 2008Date of Patent: February 4, 2014Assignee: Praxair Technology, Inc.Inventor: Henry Edward Howard
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Patent number: 8549878Abstract: There is provided a method of generating nitrogen which includes cryogenically separating compressed air introduced into a high-pressure column 11, storing liquid air 13 in a bottom portion of the high-pressure column 11 and taking nitrogen in gaseous form from an upper portion of the high-pressure column 11, introducing the liquid air 13 stored in the bottom portion of the high-pressure column 11 into a low-pressure column 12, cryogenically separating the liquid air 13 introduced into the low-pressure column 12 and storing oxygen-enriched liquid air 22 in a bottom portion of the low-pressure column 12 and taking nitrogen in gaseous form from an upper portion of the low-pressure column 12 as a product gas. Liquid air 13 taken through an extraction pipe 20 is introduced into a portion of a rectification part 12a of the low-pressure column 12 in which the number of theoretical plates from a column bottom side is set within the range of one to ten.Type: GrantFiled: June 16, 2006Date of Patent: October 8, 2013Assignee: Air Water Inc.Inventors: Akira Yoshino, Koji Tanaka, Ryosuke Matsubayashi, Junya Suenaga, Shinya Okumura
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Patent number: 8443625Abstract: A method of separating air in which a superheated air stream is introduced into a mass transfer contacting zone associated with a higher pressure column of an air separation unit. Krypton and xenon is washed from a superheated air stream introduced into the mass transfer contacting zone, thereby to form a krypton and xenon-rich liquid. The krypton and xenon-rich liquid is stripped within a stripping column to produce a krypton-xenon-rich bottoms liquid. A krypton-xenon-rich stream composed of the krypton-xenon-rich bottoms liquid from the stripping column is produced for purposes of further refinement.Type: GrantFiled: August 14, 2008Date of Patent: May 21, 2013Assignee: Praxair Technology, Inc.Inventors: Neil Mark Prosser, John Bernard Saunders
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Publication number: 20130047666Abstract: The invention relates to a method and device for obtaining pressurized nitrogen and pressurized oxygen by low-temperature separation of air. Compressed and purified feed air is cooled down in a main heat exchanger and introduced into a distillation column system comprising at least one high-pressure column and one low-pressure column. The distillation column system for nitrogen-oxygen separation in addition contains a residual gas column operating at a pressure which is lower than the operating pressure of the low-pressure column. A liquid crude oxygen fraction from the high-pressure column (50) is expanded and passed to the residual gas column at a first intermediate point. A gaseous impure nitrogen stream from the low-pressure column is introduced into a bottoms evaporator of the residual gas column and there is at least partly liquefied. The at least partly liquefied impure nitrogen stream is expanded and introduced into the upper region of the residual gas column.Type: ApplicationFiled: July 26, 2012Publication date: February 28, 2013Applicant: LINDE AKTIENGESELLSCHAFTInventor: Alexander ALEKSEEV
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Publication number: 20130042647Abstract: The present invention is an improved process for producing elevated pressure nitrogen. This method includes providing an air separation unit with at least two columns, an LP column and an MP column, and cooling a compressed feed air stream in a heat exchanger, then expanding the resulting cooled feed air stream in an expander, thereby producing a quantity of work and a cooled inlet air stream, feeding the cooled inlet air stream into the LP column. Then extracting a nitrogen stream from the MP column, and warming a first portion of the nitrogen stream in the heat exchanger, thereby producing a product nitrogen stream. Then compressing a second portion of the nitrogen stream in a compressor, thereby producing medium pressure nitrogen stream, and introducing the medium pressure nitrogen stream into an LP column vaporizer. Then extracting a second nitrogen stream from the LP column, and cooling the second nitrogen stream in a condenser thereby producing a liquid nitrogen stream.Type: ApplicationFiled: August 18, 2011Publication date: February 21, 2013Applicant: Air Liquide Process & Construction, Inc.Inventor: Paul Musicus
