Abstract: The present invention relates to the use of silylethynyl hetaryl compound as nitrification Inhibitors.

Abstract: The invention relates to a homogeneous, solid, particulate, urea ammonium sulphate (UAS)-based composition comprising urea ammonium sulphate, a urease inhibitor of the type phosphoric triamide and magnesium sulphate, characterized in that the UAS-based composition comprises 0.02 to 1 weight % of magnesium sulphate, 0.0001 to 1 weight % of the urease inhibitor and about 5 to about 30 weight % of ammonium sulphate. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer.

Abstract: Novel granular fertilizers and methods of making those fertilizers are provided. The method utilized involves recycling streams, including one that provides water having dissolved solids therein, with that water being used during the mixing and granulation process. This method results in a low-moisture, hard, substantially spherical granule, which can include any number of macronutrients and/or micronutrients. Advantageously, the granular fertilizer can be applied to the soil around plants to supply those plants with the necessary nutrients.

Abstract: Improved agriculturally useful products are provided, including solid materials such as nitrogenous fertilizers (e.g., urea), together with a polycarboxylated polymer selected from the group consisting of a salts of copolymers containing individual quantities of maleic and itaconic moieties. The polymer composition also includes from about 10-60% by weight of an organic drying agent such as a lower alcohol which enhances the quick drying properties thereof. The compositions may also include an amount of boron, and bimodal vinylic polymer made up of quantities of high and low molecular weight (MW) vinylic polymers such as PVA.

Abstract: A method for forming a pelletized evaporite mineral product, the method comprising: pulverizing an evaporite mineral feedstock to form a dry powder; mixing the dry powder with a binder in the presence of a liquid to form an intermediate blend; and processing the intermediate blend using a pelletizer to form pellets principally composed of the evaporite mineral.

Abstract: The invention relates to an integrated process for the production of 5-hydroxymethyl furfural (HMF), K2SO4, levulinic acid and formic acid from ?-carrageenan, the latter being obtained from fresh Kappaphycus alvarezii seaweed biomass after expelling the juice. Mg(HSO4)2 was used in HMF synthesis, with co-production of galactose. The aqueous stream after HMF extraction was treated with the seaweed juice which process facilitated recovery of K2SO4 in pure form. The galactose may be utilised for synthesis of levulinic acid and formic acid before or after K2SO4 recovery or, alternatively, utilised for other purposes. Catalysts required in the synthetic reactions are generated in the process itself while the process energy required is met out of additional supplies of the seaweed biomass which is subjected to combustion/gasification.

Abstract: The present invention generally relates to compositions and methods of delivering substances in a dry mode, wherein the compositions include a surface layer disposed on the outer surface of the composition that is permeable to carbon dioxide and oxygen. The compositions may be used to deliver microorganisms to remove contaminates, such as oil, chemical, waste, or sewage, from soil, water, or air. In other embodiments, the compositions can also be used for delivering liquid food, liquid food additives, liquid biotech agricultural ingredients, conventional liquid agricultural ingredients, liquid human wellness and dietary supplements, and liquid fragrances and beauty products.

Abstract: The present media is to be used with a particulate base having particles of a first maximum diameter for growing plants. The media includes granules which are of biodegradable recycled material and have a diameter relative to the first maximum diameter to penetrate further into the particulate base with each watering. The granules include plant nutrients and are of a material which coagulates after watering and adheres to the particulates of the base. The diameter of the granules may be in the range of 1/16 to ? of an inch.

Abstract: A system for the production of ammonium sulfate granules including a pipe cross reactor (PCR) configured to contact concentrated sulfuric acid with anhydrous ammonia to produce a PCR product comprising ammonium sulfate; and a granulator fluidly connected to the PCR, whereby PCR product extracted from the PCR can be introduced into the granulator, an inlet for ammonium sulfate seed material, an ammonia sparger configured to spray liquid anhydrous ammonia directly onto a bed of ammonium sulfate granules within the granulator, a granulator vent configured for extraction of a vapor comprising unreacted ammonia from the granulator, and a granulator product outlet configured for extraction of granulator product comprising ammonium sulfate granules from the granulator. A method of producing ammonium sulfate granules is also provided.

