With Annealing Or Tempering Patents (Class 65/95)
  • Patent number: 11823967
    Abstract: A glass or glass-ceramic carrier substrate, the substrate having undergone at least one complete cycle of a semiconductor fabrication process and having also undergone a reclamation process following the end of the semiconductor fabrication process; the glass or glass-ceramic carrier substrate comprising at least one of the following properties: (i) a coefficient of thermal expansion of less than 13 ppm/° C.; (ii) a Young's Modulus of 70 GPa to 150 GPa; (iii) an IR transmission of greater than 80% at a wavelength of 1064 nm; (iv) a UV transmission of greater than 20% at a wavelength of 255 nm to 360 nm; (v) a thickness tolerance within the same range as the thickness tolerance of the carrier substrate before undergoing at least one complete cycle of the semiconductor fabrication process; (vi) a total thickness variation of less than 2.5 ?m; (vii) a failure strength of greater than 80 MPa using a 4-point-bending test; (viii) a pre-shape of 50 ?m to 300 ?m.
    Type: Grant
    Filed: November 20, 2020
    Date of Patent: November 21, 2023
    Assignee: CORNING INCORPORATED
    Inventors: Robert Alan Bellman, Indrajit Dutta, Yi-Cheng Hsieh, Toshihiko Ono, Nicholas James Smith
  • Patent number: 11787724
    Abstract: A method of manufacturing a glass film includes a forming step of forming a band-shaped glass film by pulling down a glass ribbon flowing down from a forming trough while sandwiching the glass ribbon from both front and back sides through use of roller pairs and a conveyance direction changing step of changing a conveyance direction of the glass film from the vertical direction to the horizontal direction by conveying the glass film along a conveyance path having an arc shape while supporting the glass film from a back surface side with a roller conveyor so that a front surface of the glass film after having passed through the conveyance path faces upward. A first roller to be brought into abutment against the glass film from the front surface side is arranged between a roller pair arranged in a lowermost stage and the roller conveyor.
    Type: Grant
    Filed: September 21, 2017
    Date of Patent: October 17, 2023
    Assignee: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Hiroki Mori, Koichi Mori, Takuya Shioji, Toshitaka Nishijima
  • Patent number: 9296635
    Abstract: Managing pressure within a thickness-control-zone (muffle door) housing relative to pressures in a glass-making machine enclosure and an upper chamber that is disposed outside the enclosure so as to minimize or control undesired airflows that would adversely affect thickness of glass ribbon. According to one pressure management technique, the pressure at a location in the housing is managed so as to be less than the pressure at a location that is within the enclosure as well as both outside and adjacent to the housing. In the event of a leak, as by a crack or unintended opening in the housing, for example, this pressure difference reduces or prevents airflow toward the ribbon and, thereby, undesired thickness variation in the ribbon. According to a second pressure-management technique, the pressure at the location is managed so as to be greater than the pressure in the upper chamber.
    Type: Grant
    Filed: March 11, 2014
    Date of Patent: March 29, 2016
    Assignee: Corning Incorporated
    Inventors: Paul Gregory Chalk, Ahdi El Kahlout, Shawn Rachelle Markham
  • Patent number: 9038416
    Abstract: A glass-substrate manufacturing method which includes a forming step and a cooling step. In the forming step, a molten glass is formed into a sheet glass by a down-draw process. In the cooling step, the sheet glass is cooled. The cooling step includes first, second and third coating steps as defined herein.
    Type: Grant
    Filed: December 26, 2012
    Date of Patent: May 26, 2015
    Assignee: AvanStrate Inc.
    Inventor: Hiroyuki Kariya
  • Patent number: 9029280
    Abstract: A substrate for p-Si TFT flat panel displays made of a glass having a high low-temperature-viscosity characteristic temperature and manufactured while avoiding erosion/wear of a melting tank during melting through direct electrical heating. The glass substrate comprises 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-20 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-0.8 mass % of R2O, wherein R2O is total amount of Li2O, Na2O, and K2O, and 0-0.3 mass % of Sb2O3, and substantially does not comprise As2O3, wherein the mass ratio CaO/RO is equal to or greater than 0.65, the mass ratio (SiO2+Al2O3)/B2O3 is in a range of 7-30, and the mass ratio (SiO2+Al2O3)/RO is equal to or greater than 5. A related method involves melting glass raw materials blended to provide the glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: May 12, 2015
    Assignee: AvanStrate Inc.
    Inventors: Akihiro Koyama, Satoshi Ami, Manabu Ichikawa
  • Patent number: 9016092
    Abstract: A glass for a magnetic recording medium substrate permitting the realization of a magnetic recording medium substrate affording good chemical durability and having an extremely flat surface, a magnetic recording medium substrate comprised of this glass, a magnetic recording medium equipped with this substrate, and methods of manufacturing the same. The glass is an oxide glass not including As or F.
