To Enhance The Ability To Darken Or Change Color In Response To Radiation Exposure (e.g., Photochromic) Patents (Class 65/30.11)
  • Patent number: 9434781
    Abstract: The invention provides compositions and methods of treating subjects afflicted with a photoreceptor disorder. Methods for treating a subject suffering from a disorder characterized by photoreceptor cell degeneration are provided, wherein a gene encoding a photosensitive protein is introduced into a retinal cell of a subject. In one aspect of the invention, the retinal cells which receive the photosensitive protein include non-photoreceptor cells such as horizontal cells, amacrine cells, bipolar cells, and ganglion cells.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: September 6, 2016
    Assignee: THE GENERAL HOSPITAL CORPORATION
    Inventor: Richard H. Masland
  • Patent number: 8997522
    Abstract: A method of making a glass container with an optically readable graphic data carrier. A glass container is exposed to electromagnetic radiation to produce discoloration within the glass of the container, and then focused beam energy is directed at the glass container in a pattern corresponding to a desired graphic data carrier to heat the glass and selectively remove the discoloration in the pattern corresponding to the desired graphic data carrier.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: April 7, 2015
    Assignee: Owens-Brockway Glass Container Inc.
    Inventors: Carol A. Click, Brian J. Chisholm, Edward Ordway
  • Publication number: 20130341228
    Abstract: A method of making a glass container with an optically readable graphic data carrier. A glass container is exposed to electromagnetic radiation to produce discoloration within the glass of the container, and then focused beam energy is directed at the glass container in a pattern corresponding to a desired graphic data carrier to heat the glass and selectively remove the discoloration in the pattern corresponding to the desired graphic data carrier.
    Type: Application
    Filed: June 26, 2012
    Publication date: December 26, 2013
    Inventors: Carol A. Click, Brian J. Chisholm, Edward Ordway
  • Patent number: 8534095
    Abstract: The invention is directed to a glass composition and articles made from the composition that are both polarizing and photorefractive. The glass has, for example, a composition consisting essentially of, in weight percent (“wt. %”) of 70-73 SiO2, 13-17% B2O3, 8-10% Na2O, 2-4% Al2O3, 0.005-0.1% CuO, <0.4% Cl, 0.1-0.5% Ag, 0.1-0.3% Br. In another embodiment the composition consists essentially of 70-77% SiO2, 13-18% B2O3, 8-10% Na2O, 2-4% Al2O3, 0.005-0.1% CuO, <0.4% Cl, 0.1-0.5% Ag, 0.1-0.3% Br. The glass can be used make articles or elements that can exhibits both the photorefractive effect and the polarizing effect within a single element or article, and can be used to make a variety of optical elements including Bragg gratings, filtering elements, and beam shaping elements and light collection elements for use in display, security, defense, metrology, imaging and communications applications.
    Type: Grant
    Filed: April 11, 2012
    Date of Patent: September 17, 2013
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, Joseph Francis Schroeder, III, Thomas P. Seward, III
  • Publication number: 20100134705
    Abstract: A glass polarizer having an excellent transmittance and extinction ratio with respect to light in the visible light range including blue using silver halide containing glass as a starting material is provided. A manufacturing method according to the present invention to manufacture glass polarizers is characterized in that borosilicate glass in which silver halide particles are dispersed and deposited by heat treatment is reduced to generate metallic silver particles from at least a portion of silver halide and then, heated for stretching to generate silver halide particles oriented and stretched in the glass.
    Type: Application
    Filed: March 4, 2008
    Publication date: June 3, 2010
    Inventors: Khaled Jabri, Nobuhito Takeshima, Atsushi Arai, Hiromichi Nishimura, Toshiharu Yamashita, Yoshihiko Noro
  • Publication number: 20100016141
    Abstract: The present invention relates to an apparatus and a method for dyeing glass and, more particularly, an apparatus and a method, by which both surfaces of hot sheet-like glass may be dyed simultaneously and/or the surface containing tin residues of the sheet glass may be dyed to have a different colour than the surface without tin residues. The apparatus of the invention may be used for dyeing both sheet glass and utility glass, such as glass beakers.
