Abstract: The present invention provides a process for producing a titanium-containing metal oxide the coloration of which is decreased; a hologram recording material suitable for holographic memory recording using a blue laser, wherein a titanium-containing metal oxide the coloration of which is decreased is used as a metal oxide matrix; a process for producing the same; and a hologram recording medium. A process for producing a metal oxide comprising at least Ti as a metal element, the process comprising: providing an alkoxide compound of Ti to which a glycol other than any geminal diol and any vicinal diol is coordinated; hydrolyzing the alkoxide compound of Ti to which the glycol is coordinated, thereby yielding a precursor of a metal oxide; and advancing polycondensation reaction of the metal oxide precursor, thereby forming the metal oxide.

Abstract: Embodiments relate to a transparent body comprising a matrix material and a plurality of non-metal particles positioned in the matrix material. The matrix material may be selected from the group consisting of glass materials, ceramic materials, and semiconductor materials. The non-metal particles may have a mean particle size of no greater than 150 nm. The non-metal particles may be present in the body at a volume fraction of no greater than 3 percent. The non-metal particles may have a composition different than that of the matrix. Other embodiments are described and claimed.

Abstract: A transparent glass or glass ceramic pane is provided that includes a glass or glass ceramic substrate having a thermal expansion coefficient a of less than 4.2 and an infrared radiation-reflecting layer, formed as a single-layer reflection layer and having a refractive index greater than 2.2.

Abstract: A process for producing a transparent or opaque silica glass product including mixing a silica fine powder and a cellulose derivative and injection molding the mixture, followed by degreasing treatment and baking treatment, which is characterized in that the cellulose derivative is a cellulose derivative which causes reversible thermal gelation in an aqueous solution of at least one member selected from methyl cellulose, hydroxypropylmethyl cellulose and hydroxyethylmethyl cellulose; in producing a transparent silica glass product, the cellulose derivative is added in water heated at a gelation temperature thereof or higher, and after cooling, the formed aqueous solution is kneaded with the silica fine powder; and in producing an opaque silica glass product, the cellulose derivative is added in a silica slurry containing a silica powder and heated at a gelation temperature of the cellulose derivative or higher.

Abstract: In a production process of an organic-inorganic hybrid glassy material, the invention relates to a process for producing an organic-inorganic hybrid glassy material, characterized in that the process comprises at least the three steps of producing a gel body by a sol-gel method; melting by heating; and aging, and it relates to an organic-inorganic hybrid glassy material produced by this process.

Abstract: Embodiments of the invention provide organosilicon silicon nanoparticle composites, where the silicon nanoparticles are highly luminescent. Preferred embodiments of the invention are Si—O solid composite networks, e.g., glass, having a homogenous distribution of luminescent hydrogen terminated silicon nanoparticles in a homogenous distribution throughout the solid. Embodiments of the invention also provide fabrication processes for organosilicon silicon nanoparticle composites. A preferred method for forming an organosilicon nanoparticle composite disperses hydrogen terminated silicon nanoparticles and an inorganic precursor of an organosilicon gel in an aprotic solvent to form a sol. A catalyst is mixed into the sol. The sol is then permitted to dry into a gel of the organosilicon nanoparticle composite.

Abstract: A process for producing a transparent or opaque silica glass product including mixing a silica fine powder and a cellulose derivative and injection molding the mixture, followed by degreasing treatment and baking treatment, which is characterized in that the cellulose derivative is a cellulose derivative which causes reversible thermal gelation in an aqueous solution of at least one member selected from methyl cellulose, hydroxypropylmethyl cellulose and hydroxyethylmethyl cellulose; in producing a transparent silica glass product, the cellulose derivative is added in water heated at a gelation temperature thereof or higher, and after cooling, the formed aqueous solution is kneaded with the silica fine powder; and in producing an opaque silica glass product, the cellulose derivative is added in a silica slurry containing a silica powder and heated at a gelation temperature of the cellulose derivative or higher.