Abstract: The invention employs composites of zeolite and ferric oxide hydroxide for removal of inorganic nitrogen and phosphorus wastes from animal environments.

Abstract: A method for preparing a boron fertilizer, including: (1) heating boric acid to a temperature of 180-200° C., maintaining the temperature for 20-30 min for dehydration of the boric acid to yield pyroboric acid; and (2) cooling down the pyroboric acid to a temperature of 40-60° C., crushing, and screening to yield a powdered, weakly acidic, high-content boron fertilizer. The method is energy-saving, environmentally friendly, and low in cost.

Abstract: A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H2, CH4, CO, CO2, ammonia and hydrogen sulfide.

Abstract: A composition provides increased. lithium and selenium content in vegetables and in their bio-technologically and/or technologically processed products. This composition comprises an aqueous solution of lithium compounds and selenium salts having a lithium content ranging from 0.0001 to 15.Og/l and selenium ranging from 0.0001 to 12.Og/l and at least an adjuvant selected among at least alkaline soap, chitosan hydrolysate, chitosan hydrolysate added with lecithin, and tannic acid and/or mixtures thereof where at least an adjuvant is assigned to increase the lithium and selenium ions absorption.

Abstract: To compete with the increasing global food demand, it is necessary to increase the food production. Fertilizers which are in practice now a days has major disadvantage that 50% of nutrient contents loss due to leaching and also leads to ground water contamination. Slow release nitrogenous fertilizers are good in this regard in that they have minimum nutrient loss due to leaching. Potassium aluminum silicate (Leucite) nanoparticles occluded by calcium ammonium nitrates are slow release fertilizers and are synthesized by hydrothermal method. Its application as slow released nitrates fertilizers was determined by observing nitrate release for 16 days.

Abstract: An alkali metal ion source with a moderate rate of release of the ion (e.g. potassium) is formed by a method that includes: 1) combining an particulate ore that contains at least one of an alkali metal ion-bearing framework silicate (e.g. syenite ore) with at least one of an oxide and hydroxide of at least one of an alkali metal and alkaline earth metal such as calcium hydroxide; 2) milling the mixture of these two components optionally, with water, optionally, milling the dry components separately and blended thereafter, optionally, with water; 3) forming a mixture by adding water to the solid mixture after milling, if water was not added before milling; 4) exposing the mixture to an elevated temperature and pressure to form a gel that includes silica and the alkali metal of the framework silicate.

Abstract: It is described an integrated process for the production of clinker by dry process, with treatment in continuous of by-pass dusts produced by the kiln, wherein the solid matter to treat consists of bypass dusts of a clinker production process, containing compounds of chloride, sodium, potassium and sulphur, such a process comprising the following steps: a) extraction of the bypass dusts directly from the phase of quench, without intermediate storage, at a temperature comprised between 150 and 200° C., with a moisture content varying from 0.1 to 3% by weight, preferably from 0.1 to 0.5% by weight, and with a quantity of calcium carbonate lower than 55% by weight; b) mixing of said dusts coming from step a), within a maximum time comprised between 2 and 10 minutes, preferably lower than about 5 minutes, with water up to a water/dusts ratio varying from 2:1 to 4:1, preferably from 2.5:1 to 3.

Abstract: A fertilizer composition is provided that includes boron and sulfur. The fertilizer composition can be a controlled release fertilizer that includes elemental sulfur, an anhydrous boron-containing compound, and a swelling material. The fertilizer composition can be produced by mixing molten elemental sulfur with the anhydrous boron-containing compound and cooling the mixture.

Abstract: A method employing a composition of bioavailable minerals directed at supplementing nutritional intake of a living plant. The composition includes the ionic mineral(s) copper and zinc in a ligand complex and a pharmaceutically acceptable carrier including water, H2SO4 and (NH4)2SO4. The composition for use in the method may also include other supporting plant nutrients such as botanical extracts, urea, plant hormones, vitamins and mineral supplements necessary for plant health.

