Abstract: Installation including an industrial glass furnace (1) including a tank (2) for molten glass (3), a combustion heating chamber (4) situated above the tank (2), and a duct for evacuation of flue gases in communication with said heating chamber (4), and a stone furnace including a firing zone (21) for stone to be fired, the flue gas evacuation duct including a flue gas outlet that is connected to the firing zone (21) of stone to be fired and supplying the firing zone (21) of stone to be fired with flue gases at high temperature.

Abstract: Operation of a thermochemical regenerator to generate soot or to increase the amount of soot generated improves the performance of a furnace with which the thermochemical regenerator is operated.

Abstract: A method of treating a carbon dioxide rich flue gas and a flue gas treatment system for treatment of a carbon dioxide rich flue gas are provided. A boiler system includes a boiler, being operative for combusting a fuel and generating a carbon dioxide rich flue gas, and the flue gas treatment system. The flue gas treatment system includes a gas cleaning system, a nitrogen oxides reduction unit, being operative for reducing at least a portion of a nitrogen oxide(s) content of the flue gas, and a compression and cooling device being operative for pressurizing and cooling at least a portion of the flue gas treated by the gas cleaning system and the nitrogen oxide(s) reduction unit.

Abstract: Employing furnace combustion gases for both thermochemical regeneration and heating of regenerators to preheat oxidant for the furnace provides synergistic efficiencies and other advantages.

Abstract: Processes and systems for producing molten glass using submerged combustion melters, including densifying an initial composition comprising vitrifiable particulate solids and interstitial gas to form a densified composition comprising the solids by removing a portion of the interstitial gas from the composition. The initial composition is passed from an initial environment having a first pressure through a second environment having a second pressure higher than the first pressure to form a composition being densified. Any fugitive particulate solids escaping from the composition being densified are captured and recombined with the composition being densified to form the densified composition. The densified composition is fed into a feed inlet of a turbulent melting zone of a melter vessel and converted into turbulent molten material using at least one submerged combustion burner in the turbulent melting zone.

Abstract: The present invention relates to a glass melting furnace comprising a channel-shaped melting tank, the batch materials being introduced at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which the combustion energy is produced by oxy-fuel combustion in respect of at least 65% thereof, the burners being distributed on the walls along the length of the furnace, in which flue gas discharge is mostly localized close to the upstream end near the openings through which the batch materials are introduced, the rest of the flue gas being removed close to the downstream part so as to maintain dynamic sealing with respect to the surrounding atmosphere.

Abstract: This invention relates to the continuous production of molten glass for further production of glassware and can be used for glass melting and obtaining glass semiproduct. The technical objective of this invention is to provide a method and a furnace for producing molten glass with stabilized physical properties due to an increased phase boundary area, higher temperature in the glass furnace bath and intensified mixing as well as due to a higher output of the glass furnace. Molten glass layer bubbling glass melting method comprising melting the glass layer in the first chamber of the furnace to the working level, further uninterrupted loading of large and small charge portions into the molten glass layer with simultaneous intense bubbling of the molten glass layer with high-temperature combustion products aiming at the formation of the maximum possible charge/molten glass phase boundary area and achieving a molten glass temperature of at least 1500° C.

Abstract: A nozzle housing assembly, which is used in a convection heating furnace for a heat treatable glass sheet. The nozzle housing assembly comprises an elongated enclosure, at least one elongated heating resistance in the enclosure for heating convection air, and orifices in a bottom surface of the enclosure for blasting heated convection air against the glass sheet. The enclosure is divided with a flow-throttling partition into a top supply duct and a bottom nozzle box, the heating resistances being housed in the latter. Flow-throttling openings present in the partition are positioned to comply with the location and shape of the heating resistances.

Abstract: An apparatus for the production of a mineral melt burns combustible material in the presence of inorganic material to form a melt. The apparatus includes a circulating combustion chamber which receives a fuel, pre-heated mineral material and a combustion gas, melts the mineral material and generates exhaust gases which are separated from the melt. The gases pass through an exhaust pipe to a conduit of a heat exchange system. The apparatus includes a quenching hood for quenching the exhaust gases by drafting a cooling fluid, such as ambient air, into the flow of exhaust gases around the exhaust pipe, and wherein the exhaust gases exit the exhaust pipe inside the hood.