Abstract: An apparatus for and method of depositing material on a substrate, the method comprising the steps of: delivering from a first outlet a stream of droplets of a precursor liquid towards a substrate; applying an electric field between the first outlet and the substrate; and delivering from a second outlet a flow of fuel about the stream of droplets such as to provide an annular flame combustion region between the first outlet and the substrate through which at least a portion of the stream of droplets passes before reaching the substrate, whereby the precursor liquid is one or both of chemically reacted and decomposed to provide the deposited material.

Abstract: An optical element includes an optical surface formed by a press molding method, wherein a ray effective portion of the optical surface has formed thereon an antireflection structure including a minute uneven structure, which contains a component different from that of a base of the optical element and has an average pitch of 400 nm or less.

Abstract: Methods for producing an independent glass ceramic film including the steps of mixing a colloidal silica sol having a pH of about 4 or less, a zirconium-containing compound, a binder, and a crosslinking agent capable of crosslinking with the binder at about 50° C. or less, to produce a mixed liquid; coating the mixed liquid on a substrate; drying the coated mixed liquid to form a precursor film on the substrate; separating the precursor film from the substrate; and firing the separated precursor film. A precursor liquid that includes colloidal silica sol having a pH of about 4 or less, a zirconium-containing compound, a binder, and a crosslinking agent capable of crosslinking with the binder at about 50° C. or less is also disclosed.

Abstract: The invention relates to the production and use of a gray hue palette for decorative coatings based on a sol-gel method for glass and glass-ceramic articles, wherein flake-form pigments and solid lubricant are used in specific mass ratios as decorative pigments. The pigmentation provides a high-temperature-stable decorative layer, has good adhesive strength between the substrate and the decorative layer, has good impermeability relative to fluids and gases during use, as well as a high resistance to scratching. The invention further relates to glass or glass-ceramic articles with decorative coatings which are produced, in particular, according to the method of the invention, which are suitable particularly for use as glass-ceramic cooktops due to the named good layer properties of the decorative layer.

Abstract: The invention relates to a method for producing monolithic molded elements e.g. as sorbents for chromatographic columns or capillary vessels. The aim of the invention is for said molded elements to be able to remain directly in the gel mold thereof following the production process. Said aim is achieved by the inventive method, according to which the surface of the gel mold is activated by etching, increasing the surface, or chemically modifying the surface before the gelling mold is filled with the monomer sol.

Abstract: As a jig material to use under plasma reaction for producing semiconductors, the present invention provides a quartz glass having resistance against plasma corrosion, particularly corrosion resistance against fluorine-based plasma gases, and which is usable without causing anomalies to silicon wafers; the present invention furthermore provides a quartz glass jig, and a method for producing the same. A quartz glass containing 0.1 to 20 wt % in total of two or more types of metallic elements, said metallic elements comprising at least one type of metallic element selected from Group 3B of the periodic table as a first metallic element and at least one type of metallic element selected from the group consisting of Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, lanthanoids, and actinoids as a second metallic element, provided that the maximum concentration of each of the second metallic elements is 1.0 wt % or less.

Abstract: The methods and materials described herein provide novel and simple procedures for the preparation of nano/macroporous glasses, in which the pore structure is characterized by interconnected pores of, e.g. both hundreds of micrometers and several to tens of nanometers in size. Such materials may be used for enhanced bone regeneration, bioscaffolds, drug delivery devices, and filtration media, among other uses. For example, silica-based bone tissue scaffolds are made with a controlled nano/macroporosity, which enhances bone regeneration performance. Also provided herein are new biocompatible CaO—Na2O—P2O5—SiO2 glasses prepared by thermal melt-quench methods that result in spinodal phase separation and crystallization of phases at very different length scales. Selective chemical leaching of these phases causes formation of interconnected multi-modal porosity, with pore sizes ranging from several nanometers to tens of micrometers.

Abstract: Methods for producing glass powders are provided. The methods include generating an aerosol stream comprising droplets that include a liquid and a glass precursor. Glass particles are formed in the aerosol stream having a small average particle size. The powders can also have a small particle size, narrow size distribution, a high density and a spherical morphology. The invention also includes devices and products formed from the glass powders.