Abstract: A controlled release fertilizer material comprising a particulate plant nutrient surrounded by a coating of a mixture including an isocyanate and a polyol, and further comprising a modified wax that may include a polyhydroxyl compound in which the wax and/or the polyhydroxyl compound are cross-linked with a sulfur or oxygen or a peroxide cross-linking moiety. In certain embodiments, the wax and polyhydroxyl compound are cross-linked at unsaturated sites in the wax or polyhydroxyl compound using heat, UV or ionizing radiation.

Abstract: Agricultural blends are described. The agricultural blend includes synthetic gypsum having ammonium sulfate and a by-product of slag, the slag being selected from the group consisting of steel slag, stainless steel slag, alloy steel slag, carbon steel slag, and phosphate slag. Additionally or alternatively, the agricultural blend is delivered to soil, is a mineral soil amendment, is a soil conditioner, is a liming agent, is an additive to increase soil pH, is an additive to decrease metal toxicity, or a combination thereof.

Abstract: This invention relates to a coating composition for a fertilizer comprising at least 50 wt % of a cross-linked lipid; and less than 0.20 wt %, relative to the total weight of the lipid, of a catalyst for cross-linking an unsaturated lipid. The cross-linked lipid has a viscosity at 20 degree Celsius (° C.) in the range of 110 and 800 mPa·s.

Abstract: A method of producing a granulated and compacted fertilizer having incorporated micronutrients in which the granulated primary nutrient and micronutrients are mixed at smaller particle sizes before being compacted into a larger, easier to handle particle sizes.

Abstract: A granulation method may include feeding a graded powder into a granulator. The powder may have a particle size distribution (PSD) of at least 98%-115 mesh and at most 50%-200 mesh. The powder may have a PSD of at least 98% less than or equal to 4.2% of a median product particle size and at most 50% less than or equal to 2.5% of the median product particle size. The powder may have a PSD of between 40% and 80% between 3% and 6% of the median product particle size, between 5% and 30% between 2% and 4% of the median product particle size, and between 10% and 40% between 1% and 3% of the median product particle size. A liquid binder may be fed into the granulator. Wet granules may be discharged from the granulator and may have a moisture content of between 7% and 12%.

Abstract: The invention relates to a potassium sulphate powder wherein about 80 wt % or more of the powder has a particle size of about 0.2 mm or lower, preferably about 0.13 mm or less. The particle size preferably is such, that about 80 wt % or more is about 0.02 mm or higher, more preferably about 0.04 mm or higher. This potassium sulphate powder dissolves easily in water, more in particular, 50 gram of said potassium sulphate powder dissolves in 1 litre of water without stirring within 1 minute, preferably within 30 sec. This potassium sulphate powder is very suitable as foliar fertilizer, in particular for broad acre crops. Further, the invention relates to the use of foliar potassium fertilizer, to enhance the uptake of potassium from the soil.

Abstract: Animal waste is processed to form a biomaterial that is employed as a coating layer for typical fertilizer particles. The biomaterial coating layer can be used neat or with additives and serves to do one or more or any combination of the following: (a) impart a slow or controlled release property to the fertilizer, (b) prevent or reduce the tendency of the fertilizer particles to cake together, or (c) prevent or reduce the tendency of the fertilizer particles to create dust. The biomaterial coating layer can also release nutrients when used as part of a fertilizer composition.

Abstract: A urea fertilizer having reduced ammonia volatilization upon application to soil including a central particle having an outer surface and comprising ammonia volatilization inhibiting compounds containing one or more of boron and iodine, and a coating of urea on the outer surface of the central particle, and further a process of making the fertilizer including the steps of: granulating ammonia volatilization inhibiting compounds containing one or more of boron and iodine, with a binder to produce volatilization inhibitor particles; screening the inhibitor particles to a preselected particle size; spraying melted urea onto the surface of the inhibitor particles to produce a coating on the inhibitor particles; granulating the coated inhibitor particles with sprayed melted urea to produce granules of urea coated central volatilization particles; and cooling the granules.

