Melt Accelerator Or Color Modifier Utilized (e.g., Fining Agent, Etc.) Patents (Class 65/134.3)
  • Patent number: 11459263
    Abstract: A method of fining glass is disclosed that includes flowing a molten glass bath through a fining chamber. The molten glass bath has an undercurrent that flows beneath a skimmer that is partially submerged in the molten glass bath. One or more fining agents are introduced into the undercurrent of the molten glass bath directly beneath the skimmer from a dissolvable fining material component. In this way, the fining agent(s) may selectively target the gas bubbles drawn under the skimmer within the undercurrent of the molten glass for removal. The method may be employed to fine molten gas produced in a submerged combustion melter. A fining vessel for fining molten glass is also disclosed.
    Type: Grant
    Filed: October 1, 2019
    Date of Patent: October 4, 2022
    Assignee: Owens-Brockway Glass Container Inc.
    Inventors: Scott Weil, Zhongming Wang, Roger P. Smith
  • Patent number: 11186740
    Abstract: An inorganic particle dispersion having high spinnability comprises an inorganic powder, hydrophilic fumed silica, and a resin having a hydroxyl group.
    Type: Grant
    Filed: March 30, 2018
    Date of Patent: November 30, 2021
    Assignee: HARIMA CHEMICALS, INC.
    Inventors: Takayasu Arakawa, Yoshiaki Yamabayashi, Hideyuki Goto
  • Patent number: 9370762
    Abstract: A chemical reaction apparatus includes: a horizontal flow-type reactor inside of which has been partitioned into multiple chambers by a partition plate, and a liquid content horizontally flows with an unfilled space being provided thereabove; a microwave generator that generates microwaves; and at least one waveguide that transmits the microwaves generated by the microwave generator to the unfilled space in the reactor. The reactor has a shape in which an area of a liquid surface does not change even in a case where a height of the liquid surface changes according to a change in an amount of the content.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: June 21, 2016
    Assignee: MICROWAVE CHEMICAL CO., LTD.
    Inventors: Akinori Ishizuka, Iwao Yoshino, Kunitaka Momota, Yasunori Tsukahara
  • Patent number: 9334189
    Abstract: This invention relates to lead free and cadmium free copper-containing glass frits that can be used as pigments to color other glass frits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.
    Type: Grant
    Filed: November 7, 2014
    Date of Patent: May 10, 2016
    Assignee: Ferro Corporation
    Inventors: Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
  • Publication number: 20140356608
    Abstract: A method for producing bubble-free glasses is provided, in which a glass mixture that is arsenic-free and antimony-free with the exception of any unavoidable raw material impurities and a sulfate compound and SnO2 as refining agents are used. The glass mixture is melted and primarily refined in a first region of a melting tank, an average melting temperature (T1) is set at T1>1560° C. and an average melt residence time (t1) is set at t1>2 hours. The proportion of SO3 resulting from the decomposition of the sulfate compound is reduced to less than 0.002 wt. % as the primary refinement is carried out. A secondary refinement is carried out in a second region of the melting tank, an average melting temperature (T2) is set at T2>1640° C. and an average melt residence time (t2) is set at t2>1 hour.
    Type: Application
    Filed: August 19, 2014
    Publication date: December 4, 2014
    Inventors: Frank-Thomas LENTES, Karin NAUMANN, Ulrich SCHIFFNER, Friedrich SIEBERS, Christian MUELLER, Klaus SCHOENBERGER, Evelin WEISS
  • Publication number: 20140356609
    Abstract: A method for producing bubble-free glasses is provided, in which a glass mixture that is arsenic-free, antimony-free and tin-free with the exception of any unavoidable raw material impurities and at least one sulfate compound as a refining agent are used. The glass mixture and refining agent are melted and primarily refined in a first region of a melting tank, an average melting temperature (T1) is set at T1>1580° C. and an average melt residence time (t1) is set at t1>2 hours. A secondary refinement is carried out in a second region, an average melting temperature (T2) is set at T2>1660° C. and an average melt residence time (t2) is set at t2>1 hour, and the proportion of the SO3 resulting from decomposition of the sulfate is reduced to less than 0.002 wt. %.