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Publication number: 20120260693Abstract: A compression method, a multistage compression system incorporating such method and an air separation method and plant utilizing such compression method and system in which a gas is compressed in a series of compression stages to produce a compressed gas and each of the compression stages incorporate a variable speed compressor. In such compression method and system, the compressed air is produced at a pressure that remains stable during both normal operational conditions and during turn down conditions during which the flow rate of the gas is reduced. This reduction is accomplished by reducing the speed of the compressor in an initial compression stage such that the compressor operates along a peak efficiency operating line at which the pressure ratio is directly proportional to the flow rate and such that the lower turn down flow rate is obtained at a reduced pressure which is made up in successive compression stages.Type: ApplicationFiled: April 15, 2011Publication date: October 18, 2012Inventors: Daniel D. DeMore, Robert L. Baker, John H. Royal
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Patent number: 8286446Abstract: Method and apparatus of separating an oxygen and nitrogen containing feed stream, for example, air, in higher and lower pressure columns. A crude liquid oxygen stream condenses nitrogen vapor in the higher pressure column for reflux purposes and results in the partial vaporization of the crude liquid oxygen stream to produce vapor and liquid fractions thereof. The liquid fraction condenses a lower pressure part of the feed stream and results in the liquid fraction being at least partially vaporized. Both the vapor fraction of the crude liquid oxygen stream and the liquid fraction after having been at least partially vaporized are introduced into the lower pressure column. Boil-up is produced within a bottom region of the lower pressure column by partially vaporizing an oxygen-rich liquid column bottoms against condensing a higher pressure part of the feed stream and then utilizing vapor or residual liquid as an oxygen product.Type: GrantFiled: May 7, 2008Date of Patent: October 16, 2012Assignee: Praxair Technology, Inc.Inventors: Henry Edward Howard, Richard John Jibb, Kirk Frederick Larson
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Publication number: 20120125045Abstract: A method and apparatus for separating air in which an argon refining column of a distillation column system is reboiled with a liquid air stream. The argon refining column further refines crude argon produced by a crude argon column connected to a lower pressure column of the distillation column system. At least one intermediate reflux stream is formed, at least indirectly, from at least part of the liquid air stream, and is introduced into the lower pressure column at a level thereof above where a crude liquid oxygen column bottoms of a higher pressure column of such system is further refined to increase a liquid to vapor ratio below said level and therefore, argon recovery from the argon refining column.Type: ApplicationFiled: November 18, 2010Publication date: May 24, 2012Inventor: Henry Edward Howard
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Patent number: 8136369Abstract: A hybrid system which utilizes high purity oxygen from a local pipeline, which is blended with low purity oxygen from an on-site or local cryogenic distillation system, thus resulting in a blend of intermediate quality which satisfies the needs of the customer. In order to offset the operating and energy costs associated with this fairly low profit margin intermediate purity oxygen, high purity nitrogen at high pressure is simultaneously exported to the local pipeline, thereby acting as a credit to the overall system.Type: GrantFiled: August 8, 2006Date of Patent: March 20, 2012Assignees: L'Air Liquide Societe Anonyme pour L'Etude, et l'Exploitation des Procedes Georges Claude, Air Liquide Process and Construction, Inc.Inventors: Jean-Renaud Brugerolle, Bao Ha
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Publication number: 20110214453Abstract: The process and the device serve for cryogenic air fractionation, in particular for supplying an oxygen-enriched (product stream to an oxyfuel power plant. The distillation column system for nitrogen/oxygen separation has a high-pressure column (26) and a low-pressure column (32). The high-pressure column (26) and the low-pressure column (32) are thermally coupled via a condenser-evaporator (37). Feed air (1) is compressed in an air compressor (3), cooled at least in a first post-cooler (6) and purified in a purification device (22), cooled in a main heat exchanger (23a, 23b, 23c) and introduced at least in part (25, 29) into the high-pressure column (26). At least one liquid stream (33, 35) is introduced from the high-pressure column (26) into the low-pressure column (32). An oxygen-enriched product stream (41, 45, 46,47, 48) is taken off from the low-pressure column (32).Type: ApplicationFiled: August 11, 2009Publication date: September 8, 2011Applicant: LINDE AKTIENGESELLSCHAFTInventor: Alexander Alekseev
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Publication number: 20110197630Abstract: A process and apparatus for the separation of air by cryogenic distillation is provided.Type: ApplicationFiled: August 10, 2007Publication date: August 18, 2011Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'E XPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Alain Guillard, Lasad Jaouani, Xavier Pontone