Abstract: Methods and systems for treating bioreactor wastewater streams are provided. In some embodiments, the methods and systems involve producing a composition, for example in the form of a solution, comprising ammonia or ammonium from the bioreactor wastewater stream. In some cases, the bioreactor is an anaerobic digester.

Abstract: The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation.

Abstract: The present intention relates to an agricultural blend and a method of forming an agricultural blend. The agricultural blend includes a sulfate source and calcium silicate or a by-product of slag, the slag being selected from the group consisting of steel slag, stainless steel slag, alloy steel slag, carbon steel slag, and phosphate slag. The method includes blending a sulfate source and calcium silicate.

Abstract: An environment is moderated in an area where animal wastes are collected in a fluid containing compartment. Animal wastes are collected in a fluid containing compartment. The animal wastes are of the type that generate or provide in or above the fluid containing compartment at least one waste selected from the group consisting of carbon dioxide, hydrogen sulfide, ammonia, mercaptans and organic acids. A combination is provided of i) a polymer capable of absorbing at least ten times its weight in water (preferably a superpolymer) and ii) a combination of salts that react to liberate I2. At least one waste is flocculated with liberated I2 (and any cations from the reactive salts) to form a flocculent that has reduced odor and reduced microbial content. The flocculent may be used as a fertilizer.

Abstract: An agricultural fertigation method includes the continuous in situ manufacture of one or more nitrogen-nutrient raw fertilizers within the irrigation system upstream of the agricultural field being irrigated for a prolonged term. Raw materials, namely nitric acid, urea, ammonium hydroxide, calcium nitrate and/or magnesium nitrate, are intermixed with each other and/or with the stream of the flowing irrigation water. The stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein raw materials are efficiently continuously fed to the irrigation system main line or a side-arm reactor efficiently implements the method.

Abstract: A dry, flowable fertilizer is provided that includes multiple dry, flowable biosolids pellets. Each of the pellets has a pellet surface. Potassium salt grains are adhered to the pellet surfaces and a dust control agent coating is applied to retain the grains on the pellet surfaces. The resultant dry, flowable fertilizer has higher potassium loadings to the potassium salt grains than previous biosolids based fertilizers. A process of forming a fertilizer is also provided that includes tumbling dry, flowable biosolids pellets with powdered potassium salt grains to form a mixture. An aqueous spray is added to adhere the salt grains to the pellet surfaces. With the application of a dust control agent, the salt grains are retained. Potassium levels in NPK units of from 1 to 15 are routinely achieved with greater than 90 elemental % of the potassium is from the surface decorating potassium salt grains.

Abstract: A method is disclosed for producing sulphate or phosphate-based fertilizer from hydrogen sulphide. The method involves feeding a stream containing a substantial volume of hydrogen sulphide and air to a furnace, where it is burned to produce a sulphur dioxide rich gas stream. The sulphur dioxide rich gas stream is then fed to a reactor to produce a sulphuric acid stream and a waste stream comprising carbon dioxide, nitrogen, oxygen, trace impurities and trace amounts of unreacted sulphur dioxide. The sulphuric acid stream is finally converted to a sulphate or phosphate-based fertilizer.

Abstract: A liquid mineral composition for leaf spraying to improve the adaptive response of plants to a change in environmental conditions. The composition includes the following formula (I) with percentages based on weight per total weight of the composition: total ammoniacal nitrogen (N %) 0.08% to 2% potassium as K20 3% to 6% magnesium as MgO 0.4% to 0.8% sodium as Na20 1% to 2% calcium as CaO 0% to 0.5% total sulphates as SO3 3% to 6% total phosphorus as P2O5 0% chlorides Cl 1% to 2% hydrogen carbonate (% of HCO3) 1.2% to 3.0% boron 0.1 to 0.2% copper 0.018% to 0.03% manganese 0.00005% to 0.006% iodine 0.02% to 0.04% zinc 0.00005% to 0.006% iron (mg/kg) 0.0002 to 0.003 water amount sufficient for 100%.