    Type: Application
    Filed: August 20, 2014
    Publication date: December 4, 2014
    Inventors: Frank-Thomas LENTES, Karin NAUMANN, Ulrich SCHIFFNER, Friedrich SIEBERS, Christian MUELLER, Klaus SCHOENBERGER, Evelin WEISS
  • Patent number: 8769991
    Abstract: In a method for producing a fluorophosphate optical glass comprising melting a glass raw material to give a molten glass, and refining, homogenizing and then quickly quenching the molten glass to produce the fluorophosphate optical glass, even if the glass is flown from a refining tank that is set to a high temperature to an operation tank that is set to a low temperature, bubbles are not generated in the glass. The content of Fe in terms of Fe2O3 and the content of Cu in terms of CuO is controlled so that the total of the contents of Fe and Cu is 20 ppm or more, and the obtained fluorophosphate optical glass has such transmittance property that the internal transmittance in terms of a thickness of 10 mm becomes 98% or more at a wavelength region of at least from 400 to 500 nm.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: July 8, 2014
    Assignee: Hoya Corporation
    Inventor: Mikio Kenishi
  • Patent number: 8741794
    Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R?2O (in which R? is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: June 3, 2014
    Assignee: Avanstrate Inc.
    Inventors: Junji Kurachi, Akihiro Koyama, Yoichi Hachitani
  • Patent number: 8661853
    Abstract: A process for producing a glass in the production of a glass molded article formed of an optical glass by melting and clarifying a glass raw material to prepare a molten glass and molding said molten glass, the process comprising preparing a glass raw material that gives an oxide glass comprising, by cationic %, 12 to 65% of B3+, 0 to 20% of Si4+, 0 to 6% of Ge4+, 15 to 50% of total of La3+, Gd3+, Y3+, Yb3+, Sc3+ and Lu3+, 4 to 54% of total of Ta5+, Zr4+, Ti4+, Nb5+, W6+ and Bi3+, 0 to 35% of Zn2+, 0 to 9% of total of Li+, Na+ and K+, and 0 to 15% of total of Mg2+, Ca2+, Sr2+ and Ba2+, a total content of said cationic components in the oxide glass being 99 to 100%, and said glass raw material comprising carbonate and sulfate.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: March 4, 2014
    Assignee: Hoya Corporation
    Inventors: Tomoaki Negishi, Yasuhiro Fujiwara
  • Patent number: 8640498
    Abstract: Glasses are disclosed which can be used to produce substrates for flat panel display devices, e.g., active matrix liquid crystal displays (AMLCDs). The glasses have MgO concentrations in the range from 1.0 mole percent to 3.0 mole percent and ?[RO]/[Al2O3] ratios greater than or equal to 1.00, where [Al2O3] is the mole percent of Al2O3 and ?[RO] equals the sum of the mole percents of MgO, CaO, SrO, and BaO. These compositional characteristics have been found to improve the melting properties of batch materials used to produce the glass, which, in turn, allows the glasses to be fined (refined) with more environmentally friendly fining agents, e.g., tin as opposed to arsenic and/or antimony.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: February 4, 2014
    Assignee: Corning Incorporated
    Inventor: Adam J. G. Ellison
  • Patent number: 8631668
    Abstract: Methods of creating a batch of recycled glass from mixed color glass cullet. In one embodiment, the method includes receiving at a glass plant a weight and color composition percentage of a first batch of mixed color cullet. The glass plant also receives a weight and color composition percentage of a second batch of mixed color cullet. The weight and color composition percentage of the first batch and the second batch are combined to generate a combined weight and composition percentage. The combined weight and composition are percentage are used to generate, automatically at a glass plant, a formulation to produce glass of a desired color.
    Type: Grant
    Filed: November 10, 2005
    Date of Patent: January 21, 2014
    Assignee: MPH Energy LLC
    Inventors: Sean Duffy, Warren Blasland, Rick Lehman
  • Publication number: 20130239618
    Abstract: Objective of the present invention is to provide a glass melting furnace, a process for modifying a glass melt and a process for producing glass melt, whereby composition-modified glass melt containing an additive component at a high concentration can be produced with an excellent quality. The glass melting furnace 10 of the present invention is a glass melting furnace 10 for adding an additive to a molten state glass to form composition-modified glass melt, discharging the composition-modified glass melt, and a forehearth 20, said forehearth comprising a feed portion to feed an additive, and a heating means to form a heating gas phase portion above the liquid surface of the glass melt to convert the additive from the feed portion into melted particles of additive below the feed portion.
    Type: Application
    Filed: May 2, 2013
    Publication date: September 19, 2013
    Applicant: Asahi Glass Company, Limited
    Inventors: Yutaka Ishikawa, Chikao Tanaka
  • Publication number: 20130111955
    Abstract: A process for making silica-based glass includes: (a) forming a glass precursor melt that includes glass network formers and glass network modifiers, the glass precursor melt being at a temperature in the range of 900 C to 1700 C and having a viscosity of not more than 3 Pa·s, and (b) refining the glass precursor melt. Either or both steps (a) and (b) can include stirring and/or be carried out under reduced pressure to enhance refining. The refined glass precursor melt preferably is mixed with additional materials including silica (SiO2) to form a silica-based glass melt.