Abstract: Method for the production of glassy monoliths via the sol-gel process, whereby the sol is gelled and dried to a Xerogel, which is sintered to a glassy monolith.

Abstract: The present invention relates to a household glass product, comprising a glass surface and a switchable hydrophobic or hydrophilic coating which is applied to at least a region of the glass surface, wherein at least the region of the surface of the household glass product to which the coating is applied is roughened and has a root mean square roughness value Ra in the range of 0.1 to 50 nm, so that the surface has a super-hydrophobic or super-hydrophilic property, and to a method for producing such a household glass product.

Abstract: Sol-gel process comprising preparation of a solution of at least one compound having the formula Xm-M-(OR)n-m addition to the solution of the dopants, hydrolysis of the compound to form the sol, possible addition of an oxide, gelling the sol, recycling the liquid and adjusting the pH-value of the liquid in order to fix the dopants in the aquagel, gel drying and densifying to obtain the glass.

Abstract: Sol-gel process for the production of large glass monoliths, whereby tetraalkoxysilane is added to a dispersion of pyrogenically produced silica and the ratio of SiO2:TEOS is 2.6 to 5.5:1.

Abstract: The invention discloses a glass-ceramic composition, a slurry, and a method for manufacturing a dielectric ceramic component with high frequency. The glass-ceramic composition comprises 5-30 wt % of aluminum oxide and 70-95 wt % of BiZnBSiAl glass. The invention mixes the glass-ceramic composition with an organic carrier to make a slurry, processes the slurry into green body, and then densities the green body to obtain dielectric ceramic component with high frequency, which can be sintered and densified under low temperature. Accordingly, the product of quality factor and resonance frequency of the component can meet the requirements of high quality factor and dielectric constant for industries.

Abstract: A laminated sheet includes a surface layer having an optical surface that is of fire-polished quality and a core layer having a higher modulus than the surface layer to increase an overall stiffness or fracture toughness of the laminated sheet.

Abstract: A process for the production of a self-supporting glass film is described. The method includes the steps of preparing a mixture containing a colloidal silica sol, at least one alkanolamine organic additive and an organic binder; coating the mixture onto a base material; drying the coated mixture to form a precursor film on the base material; releasing the precursor film from the base material; and firing the released precursor film to form a self-supporting glass film. Self-supporting glass films produced by the disclosed process are also described.

Abstract: A process is described for production of a self-supporting glass film that includes the steps of preparing a boron-containing aqueous solution containing boric acid and an alkanolamine; producing a mixture that includes the boron-containing aqueous solution, a colloidal silica sol and an organic binder; applying the mixture onto a base material to form a coating; drying the coating to form a precursor film on the base material; releasing the precursor film from the base material; and firing the released precursor film. A self-supporting glass film prepared using this process is also described.

Abstract: A method of making a thin film transistor comprises (a) solution depositing a dispersion comprising semiconducting metal oxide nanoparticles onto a substrate, (b) sintering the nanoparticles to form a semiconductor layer, and (c) optionally subjecting the resulting semiconductor layer to post-deposition processing.

Abstract: 12CaO.7Al2O3 polycrystal having high conductivity is provided. It has become obvious that the conductivity of the 12CaO.7Al2O3 polycrystal becomes 100 [S/cm] or more by controlling a nitrogen content in the 12CaO.7Al2O3 polycrystal within a range of 0.3 to 1.1 [wt %], and that the conductivity becomes 150 [S/cm] or more by controlling the nitrogen content within a range of 0.5 to 0.9 [wt %].

Abstract: The invention provides a method for producing a quartz glass jig for use in semiconductor industries, which enables increasing the surface layer cleanliness simply and surely at low cost; it also provides a quartz glass jig improved in surface layer cleanliness. The inventive means for resolution are a method comprising processing a quartz glass raw material into a desired shape by a treatment inclusive of fire working, annealing for stress removal, and cleaning treatment to obtain the final product, the method is characterized by that it comprises performing gas phase etching step and gas phase purification step on the surface layer of the quartz glass jig after applying the annealing treatment for stress removal but before the cleaning treatment, wherein the gas phase purification step is carried out continuously after the gas phase etching step.