Abstract: The method for increasing yield of crop plants uses foliar application to the plants during the plant growth stage of a granular fertilizer consisting essentially of urea, ammonium sulfate and a fertilizer stabilizing agent. The stabilizing agent regulates and slows down decomposition nitrogen in urea and/or ammonium sulfate to maximize use thereof. The granular fertilizer has a urea/ammonium sulfate weight ratio of about 4/1 and contains at least 40% nitrogen and at least 4% sulfur. The relatively high N—S fertilizer is applied at relatively high rates of about 100 to 150 pounds per acre to ensure that the fertilizer nutrients are always available to the plants at several stages of growth.

Abstract: A macronutrient sustained release composition for a plant locus having nitrogen containing macronutrient compound adsorbed on the surface of hydroxyapatite phosphate nanoparticles, and a process for preparation thereof. The macronutrient adsorbed hydroxyapatite phosphate nanoparticles are encapsulated within cavities present in wood such that the biodegradation of the wood releases the adsorbed macronutrient compounds in a slow and sustained manner to the soil. Further, the macronutrient particles are encapsulated within the cell cavities of wood and wood is coated with cellulose modified hydroxyapatite phosphate nanoparticles such that the rupture of the nanocoating initiates the nitrogen release followed by the biodegradation of the wood releases the rest of the adsorbed macronutrient compounds in a slow and sustained manner to the soil.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: The present invention provides a new liquid fertilizer comprised of potassium sulfite and potassium bisulfite, with neutral to slightly alkaline pH, relatively lower salt index and potentially lower phytotoxicity damage compared to other sources of potassium and sulfur products applied in equal amounts as a starter fertilizer. More specifically, the present invention further relates to methods for fertilizing using a composition of potassium sulfite and potassium bisulfite, particularly as a starter fertilizer, in-furrow fertilizer, side dress fertilizer, and for foliar, broadcast, soil injection and fertigation applications. The fertilizer composition is comprised primarily of potassium sulfite and potassium bisulfite (with the fertilizer grade of 0-0-23-8S).

Abstract: A functional fertilizer composition containing natural mineral ingredients and a method of preparing the same are disclosed. More particularly, a functional fertilizer composition that is environmentally friendly, significantly accelerates growth of plants, relieves physiological disorders, is suitable for use as an agent for odor removal and a gas generation inhibitor, and enables preparation of a soil conditioner from a residue from which mineral ingredients are extracted and a method of preparing the same are disclosed. To this end, the method includes pulverizing vermiculite, mixing the pulverized vermiculite with water, adding sulfur or sulfuric acid to the mixture of pulverized vermiculite and water, stirring the mixture to which sulfur or sulfuric acid has been added, aging the stirred mixture to prepare an aqueous solution, and separating and extracting an aqueous solution containing mineral ingredients from the prepared aqueous solution.

Abstract: This invention is directed to systems, devices and methods to beneficiate heat-dried biosolids or sludge pellets or granules as presently manufactured by municipalities or companies from a) dewatered municipal wastewater biosolids or sludges within the municipal wastewater treatment plant heat-dried biosolids production facility or from b) finished dry heat dried biosolids pellets or granules in a separate manufacturing facility from the municipal wastewater treatment plant to produce a fertilizer containing sufficient organic and inorganic plant nutrients to be valuable and saleable into the commercial agricultural industry. The present invention describes beneficiation methods to increase the plant nutrient content of the fertilizer and also to reduce the odors associated with traditionally-produced heat dried biosolids.

Abstract: A composition has a core of at least one fertilizer substance and at least one layer of a coating material surrounding the core. The core may contain nitrogen and the coating material may include one or more linear, saturated aliphatic monocarboxylic acids.

Abstract: The invention describes a new method for the production of high nitrogen organically-augmented inorganic fertilizer that incorporates municipal biosolids or organic sludges that can compete with traditional fertilizers such as ammonium phosphate, ammonium sulfate and urea on the commodity fertilizer marketplace. The method creates a thixotropic paste-like material from the biosolids or organic sludge that is blended with hot or molten ammonium salts, especially a mixture of ammonium phosphate and ammonium sulfate. The invention can be an add-on to commercial production of ammonium salts or it can stand alone by manufacturing ammonium salts prior to their introduction to the conditioned biosolids. The invention is oriented to be tailored to production facilities for individual municipal waste treatment plants in order to keep manufacturing plants small with a minimization of logistics and liability.