    Type: Grant
    Filed: March 18, 2009
    Date of Patent: April 28, 2015
    Assignee: Hoya Corporation
    Inventors: Yoichi Hachitani, Kinobu Osakabe
  • Patent number: 9010151
    Abstract: A glass sheet cutting device fuses and divides a glass substrate using a preset cutting line as a boundary while supplying an assist gas and a laser beam from above the glass substrate along the preset cutting line of the glass substrate. The glass sheet cutting device includes a first laser irradiator for radiating a fusing laser beam and a second laser irradiator for radiating an annealing laser beam. Through a fusing gap formed between fused end surfaces by fusing, the second laser irradiator radiates the annealing laser beam obliquely from above onto the fused end surface to be annealed.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: April 21, 2015
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Takahide Fujii, Setsuo Uchida, Naotoshi Inayama, Takayuki Noda, Sho Itoh, Michiharu Eta
  • Patent number: 8991212
    Abstract: A method for manufacturing a plate inorganic nonmetal material by using a molten slag by introducing the molten slag into a pool for preserving heat and modifying, wherein a temperature of the molten slag is 1450° C.-1600° C., and modifying a viscosity and/or a color of the molten slag according to requirements of the product manufactured. The modified molten slag is introduced into a float process furnace using tin or tin alloy carrier forming a plate of inorganic nonmetal material which is discharged at 1000-1300° C. The plate is maintained at 600° C.-900° C. for 0.5-2 hours in a non-reducing atmosphere, and then cooled to a room temperature within 1-2 hours. An energy-saving and efficient method for comprehensively utilizing the blast furnace slag is provided. The produced plate inorganic nonmetal material has such characteristics as stable color quality, abrasion resistance, pressure resistance, strong adhesiveness, low coefficient of expansion and low shrinkage ratio.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: March 31, 2015
    Assignee: Shandong Coking Group Co., Ltd.
    Inventors: Qingtao Wang, Xianjin Yu, Xin Zhao, Benkui Gong, Zhenxia Wei, Yueyun Li, Jun Ming
  • Publication number: 20150079400
    Abstract: Alkali boroaluminosilicate glasses with high resistance to crack initiation and damage due to sharp impact are provided. The glass compositions have melting and forming temperatures that allow forming the glass into sheets via float-based processes while still allowing for the glass to be efficiently ion exchanged. The glass compositions contain MgO, and when ion exchanged, have a Vickers indentation crack initiation load of at least about 10-15 kgf.
    Type: Application
    Filed: September 9, 2014
    Publication date: March 19, 2015
    Inventors: Qiang Fu, Xiaoju Guo
  • Patent number: 8966940
    Abstract: In a heating drawing, a base material glass plate is heated and softened in a heating furnace, and drawn to a desired thickness to form a glass strip. In the heating drawing, the base material glass plate is heated so that the base material glass plate has a U-shaped temperature distribution in a width direction. Such process can be realized through heating by a heating element which has a non-heating portion at a position opposite to a central portion of the base material glass plate in the width direction and a heating portion on both sides of the non-heating portion. Thus provided is a method of manufacturing a glass strip, the method includes heating and softening the base material glass plate, and drawing the base material glass plate to a desirable thickness to form a glass strip, and is capable of manufacturing a thin, rod-like glass strip with an excellent flatness.
    Type: Grant
    Filed: November 1, 2006
    Date of Patent: March 3, 2015
    Assignee: The Fukukawa Electric Co., Ltd.
    Inventors: Tetsuya Kumada, Yasuhiro Naka, Toshihiro Nakamura, Toshiaki Tateishi
  • Publication number: 20150002932
    Abstract: Invention relates to lenticular sheets made of thermally or chemically hardened mineral glass used for decorative panels, to create three-dimensional visual effects combined with an encoded image. One of the advantages of invention is the fact that it is a proposed mineral lenticular sheet, which underwent chemical or mechanical hardening of its outer parts 18. This increases the mechanical strength and impact resistance. This aspect makes it safer for use under the influence of external factors and in contact with a person. This allows for applying the invention in large scopes in comparison with plastic lenticular screens. Pre-stressing is achieved by thermal or chemical hardening.
    Type: Application
    Filed: January 31, 2013
    Publication date: January 1, 2015
    Inventors: Denys Bityutskyy, Andrii Karlov, Ievegen Viunskovskyi, Roman Kulniev
  • Patent number: 8893527
    Abstract: A method for annealing a glass disk is disclosed. The glass disk is placed on a base, whereby the bottom surface of the glass disk makes a contact with the base, and the top surface of the glass disk is exposed to air. The glass disk is heated with thermal energy supplied to the glass disk, the thermal energy comprising first thermal energy supplied from the air through the top surface and second thermal energy supplied from the base through the bottom surface.
