By Vibration Patents (Class 73/61.45)
  • Patent number: 11975491
    Abstract: A system for predicting one or more analytes based on outputs from thin film gas sensors is provided. The system may comprise an electronic nose (e-nose). The e-nose may comprise the gas sensors and a first processor. The system may further comprise a second processor. The second processor may be configured to receive the output from each of the gas sensors, evaluate a prediction accuracy using an evaluation parameter of each of a plurality of models which are trained and tested and select a model from among the plurality of models to deploy based on a comparison of the evaluation parameter for each of the plurality of models and use the same. The second processor may also receive, an output of each of the gas sensors caused by unknown one or more analytes; and predict, using the deployed model, the one or more analytes that causes the output.
    Type: Grant
    Filed: September 23, 2021
    Date of Patent: May 7, 2024
    Assignee: UT-BATTELLE, LLC
    Inventors: Ilia N. Ivanov, Eric S. Muckley, Nicholas West
  • Patent number: 11320615
    Abstract: Systems and methods are provided for applying a protective graphene barrier to waveguides and using the protected waveguides in wellbore applications. A well monitoring system may comprise a waveguide comprising a graphene barrier, wherein the graphene barrier comprises at least one material selected from the group consisting of graphene, graphene oxide, and any combination thereof; a signal generator capable of generating a signal that travels through the waveguide; and a signal detector capable of detecting a signal that travels through the waveguide.
    Type: Grant
    Filed: October 30, 2014
    Date of Patent: May 3, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Satyan Gopal Bhongale, Jerzy Gazda, Etienne M. Samson
  • Patent number: 11262321
    Abstract: A system for determining one or more properties of one or more gases. The system comprises sensors configured to measure thermal conductivity and exothermic responses of a sample at multiple temperatures. Sensor responses to exposure to a gas sample at two or more temperatures are compensated and analyzed by a subsystem. The subsystem is configured to determine a thermal conductivity of the gas sample at each of the two or more temperatures and determine at least one component of the gas sample based at least in part on the thermal conductivity value of the sample at each of the two or more temperatures. Related systems and methods of determining one or more properties of a sample are also disclosed.
    Type: Grant
    Filed: July 27, 2020
    Date of Patent: March 1, 2022
    Assignee: Nevada Nanotech Systems Inc.
    Inventors: Benjamin S. Rogers, Christopher J. Dudley, Jesse D. Adams, Ralph G. Whitten, Alexander C. Woods, Vaughn N. Hartung
  • Patent number: 11226299
    Abstract: A system for determining one or more properties of one or more gases. The system comprises sensors configured to measure thermal conductivity and exothermic responses of a sample at multiple temperatures. Sensor responses to exposure to a gas sample at two or more temperatures are compensated and analyzed by a subsystem. The subsystem is configured to determine a thermal conductivity of the gas sample at each of the two or more temperatures and determine at least one component of the gas sample based at least in part on the thermal conductivity value of the sample at each of the two or more temperatures. Related systems and methods of determining one or more properties of a sample are also disclosed.
    Type: Grant
    Filed: July 27, 2020
    Date of Patent: January 18, 2022
    Assignee: Nevada Nanotech Systems Inc.
    Inventors: Benjamin S. Rogers, Christopher J. Dudley, Jesse D. Adams, Ralph G. Whitten, Alexander C. Woods, Vaughn N. Hartung
  • Patent number: 11118949
    Abstract: According to at least one aspect, a monolithic sensor mount can include a first cylindrical portion and a second cylindrical portion. The first cylindrical portion can have a first diameter and the second cylindrical portion can have a second diameter larger than the first diameter. The second cylindrical portion defining a recess region to host an ultrasonic transducer. The second cylindrical portion can have an outer surface that defines a male thread to mechanically engage a female thread of a cavity within a fluid flow tube configured to host the sensor mount.