Abstract: A photomask assembly is described having a frame for supporting a transparent pellicle above a photomask substrate, defining a closed pellicle space overlaying the substrate. The frame is formed of a porous material configured to allow the pellicle space to be purged with an inert gas within a reasonable processing time period, thereby removing any harmful chemicals that might be present. The frame preferably is made by a method that includes preparing a gel by a sol-gel process, drying the gel, and partially densifying the dry gel. The resulting frame has a gas permeability to oxygen or nitrogen higher than about 10 ml.mm/cm2.min.MPa, an average pore size between 0.001 micrometer and 10 micrometers, and a coefficient of thermal expansion between 0.01 ppm/° C. and 10 ppm/° C.

Abstract: The present invention relates to a preform for a glass ferrule and a fabrication method thereof. It is an objective of the present invention to fabricate dual hole ferrules having various distances between two holes by using a single preform. It is another objective of the present invention to fabricate a preform for a dual hole glass ferrule by a simple process. To meet the above and other objectives, the present invention provides a preform for a glass ferrule, comprising two holes which are formed through the preform and exit out both side cross-sections of the preform, wherein the two holes are symmetrical to the center in a diameter direction of the preform and a distance between the two holes changes in a lengthwise direction of the preform.

Abstract: It has been discovered that aquagels, formed from acid catalized composite sols, survive to conditions of high-tension when they are prepared by a process that hydrolyzes the silicon alkoxides in presence of fumed silica. The aquagel can be used for the production of monoliths of glass.

Abstract: In the production of an organic-inorganic hybrid glassy material using raw materials which are used in a sol-gel process as starting materials, the present invention relates to a process for producing an organic-inorganic hybrid glassy material, which is characterized in that, there is a heating reaction step between a mixing step and a melting step of the starting materials and there is further an aging step after the melting step. In accordance with the present invention, an organic-inorganic hybrid glassy material satisfying both heat resistance as well as airtight property and low-melting characteristic, which has been believed to be very difficult to produce, is now able to be produced in a very shorter period than before.

Abstract: A conformable nosing device is described herein which conforms to have a bowed shape that substantially matches a bowed shape of a glass sheet and which engages the glass sheet to help minimize the motion of the glass sheet and to help reduce the stress within the glass sheet while the glass sheet is being scored and separated into individual glass sheets. In addition, the conformable nosing device can include a passive nosing device which can be controlled to further help minimize the motion of the glass sheet while the glass sheet is being scored and separated into individual glass sheets.

Abstract: Method for fabricating a glass-monolith by the sol-gel process, in which a pyrogenically produced silica (fumed silica) is used in the form of a powder and/or a dispersion, characterized in that as pyrogenically produced silica (fumed silica) a silica (fumed silica) deriving from the group highly pure, pyrogenically produced silica (fumed silica) with a metal content of lower than 9 ppm and/or a pyrogenically prepared silicon dioxide powder having—a BET surface area of 30 to 90 m2/g, —a DBP number of 80 or less, an average aggregate area of less than 25,000 nm2, an average aggregate circumference of less than 1,000 nm, at least 70% of the aggregates having a circumference of less than 1,300 nm is used.

Abstract: A fused silica glass having a composition for use in bulk IR optical applications. The fused silica glass has a OH concentration of less than 5 ppm (parts per million) by weight and an absorbance of less than about 50 ppm/cm at a wavelength of about 1.3 ?m. A method of making the fused silica glass is also described.

Abstract: Ultraporous sol gel monoliths and methods for preparing the same are provided, having superior flow characteristics for chromatography and analytical chemistry applications. The methods for forming an ultra porous sol-gel monolith include (a) forming a solution comprising a porogen, a matrix dissolving catalyst and a sol gel precursor; (b) allowing the solution to form a gel; and (c) drying the gel at an elevated temperature. The ultraporous sol gel monoliths are characterized by a porosity of up to about 97%, a BET surface area of at least about 50 m2/g and substantially no micropores.