    Type: Application
    Filed: November 3, 2011
    Publication date: May 9, 2013
    Inventors: D. Wayne Leidy, Dawid Dewet-Smith, Carl L. Fayerweather, Brett E. Hixson
  • Patent number: 8383530
    Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R?2O (in which R? is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.
    Type: Grant
    Filed: June 15, 2010
    Date of Patent: February 26, 2013
    Assignee: Avanstrate Inc.
    Inventors: Junji Kurachi, Akihiro Koyama, Yoichi Hachitani
  • Patent number: 8377834
    Abstract: A glass composition for substrates excellent in productivity is provided by lowering the high temperature viscosity while securing characteristics and quality required for FPD substrates, particularly for PDP substrates. A glass composition for substrates, which is characterized by comprising, as represented by mass% based on oxides, from 55 to 75% of SiO2, from 5 to 15% of Al2O3, from 4 to 18% of MgO, from 3 to 12% of CaO, from 4 to 18% of SrO, from 0 to 20% of BaO, from 6 to 20% of Na2O+K2O, from 0.5 to 6% of ZrO2 and from 18 to 25% of MgO+CaO+SrO+BaO, as a glass matrix composition, and containing from 0.001 to 0.6% of SO3, and which is further characterized in that when the viscosity is represented by ?, the temperature satisfying log?=2 is at most 1,545° C. and the devitrification temperature is at most the temperature satisfying log?=4, the thermal expansion coefficient is from 75×10?7 to 90×10?7/° C., the specific gravity is at most 2.8, and the glass transition point is at least 600° C.
    Type: Grant
    Filed: February 4, 2010
    Date of Patent: February 19, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Kensuke Nagai, Tetsuya Nakashima, Kei Maeda
  • Publication number: 20120272685
    Abstract: A method and apparatus for melting a raw material such as glass. The method comprises a creating a flow of raw material interrupted by a heated phase separation barrier (3,31,32), wherein melting is achieved by transfer of heat from the phase separation barrier to the raw material. The process comprises: providing solid raw material to the phase separation barrier, wherein the phase separation barrier supports the solid raw material; heating the phase separation barrier to a temperature which is (a) at least 700° C. and (b) sufficient to cause melting of the solid raw material which contacts the barrier, wherein any melted raw material formed on contact with the phase separation barrier flows off or through the phase separation barrier; and collecting the melted raw material; wherein the phase separation barrier causes separation of the solid and melted phases within the flow of the raw material.
    Type: Application
    Filed: November 12, 2010
    Publication date: November 1, 2012
    Inventor: Roger Pauli
  • Patent number: 8283270
    Abstract: The neutral glass according to the present invention is characterized by excellent hydrolytic stability, a relatively low processing temperature and low content of boron oxide. Here, the neutral glass has the following composition, in percent by weight based on oxide content: SiO2, 70-79; B2O3, 0-<5; Al2O3, <5; ZrO2, 0.5-<5; TiO2, 0.5-6; Na2O, 1-6; K2O, 3 to 8; and Li2O, 0-0.5, wherein a total amount of SiO2 and B2O3 is less than 83 percent by weight.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: October 9, 2012
    Assignee: Schott AG
    Inventors: Joerg Hinrich Fechner, Christof Kass
  • Publication number: 20120238432
    Abstract: The present invention is generally directed to a method of making chalcogenide glasses including holding the melt in a vertical furnace to promote homogenization and mixing; slow cooling the melt at less than 10° C. per minute; and sequentially quenching the melt from the top down in a controlled manner. Additionally, the present invention provides for the materials produced by such method. The present invention is also directed to a process for removing oxygen and hydrogen impurities from chalcogenide glass components using dynamic distillation.
    Type: Application
    Filed: May 29, 2012
    Publication date: September 20, 2012
    Inventors: Vinh Q Nguyen, Jasbinder S. Sanghera, Shyam S. Bayya, Geofi Chin, Ishwar D. Aggarwal
  • Publication number: 20120216574
    Abstract: A process for making soda-lime glass includes calcinating calcium carbonate in solid phase and at elevated temperature to form calcium oxide and release gases such as carbon dioxide. Sodium silicate glass is formed separately in liquid phase while releasing gaseous reaction products. The calcium oxide and the sodium silicate glass intermediate products are mixed in liquid phase to form a soda-lime glass melt. Formation of sodium silicate glass as an intermediate product before mixing with the calcium oxide has the advantage of promoting release of gaseous reaction products in the sodium silicate due at least in part to the relatively low viscosity of the sodium silicate glass. The calcination step and/or the sodium silicate-forming step and/or the final mixing step can be carried out under reduced pressure further to promote release of gases and reduce bubble formation.