    Type: Application
    Filed: October 22, 2007
    Publication date: January 21, 2010
    Applicant: BENEQ OY
    Inventors: Markku Rajala, Jussi Wright, Joe Pimenoff, Kai Asikkala, Jari Sinkko
  • Patent number: 7648656
    Abstract: The invention is directed to a silver-containing polarizing boroaluminosilicate glass composition that has been doped with a noble metal selected from the group consisting of Pt, Pd, Os, Ir, Rh and Ru, including mixtures thereof, to nucleate and precipitate silver ions to silver metal without the need for a reducing atmosphere step. The invention is further directed to a method for making the glass composition of the invention. Using the composition and method of the invention, one can prepare a glass having a selected null transmission range.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: January 19, 2010
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, George Bigelow Hares, David John McEnroe, Joseph Francis Schroeder, III
  • Patent number: 7584630
    Abstract: Described are photochromic ocular devices such as contact lenses and intraocular lenses made of an organic polymeric material and at least one photochromic material capable upon exposure to actinic radiation to change from a less ultraviolet radiation absorbing unactivated form to a more ultraviolet radiation absorbing activated form. The photochromic ocular device is capable upon exposure to actinic radiation to exhibit a ratio of greater than 0.5:1.0 of increased ultraviolet radiation absorbance to increased visible radiation absorbance as measured in the Ultraviolet Photochromic Performance Test described herein.
    Type: Grant
    Filed: August 3, 2005
    Date of Patent: September 8, 2009
    Assignee: Transitions Optical, Inc.
    Inventor: Barry Van Gemert
  • Patent number: 7573630
    Abstract: A window assembly having photochromatic properties is described. The window assembly includes a substrate being adjacent to a coating. A photochromatic film is located between the substrate and the coating, whereby the photochromatic film darkens when the window assembly is exposed to ultraviolet light.
    Type: Grant
    Filed: June 2, 2006
    Date of Patent: August 11, 2009
    Assignee: Exatec, LLC
    Inventors: Wilfried Hedderich, Christophe Lefaux, Keith D. Weiss
  • Patent number: 7468148
    Abstract: The invention is directed to a silver-containing polarizing boroaluminosilicate glass composition that has been doped with a noble metal selected from the group consisting of Pt, Pd, Os, Ir, Rh and Ru, including mixtures thereof, to nucleate and precipitate silver ions to silver metal without the need for a reducing atmosphere step. The invention is further directed to a method for making the glass composition of the invention. Using the composition and method of the invention, one can prepare a glass having a selected null transmission range.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: December 23, 2008
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, George Bigelow Hares, David John McEnroe, Joseph Francis Schroeder, III
  • Patent number: 7251082
    Abstract: A photochromic/vitroceramic window assembly that restores some of the natural illumination and warm blue-green colors normally excluded from the interior of an enclosed space after blocking at least a portion of infrared and/or UV light, comprising: a) A transparent window pane; b) a first self-adhesive material adhered to the exterior of the window pane, of a transparent plastic film containing a UV-activated photochromic dye; and c) a second self-adhesive material adhered to the interior of the window pane, of a transparent plastic film containing i) a rare earth doped vitroceramic that up-converts any infrared not blocked by the first self-adhesive film to a warm visible blue or green color, and ii) a diarylethene that converts any UV not blocked by the first self-adhesive film to a visible yellow-white color.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: July 31, 2007
    Inventor: Galen W. Barlow
  • Patent number: 7168268
    Abstract: A method for the manufacture of colored structures of a glass, particularly for applying an inscription to the glass, by locally heating volume elements of the glass by means of a laser beam. The glass contains ions of metals which, in the form of submicroscopic particles, color the glass wherein the local heating of the non-doped glass is accomplished through a solution or gel of a metallic salt which transmits the laser beam well and is directly contacted with a surface of the glass.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: January 30, 2007
    Assignee: Sator Laser GmbH
    Inventor: Walter Czarnetzki
  • Patent number: 7104090
    Abstract: Polarizing glass articles and methods of manufacturing polarizing glass articles are disclosed. The method involves forming a polarizing layer on the surface of the glass article by ion-exchanging silver or copper into the surface.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: September 12, 2006
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Donald M. Trotter, Jr.