    Type: Grant
    Filed: March 30, 2018
    Date of Patent: September 14, 2021
    Assignee: Reliance Worldwide Corporation
    Inventors: Francis McCarthy Mess, Jorge Carlos Almirall, Michael Paul Hammond, Alexander Neal Rycroft, Thimuthu Weragoda Vidanelage
  • Patent number: 10670574
    Abstract: An NMR-based system (10) to analyze one or more of the following: (i) crude oil property, (ii) crude oil rheology of crude oil, comprising an NMR device (11) for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile, said NMR having a crude oil inflow pipe (13), and is in a fluid connection (14) with a crude oil refinery facility (12); wherein said system further comprising a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product (standard crude oil product, SCOP), thereby providing said system means to compare NMR analysis and/or crude oil rheological profile of said SCOP with said time or batch resolved crude oil.
    Type: Grant
    Filed: January 17, 2016
    Date of Patent: June 2, 2020
    Assignee: ASPECT INTERNATIONAL (2015) PRIVATE LIMITED
    Inventors: Uri Rapoport, Tal Cohen
  • Patent number: 9964533
    Abstract: The system for measuring multi-phase fluid flow characteristics is an on-site system for measuring and calculating fluid density of a multi-phase fluid, such as a mixture of oil and water, as well as a water cut thereof. The system for measuring multi-phase fluid flow characteristics includes a conduit having a lower inlet and an upper outlet. The lower inlet is adapted for direct connection to an oil pipeline, an oil well, or the like for receiving the multi-phase fluid flowing therethrough. The conduit defines a pressure monitoring portion having opposing ends. First and second impulse lines connect first and second gauge pressure transmitters and a differential pressure transmitter to the opposing ends to measure total pressure drop and frictional pressure differential to an external controller, which calculates the fluid density and the water cut therefrom The system may also include temperature and volumetric flow rate sensors.
    Type: Grant
    Filed: November 12, 2015
    Date of Patent: May 8, 2018
    Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventors: Aftab Ahmad, Luai M. Alhems
  • Patent number: 9869665
    Abstract: A system including one or more generators predicts engine oil life. Generator data is received or generated by a controller. The generator data describes the operation of the generator including a load placed on the generator. Engine data may also be received or generated by the controller describing an engine coupled to the generator. The controller calculates an estimated oil life based at least on the generator data and/or the engine data.
    Type: Grant
    Filed: May 22, 2014
    Date of Patent: January 16, 2018
    Assignee: Kohler, Co.
    Inventor: William F. Chapman, III
  • Patent number: 9588934
    Abstract: A disposable conduit 1 includes piezo-electric elements 2a and 2b and a memory chip 10 in which calibration data specific to the relevant conduit is stored. Before measurement, a non-disposable electrical measuring circuit reads the calibration data out of the memory chip 10 to prepare a calibrating equation or a calibration table. A flow speed of a blood passing through the conduit or a flow rate calculated from the flow speed is corrected in accordance with the calibrating equation or calibration table.
    Type: Grant
    Filed: November 13, 2012
    Date of Patent: March 7, 2017
    Assignee: ATSUDEN CO., LTD.
    Inventor: Eiichi Murakami
  • Patent number: 9032782
    Abstract: Biosensor apparatus and associated method for detecting a target material using a vibrating resonator having a surface that operably interacts with the target material. A detector is in electrical communication with a sensor, the sensor comprising a first paddle assembly connected to a second paddle assembly, the first paddle assembly having at least one microbalance sensing resonator proximate a proximal end and at least one sensing electrical contact proximate a distal end in electrical communication with the sensing resonator. The at least one sensing resonator has a target coating for operably interacting with the target material, and the second paddle assembly has a microbalance reference resonator proximate the proximal end and at least one reference electrical contact proximate the distal end in electrical communication with the reference resonator.
    Type: Grant
    Filed: June 16, 2011
    Date of Patent: May 19, 2015
    Assignee: Rapid Diagnostek, Inc.