Abstract: Fertilizer products, and methods of making fertilizer products are provided that include an additive, such as an agrochemical, coated onto a base fertilizer particle. The outer coating bonds to the inner coating and maintains the inner coating on the base fertilizer particle until the base fertilizer particle undergoes dissolution and releases the fertilizing component.

Abstract: A simplified and enhanced process to produce thermofertiliser obtained from potassium and phosphorous-bearing minerals is provided, where these elements may or may not be in citric acid or insoluble in water. The process also includes the use of specific additives, at the beginning of the process or immediately before the beginning of the thermal treatment step, in order to increase the potassium and phosphorous contents in the product and the overall efficiency of the process and also to promote the production of a high quality thermofertiliser.

Abstract: An agrichemical is disclosed having increased bio-activity which is adapted for spray application in a form which offers reduced aerial drift and improved deposition on organisms, reduced agglomeration and gellation problems, is adapted for use with chemicals, pesticides and fertilizers and allows for lower agrichemical use rates. Various adjuvants and surfactants are combined with fertilizers or pesticides, such as herbicides fungicides and insecticides, to reduce application problems relating to droplet size, foaming, chemical stability, plant and area coverage, droplet drift, surface tension, suspension, incompatability, phytoxicity, solubility, volatilization and evaporation, while providing enhanced bio-efficacy and low aquatic toxicity. Purifying the agrichemical composition water source by any of various known processes such as oxidation, ultra-filtration, deionization, reverse osmosis or nanofiltration lowers or removes alkaline components, such as calcium, magnesium, iron, sodium, etc.

Abstract: A granular cohered MOP fertilizer having one or more micronutrients, and one or more binding ingredients. The fertilizer is prepared by compacting MOP feed material with one or more micronutrients and one or more optional binders to form a cohered MOP composition. The cohered MOP composition is then further processed, such as by crushing and sizing, to form a cohered granular MOP product containing micronutrients. The process yields a fertilizer product containing micronutrients with superior elemental and granule size distribution without comprising handling or storage qualities.

Abstract: The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation.

Abstract: The present invention relates to a method for preparing ammonium bicarbonate with flue gas and device thereof. The method includes quantitatively collecting flue gas with a carbon dioxide concentration of about 8% to about 15% (volume), decreasing the temperature of the flue gas to about 50° C. or less with an air-cooling apparatus, then increasing the pressure of the flue gas to about 0.4 to about 1.2 MPa, and finally allowing the flue gas to react with liquid ammonia to produce ammonium bicarbonate. The device for preparing ammonium bicarbonate with flue gas includes a flue gas collecting apparatus, an air-cooling apparatus, a gas storing and pressurizing apparatus and an ammonium bicarbonate synthesizing apparatus. The issue of energy consumption brought by conventional cooling approach using cooling water is addressed by using an air-cooling apparatus.

Abstract: The present invention provides a new liquid fertilizer comprised of potassium sulfite and potassium bisulfite, with neutral to slightly alkaline pH, relatively lower salt index and potentially lower phytotoxicity damage compared to other sources of potassium and sulfur products applied in equal amounts as a starter fertilizer. More specifically, the present invention further relates to methods for fertilizing using a composition of potassium sulfite and potassium bisulfite, particularly as a starter fertilizer, in-furrow fertilizer, side dress fertilizer, and for foliar, broadcast, soil injection and fertigation applications. The fertilizer composition is comprised primarily of potassium sulfite (with the fertilizer grade of 0-0-23-8S).

Abstract: A process for formulating high purity potassium chloride from a carnallite source. The process takes advantage of solubility differences and saturation levels in a multiple salt system generated upon dissolution of carnallite. In the system, the sodium chloride is kept in solution and the magnesium chloride present in the system is controlled to be in a concentration range of between 12% and 25% by weight. This avoids co-precipitation of sodium chloride with the potassium chloride during crystallization and therefore prevents the sodium chloride from contaminating the potassium chloride. The result is high grade potassium chloride.