Abstract: A method and a system for thermal dewatering and preheating aqueous mixtures for feeding glass melting plants when passing through a shaft-like container provided with heating elements disposed one above another in tiers. To avoid the feed material from becoming glued together or agglomerating in the preheaters while the feed material is heated by exhaust gases with separately guided exhaust gases and feed material, a) the uppermost tier heating elements are closed relative to the mixture and are kept above 100 C, b) the interface between the mixture and the atmosphere above the mixture is shaped and heated by the uppermost tier heating elements so that part of the thermal output is emitted to the atmosphere via the mixture, and c) as the mixture proceeds through the container it is heated by further heating elements to temperatures close to the glass melting plant feeding temperature.

Abstract: Injecting one or opposed gaseous streams into the atmosphere over molten glassmaking materials in a glassmelting furnace, in a region of the refining zone, improves the quality of the glassmelt and lessens the risk of crown corrosion.

Abstract: A glass for a display substrate composed of 50 to 70% SiO2, 10 to 25% Al2O3, 8.4 to 20% B2O3, 0 to 10% MgO, 6 to 15% CaO, 0 to 10% BaO, 0 to 10% SrO, 0 to 10% ZnO, 0 to 5% TiO2, 0 to 5% P2O5, 0.01 to 0.2% alkali metal, and from 0.01% to less than 0.4% ZrO2, as expressed in % by mass. The glass can have a ?-OH value of 0.20/mm or more and an area of 0.1 m2 or more. The glass is produced by mixing raw materials to provide the SiO2, Al2O3, B2O3, MgO, CaO, BaO, SrO, ZnO, TiO2, P2O5 and alkali metal contents, electrically melting the raw materials in a melting furnace constructed of a high zirconia refractory; and refining, homogenizing and forming the glass melt.

Abstract: The invention relates to a method for melting vitrifiable materials in a low-capacity oven, wherein at least part of the melting energy is supplied by two oxy-burners projecting into the melting chamber through the upstream wall and arranged on opposite sides of a vertical plane in which a longitudinal axis of the melting chamber is situated, in such a way as to create two flames, the respective injection axes thereof crossing at a distance from the upstream wall, between ? and ¾ of the length L of the melting chamber.

Abstract: An apparatus and method for removing volatilized chemical compounds from within enclosed or partially enclosed spaces containing molten glass. One or more condensing devices are positioned within the enclosure to produce preferential condensation of the vapor on condensing elements of the condensing devices, thereby facilitating easy removal of the condensates from the enclosure. The condensing elements may have a variety of shapes and sizes depending on the design of the enclosure.

Abstract: A glass-melting furnace, which suppresses the effect of exhaust gas on molten glass quality, a process for producing molten glass, and a process and apparatus for producing glass products. The glass-melting furnace containing: a raw glass material particle feed portion disposed downwardly at a furnace wall portion in an upper portion of the glass-melting furnace; a heating unit provided under the feed portion, which forms a gas phase portion for converting raw glass material particles into liquid glass particles; a flue inlet disposed on the upstream side of the gas phase portion in a flow direction of the molten glass liquid; a furnace-bottom portion, which accumulates the liquid glass particles that produce the molten glass liquid; and a discharge portion, which discharges the molten glass liquid.

Abstract: A process for producing silicon which comprises: bringing molten silicon containing an impurity into contact with molten salt in a vessel to react the impurity contained in the molten silicon with the molten salt; removing the impurity from the system.

Abstract: Heat in a stream of combustion products obtained from a glassmelting furnace heated by oxy-fuel combustion is passed to incoming glassmaking materials in a heat exchanger without requiring reduction of the temperature of the stream yet without causing softening of the glassmaking material.

Abstract: The present invention relates to an apparatus and a method of making a mineral melt, the method comprising the steps of providing a circulating combustion chamber (1); injecting fuel, preheated mineral material and combustion gas into the circulating combustion chamber (1); combusting the fuel in the circulating combustion chamber (1) thereby melting the mineral material to form a mineral melt and generating exhaust gases; separating the exhaust gases from the mineral melt, collecting the mineral melt (9) and passing the exhaust gases (10) to a heat exchange system, the method being characterised in that the mineral material comprises a first mineral material and a second mineral material wherein the first mineral material has a higher sintering temperature than the second mineral material and the first and second mineral materials are provided separately to the heat exchange system, wherein the first mineral material is preheated through contact with the exhaust gases and subsequently the second mineral mate

Abstract: Corrosion of the inner surface of the crown of a glassmelting furnace is reduced or avoided by directing at low velocity along that surface a gaseous stream comprising water vapor, or comprising the combustion products of an oxy-fuel burner operated at a stoichiometric ratio of at least 1.0, or the combustion products of a burner operated at a stoichiometric ratio less than 1.0, or by injecting into the furnace interior a gaseous reactant which reacts with alkali species in said space.