    Inventors: Richard A. Van Deusen, Ian R. Harmon
  • Patent number: 8640529
    Abstract: An apparatus and method for down hole gas separation from the multiphase fluid flowing in a wellbore or a pipe, for determining the quantities of the individual components of the liquid and the flow rate of the liquid, and for remixing the component parts of the fluid after which the gas volume may be measured, without affecting the flow stream, are described. Acoustic radiation force is employed to separate gas from the liquid, thereby permitting measurements to be separately made for these two components; the liquid (oil/water) composition is determined from ultrasonic resonances; and the gas volume is determined from capacitance measurements. Since the fluid flows around and through the component parts of the apparatus, there is little pressure difference, and no protection is required from high pressure differentials.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: February 4, 2014
    Assignee: Los Alamos National Security, LLC
    Inventor: Dipen N. Sinha
  • Patent number: 8578761
    Abstract: A concentration sensor device includes a sensor unit, a substrate, and a sedimentation limit unit. The sensor unit detects a concentration of a specific component contained in liquid. The substrate has a face to which the sensor unit is arranged. The sedimentation limit unit is integrally arranged with the sensor unit or arranged at an upstream side of the sensor unit in a flowing direction of the liquid. The sedimentation limit unit is configured to prevent sedimentation of a foreign object on the sensor unit. The sedimentation limit unit includes a piezoelectric element to vibrate when electricity is supplied so as to promote the foreign object to be separated from the sensor unit. The substrate has a recess recessed in a thickness direction of the substrate.
    Type: Grant
    Filed: March 25, 2009
    Date of Patent: November 12, 2013
    Assignee: DENSO CORPORATION
    Inventors: Kenji Fukumura, Tetsuo Yoshioka, Tetsuo Fujii, Takaaki Kawai, Hirofumi Higuchi, Teruo Oda, Yasuyuki Okuda
  • Patent number: 8532943
    Abstract: An apparatus for measuring the mass fractions of water and oil in a flowing mixture of oil and water through a pipe includes a sensor portion that measures sound velocity and temperature of the flowing oil water mixture at a first time and at a second time. The apparatus includes a temperature changer in thermal communication with the flowing fluid which changes the temperature of the flowing oil water mixture by a measurable amount between the first time and the second time. A method for measuring water mass fraction in a flowing mixture of oil and water through a pipe includes the steps of measuring sound velocity and temperature of the flowing oil water mixture at a first time with a sensor portion. There is the step of changing the temperature of the flowing oil water mixture by a measurable amount with a temperature changer in thermal communication with the flowing fluid.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: September 10, 2013
    Assignee: Cameron International Corporation
    Inventors: Herbert Estrada, Calvin R. Hastings
  • Publication number: 20130047709
    Abstract: A method and system for measuring a property of a multiphase fluid comprising a mixture of at least an oil phase and a water phase travelling through a conduit, the method comprising measuring the thickness of the liquid mixture, measuring the permittivity of a portion of the multiphase fluid, combining the thickness measurement with the permittivity measurement to obtain a derived value for the permittivity of the liquid mixture, and using at least the derived permittivity of the liquid mixture and a relationship between a single phase liquid property and a corresponding two-phase property of the liquid mixture, to obtain a calculated water-to-liquid ratio of the liquid mixture.
    Type: Application
    Filed: October 25, 2012
    Publication date: February 28, 2013
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Cheng-Gang XIE, Songming HUANG
  • Patent number: 8374806
    Abstract: An ultrasonic phase-shift detection device includes a clock generator, a divider, a first counter, a comparator, a phase detector and a second counter. The divider is provided for dividing the clock signal to generate ultrasonic signals. The comparator is provided for comparing the counting value of the first counter and a predetermined number. The phase detector is provided for comparing the phase shift between different ultrasonic signals. The second counter is provided for counting to generate the digital result signal.
    Type: Grant
    Filed: September 28, 2010
    Date of Patent: February 12, 2013
    Assignee: Tatung Company
    Inventors: Shu-Ting Liao, Chao-Fa Lee, Cheng-Hsing Kuo
  • Patent number: 8286466
    Abstract: An apparatus and method for determining the water cut value of a multiphase fluid flowing within a pipe is provided. The device includes a sequestering structure disposed within the pipe, a transmitting device, a receiving device, and a processing device. The sequestering structure at least partially defines a sensing passage within the pipe, which passage has a gap extending substantially normal to a direction of fluid flow within the pipe. The sensing passage is oriented to sequester an amount of a liquid component of the multi-phase fluid sufficient to form a continuous liquid body extending across the gap of the sensing passage. The transmitting device is operable to transmit a signal through the liquid across the gap of the sensing passage. The receiving device is operable to receive the signal after it has traversed the liquid within the sensing passage, and create sensor data.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: October 16, 2012
    Assignee: Expro Meters, Inc.