  • Patent number: 6990285
    Abstract: A method of making an at least one hole in an optically transparent body comprises the following steps: (i) providing an ultrashort pulse laser for producing a laser output with a wavelength ?, the laser output having a subpicosecond laser pulse duration; (ii) providing a laser output focusing lens for focusing the laser output, the focusing lens having a numerical aperture NA; (iii) providing an optically transparent body, the optically transparent body having a transparency at ? of at least 90%/cm; (iv) providing a liquid filled container situated proximate to the optically transparent body, such that the optically transparent body is in direct contact with the liquid; and (v) directing the laser output through the focusing lens to produce a focused laser output with a subpicosecond laser pulse duration proximate the optically transparent body, wherein the focused laser output traces at least one hole track pattern through the transparent glass body while the optically transparent body and said focused lase
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: January 24, 2006
    Assignee: Corning Incorporated
    Inventors: Joseph F Schroeder, Alexander Streltsov
  • Patent number: 6912087
    Abstract: A method for making a polarizing glass article is provided. The method includes first providing a precursor glass containing metal-halide particles. The precursor glass may be encased in a gas-permeable medium. Then, form at least a first polarizing layer and a non-polarizing region in the precursor glass. Bond the polarizing layer to a substrate and removing the non-polarizing region to expose the polarizing layer. Then, separate the first polarizing layer from the substrate to produce an ultra-thin polarizing glass article measuring less than or equal to about 200 ?m in thickness. The method may further comprise cutting the polarizing layer into wafers.
    Type: Grant
    Filed: April 6, 1999
    Date of Patent: June 28, 2005
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, David G. Grossman, Larry G. Mann, Jeanne M. Mordarski
  • Patent number: 6878653
    Abstract: An ultraviolet ray-absorbing, colorless and transparent soda-lime-silica glass is disclosed, which glass is prepared by irradiating a cerium containing soda-lime-silica glass with light having wavelengths in far- to near-ultraviolet region and thereby reducing transmittance to light with wavelengths in the region of 300-400 nm.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: April 12, 2005
    Assignee: Nihon Yamamura Glass Co., Ltd.
    Inventors: Masao Kitayama, Yuko Ishizu
  • Patent number: 6844669
    Abstract: A glass funnel for a cathode ray tube, which has a substantially rectangular opened end at one end and a neck portion at the other end and which constitutes, together with a glass panel having a substantially rectangular face portion, a glass bulb to be used for a cathode ray tube, wherein the glass constituting the glass funnel contains, by molar percentage, at least 60% of SiO2 and at least 7% of PbO; when the molar percentages of Na2O and K2O contained in said glass are represented by WNa and WK, respectively, 0.35?WK/(WNa+WK)?0.6; a compressive stress layer is formed by chemical tempering at least in the outer surface of a region containing a position where the tensile stress formed when the interior of the glass bulb is vacuumed to produce the cathode ray tube, becomes maximum; and either one or both of the outer surface of the chemically tempered region and the inner surface opposite to said outer surface, are colored by ion exchange coloration.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: January 18, 2005
    Assignee: Asahi Glass Company, Limited
    Inventors: Tsunehiko Sugawara, Mikio Ueki
  • Publication number: 20040191520
    Abstract: Described are photochromic articles that include a substrate and at least one photochromic material adopted to change from an unactivated form to an activated form upon exposure to actinic radiation. The activated form of the photochromic material changes from more absorbing to less absorbing of radiation in the absorption region of its unactivated form as the temperature increases from 10° C. to 35° C. The photochromic article demonstrates a more consistent photochromic response, for example, an optical density response loss of 50 percent or less over a temperature range of from 10° C. to 35° C. as measured in the Photochromic Temperature Dependence Test. Methods for producing the aforedescribed articles are also disclosed.