    Type: Grant
    Filed: July 21, 2011
    Date of Patent: November 25, 2014
    Assignee: WD Media, LLC
    Inventors: Richie Y. Chan, Magenthiran Verapatran, Mohamad F. Azmi, Beehuah Ong
  • Patent number: 8893525
    Abstract: An apparatus for manufacturing tempered glass. A transportation unit transports a glass substrate that is intended to be tempered. An ionizer ionizes alkali oxides in the glass substrate by radiating energy onto the glass substrate. A dielectric heating unit increases the temperature of the inner portion of the glass substrate in which the alkali oxides are ionized by the ionizer.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: November 25, 2014
    Assignee: Samsung Corning Precision Materials Co., Ltd.
    Inventors: Hoikwan Lee, Seo-Yeong Cho, Yoon Young Kwon, Kyungwook Park, Kyungmin Yoon, Jongsung Lee, Jaeyoung Choi, Gennady Kizevich
  • Patent number: 8857215
    Abstract: Disclosed is an apparatus and method for heat treating glass sheets, and in particular for heat treating very thing glass sheets arranged in closely spaced stacks. The glass sheets are positioned on a moving belt such that their major surfaces are substantially perpendicular to a direction of belt travel through the apparatus to aid in producing a uniform temperature profile within the glass sheets. The apparatus comprises air curtains positioned at the inlet and outlet of the apparatus to minimize the ingress of particulate into the apparatus. A reduced velocity of heated air flow within a lower portion of the apparatus relative to a velocity of the heated air in an upper portion of the apparatus causes particulate to drop out of the lower portion air flow. A rotating brush and vacuums positioned adjacent a lower portion of the belt assist in removing particulate from the moving belt.
    Type: Grant
    Filed: May 16, 2012
    Date of Patent: October 14, 2014
    Assignee: Corning Incorporated
    Inventors: George O. Dale, Juergen Tinz
  • Patent number: 8826694
    Abstract: A method of manufacturing a glass sheet includes creating split flows of molten glass in a forming body (10) and causing the molten glass to flow down, subsequently merging the flows at a merging point to form a glass sheet G and causing the glass sheet to flow downward in the vertical direction. A plurality of chambers (42b, 42c, . . . ) separated by heat-insulating plates (40a, 40b, . . . ) in the direction of movement of the glass sheet G are provided. A heater (60a, 60b, . . . ) is provided for each of the chambers (42b, 42c, . . . ) so that the temperature decreases in the direction of movement. The heat-insulating plates (40a, 40b, . . . ) are disposed facing the glass sheet G, and facing surfaces of the heat-insulating plates (40a, 40b, . . . ) are shaped so as to correspond to a sheet thickness variation of the glass sheet G.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: September 9, 2014
    Assignee: AvanStrate Inc.
    Inventors: Hiroyuki Kariya, Nobuhiro Maeda
  • Publication number: 20140249018
    Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3, and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.
    Type: Application
    Filed: May 13, 2014
    Publication date: September 4, 2014
    Applicant: AVANSTRATE INC.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
  • Publication number: 20140249019
    Abstract: A glass substrate for p-Si TFT flat panel displays that is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6. A method for manufacturing a glass substrate involves: a melting step of obtaining a molten glass by melting, by employing at least direct electrical heating, glass raw materials blended so as to provide the aforementioned glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.
    Type: Application
    Filed: May 15, 2014
    Publication date: September 4, 2014
    Applicant: AvanStrate Inc.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
  • Patent number: 8791036
    Abstract: The present invention relates to a glass plate for a substrate contains, as a glass matrix composition, in mol % on the oxide basis, SiO2: 67 to 72, Al2O3: 1 to 7, B2O3: 0 to 4, MgO: 11 to 15, CaO: 0 to 3, SrO: 0 to 3, BaO: 0 to 4, ZrO2: 0 to 4, Na2O: 8 to 15, and K2O: 0 to 7, with SiO2+Al2O3: 71 to 77, MgO+CaO+SrO+BaO: 11 to 17, Na2O+K2O: 8 to 17, and satisfying K2O/(Na2O+K2O)?0.13×(SiO2+Al2O3+0.5B2O3+0.3BaO)?9.4, in which the glass plate has a ?-OH value (mm?1) of 0.05 to 0.5, and a heat shrinkage ratio (C) of 16 ppm or less.
    Type: Grant
    Filed: March 30, 2012
    Date of Patent: July 29, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomoyuki Tsujimura, Yuichi Kuroki, Manabu Nishizawa
  • Patent number: 8733130
    Abstract: A process for coating a ribbon of float glass is disclosed. It comprises the steps of forming a glass ribbon, depositing a first transparent conductive coating upon a major surface of the ribbon which does not extend to the edges of the ribbon while the ribbon is at an elevated temperature, cooling said coated ribbon under controlled conditions in an annealing lehr and cutting off the edges of the ribbon so as to produce a ribbon having a uniform coating extending across the full width of the cut ribbon which is characterized in that a second conductive coating is deposited upon the uncoated edges of the ribbon while that edge is at a temperature which is above the ambient temperature. The invention finds particular application in the production of coated glass products where the thickness of the glass ribbon is at least 8 mm and most particularly where the thickness of the glass is at least 10 mm.