    Type: Application
    Filed: February 24, 2011
    Publication date: August 30, 2012
    Inventors: Dawid Dewet-Smith, Carl L. Fayerweather, Brett E. Hixson
  • Publication number: 20120159991
    Abstract: A fining agent for reducing the concentration of seeds or bubbles in a silicate glass. The fining agent includes at least one inorganic compound, such as a hydrate or a hydroxide that acts as a source of water. In one embodiment, the fining agent further includes at least one multivalent metal oxide and, optionally, an oxidizer. A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3 is also provided. Methods of reducing the seed concentration of a silicate glass, and a method of making a silicate glass having a seed concentration of less than about 1 seed/cm3 are also described.
    Type: Application
    Filed: January 9, 2012
    Publication date: June 28, 2012
    Inventors: Matthew John Dejneka, Sinue Gomez
  • Patent number: 8196432
    Abstract: The invention relates to a furnace for the continuous melting of a composition comprising silica, the said furnace comprising at least two tanks in series, said tanks each comprising at least one burner submerged in the melt. The invention also relates to the process for manufacturing compositions comprising silica using the furnace, the silica and the fluxing agent for the silica being introduced into the first tank. The invention makes it possible to produce glass color frits, tile frits and enamel with a high productivity, low temperatures and short transition times.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: June 12, 2012
    Assignee: Saint-Gobain Glass France
    Inventors: Remi Jacques, Pierre Jeanvoine, Biagio Palmieri
  • Publication number: 20120125050
    Abstract: A method for manufacturing a glass plate includes preparing an accommodating part made of platinum or a platinum alloy, fining molten glass of a melted feedstock, stirring and homogenizing the molten glass, and supplying the molten glass to a forming apparatus. The fining the molten glass includes causing gas bubbles to float up and out from the molten glass, and causing absorption of the gas component in the molten glass and eliminating gas bubbles. The water vapor partial pressure of an atmosphere in the causing the gas bubbles is lower than the water vapor partial pressure in at least a portion of the causing the absorption of the gas component. A boundary between the causing the gas bubbles and the causing the absorption of the gas component is a temperature lower than the maximum temperature by 30° C. or more after the molten glass has reached the maximum temperature.
    Type: Application
    Filed: September 29, 2011
    Publication date: May 24, 2012
    Applicant: AVANSTRATE INC.
    Inventor: Tsugunobu Murakami
  • Patent number: 8168552
    Abstract: The subject of the invention is a method of refining glass for which the temperature (T log 2) corresponding to a viscosity of 100 poise (10 Pa·s) is greater than or equal to 1480° C., characterized in that sulfides are used as a refining agent. It also relates to the glass article capable of being obtained by this method.
    Type: Grant
    Filed: October 9, 2006
    Date of Patent: May 1, 2012
    Assignee: Saint-Gobain Glass France
    Inventors: Laurent Joubaud, Dorothee Martin
  • Patent number: 8156763
    Abstract: Provided is a method of producing a glass, including, in order to obtain an excellent refining effect: preparing a raw glass batch including: an antimony compound containing pentavalent antimony; and an oxidizing agent (a cerium oxide, a sulfate, a nitrate); and melting the raw glass batch. In preparing the raw glass batch, it is preferable that the antimony compound be premixed with the oxidizing agent. When the nitrate is used as the oxidizing agent, the raw glass batch is prepared so as to include the antimony compound in an amount of more than 0.5 parts by mass and at most 3 parts by mass, in terms of an amount of antimony pentoxide, per 100 parts by mass of a base glass composition expressed in terms of an amount of an oxide.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: April 17, 2012
    Assignee: AvanStrate, Inc.
    Inventors: Yukihito Nagashima, Kengo Maeda
  • Patent number: 8143178
    Abstract: The present invention discloses a blue transparent glass-ceramic material comprising ?-quartz solid solution as a predominant crystalline phase and process for making same. The glass-ceramic comprises TiO2 as a nucleating agent, sulphur and at least one metal oxide, advantageously MgO and/or ZnO. The process for making the glass-ceramic material comprises including a metal sulphide, such as ZnS and/or MgS, as a reducing agent in melting the precursor glass of the glass-ceramic material.