    Inventor: Daniel L. Gysling
  • Patent number: 7775085
    Abstract: Methods and systems for determining the water, oil, and gas fractions in hydrocarbons from high water cut hydrocarbon wells. A hydrocarbon flow stream discharging from a well is subjected to hydro-separation to produce an oil-enriched fractional stream upon which water content measurements can be more accurately and reproducibly made. Calculations based on the water content of the oil-enriched fractional stream and the flow rate of at least one of the streams through the separator are conducted to determine the water content of the original stream. This provides a simple approach to measuring the water content in high water cut hydrocarbons that is real-time, accurate, and reproducible.
    Type: Grant
    Filed: September 18, 2006
    Date of Patent: August 17, 2010
    Assignee: Phase Dynamics, Inc.
    Inventor: Bentley N. Scott
  • Patent number: 7712353
    Abstract: In a system and process for ultrasonically treating a liquid having a thermal conductivity, an elongate treatment chamber housing has an inlet and an outlet such that liquid flows longitudinally through an interior space of the chamber from the inlet to the outlet. At least part of the interior space of the chamber housing is filled with a bed of particles having a thermal conductivity substantially greater than that of the liquid whereby a ratio of the thermal conductivity of the particles to the thermal conductivity of the liquid is in the range of about 2:1 to about 400:1. An elongate ultrasonic waveguide assembly extends longitudinally within the interior space of the housing and is operable at a predetermined ultrasonic frequency to generate mechanical ultrasonic vibration within the housing in direct contact with the liquid flowing therein as the liquid flows through the bed of particles.
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: May 11, 2010
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Robert Allen Janssen, Thomas David Ehlert, John Gavin MacDonald, Earl C. McCraw, Jr., Patrick Sean McNichols
  • Patent number: 7618585
    Abstract: An ultrasonic wave passes different fuels of different concentrations with different velocities. The present invention provides a detecting and controlling device where, by a non-touching method, a velocity for an ultrasonic wave in a first fuel with a first fuel concentration is measured. The velocity obtained is taken for a comparison with another velocity for the same ultrasonic wave in a fuel with a default fuel concentration so that the first fuel concentration of the fuel can be under controlled.
    Type: Grant
    Filed: August 17, 2005
    Date of Patent: November 17, 2009
    Assignee: Atomic Energy Council - Institute of Nuclear Energy Research
    Inventors: Kang-Nang Perng, Ching-Shih Liu, Kin-Fu Lin, Charn-Ying Chen, Kang-Lin Hwang, Ying-Sheng Lee
  • Publication number: 20090025460
    Abstract: An apparatus and method to determine fractions of various phases in a multiphase fluid. The apparatus includes main body including an interior configured receive a multiphase fluid and an exterior. The apparatus senses fluid pressure of multiphase fluid received in the interior and senses a fluid temperature of the multiphase fluid. The apparatus transmits an ultrasonic wave into the fluid and detects the transmitted wave to determine its velocity and attenuation. The apparatus may adjust the determined velocity and attenuation based on the temperature and pressure of the fluid to compensate for a difference between the sensed temperature and pressure and a standard temperature and pressure. The apparatus determines a gas fraction, water fraction, and a non-water fluid fraction of the multiphase fluid based on the sensed fluid pressure, the sensed fluid temperature, and the velocity and attenuation of the ultrasonic wave in the multiphase fluid.