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Publication number: 20110192194Abstract: A method and apparatus for separating a mixture, for example air, within a cryogenic rectification plant that utilizes a banked heat exchanger arrangement. In such arrangement, a lower pressure heat exchanger is used to cool part of the mixture and a higher pressure heat exchanger is used to heat one or more pumped liquid streams composed of separated nitrogen-rich and oxygen-rich fractions and thereby produce pressurized product streams. A boosted pressure stream, that can be part of the air, is utilized to supply most of the heat exchange duty in the higher pressure heat exchanger. In addition, a heat exchange stream, that can also be part of the mixture, can be partially cooled in the higher pressure heat exchanger and then further cooled in the lower pressure heat exchanger to decrease the warm end temperature difference of the higher pressure heat exchanger and therefore, the required refrigeration for the plant.Type: ApplicationFiled: February 11, 2010Publication date: August 11, 2011Inventor: Henry Edward Howard
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Publication number: 20110146343Abstract: A process for the cryogenic separation of air using a multiple column distillation system comprising at least a higher pressure column (“HP column”) and a lower pressure column (“LP column”), comprising: feeding cooled feed air to the high pressure column for separation into high pressure nitrogen-enriched overhead vapor and crude liquid oxygen; feeding at least one low pressure column feed stream comprising nitrogen and oxygen to the low pressure column for separation into nitrogen-rich overhead vapor and liquid oxygen; refluxing the low pressure column with a liquid stream from or derived from the high pressure column; feeding expanded air to an auxiliary separation column for separation into auxiliary column nitrogen-rich overhead vapor and oxygen-rich liquid and removing the nitrogen rich overhead vapour as a product stream; feeding bottom liquid from the auxiliary column to an intermediate location of the low pressure column; and refluxing the auxiliary column with a nitrogen rich liquid stream from or dType: ApplicationFiled: December 17, 2009Publication date: June 23, 2011Applicant: Air Liquide Process and Construction, Inc.Inventors: Bao Ha, Jean-Renaud Brugerolle
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Publication number: 20110138855Abstract: A method and apparatus for producing an oxygen product in which air is separated in an installation including air separation units having higher and lower pressure columns. A pumped liquid stream generated within the installation, that can be a pumped liquid oxygen stream, is warmed within a main heat exchanger through indirect heat exchange with a compressed air stream to produce a liquid air stream. An impure oxygen stream is rectified within an auxiliary column to produce an oxygen containing stream that is introduced into the lower pressure column of each of the air separation units and intermediate liquid streams, composed of the liquid air stream or another air-like stream, reflux the lower pressure columns and the auxiliary column and optionally the higher pressure column of each of the air separation units.Type: ApplicationFiled: December 10, 2009Publication date: June 16, 2011Inventors: Henry Edward Howard, Richard John Jibb
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Publication number: 20100242537Abstract: The process and the apparatus in accordance with the invention relate to cryogenic separation of air in a distillation column system that has at least one single column (12). A compressed feed air stream (6, 8) is cooled in a main heat exchanger (9) in counter-current flow to a first return stream (16, 23) from the distillation column system. Cooled feed air stream (11) is fed into the distillation column system. A nitrogen-rich fraction (15) is produced in the upper region of the single column (12). At least part (16b) of the nitrogen-rich fraction (15) is condensed in a top condenser (13), which is constructed as a condenser-evaporator. At least part (54) of the liquid nitrogen-rich fraction (52) produced in the top condenser (13) is fed into the single column (12) as reflux. An oxygen-containing recycle fraction (18a) is drawn off from the single column (12) in liquid form. The liquid recycle fraction (18a) is cooled in a counter-current subcooler (100).Type: ApplicationFiled: March 24, 2010Publication date: September 30, 2010Applicant: LINDE AGInventor: Stefan LOCHNER