    Type: Grant
    Filed: October 25, 2007
    Date of Patent: March 27, 2012
    Assignee: EuroKera
    Inventor: Lothar Wondraczek
  • Patent number: 8127572
    Abstract: A method of controlling blister formation in a glass melt flowing through a system comprising one or more refractory metal vessels by developing a blister index and determining the critical blister index value. The critical value of the blister index may be used to control the principal variables responsible for blister formation, including the water content of the melt, the concentration of reduced multivalent oxide compounds in the melt, and the hydrogen partial pressure of an atmosphere in contact with the outside surface of the refractory metal vessel. Also disclosed is a minimum partial pressure of hydrogen necessary to produce an essentially blister-free glass article in a glass essentially free of arsenic and antimony.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: March 6, 2012
    Assignee: Corning Incorporated
    Inventors: William Gurney Dorfeld, Adam James Gillmar Ellison, Qiao Li, Susan Lee Schiefelbein
  • Publication number: 20110296953
    Abstract: A method of firing a melting furnace to which flux or fining additions are made, comprising supplying the burner systems with a fuel mixture containing at least 10% glycerin wherein the glycerin contains sodium chloride (NaCl), potassium chloride (KCl), or a combination thereof. The glycerin can advantageously be raw glycerin, a by-product of biodiesel production. It can be co-fired with natural gas or fuel oil or fired alone in traditional combustion burner systems. Alternatively, the glycerin may be supplied with NaCl and KCl in the same proportion as the flux used in the melting furnace. Significant fuel cost savings and potential flux cost savings may be realized using this method. The method is applicable to furnaces used in the production of aluminum or glass having similar burner systems and utilizing NaCl and/or KCl additions as part of the melting process.
    Type: Application
    Filed: May 27, 2011
    Publication date: December 8, 2011
    Applicant: BLOOM ENGINEERING COMPANY, INC.
    Inventors: David G. Schalles, James N. Checkeye, Robert F. Green, Jason D. Sweeney
  • Publication number: 20110207591
    Abstract: The transparent glass ceramic with low thermal expansion is produced from a glass that is fined with a combination of environmentally friendly fining agents, specifically a combination of SnO2 with at least one of Sb2O3, SO42?, Br? and Cl?. The glass is free of arsenic and is preferably made from a mixture of SiO2, Al2O3, Li2O, TiO2, ZrO2 and ZnO. A mirror support for astronomy and a prism for LCD lithography are advantageously made from this glass ceramic.
    Type: Application
    Filed: February 18, 2011
    Publication date: August 25, 2011
    Inventors: Bianca Schreder, Maria-Louisa Reich, Olaf Claussen
  • Patent number: 7946130
    Abstract: In the process of producing a glass, a glass melt is formed from an initial glass batch, an inorganic or organic peroxide is include in the glass melt as a refining agent in an amount suitable for refining, and then the glass melt is refined at a refining temperature equal to or greater than a decomposition temperature of the inorganic or organic peroxide. The inorganic peroxides used in the glass-making process only include cations that are already present in components of the initial glass batch. The organic peroxides used in the glass-making process are chosen so that the organic residue remaining in the melt after release of oxygen is decomposed to volatile water and CO2.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: May 24, 2011
    Assignee: Schott AG
    Inventor: Silke Wolff
  • Patent number: 7908886
    Abstract: The invention is directed to oxyhalide fining agents for glass and processes for making glass using such a fining agent.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: March 22, 2011
    Assignee: Corning Incorporated
    Inventors: Lauren Kay Cornelius, Adam James Ellison, Shari Elizabeth Koval
  • Patent number: 7737062
    Abstract: The invention provides an opalescent forehearth color concentrate comprising a non-smelted agglomerated interspersion of particles for use in coloring glass, said concentrate comprising by weight from about 10% to about 70% of a glass component and from about 30% to about 90% of one or more opalescent pigments, the glass component comprising by weight from about 10% to about 50% ZnO and about 15 to about 60% SiO2. The invention also provides a method of using the color concentrate.
    Type: Grant
    Filed: June 5, 2007
    Date of Patent: June 15, 2010
    Assignee: Ferro Corporation
    Inventors: George E. Sakoske, Kenneth R. Ackerman, John M. Bauer
  • Patent number: 7700506
    Abstract: The PbO-free UV-absorbing glass is made under oxidative conditions and has a composition, in % by weight, of: SiO2, 55-79; B2O3, 3-25; Al2O3, 0-10; Li2O, 0-10; Na2O, 0-10; K2O, 0-10; MgO, 0-2; CaO, 0-3; SrO, 0-3; BaO, 0-3; ZnO, 0-3; ZrO2, 0-3; CeO2, 0-1; Fe2O3, 0-1; WO3, 0-3; Bi2O3, 0-3; MoO3, 0-3; ?Li2O+Na2O+K2O=0.5 to 16 and ?MgO+CaO+SrO+BaO+ZnO=0-10. It also contains from 0.1 to 10% TiO2 with at least 95% of the titanium as Ti+4 so that it has a high visible transmission, reduced color centers, and a sharp UV absorption edge.