    Type: Grant
    Filed: May 7, 2009
    Date of Patent: May 27, 2014
    Assignee: Pilkington Group Limited
    Inventors: Kevin Sanderson, Gerhard Lingl, Hans-Eckhard Leitl, Franz Michael Josef Scharnagl, Douglas M Nelson
  • Patent number: 8728961
    Abstract: A method is described for making a float glass convertible into a glass ceramic, by which a largely crystal fault-free glass can be produced. In this method the glass is cooled from a temperature (TKGmax), at which a crystal growth rate is at a maximum value (KGmax), to another temperature (TUEG), at which practically no more crystal growth occurs, with a cooling rate, KR, in ° C. min?1 according to: KR UEG KGmax ? ? ? ? T UEG KGmax 100 · KG ? ? max , wherein ?T=TKGmax?TUEG, and KGmax=maximum crystal growth rate in ?m min?1. The float glass has a thickness below an equilibrium thickness, a net width of at least 1 m and has no more than 50 crystals with a size of more than 50 ?m, especially no crystals with a size of more than 10 ?m, per kilogram of glass within the net width.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: May 20, 2014
    Assignee: Schott AG
    Inventors: Gerhard Lautenschlaeger, Andreas Langsdorf, Ulrich Lange, Bernd Ruedinger, Klaus Schneider, Michael Jacquorie, Friedrich Siebers, Wolfgang Schmidbauer
  • Patent number: 8713967
    Abstract: A process for making glass sheet with low compaction suitable for high temperature applications, such as low-temperature polysilicon-based TFT displays, and glass sheets thus made. The glass sheet desirably has an anneal point of at least 765° C., a CTE at most 42×10?7/° C. The process involves cooling the glass melt form a temperature corresponding to a viscosity of 1.0×1010 poise to a temperature corresponding to a viscosity of 1.0×1015 poise at a cooling rate CR, where CR?5° C./second. The absolute value of the measured compaction of the glass sheet desirably is at most 175 ppm upon being re-heated to 675° C. for a period of time.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: May 6, 2014
    Assignee: Corning Incorporated
    Inventors: Paul Stephen Danielson, Adam James Ellison, Timothy J Kiczenski
  • Patent number: 8697241
    Abstract: A glass film laminate includes a glass film and a supporting glass. The glass film and the supporting glass have surfaces in contact with each other, and each of the surfaces has a surface roughness Ra of 2.0 nm or less.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: April 15, 2014
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Tatsuya Takaya, Masahiro Tomamoto, Hiroshi Takimoto, Hirokazu Okamoto
  • Publication number: 20140083139
    Abstract: Granules of a glass raw material mixture, for producing alkali-free glass containing substantially no alkali metal oxides, such that the glass composition of glass obtained from the granules comprises, as represented by mol % based on oxides, 60-75 mol % of SiO2, 5-15 mol % of Al2O3, 1-9 mol % of B2O3, 0-15 mol % of MgO, 0-20 mol % of CaO, 0-12 mol % of SrO and 0-21 mol % of BaO, provided that the total of CaO, SrO and BaO is more than 0, and in an X-ray diffraction spectrum of the granules obtained by means of a CuK? ray, when the diffraction peak area of quartz (100) in a range of 2? being 19.85-21.71 degrees is taken as 1, the total of the relative values of the diffraction peak areas of strontium borate hydrate, calcium borate hydrate and barium borate hydrate, is at least 0.005.
    Type: Application
    Filed: November 25, 2013
    Publication date: March 27, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Ryota Ando, Nobuhiro Shinohara
  • Publication number: 20140075995
    Abstract: To provide a process for producing granules, wherein a component in an exhaust gas discharged from a glass melting furnace can be reused as a raw material for alkali-free glass, and a heating and drying step is not required for the reuse. Exhaust gas G1 formed in a process for melting a raw material of glass containing a boron component is brought in contact with contacting liquids L1 and L2 to obtain treated liquids S1, S2 and S3 having the boron component in the exhaust gas G1 dissolved therein; magnesium hydroxide is added to the mixture of the treated liquids in a treated liquid tank 14 to obtain a liquid containing a boron component and a magnesium component; by using the liquid, a granulation liquid is prepared; and in the presence of the granulation liquid, a raw material mixture for producing alkali-free borosilicate glass is granulated to produce granules.