Abstract: In order to avoid haloing when burning in a decoration on a glass ceramic substrate, the invention provides a method for producing a decorated glass ceramic substrate, in which a glass substrate is produced or provided, a layer containing silicon oxide is deposited on the substrate, decorative ink is applied on the layer containing silicon oxide and the decorative ink is burned in, wherein the layer containing silicon oxide is flame-pyrolytically deposited by sweeping over at least one region of the surface of a substrate with a flame and hydrolyzing a silicon compound added to the flame.

Abstract: Subjects for the invention are to obtain a quartz powder having a high purity and high quality and a process for producing the same and to obtain a glass molding formed by melting and molding the powder and extremely reduced in bubble inclusion. The invention provides a quartz powder, preferably a synthetic quartz powder obtained by the sol-gel method, which, upon heating from room temperature to 1,700° C., generates gases in which the amount of CO is 300 nl/g or smaller and the amount of CO2 is 30 nl/g or smaller.

Abstract: A production process which comprises a preform formation step of forming a fiber preform made of silicon carbide short fibers having heat resistance of 1000° C. or greater; a sol-gel preparation step of preparing a sol-gel solution containing a heat resistant compound having heat resistance of 1000° C. or greater; an impregnation-drying-calcination step of impregnating the fiber preform with the sol-gel solution, followed by drying and calcining; and a crystallization step of crystallizing the fiber preform after impregnation, drying and calcination.

Abstract: Process for the production of monoliths of glass by means of the sol-gel process, comprising the following steps: a) dispersion in water of an oxide prepared by the pyrogenic route, b) hydrolysis of an alkoxide in aqueous solution to form a hydrolysate, c) mixing of the hydrolysate of the alkoxide with the oxide prepared by the pyrogenic route to form a colloidal sol, d) optional removal of coarse contents from the colloidal sol, e) gelling of the colloidal sol in a mould, f) replacement of the water contained in the resulting aerogel by an organic solvent, g) drying of the aerogel, h) heat treatment of the dried aerogel.

Abstract: The method produces a coated three-dimensionally shaped glass ceramic body, especially a viewing window pane, which is provided with a reflective, anti-reflective or partially reflective layer. The method includes coating a flat green glass body to produce a coated green glass body and subsequently shaping the coated green glass body and ceramizing to form the coated three-dimensionally shaped glass ceramic body. In preferred embodiments the shaping the ceramizing occur at the same time. The reflective or anti-reflective coating is preferably applied to the green-glass body by an economical sol-gel process.

Abstract: Glass panels are manufactured from cracked windshields and other pieces of safety glass. Manufacturing glass panels from cracked safety glass prevents the cracked safety glass from being placed into landfills. The method of manufacturing glass panels from cracked safety glass does not require melting the glass and thus provides a low energy solution for recycling cracked safety glass.

Abstract: The invention relates to an improved method of manufacturing a compound having a sub-micron primary particle size such as a metal compound such as metal oxides, metaloxy hydroxides metal hydroxides, metal carbides, metal nitrides, metal carbonitrides, metal borides, electroceramics and other such compound, said method comprising the steps of: introducing a solid reactor filling material in a reactor, introducing a metal-containing precursor, a semi-metal-containing precursor, a metal-containing oxide or a semi-metal-containing oxide in said reactor, introducing a reactant or a substitution source into the said reactor, and introducing a supercritical solvent into the said reactor. These steps result in the formation of said compound in the proximity of the said solid reactor filling material.

Abstract: The present invention provides an optical synthetic quartz glass material which substantially does not cause changes in transmitted wave surface (TWS) by solarization, compaction (TWS delayed), rarefaction (TWS progressed) and photorefractive effect when ArF excimer laser irradiation is applied at a low energy density, e.g. at energy density per pulse of 0.3 mJ/cm2 or less. The present invention further provides a method for manufacturing the same. In order to solve the above-mentioned problems, the optical synthetic quartz glass material of the present invention is characterized in that, in a synthetic quartz glass prepared by a flame hydrolysis method using a silicon compound as a material, the followings are satisfied that the amount of SiOH is within a range of more than 10 ppm by weight to 400 ppm by weight, content of fluorine is 30 to 1000 ppm by weight, content of hydrogen is 0.