Abstract: The present invention relates to a glass melting furnace comprising a channel-shaped melting tank, the batch materials being introduced at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which the combustion energy is produced by oxy-fuel combustion in respect of at least 65% thereof, the burners being distributed on the walls along the length of the furnace, in which flue gas discharge is mostly localized close to the upstream end near the openings through which the batch materials are introduced, the rest of the flue gas being removed close to the downstream part so as to maintain dynamic sealing with respect to the surrounding atmosphere.

Abstract: A method of manufacturing glass melt and a method of manufacturing molded glass material by forming glass melt. In the method of manufacturing glass melt, the glass melt containing fluorine is prepared by melting glass raw materials and refining the resulting glass melt. The refining is conducted in a refining vat equipped with a flow inlet through which flows glass melt obtained by heating and melting the glass raw materials, and a flow outlet through which flows glass melt that has been refined, with the level of the glass melt being maintained in such a manner that the flow inlet and flow outlet remain beneath the surface of the glass melt and the glass melt does not contact external air. The method of manufacturing a molded glass material comprises the step of molding the glass melt produced by the above method.

Abstract: When waste glass that is strongly laden with organic impurities is melted, the organic constituents present in the melt give rise to so-called “black hearts” which can no longer be eliminated in a subsequent refining process, thus impairing the quality of the glass. According to the invention, gas nozzles for introducing oxygen are installed in the area of the inlet opening of a melting unit thermally connected to a combustion chamber. This allows a targeted oxidation of the organic constituents, which are then exhausted in the form of exhaust gas. With the invention, even highly contaminated waste glass such as, for instance, glass fibers, can be returned to the production process.

Abstract: A process for producing a high-quality glass from highly reactive raw materials and a glass-melting apparatus for use therewith, comprising the step of charging a material for the glass to a molten glass in a heated vessel, (1) wherein an oxidizing gas is bubbled in the molten glass and a glass raw material that behaves as a reducing agent during being melted is charged into a position of the bubbling or (2) said vessel is filled with a dry ambient gas and while the ambient gas is allowed to flow to a liquid surface of the molten glass along an charging route of the glass raw material, the glass raw material is charged.

Abstract: A glass melting furnace has a gas inlet positioned proximate to a charging section oxy-fuel combustion region to introduce gas into the region and to at least partially displace gas having a partial pressure of alkali vapor from the region, and optionally a gas outlet is adapted to provide an exit for a volume of furnace atmosphere. A method for reducing alkali vapor corrosion of glass furnace refractory structures includes providing a gas inlet proximate to the oxy-fuel combustion region; introducing a volume of gas from the inlet into the region, displacing a volume of gas having a partial pressure of alkali vapor from the region; and, optionally providing a gas outlet adapted to provide an exit for a volume of furnace atmosphere.

Abstract: During the heating of glass melting furnaces having a combustion chamber with regenerators for preheating oxidation gases, with port necks that open into the combustion chamber, with primary burners and with secondary burners that are installed in a cascade arrangement relative to the primary burners, the secondary burners are operated as cascade burners with a relatively low proportion of the fuel, the secondary fuel. Flames are thereby created in over- and sub-stoichiometric conditions and the flame gases formed are mixed with one another so that the complete combustion process in the combustion chamber is more or less stoichiometric. The secondary fuel is supplied by the secondary burners to a step, installed in the port neck.

Abstract: When waste glass that is strongly laden with organic impurities is melted, the organic constituents present in the melt give rise to so-called “black hearts” which can no longer be eliminated in a subsequent refining process, thus impairing the quality of the glass.

Abstract: In an industrial glass furnace, which optionally contains recuperators, regenerators, electric boost or other devices for providing heat to glass batch material, at least one staged combustion oxy-fuel burner is mounted in the roof of the furnace to provide heat to melt the glass batch material by providing a flow of fuel to the oxy-fuel burner; providing a flow of gaseous oxidant in association with said the oxy-fuel burner; injecting the fuel and the oxidant into the furnace; and, combusting the fuel such that at least a portion of combustion is effected in the vicinity of said glass forming material to enhance convective and radiative transfer of heat to said glass forming material without substantially disturbing the glass forming material. In one embodiment, the oxy-fuel burner is adapted for injecting liquid fuels.

Abstract: In an industrial glass furnace which contains recuperators, regenerators, electric boost or other devices for providing heat to glass batch material an oxy-fuel burner mounted in the roof of the furnace provides additional heat to melt the batch material. A method of mounting and using such a roof-mounted oxy-fuel burner including the operating parameters to maximize heat transfer while minimizing the disturbance of the batch material is disclosed.