    Type: Application
    Filed: July 27, 2007
    Publication date: January 29, 2009
    Applicant: Southern Methodist University
    Inventors: Yildirim Hurmuzlu, Peter Antich, Ali Dogru, Edmond Richer, Billy Smith
  • Patent number: 7304732
    Abstract: An integrated photoacoustic spectroscopy (PAS) cell is fabricated using microelectromechanical (MEMS) techniques. The multi-layer structure includes an inner layer with a patterned resonant cavity disposed between top and bottom outer layers and a microphone acoustically coupled to the resonant cavity. In the preferred embodiment, the microphone is a piezoelectric thin-film membrane formed on one of the outer layers. The inner layer is additionally patterned to include buffer cavities on either side of the resonant cavity, and one or both of the top and bottom outer layers are also patterned to include buffer cavities aligned with the buffer cavities in the inner layer on either side of the resonant cavity. The preferred fabrication method involves joining an inner silicon substrate to a pair of outer silicon substrates, thereby encapsulating the resonant cavity, and depositing a piezoelectric thin film onto one of the outer substrates which is then patterned to create an acoustic sensor.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: December 4, 2007
    Assignee: United States of America as represented by the Secretary of the Army
    Inventors: Ronald G. Polcawich, Paul Pellegrino
  • Patent number: 7281415
    Abstract: Embodiments of the present invention generally provide methods, apparatus, and systems for determining void fractions of individual phase components of a multiphase mixture. The void fractions may be determined based on measured parameters of the mixture as a whole, such as differential pressure, bulk velocity of the mixture and speed of sound in the mixture. According to some embodiments, the mixture parameters may be measured using non-intrusive fiber optic based sensors. Various other parameters may also be derived from the void fractions, such as individual phase flow rates, liquid holdup and watercut parameters (for oil and gas mixtures).
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: October 16, 2007
    Assignee: Weatherford/Lamb, Inc.
    Inventor: Espen S. Johansen
  • Patent number: 7140238
    Abstract: Method for determining the composition of a homogeneous fluid, for example a petroleum effluent on flow, an emulsion consisting of water and oil, or a foam consisting of oil and gas. The attenuation and the phase shift of microwave beams that have traversed a fluid of unknown composition with paths of different lengths are measured (stage A). Two equations approaching the measured values are determined, the first equation giving a relation between the attenuation and the length of the path, the second equation giving a relation between the phase shift and the length of the path (stage C). Then the composition of the fluid is determined by comparing the two equations with pairs of equations stored in form of databases, each pair of equations corresponding to a fluid of known composition (stage D).
    Type: Grant
    Filed: April 2, 2004
    Date of Patent: November 28, 2006
    Assignee: Institut Francais du Petrole
    Inventors: Claude Beauducel, Yohan Bentolila, Abdelaziz Faraj, Michel Constant
  • Patent number: 6945089
    Abstract: In a mass-sensitive sensor consisting of an acoustic surface wave component on the basis of shear waves, the sensor includes a substrate with an active surface carrying two different layers, one which is a parylene layer of a thickness of between 0.2 and <1.6 ?m, which has been produced on the substrate by a vacuum-based deposition method and is capable of generating Love waves and the second layer forms a utilization layer, which interacts with an analyte disposed in a medium contacting the utilization layer.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: September 20, 2005
    Assignee: Forschungszentrum Karlsruhe GmbH
    Inventors: Nicole Barie, Ulrich Stahl, Michael Rapp
  • Patent number: 6945095
    Abstract: Embodiments of the present invention generally provide methods, apparatus, and systems for determining void fractions of individual phase components of a multiphase mixture. The void fractions may be determined based on measured parameters of the mixture as a whole, such as differential pressure, bulk velocity of the mixture and speed of sound in the mixture. According to some embodiments, the mixture parameters may be measured using non-intrusive fiber optic based sensors. Various other parameters may also be derived from the void fractions, such as individual phase flow rates, liquid holdup and watercut parameters (for oil and gas mixtures).
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: September 20, 2005
    Assignee: Weatherford/Lamb, Inc.
    Inventor: Espen S. Johansen
  • Patent number: 6912891
    Abstract: A method of using ultrasonic reflectance to characterize physical properties of fluids, particularly food solutions. In general, the method comprises the steps of: (a) generating longitudinal ultrasonic waves, (b) coupling the transducer to the fluid being investigated, (c) detecting the reflected longitudinal waves, and (d) determining the physical property of interest by correlating certain characteristics of the reflected ultrasonic waves with the physical property being measured. A particular aspect of the invention is a self-calibrating ultrasonic device useful as a solids concentration sensor and/or a dissolution/precipitation sensor. Self calibration is accomplished via a twin delay line. The invention is particularly useful as an on-line sensor in the processing of food solutions such as milk, ketchup, syrup, chocolate and other confectionary.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: July 5, 2005
    Assignee: The Penn State Research Foundation
    Inventors: John N. Coupland, Raffaella Saggin
  • Publication number: 20040216515
    Abstract: The present invention relates to physical chemistry and can be used for a quality test of liquids, in particular, multi-component liquid products, to ascertain the conformity of various process liquids, pharmaceutical preparations, foodstuffs, biological liquids to standard in pharmacology, food processing and chemical industries, and in medical diagnostics. The method of invention enables determining of the mechanical impedance within a drop (1) of test liquid having a specified volume, in the preferred embodiment, 5 mcl, placed on the surface of a piezoelectric resonator (3) of ultrasound frequencies, which provides for excitation of shear modes within drop (1) while it is drying up. The obtained time dependence of the mechanical impedance of drop (1) is used as the information parameter.