Abstract: A method for fabricating silica glass is disclosed. The method includes the steps of (a) hydrolyzing silicon alkoxide; (b) hydrolyzing heterometal alkoxide containing Bi and Ti components; (c) mixing a solution containing hydrolyzed products of the silicon alkoxide and a solution containing hydrolyzed products of the heterometal alkoxide, thus forming a mixed solution; (d) molding gel by pouring the mixed solution into a forming mold; (e) drying the molded gel; and (e) performing heat-treatment of the dried gel so as to vitrify the gel.

Abstract: The present invention is directed to method of bonding mineral fibers in a mineral fiber material, according to which an acid is applied to the mineral fiber material in an amount sufficient to dissolve mineral material from the fiber to form a silica containing binder on the mineral fiber, and curing the mineral fiber material to bond the fibers.

Abstract: It is described a sol-gel process that allows to obtain dry gels, and possibly the corresponding dense glassy bodies, having higher dimensions compared to similar known processes.

Abstract: Methods of reducing the intrusions or migrations of photolithography materials by introducing a sol-gel layer onto a porous thin film prior to applying the photolithography/photoresist material layer. Curing the sol-gel layer results in the sol-gel layer merging or unifying with the underlying porous thin film layer so that the combined sol-gel/thin layer exhibits substantially the same properties as the untreated porous thin film layer before the sol-gel was applied. As a result, a greater etching accuracy is achieved.

Abstract: Glassy articles are prepared by subjecting to hydrolysis and policondensation a solution or suspension of a suitable precursor, mainly comprising a silicon alkoxide, and by drying the obtained gel in a pressure chamber, the gel solvent having been substituted by a non-protic solvent, mainly acetone, under nitrogen flowing, at temperature and pressure conditions lower than the gel solvent critical values. The dried gel is then densified by a thermal treatment.

Abstract: Techniques for producing a glass structure having interconnected macroscopic pores, employing steps of filling polymerizable glass precursors into pores in a polymeric structure having interconnected macroscopic pores; polymerizing the precursors; and decomposing the polymers to produce a glass oxide structure having interconnected macroscopic pores. Further techniques employ steps of exposing portions of a photosensitive medium including glass precursors to an optical interference pattern; polymerizing or photodeprotecting the exposed portions and removing unpolymerized or deprotected portions; and decomposing the polymerized or deprotected portions to produce a glass structure having interconnected macroscopic pores. Techniques for filling pores of such glass structure with a material having a high refractive index, and for then removing the glass structure.

Abstract: Silica sol techniques are described for making thick silica or silica based films useful for planar optical waveguides. The process involves coating of a colloidal silica sol onto a substrate, drying the sol, and consolidating the dried sol to form the planar waveguide. Coating is performed in a simple operation, either by dipping, or preferably by spin coating. In a preferred embodiment the substrate is coated with a wetting agent prior to spin coating. It is found that the wetting agent substantially improves the thickness uniformity of the layer. Thick waveguide layers may be produced by repeating the coating process one or more times to produce a layer with the desired thickness. Buried waveguides are produced by forming a doped core layer, patterning the doped core layer and using the coating technique of the invention to form the cladding material.

Abstract: The invention relates to a method for manufacturing optical glasses and colored glasses with the aid of a fluid phase sintering process from a basic material encompassing at least SiO.sub.2 powder as well as additives for reducing the temperature of the fluid phase sintering and/or melting process encompassing the following steps: the starting materials are dissolved in any sequence in a fluid medium to produce a solution as far as is possible and a suspension to the extent that they are not dispersed in solution; a greenbody is produced from the dissolved and dispersed starting materials; the greenbody is dried the dried greenbody is fluid-phase sintered at temperatures below 1200° C., in particular in the temperature range from 600° C. to 1200° C.