    Type: Application
    Filed: March 20, 2003
    Publication date: September 30, 2004
    Inventors: Anil Kumar, Barry Van Gemert, Forrest R. Blackburn, Clara E. Nelson
  • Publication number: 20040185268
    Abstract: Described are photochromic articles that include a substrate and at least one photochromic material adapted to change from an unactivated state to an activated state by exposure to radiation substantially in a wavelength range from 380 to 410 nanometers (nm) when measured over a wavelength range of from 380 to 700 nm. The photochromic articles demonstrate a photochromic response when activated behind an ultraviolet blocking transparency such as an automotive windshield. For example, the photochromic articles retain at least 12 percent of the activation measured as change in optical density or delta OD under outdoor simulating conditions in the Outdoor Test when tested under conditions simulating an eyeglass wearer behind an automotive windshield in the Behind the Windshield Test. Methods for producing the aforedescribed photochromic articles are also described.
    Type: Application
    Filed: March 20, 2003
    Publication date: September 23, 2004
    Inventors: Anil Kumar, Michael S. Misura, Robert W. Walters, Barry Van Germert, Anu Chopra, Clara E. Nelson
  • Patent number: 6754429
    Abstract: The invention provides a method of making optical fiber devices.
    Type: Grant
    Filed: June 25, 2002
    Date of Patent: June 22, 2004
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Joseph F. Schroeder, Alexander Streltsov, Edward F. Murphy
  • Publication number: 20030196454
    Abstract: A glass substrate a vanadium dioxide-based switchable film and a visible-light anti-reflection film. The vanadium dioxide-based switchable film and said visible-light anti-reflection film are coated on to the glass substrate. The vanadium dioxide-based switchable film has a switching temperature set approximately at a proper temperature or a target air-conditioning temperature to be controlled in an interior space in contact with said glass, thereby providing a solar switching and heat-insulating functions to said glass.
    Type: Application
    Filed: March 27, 2003
    Publication date: October 23, 2003
    Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventor: Ping Jin
  • Patent number: 6606885
    Abstract: A glass polarizer and a method of making the polarizer, the polarizer being produced from an R2O—Al2O3—B2O3—SiO2 glass containing limited amounts of ZrO2 and TiO2, and having a silver halide liquidus temperature and a rutile liquidus temperature, both temperatures being not over 995° C.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: August 19, 2003
    Assignee: Corning Incorporated
    Inventors: Michael D. Harris, Thomas G. Havens, William E. Horsfall, David J. Kerko
  • Patent number: 6536236
    Abstract: A method of producing a polarizing glass article that exhibits a broad band of high contrast polarizing properties in the infrared region of the radiation spectrum. The polarizing glass is phase-separated or exhibits photochromic properties based on silver, copper, or copper-cadmium halide crystals or a combination thereof, which are precipitated in the glass and having a size in the range of 200-5000 Å. The glass has a surface layer containing elongated silver, copper, or copper cadmium metal particles, or a mixture thereof. The method comprises subjecting the glass article to a time-temperature cycle in which the temperature is at least about 76° C. or greater above the glass softening point, in a step to thermally form and precipitate large halide crystals, and elongated metallic particles under a stress of not over about 3000 psi, preferably not over about 2675 psi.