    Type: Application
    Filed: November 25, 2013
    Publication date: March 20, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Ryota ANDO, Yasuo HAYASHI
  • Publication number: 20140038807
    Abstract: According to the present invention, an alkali-free glass for a substrate, having a thickness of 0.1 mm to 0.3 mm and a compaction of 9 ppm or lower can be obtained without performing heat treatment as a post-treatment for the alkali-free glass for a substrate after production (after forming, annealing and cutting).
    Type: Application
    Filed: October 8, 2013
    Publication date: February 6, 2014
    Applicant: Asahi Glass Company, Limited
    Inventors: Tomoyuki TSUJIMURA, Manabu Nishizawa, Nobuhiko Higuchi
  • Publication number: 20140007621
    Abstract: A method for manufacturing a polysilicon ingot includes: (a) providing molten silicon in a container; (b) maintaining a surface temperature of the molten silicon higher than its melting point while decreasing the temperature of a base portion of the container to a temperature (T1) lower than the melting point at a rate of at least 2.6° C./min; (c) increasing the temperature of the base portion to a temperature (T2) lower than the melting point; (d) maintaining the surface temperature of the molten silicon higher than the melting point while decreasing and then increasing the temperature of the base portion to a temperature lower than the melting point of silicon; and (e) reducing the temperature of the molten silicon to form the polysilicon ingot.
    Type: Application
    Filed: March 18, 2013
    Publication date: January 9, 2014
    Applicant: MOTECH INDUSTRIES INC.
    Inventors: Kai-An Ho, Chien-Kang Chou
  • Patent number: 8607589
    Abstract: A method and an apparatus for annealing a glass sheet, which can sufficiently reduce I/T formed in the glass sheet, are provided. In the method for annealing a glass sheet G of the present invention, in a state that a heated and bent glass sheet G is placed on a forming mold 16, first, a region of the glass sheet G to be lifted up is cooled by cooling devices 20, 22, to make the temperature of the region to be lifted up to be a temperature of at most the strain point. Next, in this state, a lift-up member 36 is operated to lift up the region of the glass sheet G to be lifted up, by rods 38, to separate the glass sheet G from the forming mold 16.
    Type: Grant
    Filed: July 31, 2012
    Date of Patent: December 17, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroshi Yamakawa, Akira Sugahara, Yasumasa Kato
  • Patent number: 8596094
    Abstract: A method of making a silica glass having a uniform fictive temperature. The glass article is heated at a target fictive temperature, or heated or cooled at a rate that is less than the rate of change of the fictive temperature, for a time that is sufficient to allow the fictive temperature of the glass to come within 3° C. of the target fictive temperature. The silica glass is then cooled from the target fictive temperature to a temperature below the strain point of the glass at a cooling rate that is greater than the relaxation rate of the glass at the target fictive temperature. The silica glass has a fictive temperature that varies by less than 3° C. after the annealing step. A silica glass made by the method is also described.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: December 3, 2013
    Assignee: Corning Incorporated
    Inventors: Carlos Duran, Kenneth Edward Hrdina, Ulrich Wilhelm Heinz Neukirch
  • Publication number: 20130186140
    Abstract: A lithium aluminosilicate glass and a method for producing such lithium aluminosilicate glass are provided. The glass has a composition, in mol %, of: SiO2 60-70; Al2O3 10-13; B2O3 0.0-0.9; Li2O 9.6-11.6; Na2O 8.2-less than 10; K2O 0.0-0.7; MgO 0.0-0.2; CaO 0.2-2.3; ZnO 0.0-0.4; ZrO2 1.3-2.6; P2O5 0.0-0.5; Fe2O3 0.003-0.100; SnO2 0.0-0.3; and CeO2 0.004-0.200. Further, the composition complies with the following relations and conditions: (Li2O+Al2O3)/(Na2O+K2O) greater than 2; Li2O/(Li2O+Na2O+K2O) greater than 0.47 and less than 0.70; CaO+Fe2O3+ZnO+P2O5+B2O3+CeO2 greater that 0.8 and less than 3, where at least four out of the six oxides are included. The glass exhibits a modulus of elasticity of at least 82 GPa and has a glass transition point below 540° C. and/or a working point below 1150° C.
    Type: Application
    Filed: February 25, 2011
    Publication date: July 25, 2013
    Applicant: SCHOTT AG
    Inventors: Peter Brix, Wolfram Beier, Jochen Alkemper
  • Publication number: 20130152634
    Abstract: In an annealing zone (3) of a glass sheet producing method, a curved portion (5) is formed by curving a glass ribbon (G) in a width direction, and a concavo-convex direction in a front and back direction of the curved portion (5) is reversed at least between an upper side and a lower side of a part of a region in the width direction of the glass ribbon (G). Therefore, a bending resistance in an upper and lower direction of the glass ribbon (G) and a bending resistance in the width direction of the glass ribbon (G) are increased.