    Type: Grant
    Filed: April 8, 2008
    Date of Patent: April 20, 2010
    Assignee: Schott AG
    Inventors: Joerg Fechner, Andreas Reisse, Franz Ott, Brigitte Hueber
  • Patent number: 7696113
    Abstract: Alkali-free glasses are disclosed which can be used to produce substrates for flat panel display devices, e.g., active matrix liquid crystal displays (AMLCDs). The glasses contain iron and tin as fining agents, and preferably are substantially free of arsenic and antimony. In certain embodiments, the glasses are also substantially free of barium. Methods for producing alkali-free glass sheets using a downdraw process (e.g., a fission process) are also disclosed.
    Type: Grant
    Filed: December 1, 2008
    Date of Patent: April 13, 2010
    Assignee: Corning Incorporated
    Inventor: Adam James Gillmar Ellison
  • Patent number: 7624595
    Abstract: A process for melting and refining vitrifiable materials, such that all or part of the thermal energy necessary for melting the said vitrifiable materials is supplied by the combustion of fossil fuel(s) with at least one oxidizer gas, the fuel(s)/gas or the gaseous products resulting from the combustion being injected below the level of the mass of vitrifiable materials (7). The refining of the vitrifiable materials after melting comprises at least one step of subjecting them to subatmospheric pressure while centrifuging.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: December 1, 2009
    Assignee: Saint-Gobain Glass France
    Inventors: Pierre Jeanvoine, Tanguy Massart, Anne Berthereau
  • Publication number: 20090215607
    Abstract: A fining agent for reducing the concentration of seeds or bubbles in a silicate glass. The fining agent includes at least one inorganic compound, such as a hydrate or a hydroxide that acts as a source of water. In one embodiment, the fining agent further includes at least one multivalent metal oxide and, optionally, an oxidizer. A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3 is also provided. Methods of reducing the seed concentration of a silicate glass, and a method of making a silicate glass having a seed concentration of less than about 1 seed/cm3 are also described.
    Type: Application
    Filed: February 25, 2009
    Publication date: August 27, 2009
    Inventors: Matthew John Dejneka, Sinue Gomez
  • Patent number: 7490486
    Abstract: The process of producing a refined borosilicate glass includes preparing a glass batch with a composition in wt. % on the basis of oxide content of SiO2, 65-82; Al2O3, 2-8; B2O3, 5-13; MgO+CaO+SrO +BaO+ZnO, 0-7; ZrO2, 0-2; and Li2O+Na2O+K2O, 3-10; adding 0.05 wt. % to 0.6 wt. % of sulfate(s) expressed as SO3 to the glass batch as the refining agent; melting the glass batch including the refining agent to form melted glass; and then hot-shaping the borosilicate glass. The refining agent may also include from 0.01 wt. % to 0.6 wt. % of F? or from 0.015 wt. % to 0.6 wt. of Cl?. The sulfate is preferably an alkali metal and/or alkaline earth metal sulfate or sulfates.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: February 17, 2009
    Assignee: Schott AG
    Inventors: Karin Naumann, Christof Kass, Franz Ott
  • Publication number: 20090023573
    Abstract: The present invention relates to the use of organic and/or inorganic peroxides as refining agents in a process for refining of glass melts. These peroxides are available in such a bandwidth that they can be chosen specifically according to the viscosity temperature profile of a glass and can therefore be integrated in an applicatively meaningful synthesis so that in the final product, in the raw glass, no traces of the peroxides are detectable.