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: March 25, 2003
    Assignee: Corning, Incorporated
    Inventors: David G. Grossman, Lisa R. Vandegrift, Joseph M. Williams, George N. Whitbred, III
  • Patent number: 6524773
    Abstract: Polarizing glass having localized regions or patterns of non-polarizing glass is disclosed. The glass is formed by use of reducing gas-blocking material, by local thermal heating of the glass, or by an etching technique.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: February 25, 2003
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Chad B. Moore, Paul A. Sachenik
  • Patent number: 6516633
    Abstract: The present invention is directed to microemulsion techniques for rapidly preparing photochromic glass nanoparticles and to the photochromic glass nanoparticles so prepared. More particularly, the method of the invention comprises the combination of two microemulsions, one containing a water-soluble silver salt and a glass precursor and the other containing a halide salt and an initiator for glass formation, which process rapidly yields silver halide particles. This invention gives nanometer-sized silver halide particles embedded in glass, thus providing photochromic glass nanoparticles without further annealing, or at most mild annealing. These nanoparticles are valuable as added components to any macro-material that one might wish to have photochromic properties. The particles would impart photochromism while not affecting the physical properties of the material.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: February 11, 2003
    Assignee: Nano-Tex, LLC
    Inventors: Lael L. Erskine, Dan B. Millward, David S. Soane
  • Patent number: 6408650
    Abstract: The invention is a method of retaining selenium in a lass containing selenium by including a manganese compound and not including nitrates or nitrites routinely used in the industry to retain selenium. Particularly, a preferred embodiment involves manufacturing a gray soda-lime-silica glass composition including selenium as a colorant, the components of the gray soda-lime-silica glass have colorants consisting essentially of: greater than 0.9 to 1.9 wt. % total iron oxide as Fe2O3; 0.10 to 1.00 wt. % manganese compound as MnO2; 0.0010 to 0.0060 wt. % selenium as Se; 0.002 to 0.025 wt. % cobalt oxide as Co, and 0 to 1.0 wt. % titanium oxide as TiO2 which are combined and melted to make the glass composition. The glass composition has at 4.0 mm. thickness: 10 to 55% light transmittance using Illuminant A, less than 25% ultra violet transmittance, and less than 50% infra red transmittance.
    Type: Grant
    Filed: December 10, 1997
    Date of Patent: June 25, 2002
    Assignee: Ford Global Technologies, Inc.
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Publication number: 20020059811
    Abstract: Photochromic float glass and methods of making the same are provided. In especially preferred forms, the present invention is embodied in float glass having a non-photochromic glass substrate layer and a photochromic layer fused onto the substrate layer. During production, layers of the photochromic and non-photochromic glass are brought into contact with under conditions which fuse the layers one to another.
    Type: Application
    Filed: September 6, 2001
    Publication date: May 23, 2002
    Inventors: Ksenia A. Landa, Leonid M. Landa, Anthony V. Longobardo, Scott Thomsen
  • Patent number: 6363748
    Abstract: An ophthalmic, protective, filter lens, and a method of producing such lens, the lens having a ratio of Z and Y tristimulus values between 0.25-0.40, a dominant wavelength between 570-580 nm. on a color mixture diagram, a sharp transmission drop between 450-500 nm. and a transmission not over 30% between 400-450 nm. The lens is produced by firing a silver halide-containing, photochromic glass lens in a hydrogen-containing atmosphere within a temperature range of 465° C. to 495° C. for less than 20 minutes.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: April 2, 2002
    Assignee: Corning SA
    Inventors: Thomas G. Havens, David J. Kerko, Brent M. Wedding
  • Patent number: 6298691
    Abstract: Method is disclosed for making glass having both polarizing and non-polarizing regions integral thereto by either ion-exchange or by exposure to light and heat. The polarizing regions of the resulting glass is effective in polarizing light radiation, that is, the glass exhibits permanent dichroic behavior and has at least some polarizing effect in the wavelength range of 400 to 700 nm. The base glass composition contains Cu, Ag and at least one halide such that the resulting precipitated crystal phase consists of a halide.
    Type: Grant
    Filed: October 21, 1999
    Date of Patent: October 9, 2001
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Dennis W. Smith
  • Patent number: 6221480
    Abstract: A polarizing glass article, and a method of making the article, that exhibits a broad band of high contrast polarizing properties in the infrared region of the radiation spectrum, that is phase-separated by precipitating silver, copper, or copper-cadmium halide crystals in the glass within a size range of 200-5000 Å, and that contains elongated silver, copper, or copper-cadmium metal particles formed on or in the halide crystals, and having an elongated aspect ratio of at least 2:1, the article having a contrast ratio of at least 100,000 over a range of at least 300 nm.
    Type: Grant
    Filed: June 2, 1999
    Date of Patent: April 24, 2001
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Larry G. Mann, George N. Whitbred, III