    Type: Application
    Filed: August 22, 2011
    Publication date: June 20, 2013
    Inventors: Hidetaka Oda, Noritomo Nishiura, Koki Ueda, Tomonori Kano
  • Patent number: 8429936
    Abstract: Methods of drawing glass sheet via a downdraw process are provided. In certain aspects, the methods utilize rapid cooling below the root (70) of the forming apparatus (10). Such rapid cooling can, for example, facilitate the use of glass having a liquidus viscosity less than about 100,000 poise. In other aspects, the methods utilize slow cooling between the viscosities of 1011 poises and 1014 poises. Such slow cooling can facilitate the production of glass substrates which exhibit low levels of compaction. In further aspects, substrates are removed from the glass sheet at elevated temperatures which can facilitate increases in the production rates of downdraw machines. In still further aspects, rapid cooling below the root, slow cooling between the viscosities of 1011 poises and 1014 poises, and/or substrate removal at elevated temperatures are combined. Such combinations can facilitate economically effective utilization of downdraw equipment.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: April 30, 2013
    Assignee: Corning Incorporated
    Inventors: Douglas Clippinger Allan, Olus Naili Boratav, Andrey V. Filippov, Allan Mark Fredholm, Leonard R. Kent, Lewis Kirk Klingensmith, Terry Jay Ott, Randy Lee Rhoads
  • Patent number: 8402790
    Abstract: To provide a process to improve acid resistance of a glass substrate for an information recording medium. A process for producing a glass substrate for an information recording medium, comprising processing a glass formed into a plate by a float process, a down-draw method or a press method, wherein, in cooling of the glass in the last step where the glass has a temperature of at least its strain point, the time during which the glass temperature is at least its strain point and at most a temperature where the glass viscosity is 1010 dPa·s is at least 13 minutes.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: March 26, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Jun Endo, Tetsuya Nakashima
  • Publication number: 20130065748
    Abstract: A flat panel display glass substrate includes a glass comprising, in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, and 3-25% RO (the total amount of MgO, CaO, SrO, and BaO). The contents in mol % of SiO2, Al2O3, and B2O3 satisfy a relationship (SiO2+Al2O3)/(B2O3)=7.5-17. The strain point of the glass is 665° C. or more. The devitrification temperature of the glass is 1250° C. or less. The substrate has a heat shrinkage rate of 75 ppm or less. The rate of heat shrinkage is calculated from the amount of shrinkage of the substrate measured after a heat treatment which is performed at a rising and falling temperature rate of 10° C./min and at 550° C. for 2 hours by the rate of heat shrinkage (ppm)={the amount of shrinkage of the substrate after the heat treatment/the length of the substrate before the heat treatment}×106.
    Type: Application
    Filed: June 29, 2012
    Publication date: March 14, 2013
    Applicant: AvanStrate Inc.
    Inventors: Akihiro KOYAMA, Satoshi Ami, Manabu Ichikawa
  • Publication number: 20130059718
    Abstract: A substrate for p-Si TFT flat panel displays made of a glass having a high low-temperature-viscosity characteristic temperature and manufactured while avoiding erosion/wear of a melting tank during melting through direct electrical heating. The glass substrate comprises 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-20 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-0.8 mass % of R2O, wherein R2O is total amount of Li2O, Na2O, and K2O, and 0-0.3 mass % of Sb2O3, and substantially does not comprise As2O3, wherein the mass ratio CaO/RO is equal to or greater than 0.65, the mass ratio (SiO2+Al2O3)/B2O3 is in a range of 7-30, and the mass ratio (SiO2+Al2O3)/RO is equal to or greater than 5. A related method involves melting glass raw materials blended to provide the glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.
    Type: Application
    Filed: June 29, 2012
    Publication date: March 7, 2013
    Applicant: AVANSTRATE INC.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
  • Publication number: 20130047671
    Abstract: Disclosed is a method of reducing the compaction of glass formed by a down draw process. The glass may be a glass sheet or a glass ribbon. Once the glass is formed, it is thermally treated on a molten metal bath for a time and at a temperature effective to reduce the fictive temperature of the glass below a predetermined level. In one embodiment, a glass ribbon is formed in a fusion process and the glass ribbon redirected onto a molten metal bath where the ribbon is thermally treated.
    Type: Application
    Filed: August 29, 2011
    Publication date: February 28, 2013
    Inventor: Jeffrey T. Kohli
  • Publication number: 20130029830
    Abstract: Provided are: a glass substrate for p-Si TFT flat panel displays that is composed of a glass having high characteristic temperatures in the low-temperature viscosity range, typified by the strain point and glass transition point, having a small heat shrinkage rate, and being capable of avoiding the occurrence of the problem regarding the erosion/wear of a melting tank at the time of melting through direct electrical heating; and a method for manufacturing same. The present glass substrate is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6.