    Type: Application
    Filed: July 14, 2008
    Publication date: January 22, 2009
    Inventor: Silke Wolff
  • Patent number: 7375043
    Abstract: The method for making UV-absorbing glass, which transmits in a visible range, includes melting raw materials to form a melt and producing the melt under oxidative conditions. The UV-absorbing glass is free of PbO and has the following composition (in % by weight): SiO2, 55-79; B2O3, 3-25; Al2O3, 0-10; Li2O, 0-10; Na2O, 0-10; K2O, 0-10; MgO, 0-2; CaO, 0-3; SrO, 0-3; BaO, 0-3; ZnO, 0-3; ZrO2, 0-3; CeO2, 0-1; Fe2O3, 0-1; WO3, 0-3; Bi2O3, 0-3; MoO3, 0-3; with ? Li2O+Na2O+K2O=0.5 to 16 and ? MgO+CaO+SrO+BaO+ZnO=0-10. The melt composition is characterized by including 0.1 to 10 % TiO2 and from 0.01-10 % As2O3. The glass made by the method and its properties are also disclosed. The glass is useful in lamps, LCD displays, monitors and glass-to-metal seals with molybdenum, tungsten and Fe—Co—Ni alloys.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: May 20, 2008
    Assignee: Schott AG
    Inventors: Joerg Fechner, Andreas Reisse, Franz Ott, Brigitte Hueber
  • Patent number: 7296441
    Abstract: The invention relates to an apparatus and a method for low-contamination melting of high-purity, aggressive and/or high-melting glass or glass-ceramic. According to the invention, for this purpose a melt is heated in a crucible or melting skull crucible by means of high-frequency radiation and is mixed or homogenized in the melting crucible. It is preferable for a gas nozzle, from which gas bubbles, e.g. oxygen bubbles (known as O2 bubbling), escape into the melt, to be provided at the base of the crucible. This alone makes it possible to achieve surprising multiple benefits in the melting skull crucible. Firstly, unmelted batch which drops into the melt in solid form, for example from above, is melted down more quickly as a result of more intensive mixing with the liquid fraction of the melt, secondly the temperature distribution in the melt is made more even, thirdly a uniform distribution or mixing of different glass constituents is achieved, and fourthly the redox state of the glass can be adjusted.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: November 20, 2007
    Assignee: Schott AG
    Inventors: Michael Leister, Ernst-Walter Schäfer, Leopold Eichberg, Volker Ohmstede
  • Patent number: 7260960
    Abstract: A method of controlling reaction paths of glass batch components added to a resident glass melt is provided, including the steps of providing a plurality of raw material batch components according to a batch recipe, selectively combining a portion of the batch components into a first combination material having a melting temperature in a range of 60 to 90% of a resident melt temperature (K) and a viscosity3 a melt viscosity/100, and selectively combining another portion of the batch components into a second combination material having a reaction temperature in a range of 60 to 100% of the resident melt temperature, the second combination material being capable of forming an intermediate compound via a solid state reaction before reacting with the glass melt. The first and second combination materials and any remaining batch components are mixed and introduced into a glass melter.
    Type: Grant
    Filed: August 26, 2004
    Date of Patent: August 28, 2007
    Inventor: William M. Carty
  • Patent number: 7208431
    Abstract: A glass with high internal transmission as well as low tendency to radiation-caused physical compaction and low tendency to solarization, comprising 18 to 31% by weight of SiO2, 0 to 7% by weight of Na2O3, 0 to 7% by weight of K2O, 65 to 84% by weight of PbO, 0.001 to 1% by weight of As2O3+As2O5, which is characterized by a content of 0 to 5000 ppm of Sb2O3 0 to 500 ppm of TiO2 0 to 100 ppm of CuO 0 to 1000 ppm of F. The ?(As2O3, As2O5, Sb2O3, F)?20 ppm and the ratio of As(III)/As(V) is at least 0.5. Such a glass is suitable for the use as optical element.
    Type: Grant
    Filed: January 7, 2005
    Date of Patent: April 24, 2007
    Assignee: Schott AG
    Inventors: Silke Wolff, Ute Woelfel
  • Patent number: 7137278
    Abstract: The process of the invention produces alkali-free aluminosilicate glass having an Al2O3-content of more than 12% by weight with the addition of from 0.005% by weight to 0.6% by weight of sulfate for batch formulation.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: November 21, 2006
    Assignee: Schott AG
    Inventors: Franz Ott, Karin Naumann, Otmar Becker, Ralf Diezel
  • Patent number: 7137277
    Abstract: The invention relates to a method and a device for producing colored glasses. The aim of the invention is to obtain a paricularly intimate mixture and to enable a quick change of the melt at the same time. To this end, the following procedure steps are applied: a melt made of a compound or fragments of glass is produced, the glass melt is further processed in at least one additional vessel, the melt is supplied to a skull device (3) (skull pot or skull channel) during subsequent processing, a dye is supplied (6, 6.1) to the melt after the melt was in the melting station (1) but before the melt enters the skull device (3) or while said melt is in the skull device.
    Type: Grant
    Filed: August 16, 2000
    Date of Patent: November 21, 2006
    Assignee: Schott AG
    Inventors: Hildegard Romer, Werner Kiefer, Wolfgang Schmidbauer
  • Patent number: 6935138
    Abstract: An infra-red absorption glass for a reed switch is suitable for encasement of a reed switch using magnetic wire members made of Fe—Ni based alloy (52 alloy). In the infra-red absorption glass, an infra-red transmittance at a wavelength of 1050 nm is not greater than 10% for a thickness of 0.5 mm and the content of Cl in the glass is not greater than 150 ppm. In the glass, a coefficient of thermal expansion in a temperature range between 30 and 380° C. is preferably 85-100×10?7/° C. In addition, the infra-red absorption glass preferably has a composition consisting essentially of, by weight percent, 60-75% of SiO2, 1-10% of Al2O3, 0-10% of B2O3, 3.5-10% of RO (R being one or more selected from Ca, Mg, Ba, Sr, and Zn), 0.5-5% of Li2O, 8-17% of Na2O+K2O, 2-10% of Fe3O4.