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Publication number: 20100180633Abstract: Apparatus for treating a gaseous hydrocarbon fraction to obtain a gaseous fraction and a liquid fraction which apparatus comprises a shell-and-tube heat exchanger and a distillation column, wherein the shell-and-tube heat exchanger comprises an inlet and an outlet for cooling fluid which inlet and outlet are in fluid communication with the tube side of the heat exchanger, and an inlet for the gaseous hydrocarbon fraction at the upper end of the heat exchanger which inlet is in fluid communication with the shell side of the heat exchanger, and a conduit for guiding hydrocarbons from the heat exchanger to the distillation column which distillation column comprises an outlet for gas at its upper end and an outlet for liquid at its lower end, and process in which such apparatus is used.Type: ApplicationFiled: December 4, 2009Publication date: July 22, 2010Inventor: George ANDERSON
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Publication number: 20100146929Abstract: The invention relates to a method for increasing the efficiency of a combined gas/steam power station (10) with integrated gasification combined cycle. Said power station comprises a gas turbine compressor (14) and an air-separation unit (18) having a defined working pressure. Compressed air is removed from the gas turbine compressor (14) at a pressure level that is adapted to the working pressure of the air-separation unit (18). The removed air is then supplied to the air-separation unit (18) where the air is broken down into its individual constituents, especially oxygen and nitrogen. The nitrogen produced in the air-separation unit (18) is removed from the air-separation unit and at least a part of the removed nitrogen quantity is used as a coolant in the gas/steam power station in order to improve its efficiency.Type: ApplicationFiled: July 26, 2006Publication date: June 17, 2010Inventors: Werner Günster, Erik Wolf, Gerhard Zimmermann
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Publication number: 20100132360Abstract: The invention relates to a steam generation plant, comprising a steam generator (1) with a combustion chamber (8), an evaporator, a superheater (9), an intermediate superheater (12), a condenser (14), a feed water preheater (16, 19, 19?) regeneratively heated by steam, a steam turbine set (2) with a high-pressure section (4), a medium pressure section (5) and a low-pressure section (6), a flue gas line (22), connected to the combustion chamber (8), an air supply line (21), for the supply of combustion air to the burner in the combustion chamber (8) and an air preheater (3) with flue gas and combustion air passing therethrough. An air line (23) branches off from the air supply line (21) downstream of the air preheater (3) in said steam generation plant and supplies an air-fractionation unit (25). Air coolers (34, 35) are arranged in the air line (23) through which the condensate or feed water from the condensate/feed water circuit from the steam generator (1) flows.Type: ApplicationFiled: June 3, 2006Publication date: June 3, 2010Applicant: MAN TURBO AGInventor: Bernd Gericke
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Publication number: 20090314031Abstract: An air distillation unit comprises an air distillation column (10) suitable for producing a nominal flow of gaseous nitrogen, the top of said column being connected to a liquid nitrogen source (8), and operates by carrying out the following steps: a flow of compressed, cooled and purified air is sent to an exchanger (11) and then to the column, a flow of gaseous nitrogen is withdrawn from the column, the level of liquid at the bottom of the column is controlled; and injection liquid (20), sent from the source to the column, is no longer sent if the required production reduces to at most the nominal production. Application to the separation of air by cryogenic distillation.Type: ApplicationFiled: June 19, 2007Publication date: December 24, 2009Applicant: L'Air Liquide Societe Anonyme Pour L'Etude et L'Etude et Exploitation Des Procedes Georges ClaudInventors: Benoit Davidian, Pierre Bodelin
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Patent number: 7632337Abstract: The present invention relates to cryogenic air separation processes and systems that employ a pressure swing adsorption (PSA) prepurification process. It is advantageous to operate the PSA process at a pressure comparable to or below the operating pressure of the highest pressure column in the cryogenic separation unit. Following PSA prepurification, the air can be split into at least two fractions, with at least a portion of the air being directed to the cryogenic separation unit and at least a portion of the remaining air being further pressurized in at least one stage of compression.Type: GrantFiled: June 30, 2006Date of Patent: December 15, 2009Assignee: Praxair Technology, Inc.Inventors: Henry Edward Howard, Jeffert John Nowobilski