    Type: Application
    Filed: July 21, 2003
    Publication date: November 4, 2004
    Inventors: Tatjana Anatoljevna Yakhno, Vladimir Grigorievich Yakhno, Ivan Ivanovich Shmeljov, Anatoly Gennadievich Sanin, Evgeny Valerievich Krotov, Yuri Yakovievich Brodsky
  • Publication number: 20040194539
    Abstract: An apparatus 10 is provided that measures the speed of sound propagating in a multiphase mixture to determine parameters, such as mixture quality, particle size, vapor/mass ratio, liquid/vapor ratio, mass flow rate, enthalpy and volumetric flow rate of the flow in a pipe or unconfined space, for example, using acoustic and/or dynamic pressures. The apparatus includes a pair of ultrasonic transducers disposed axially along the pipe for measuring the transit time of an ultrasonic signal to propagate from one ultrasonic transducer to the other ultrasonic transducer. A signal process, responsive to said transit time signal, provides a signal representative of the speed of sound of the mixture. An SOS processing unit then provides an output signal indicative of at least one parameter of the mixture flowing through the pipe. The frequency of the ultrasonic signal is sufficiently low to minimize scatter from particle/liquid within the mixture.
    Type: Application
    Filed: January 13, 2004
    Publication date: October 7, 2004
    Inventor: Daniel L. Gysling
  • Patent number: 6786082
    Abstract: A non-invasive online system for continuous measurements of phase levels in a converter or pyrometallurgical furnace in smelting and conversion processes, consisting in a electrical signal generator, transducers that convert said electrical signals in mechanical waves placed on the outer end of air blowing tuyeres, coupling means between said system and the shell of the converter, transducers placed in the direction of the axis orthogonal to the phases plane for applying mechanical waves that travel in a transversal direction into the converter, a mechanical waves sensor placed around the external wall of the shell of the converter that receives the reflected signal, a crystal local oscillator, means for the preamplification of the signal, an analogous/digital interface, a means for data acquisition, a means for processing the signals so as to determine the power of the reflected signal and the propagation time of the signal between the moment it is emitted by the transducer and the moment in which the reflec
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: September 7, 2004
    Inventors: Luis Paredes Rojas, Alfredo Zolezzi Garreton
  • Publication number: 20040139791
    Abstract: Embodiments of the present invention generally provide methods, apparatus, and systems for determining void fractions of individual phase components of a multiphase mixture. The void fractions may be determined based on measured parameters of the mixture as a whole, such as differential pressure, bulk velocity of the mixture and speed of sound in the mixture. According to some embodiments, the mixture parameters may be measured using non-intrusive fiber optic based sensors. Various other parameters may also be derived from the void fractions, such as individual phase flow rates, liquid holdup and watercut parameters (for oil and gas mixtures).
    Type: Application
    Filed: January 21, 2003
    Publication date: July 22, 2004
    Inventor: Espen S. Johansen
  • Patent number: 6748793
    Abstract: Systems and methods for ultrasound sensing a compound's concentration in aqueous solution are provided. As a result of the ultrasound sensing, an accurate real time measurement of the concentration of the compound of interest in aqueous solution is obtained. In various non-limiting embodiments, the invention provides ultrasound sensing of methanol's concentration in aqueous solution in connection with a fuel circulation process for a direct methanol fuel cell. Since the speed of sound in a water-methanol system increases significantly with methanol content, techniques for measuring characteristic sound velocities are used to give sufficient resolution for a fuel circulation process.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: June 15, 2004
    Assignees: E. I. du Pont de Nemours and Company, ABB Research Ltd.