    Type: Application
    Filed: June 29, 2012
    Publication date: January 31, 2013
    Applicant: AVANSTRATE INC.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
  • Publication number: 20130023400
    Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3 and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.
    Type: Application
    Filed: June 29, 2012
    Publication date: January 24, 2013
    Applicant: AvanStrate Inc.
    Inventors: Akihiro KOYAMA, Satoshi Ami, Manabu Ichikawa
  • Patent number: 8349476
    Abstract: To provide a process to improve acid resistance of a glass substrate for an information recording medium. A process for producing the glass substrate for an information recording medium, includes processing a glass formed into a plate by a float process, a down-draw method or a press method, wherein, in cooling the glass at the last step the glass has a temperature of at least its strain point, the time during which the glass temperature is at least its strain point and at most a temperature where the glass viscosity is 1010dPa·s is at least 13 minutes.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: January 8, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Jun Endo, Tetsuya Nakashima
  • Patent number: 8322161
    Abstract: A process produces a glass sheet. The process includes down-drawing a molten glass into a sheet-like glass ribbon, in which the molten glass is fed to a forming trough arranged in a forming furnace and the molten glass is caused to flow down from the forming trough through a conveyance passage extending vertically. The process also includes removing an internal strain in the glass ribbon in an annealing furnace, cooling the glass ribbon to around room temperature in a cooling chamber, and cutting the glass ribbon into a given size, in which the cooling chamber is provided with a gas exhausting passage, thereby exhausting air in the cooling chamber to an outside.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: December 4, 2012
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Noritomo Nishiura, Koki Ueda, Hidetaka Oda, Tomonori Kano, Daisuke Nagata
  • Patent number: 8322160
    Abstract: A process produces a glass sheet. The process includes down-drawing a molten glass into a sheet-like glass ribbon, in which the molten glass is fed to a forming trough arranged in a forming furnace and the molten glass is caused to flow down from the forming trough through a conveyance passage extending vertically. The process also includes removing an internal strain in the glass ribbon in an annealing furnace, cooling the glass ribbon to around room temperature, and cutting the glass ribbon in a given size, in which a pressure in an outside atmosphere of the forming furnace and/or the annealing furnace is elevated.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: December 4, 2012
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Noritomo Nishiura, Koki Ueda, Hidetaka Oda, Tomonori Kano, Daisuke Nagata
  • Patent number: 8316668
    Abstract: A method for manufacturing glass hard disk substrates comprises annealing and then tempering previously formed glass hard disk substrates. The annealed and tempered glass hard disk substrates have improved strength and stress resistance without chemical treatments.
    Type: Grant
    Filed: September 23, 2010
    Date of Patent: November 27, 2012
    Assignee: WD Media, Inc.
    Inventors: Richie Yuan Lin Chan, Magenthiran Verapatran, Mohamad Faisal Azmi, Beehuah Ong
  • Patent number: 8281618
    Abstract: The invention provides an alkali-free glass substrate small in the variation of the thermal shrinkage and a process for producing the same. An alkali-free glass substrate of the invention has an absolute value of a thermal shrinkage of 50 ppm or more when the alkali-free glass substrate is heated at a rate of 10° C./min from a room temperature, kept at a holding temperature of 450° C. for 10 hr and then cooled at a rate of 10° C./min.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: October 9, 2012
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Yoshinari Kato, Tatsuya Takaya
  • Publication number: 20120208309
    Abstract: The present invention relates to a glass plate for a substrate contains, as a glass matrix composition, in mol % on the oxide basis, SiO2: 67 to 72, Al2O3: 1 to 7, B2O3: 0 to 4, MgO: 11 to 15, CaO: 0 to 3, SrO: 0 to 3, BaO: 0 to 4, ZrO2: 0 to 4, Na2O: 8 to 15, and K2O: 0 to 7, with SiO2+Al2O3: 71 to 77, MgO+CaO+SrO+BaO: 11 to 17, Na2O+K2O: 8 to 17, and satisfying K2O/(Na2O+K2O)?0.13×(SiO2+Al2O3+0.5B2O3+0.3BaO)?9.4, in which the glass plate has a ?-OH value (mm?1) of 0.05 to 0.5, and a heat shrinkage ratio (C) of 16 ppm or less.
    Type: Application
    Filed: March 30, 2012
    Publication date: August 16, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Tomoyuki TSUJIMURA, Yuichi Kuroki, Manabu Nishizawa
  • Patent number: 8234883
    Abstract: A method of tempering a glass sheet heated to a tempering temperature includes cooling the glass sheet at a first heat transfer coefficient at a first quench station and cooling the glass sheet at a second heat transfer coefficient at a second quench station downstream of the first quench station. The second heat transfer coefficient is greater than the first heat transfer coefficient. In a multistage process of the invention, a plurality of quench stations could be used with each downstream quench station having a larger heat transfer coefficient than the previous upstream quench station.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: August 7, 2012
    Assignee: PPG Industries Ohio, Inc.