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Publication number: 20090241595Abstract: A distillation method and apparatus having application to the distillation of air in which liquid production make is varied by varying the pressure ratio across a turboexpander used in generating refrigeration. The pressure ratio is varied by varying the pressure of a compressed stream fed to the turboexpander. This is done by solely compressing such compressed stream by a first booster compressor during a low rate of production of liquid products. During a high rate of production of liquid products, the compressed stream is also compressed within a second booster compressor. The second booster compressor is driven by a variable speed drive to allow a variety of liquid production rates between the low level of liquid production and the high level of liquid production.Type: ApplicationFiled: March 27, 2008Publication date: October 1, 2009Applicant: PRAXAIR TECHNOLOGY, INC.Inventors: Murali Chinta, Robert Leroy Baker, Jeremiah Rauch
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Publication number: 20090223247Abstract: There is provided a method of generating nitrogen which includes cryogenically separating compressed air introduced into a high-pressure column 11, storing liquid air 13 in a bottom portion of the high-pressure column 11 and taking nitrogen in gaseous form from an upper portion of the high-pressure column 11, introducing the liquid air 13 stored in the bottom portion of the high-pressure column 11 into a low-pressure column 12, cryogenically separating the liquid air 13 introduced into the low-pressure column 12 and storing oxygen-enriched liquid air 22 in a bottom portion of the low-pressure column 12 and taking nitrogen in gaseous form from an upper portion of the low-pressure column 12 as a product gas. Liquid air 13 taken through an extraction pipe 20 is introduced into a portion of a rectification part 12a of the low-pressure column 12 in which the number of theoretical plates from a column bottom side is set within the range of one to ten.Type: ApplicationFiled: June 16, 2006Publication date: September 10, 2009Applicant: AIR WATER INC.Inventors: Akira Yoshino, Koji Tanaka, Ryosuke Matsubayashi, Junya Suenaga, Shinya Okumura
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Patent number: 7536873Abstract: For cooling a gas by direct heat exchange with a cooling liquid, the gas (1) to be cooled is introduced into the lower region of a direct contact cooler (2). A first stream of cooling liquid (8) is fed into the direct contact cooler (2) above the point of introduction of the gas (1). Cooled gas (5) is removed above the point of introduction of the gas (1) from the direct contact cooler (2). A liquid backflow (10) is drawn off from the lower region of the direct contact cooler (2). At least at times, a second stream of cooling liquid (13) with a temperature that is lower than that of the backflow (10) is fed into the liquid backflow (10) and combined with the latter to form a return flow (11).Type: GrantFiled: February 10, 2006Date of Patent: May 26, 2009Assignee: Linde AktiengesellschaftInventor: Thomas Nohlen
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Patent number: 7516627Abstract: A krypton-xenon concentrate is first divided into krypton and xenon fractions in a preliminary rectifying column. Semi-volatile impurities are removed from each fraction, and production krypton and xenon are obtained from the refined fractions in krypton and xenon production columns. A recovered krypton flow is produced in a krypton recovery rectifying column. Reflux is formed in condensers-evaporators of rectification columns of the device in such a way that the formation of a solid phase is excluded. The operation of the rectification columns is initiated by supplying krypton to a contacting space.Type: GrantFiled: October 7, 2003Date of Patent: April 14, 2009Inventor: Mikhail Yurievich Savinov
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Patent number: 7497092Abstract: Process and apparatus for optimization of integrated air separation systems. In an integrated process for the compression, cooling, and purification of air, an adiabatic compressor compresses an air stream to produce a compressed air stream. The compressed air stream is used to warm a first pressurized stream at a first pressure and a second pressurized stream at a second pressure. The produced streams include a first warmed pressurized stream, a second warmed pressurized stream, and a cooled compressed air stream. The first warmed pressurized stream is gaseous and is expanded in a turbine. At least part of the work produced by the turbine is used to power the adiabatic compressor. The cooled compressed air stream is further cooled by a cooling unit by heat exchange with water, and then purified in a purifying unit using a TSA process.Type: GrantFiled: October 19, 2005Date of Patent: March 3, 2009Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Patrick Le Bot