Abstract: Rock fibres are made from a melt formed from a blend of low and high halogen waste materials. 80 to 98% are low halogen materials (containing less than 0.5 wt. % halogen) and 2 to 20% are high halogen materials (containing at least 1 wt. % halogen).

Abstract: A method and apparatus is taught for preheating of glass batch materials by direct contact with glass furnace exhaust gases. Furnace gases 15 flow through a batch hopper 1 in horizontal tunnels formed by open bottom tubes 6, with a free surface of batch forming the bottom portion of the tunnel. The tubes are electrically grounded and a high voltage discharge electrode 18 is located axially in each tunnel. The corona discharge from the electrode acts to retain batch and prevent it's entrainment into the flowing gases. Particulate matter from the gases is simultaneously precipitated onto the batch surface. Acidic gas components such as SO2, HCl, and HF are chemically reacted with batch constituents, thereby removing them from the gas stream. Heat is transferred from the gases to the batch by direct contact. Cooled gases 16 exit the hopper, cleaned of pollutants to levels in compliance with strict environmental regulations.

Abstract: The present invention relates to a vitrification process for a pulverulent material and an apparatus for implementing said process. The process consists in introducing the pulverulent material into the fusion area of a furnace via injection means, where it is melted by means of at least one plasma torch to obtain a melt, and where the melt is removed from the furnace via a casting zone, the material being introduced laterally into the fusion zone in a direction comprising a horizontal component, and the melt being removed from the furnace by overflowing via the said casting zone, more or less along said horizontal component and away from the means for injecting the material into the furnace, in relation to the fusion zone.

Abstract: Glass is produced in a glassmelting furnace by combusting fuel and oxidant having an oxygen content greater than 80 vol. % oxygen in a melting zone to form molten glass, wherein the surface of the molten glass is exposed to the gaseous atmosphere in the melting zone and the water vapor content of the atmosphere at the surface of the molten glass is greater than 35 vol. %, and oxidant having an oxygen content greater than 80 vol. % is injected into the refining zone of the furnace under conditions to minimize mixing of said oxidant with gases above said oxidant and sweep water vapor at the surface of the molten glass into the melting zone to lower the water vapor content of the atmosphere at the surface of the molten glass.

Abstract: Methods for producing high purity fused silica (HPFS) glass having desired levels of dissolved hydrogen are provided. The methods involve measuring the level of hydrogen in the cavity of the furnace used to produce the glass and controlling the pressure within the furnace and/or gas flows to the furnace's burners so that the measured concentration has a desired value. In this way, the level of dissolved hydrogen in the glass can be controlled since, as shown in FIG. 3, there is a direct correlation between the hydrogen concentration in the cavity atmosphere and level of dissolved hydrogen in the glass.

Abstract: A process and furnace for melting glass is set forth wherein the majority of the combustion energy over the melting zone of the furnace is provided by oxy-fuel combustion while a majority of the combustion energy over the fining zone of the furnace is provided by air-fuel combustion. In many cases, it will be preferable to provide greater than 70% and up to and including 100% of the combustion energy over the melting zone by oxy-fuel combustion and greater than 70% and up to and including 100% of the combustion energy over the fining zone by air-fuel combustion. By proper tailoring of the combustion space atmosphere through oxy-fuel and air-fuel firing, the present invention can result in an improvement in glass productivity and quality. The present invention can be applied in the construction of a new furnace or can be applied to existing air-fuel furnaces.

Abstract: A glass melting furnace has a gas inlet positioned proximate to a charging section oxy-fuel combustion region to introduce gas into the region and to at least partially displace gas having a partial pressure of alkali vapor from the region, and optionally a gas outlet is adapted to provide an exit for a volume of furnace atmosphere. A method for reducing alkali vapor corrosion of glass furnace refractory structures includes providing a gas inlet proximate to the oxy-fuel combustion region; introducing a volume of gas from the inlet into the region, displacing a volume of gas having a partial pressure of alkali vapor from the region; and, optionally providing a gas outlet adapted to provide an exit for a volume of furnace atmosphere.

Abstract: A method for melting glass forming batch material includes charging the glass forming batch material to a glass melting apparatus; impinging a flame proximate to the surface of the batch materials to form a glass melt from the batch material; and bubbling the glass melt in proximity to the impinging flame with a fluid, advantageously producing a shearing action sufficient to enhance the solution rate of the glass forming batch material relative to the same system without bubbling, but without splashing glass and without significant production of seeds or blisters in the glass melt. Melting of the glass forming batch material with bubbling proceeds more quickly, and/or at lower temperatures than occurs in a comparable conventional glass melting furnace.