    Inventors: Arnold Rabinovich, Daryl Tulimieri
  • Publication number: 20040099050
    Abstract: A method for analyzing a fluid contained within a machine, comprising the steps of providing a machine including a passage for containing a fluid; placing a sensor including a mechanical resonator in the passage; operating the resonator to have a portion thereof translate through the fluid; and monitoring the response of the resonator to the fluid in the passage. A preferred sensor includes a tuning fork resonator.
    Type: Application
    Filed: June 2, 2003
    Publication date: May 27, 2004
    Applicant: Symyx Technologies, Inc.
    Inventors: Leonid Matsiev, James Bennett, Daniel M. Pinkas, Mikhail Spitkovsky, Oleg Kolosov
  • Patent number: 6716358
    Abstract: The invention includes a method for demulsification of water-in-oil emulsions.
    Type: Grant
    Filed: January 28, 2003
    Date of Patent: April 6, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Ramesh Varadaraj
  • Publication number: 20030209078
    Abstract: A non-invasive online system for continuous measurements of phase levels in a converter or pyrometallurgical furnace in smelting and conversion processes, consisting in a electrical signal generator, transducers that convert said electrical signals in mechanical waves placed on the outer end of air blowing tuyeres, coupling means between said system and the shell of the converter, transducers placed in the direction of the axis orthogonal to the phases plane for applying mechanical waves that travel in a transversal direction into the converter, a mechanical waves sensor placed around the external wall of the shell of the converter that receives the reflected signal, a crystal local oscillator, means for the preamplification of the signal, an analogous/digital interface, a means for data acquisition, a means for processing the signals so as to determine the power of the reflected signal and the propagation time of the signal between the moment it is emitted by the transducer and the moment in which the reflec
    Type: Application
    Filed: May 13, 2002
    Publication date: November 13, 2003
    Inventors: Luis Paredes Rojas, Alfredo Zolezzi Garreton
  • Publication number: 20030121315
    Abstract: Systems and methods for ultrasound sensing a compound's concentration in aqueous solution are provided. As a result of the ultrasound sensing, an accurate real time measurement of the concentration of the compound of interest in aqueous solution is obtained. In various non-limiting embodiments, the invention provides ultrasound sensing of methanol's concentration in aqueous solution in connection with a fuel circulation process for a direct methanol fuel cell. Since the speed of sound in a water-methanol system increases significantly with methanol content, techniques for measuring characteristic sound velocities are used to give sufficient resolution for a fuel circulation process.
    Type: Application
    Filed: December 28, 2001
    Publication date: July 3, 2003
    Inventors: Arnold Rabinovich, Daryl Tulimieri
  • Patent number: 6575020
    Abstract: The present invention relates to integrated micro-cantilevers, micro-bridges or micro-membranes in micro-liquid handling systems. Such micro-liquid handling systems provide novel detection mechanisms for monitoring the physical, chemical and biological properties of fluids in such systems. The present invention further relates to micro-cantilever, micro-bridge or micro-membrane type sensors having integrated readout. Such constructions allow laminated flows of different liquids to flow in a channel without mixing, which opens up for new type of experiments and which reduces noise related to the liquid movement. The present invention even further relates to sensors having adjacent or very closely spaced micro-cantilevers, micro-bridges or micro-membranes which can be exposed to different chemical environments at the same time.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: June 10, 2003
    Assignee: Cantion A/S
    Inventors: Hasin Francois de Charmoy Grey, Tove Maria Henriette Jensenius, Jacob Thaysen, Anja Boisen
  • Patent number: 6298724
    Abstract: Apparatus and method for detecting the formation and dissociation of gas hydrates in a fluid. The apparatus used comprises a piezoelectric crystal sensor and a signal analyzer. The crystal sensor has a deposition surface in contact with the fluid. Under a range of pressures and or temperatures the resonant frequency or an electrical parameter dependent on the resonant frequency of the piezoelectric sensor is measured. There is a step change in the resonant frequency which occurs upon the formation or dissociation of a clathrate hydrate on the deposition surface, so that the formation or dissociation of said clathrate hydrate may be detected.