    Type: Grant
    Filed: February 26, 2004
    Date of Patent: August 30, 2005
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Koichi Hashimoto, Hiroyuki Kosokabe
  • Patent number: 6883349
    Abstract: The subject of the invention is a process for manufacturing compounds based on one or more silicates of alkali metals, such as Na and K and/or alkaline earth metals such as Ca, Mg, and/or on rare earths, such as Ce, optionally in the form of mixed silicates which combine alkaline-earth metals, such as Ca, with the alkali metal(s) and the rare earth(s), by conversion of silica and of halides, especially of one or more chlorides, or sulfate or nitrate, of the said alkali metals and/or of the said rare earths and/or of the said alkaline-earth metals, such as NaCl, KCl or CeCl4. The heat needed for the conversion is supplied, at least partly, by one or more submerged burners. The subject of the invention is also an apparatus for carrying out the process and for its use.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: April 26, 2005
    Assignee: Saint-Gobain Glass France
    Inventor: Pierre Jeanvoine
  • Patent number: 6878653
    Abstract: An ultraviolet ray-absorbing, colorless and transparent soda-lime-silica glass is disclosed, which glass is prepared by irradiating a cerium containing soda-lime-silica glass with light having wavelengths in far- to near-ultraviolet region and thereby reducing transmittance to light with wavelengths in the region of 300-400 nm.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: April 12, 2005
    Assignee: Nihon Yamamura Glass Co., Ltd.
    Inventors: Masao Kitayama, Yuko Ishizu
  • Patent number: 6871514
    Abstract: There is now provided a method and a device for the control and setting of the redox state of redox fining agents in a glass melt, in which method, during the melting process, essentially oxygen gas is blown through the glass melt.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: March 29, 2005
    Assignee: Schott Glas
    Inventors: Wolfgang Muschik, Hildegard Rōmer, Rainer Eichholz, Paul Kissl, Johann Collignon, Reinhard Zintl
  • Publication number: 20040176237
    Abstract: The invention relates to a method for producing borosilicate glasses of hydrolytic class 1, consisting of the following steps; preparing the mixture by adding at least one refining agent, insertion of the glass batch, melting the glass and subsequently heat forming the melted glass, whereby 0.01 wt.-%-0.8 wt.-% of one of more sulphates in the form of SO3 are added to the glass mixture.
    Type: Application
    Filed: December 9, 2003
    Publication date: September 9, 2004
    Inventors: Franz Ott, Christof Kass, Karin Naumann
  • Publication number: 20040168474
    Abstract: The invention relates to a plant and to a process for manufacturing a glass, comprising the production of a main stream of a liquid main glass, by a main plant that includes a main furnace, and the production of an auxiliary stream of a liquid auxiliary glass, by an auxiliary plant that includes an auxiliary furnace, the auxiliary stream being smaller than the main stream, the auxiliary glass having a composition different from that of the main glass and the two streams then being mixed to form a single total stream of the final glass. The auxiliary furnace may especially be fitted with submerged burners, and provide the function of colouring the main glass so that the final glass is a coloured glass. A highly homogeneous and bulk-coloured flat glass may thus be manufactured by an installation having short transition times.
    Type: Application
    Filed: May 27, 2003
    Publication date: September 2, 2004
    Applicant: SAINT-GOBAIN GLASS FRANCE
    Inventors: Pierre Jeanvoine, Luis Grijalba Goicoechea, Ramon Rodriguez Cuartas, Maurice Lemaille
  • Patent number: 6763280
    Abstract: An automated method for recycling mixed colored cullet glass (i.e., broken pieces of glass of mixed colors and types) into new glass products. A computer controlled process identifies the virgin glass raw materials, the desired target glass properties, the composition of a batch of mixed colored cullet, and the quantity of cullet to be used in the glass melt, and the computer controlled process automatically determines the proper amounts of raw materials to add to the batch of mixed colored cullet so that recycled glass is produced having the desired coloring oxides, redox agents, and glass structural oxides in the proper proportion. The recycled glass is then used to make glass products such as beer bottles.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: July 13, 2004
    Assignee: GR Technology, Inc.
    Inventor: Richard L. Lehman