Abstract: During the heating of glass melting furnaces having a combustion chamber with regenerators for preheating oxidation gases, with port necks that open into the combustion chamber, with primary burners and with secondary burners that are installed in a cascade arrangement relative to the primary burners, the secondary burners are operated as cascade burners with a relatively low proportion of the fuel, the secondary fuel. Flames are thereby created in over- and sub-stoichiometric conditions and the flame gases formed are mixed with one another so that the complete combustion process in the combustion chamber is more or less stoichiometric. The secondary fuel is supplied by the secondary burners to a step, installed in the port neck.

Abstract: In an industrial glass furnace which contains recuperators, regenerators, electric boost or other devices for providing heat to glass batch material an oxy-fuel burner mounted in the roof of the furnace provides additional heat to melt the batch material. A method of mounting and using such a roof-mounted oxy-fuel burner including the operating parameters to maximize heat transfer while minimizing the disturbance of the batch material is disclosed.

Abstract: A system for melting and delivering glass to a work area such as spinners for making fiberglass includes a melter with heaters so arranged that the “hot spot” in the molten glass is located away from the walls and corrosion sensitive parts so that the various elements of the melter wear out at substantially the same time. The system is further provided with a dual exhaust arrangement when the melter, conditioner and forehearth are located on the same floor of the plant, the first exhaust being at the juncture of the melter and conditioner, and the second being an alternating replacement for one of the heating/cooling orifices and mechanisms in the conditioner, so as to effectively limit the amount of corrosive volatiles reaching the forehearth.

Abstract: A system for melting and delivering glass to a work area such as spinners for making fiberglass includes a melter with heaters so arranged that the “hot spot” in the molten glass is located away from the walls and corrosion sensitive parts so that the various elements of the melter wear out at substantially the same time. The system is further provided with a dual exhaust arrangement when the melter, conditioner and forehearth are located on the same floor of the plant, the first exhaust being at the juncture of the melter and conditioner, and the second being an alternating replacement for one of the heating/cooling orifices and mechanisms in the conditioner, so as to effectively limit the amount of corrosive volatiles reaching the forehearth.

Abstract: During the melting of glass from charging material in furnaces with burners and regenerators for the recovery of waste heat, oxygen and primary fuel are introduced into the area around the flame roots under slightly sub-stoichiometric conditions to cover the heat requirement of the melting process. In order to further reduce the levels of NOx, and CO in the waste gases by re-burning or post oxidation, secondary fuel and, further downstream, additional air are introduced beyond the flame in order to reduce the level of NOx, in or above the checkerwork by means of the secondary fuel and to carry out re-burning or post oxidation downstream by means of the supply of air, so that ultimately approximately stoichiometric combustion takes place. Before the waste gases enter a waste gas stack they are used to preheat the charging material in at least one raw material pre-heater.

Abstract: A method and apparatus is taught for preheating of glass batch materials by direct contact with glass furnace exhaust gases. Furnace gases 15 flow through a batch hopper 1 in horizontal tunnels formed by open bottom tubes 6, with a free surface of batch forming the bottom portion of the tunnel. The tubes are electrically grounded and a high voltage discharge electrode 18 is located axially in each tunnel. The corona discharge from the electrode acts to retain batch and prevent it's entrainment into the flowing gases. Particulate matter from the gases is simultaneously precipitated onto the batch surface. Acidic gas components such as SO2, HCl, and HF are chemically reacted with batch constituents, thereby removing them from the gas stream. Heat is transferred from the gases to the batch by direct contact. Cooled gases 16 exit the hopper, cleaned of pollutants to levels in compliance with strict environmental regulations.

Abstract: A method for regulating or controlling the content of NOx in the exhaust gases of a glass-melting furnace having several burners operated in alternation, wherein both the beginning and the end of a combustion break (FP+, FP−) are supplied to a binary signal generator (8) which passes a signal to a regulator (4) with a time delay and upon receipt of the time-regulator (4), and the amount of NH3 supplied to the denitrating plant is adjusted to a lower constant fixed value F1 via a control, and by means of a memory element (7) a higher constant fixed value F2 is calculated as amount of NH3 and supplied to the regulator (4), whereupon as soon as the regulator (4) has received the signal of the time-delayed end of a combustion break, the fixed value F1 is adjusted to the fixed value F2 via a control, and subsequently the regulation is directly continued.