    Type: Grant
    Filed: December 27, 1999
    Date of Patent: October 9, 2001
    Assignee: Heriot-Watt University
    Inventors: Rhoderick William Burgass, Adrian Christopher Todd, Sayed Ali Danesh, Bahman Tohidi Kalorazi
  • Patent number: 6244101
    Abstract: The present invention is a transducer for photoacoustic detection having at least two piezoelectric elements wherein at least a first piezoelectric element has a first frequency and at least a second piezoelectric element has a second frequency. The improvement according to the present invention is that at least two piezoelectric elements are longitudinal elements for longitudinal waves; and the first frequency is different from said second frequency. In other words, the invention is a multi-frequency longitudinal transducer for photoacoustic detection.
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: June 12, 2001
    Assignee: Battelle Memorial Institute
    Inventors: S. Thomas Autrey, Gerald J. Posakony, James E. Amonette, Nancy S. Foster-Mills
  • Patent number: 6234006
    Abstract: A vapor sensing device that is sufficiently small and lightweight to be handheld, and also modular so as to allow the device to be conveniently adapted for use in sensing the presence and concentration of a wide variety of specified vapors as resulting from gases released during either decomposition and spoilage of food stuffs, or as released into either the breath or body fluids of a sick patient being medically diagnosed. The device provides these benefits using a sensor module that incorporates a sample chamber and a plurality of sensors located on a chip releasably carried within or adjacent to the sample chamber. Optionally, the sensor module can be configured to be releasably plugged into a receptacle formed in the device. Vapors are directed to pass through the sample chamber, whereupon the sensors provide a distinct combination of electrical signals in response to each.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: May 22, 2001
    Assignee: Cyrano Sciences Inc.
    Inventors: Steven A. Sunshine, M. Gregory Steinthal, Christopher K. Boehr, Robert K. Nakayama
  • Patent number: 6223588
    Abstract: Apparatus and method for detecting the dew point or bubble point phase transition in fluid. The apparatus used comprises a piezoelectric crystal sensor and a signal analyser. The phase transition of the fluid is measured by monitoring, directly or indirectly, change in the resonant frequency of the piezoelectric crystal sensor while said one of the temperature and pressure is varied, so as to detect a substantial change in said resonant frequency and/or in the rate of change in resonant frequency with change in the varying one of the temperature and pressure.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: May 1, 2001
    Assignee: Heriot-Watt University
    Inventors: Rhoderick William Burgass, Adrian Christopher Todd, Sayed Ali Danesh, Bahman Tohidi Kalorazi
  • Patent number: 6223589
    Abstract: The chemical and/or physico-chemical determination of the ageing of a motor oil is very expensive and requires measuring methods which cannot be carried out on board a motor vehicle. The determination of only one oil condition parameter, for example the viscosity, only enables conditional statements to be made with respect to oil quality since conflicting effects may exist to varying degrees in this case. According to the invention, oil quality can be determined by a quartz base coated with a sensitive layer. The sensitive layer has a surface or volume which is adapted to an oil component and is suitable for the repeated incorporation and release of the oil component according to the concentration thereof. When the oil component is present, it is incorporated in the sensitive layer causing the resonant frequency of the layer to decrease via a mass effect or causing an effective increase of the component thickness or mass.
    Type: Grant
    Filed: April 26, 1999
    Date of Patent: May 1, 2001
    Assignee: Volkswagen AG
    Inventors: Franz Dickert, Peter Forth, Peter Lieberzeit, Günter Voigt, Klaus Dieter Marquardt
  • Patent number: 6196059
    Abstract: Disclosed is a piezoelectric resonator, a process for the fabrication thereof and its use as a sensor element, which implemented in a through-flow cell, is integratable in a measurement system for the determination of the concentration of a substance contained in a liquid and/or for the determination of the physical properties of the liquid. The piezoelectric resonator is designed plane and is provided on its surface with electric contact areas for an electrode and a counter electrode, which is connectable to a signal source as well as to a measurement device. For measuring, the piezoelectric resonator is brought into contact with the to-be-examined liquid on one side, with the resonator responding to the accumulation of the mass of the to-be-detected substance or to a change in the physical properties of the liquid by changing its resonance frequency and/or oscillation amplitude.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: March 6, 2001
    Assignee: Fraunhofer Gesellschaft zur Forderung der angewandten Forschung e.V.
    Inventors: Conrad Kösslinger, Erich Uttenthaler, Andreas Nitsch, Thomas Härle