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Publication number: 20080307828Abstract: A compressed air stream is cooled to a temperature suitable for its rectification within a lower pressure heat exchanger and a boosted pressure air stream is liquefied or converted to a dense phase fluid within a higher pressure heat exchanger in order to vaporize pumped liquid products. Thermal balancing within the plant is effectuated with the use of waste nitrogen streams that are introduced into the higher and lower pressure heat exchangers. The heat exchangers are configured such that the flow area for the subsidiary waste nitrogen stream within the higher pressure heat exchanger is less than that would otherwise be required so that the subsidiary waste nitrogen streams were subjected to equal pressure drops in the higher and lower pressure heat exchangers. This allows the higher pressure heat exchanger be fabricated with a reduced height and therefore a decrease in fabrication costs.Type: ApplicationFiled: June 15, 2007Publication date: December 18, 2008Inventors: Neil Mark Prosser, Richard John Jibb
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Publication number: 20080223075Abstract: A process for separating air by cryogenic distillation in a column system comprising a high pressure column and a low pressure column comprises compressing all the feed air in a first compressor to a first outlet pressure, sending a first part of the air at the first outlet pressure to a second compressor and compressing the air to a second outlet pressure, cooling at least part of the air at the second outlet pressure in a heat exchanger liquefying at least part of the air at the second outlet pressure and sending the liquefied air to at least one column of the column system wherein at least 50% of the liquefied air sent to the column system has been compressed in the second compressor, cooling a second part of the air at the first outlet pressure in the heat exchanger and expanding at least part of the second part of the air in an expander from the first outlet pressure to the pressure of a column of column system and sending the expanded air to that column, at least partially vaporizing an auxiliary fluid,Type: ApplicationFiled: September 21, 2006Publication date: September 18, 2008Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exloitation Des Procedes Georges ClaudeInventor: Jean-Pierre Tranier
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Patent number: 7225637Abstract: Process and apparatus for optimization of integrated air separation systems. In an integrated process for the compression, cooling, and purification of air, an adiabatic compressor compresses an air stream to produce a compressed air stream. The compressed air stream is used to warm a first pressurized stream at a first pressure and a second pressurized stream at a second pressure. The produced streams include a first warmed pressurized stream, a second warmed pressurized stream, and a cooled compressed air stream. The first warmed pressurized stream is gaseous and is expanded in a turbine. At least part of the work produced by the turbine is used to power the adiabatic compressor. The cooled compressed air stream is further cooled by a cooling unit by heat exchange with water, and then purified in a purifying unit using a TSA process.Type: GrantFiled: December 27, 2004Date of Patent: June 5, 2007Assignee: L'Air Liquide Société Anonyme á´ Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Patrick Le Bot
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Patent number: 7076971Abstract: A process and apparatus for highly efficient production of industrial gases by the cryogenic distillation of air, wherein a feed stream of compressed air, is supercharged to high pressure, cooled, and mixed with various recycle streams of supercharged air, to regulate the expander turbine operating temperature. The need for pre-cooling equipment downstream of the supercharger, which is widely employed in industry to manage the temperature of the incoming compressed air stream, is eliminated.Type: GrantFiled: February 13, 2004Date of Patent: July 18, 2006Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Expolitation des Procédés Georges ClaudeInventors: Lasad Jaouani, Bao Ha, Ovidiu Balog, Maurice Grenier, Xavier Pontone
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Patent number: 6984258Abstract: Method and apparatus for treating a gas by adsorption. A gas is compressed and then treated by being circulated in an adsorber. A regenerating fluid is indirectly heated by the gas coming from the compressor. In a second regeneration phase, the regenerating fluid is sent directly to the adsorber, while the treated gas is refrigerated by an auxiliary refrigerator.Type: GrantFiled: October 9, 2002Date of Patent: January 10, 2006Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Norbert Niclout, Marc Wagner
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Patent number: 6871513Abstract: In a process for separation of air by cryogenic distillation integrated with an associated process, air is separated in a separation unit (1), fluid is sent from the separation unit to an associated process, steam (3) is derived from the associated process, at least part of the steam is used in the separation unit and at least one fluid stream (11) is sent from the air separation unit to the atmosphere, at least when the steam is used in the air separation unit.Type: GrantFiled: October 29, 2001Date of Patent: March 29, 2005Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Alain Guillard