    Inventors: William R. Krall, Jr., William R. Siskos, Thomas M. Sailock, Joseph Medzius, DeWitt W. Lampman
  • Patent number: 8234882
    Abstract: The invention relates to a method for producing iridescent crystal glass. The glass products produced with the method of present invention have the advantages of good streamline shape, natural color transition, and excellent visual effect, etc.; the method is helpful for accelerating product upgrade, improving product appearance and visual effects, and enhancing competence of products. Therefore, we paint iridescent crystal ink on glass products, and add patterns suitable for household electric appliances and buildings, thereby greatly improving the appearance of the product. In addition, due to the high safety performance of toughened glass and suitability of patterns and colors, iridescent crystal glass products have been accepted by the consumers gradually. The method comprises the following steps: a. cutting; b. edge processing; c. toughening; d. ink preparation; e. iridescent crystal printing; f.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: August 7, 2012
    Assignee: Jiangsu Xiuqiang Glasswork Co., Ltd.
    Inventor: Xiuqiang Lu
  • Patent number: 8230698
    Abstract: The present invention discloses a method for temperature monitoring of Horizontal Tempering and bending system (HTBS) furnace in glass industries. The present invention improves furnace heaters shut down performance, thereby causing longer lifetime for furnace equipments. The present invention further increases transparency for output tempered and bent glass. The present invention discloses multiple sensors for temperature control of the furnace, wherein said sensors provide a precise and accurate measurement of the glass temperature separately. After acquiring sensors data, the fusion process is done using Bayesian approach in order to achieve more accurate values for glass temperature, thereby enhancing the system performance and decreasing the number of unnecessary emergency shut downs (unnecessary ESDs) of the furnace heating elements, which are produced due to false alarms.
    Type: Grant
    Filed: November 3, 2007
    Date of Patent: July 31, 2012
    Inventors: Behzad Moshiri, Behrooz Sadeghi
  • Publication number: 20120184427
    Abstract: An apparatus for manufacturing a float glass includes a float bath in which a molten glass moves on a surface of a floatable molten metal to form a glass ribbon, a casing deformation preventing member for allowing an inert gas to flow around an end casing at an outlet of the float bath to prevent the end casing from deforming, a dross box disposed adjacent to a downstream end of the float bath and having lift-out rollers for drawing the glass ribbon, an introduction member for introducing an inert gas into the dross box, and a recycling path for supplying an inert gas, which discharges from the casing deformation preventing member, to the introducing member.
    Type: Application
    Filed: March 27, 2012
    Publication date: July 19, 2012
    Inventors: Woo-Hyun Kim, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
  • Publication number: 20120178613
    Abstract: The invention provides an alkali-free glass substrate small in the variation of the thermal shrinkage and a process for producing the same. An alkali-free glass substrate of the invention has an absolute value of a thermal shrinkage of 50 ppm or more when the alkali-free glass substrate is heated at a rate of 10° C./min from a room temperature, kept at a holding temperature of 450° C. for 10 hr and then cooled at a rate of 10° C./min.
    Type: Application
    Filed: February 22, 2012
    Publication date: July 12, 2012
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Yoshinari KATO, Tatsuya Takaya
  • Publication number: 20120132269
    Abstract: A glass substrate may be processed at high temperatures without substantially losing its thermal-strengthening characteristics or deforming. In some examples, the glass substrate exhibits an increased annealing point and/or softening point as compared to standard glass substrates. In some examples, the glass substrate includes a relatively high amount of CaO and/or MgO, and/or a relatively low amount of Na2O, as compared to traditional soda-lime-silica-based glass. Depending on the composition, the glass substrate may be useful, for example, to fabricate a glass-based solar cell that mates two substantially flat glass substrates together.
    Type: Application
    Filed: May 20, 2011
    Publication date: May 31, 2012
    Applicant: CARDINAL FG COMPANY
    Inventors: Brad Hickman, Patrick D. Watson, Kelly J. Busch
  • Publication number: 20120090357
    Abstract: After a glass film ribbon (3) is formed while allowing a glass to descend, the glass film ribbon (3) is annealed while allowing the glass film ribbon (3) to descend in an annealer (5) to remove an internal strain. Then, when the glass film ribbon (3) having a thickness at a center portion excluding both widthwise ends of 300 ?m or less is cut, after processing in the annealer (5) is executed and before a cutting step is executed, main tensile rollers (6R) that play a role as principal tensile rollers hold the descending glass film ribbon (3) and are driven to rotate, to thereby provide at least the glass film ribbon (3) in the annealer (5) with tension in a vertical direction.
    Type: Application
    Filed: October 17, 2011
    Publication date: April 19, 2012
    Inventors: Takahide NAKAMURA, Katsutoshi Fujiwara, Michiharu Eta