With Another Nonmetal Patents (Class 75/237)
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Patent number: 5149361Abstract: A cermet alloy having a structure including a hard phase and a bonding phase which is composed of at least one ferrous metal, said bonding phase containing fine hard grains of a mean grain size not greater than 2000 .ANG. dispersed therein. The structure has a composition consisting of 10 to 70 wt % of TiCN, 5 to 30 wt % of WC, 5 to 30 wt % of NbC, 1 to 10 wt % of Mo.sub.2 C, 0.5 to 5 wt% of VC, 0.05 to 3 wt % of ZrC, 5 to 25 wt % of (Ni, Co), and not smaller than 2.5 wt% of total nitrogen and incidental impurities.Type: GrantFiled: December 26, 1989Date of Patent: September 22, 1992Assignees: Hitachi, Ltd., Hitachi Taga Engineering Co., Ltd.Inventors: Yusuke Iyori, Nobuhiko Shima
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Patent number: 5145505Abstract: Disclosed are a high toughness cermet comprising a sintered alloy comprising 75 to 95% by weight of a hard phase of carbide, nitride or carbonitride containing Ti, at least one of W, Mo and Cr, and N and C, and the balance of a binder phase composed mainly of an iron group metal, and inevitable impurities,wherein the content of Ti in said sintered alloy is 35 to 85% by weight calculated on TiN or TiN and TiC, and the contents of W, Mo and Cr are 10 to 40% by weight in total calculated on WC, Mo.sub.2 C and/or Cr.sub.3 C.sub.2,the relative concentration of said binder phase at the 0.01 mm-inner portion from the surface of said sintered alloy is 5 to 50% of the average binder phase concentration of the inner portion, and the relative concentration of said binder phase at the 0.1 mm-inner portion from the surface of said sintered alloy is 70 to 100% of the average binder phase concentration of the inner portion, anda compression stress of 30 kgf/mm.sup.Type: GrantFiled: February 7, 1992Date of Patent: September 8, 1992Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Takeshi Saito, Kozo Kitamura, Mitsuo Ueki
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Patent number: 5143540Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceamic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and pressing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressures of 60-250 kpsi employed at a rate of 5-250 kpsi/second.Type: GrantFiled: September 18, 1990Date of Patent: September 1, 1992Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Robert R. McDonald, Alexander Pecnenik
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Patent number: 5125990Abstract: A magnetically anisotropic hot-worked magnet made of an R-T-B alloy containing a transition metal T as a main component, a rare earth element R including yttrium, and boron B; the magnet having the fine crystal grains having an average grain size of 0.02 -1.0 .mu.m, and having a carbon content of 0.8 weight % or less and an oxygen content of 0.5 weight % or less. The angular variance of orientation of the crystal grains is within 30.degree. from the C axes of the crystal grains when measured by X-ray. This magnet can be produced by mixing the magnet flakes with an additive composed of at least one organic compound having a boiling point of 50.degree. C. or higher.Type: GrantFiled: June 1, 1990Date of Patent: June 30, 1992Assignee: Hitachi MetalsInventors: Katsunori Iwasaki, Shigeho Tanigawa, Masaaki Tokunaga
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Patent number: 5110349Abstract: A cutting insert of a sintered carbonitride alloy and with a complicated geometry, the insert having improved efficiency. This is obtained by giving the powder non-uniform compaction during pressing of the powder into a press-body so that the ultimate working edges will have a higher relative density than the surrounding, more "supporting" material in the press-body. By these means are often obtained surface defects in the form of cracks because of dissolved strains during the sintering.Type: GrantFiled: November 14, 1990Date of Patent: May 5, 1992Assignee: Sandvik ABInventors: Kenneth Westergren, Gerold Weinl, Rolf Oskarsson
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Patent number: 5089047Abstract: A dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The granular hard phase consists essentially of a ceramic material selected from the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, and borides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, boron, and mixtures thereof. The metal phase consists essentially of a combination of nickel and aluminum having a weight ratio of nickel to aluminum of from about 90:10 to about 70:30 and 0-5% by weight of an additive selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, or carbon, or combinations thereof. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure.Type: GrantFiled: December 20, 1990Date of Patent: February 18, 1992Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5053074Abstract: A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.Type: GrantFiled: December 20, 1990Date of Patent: October 1, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5041261Abstract: A method for manufacturing a dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal binder phase. The hard phase is (a) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, borides, and mixtures thereof of the elements selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and B, or (b) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, and carboxynitrides, and mixtures thereof of a cubic solid solution of Zr--Ti, Hf--Ti, Hf--Zr, V--Ti, Nb--Ti, Ta--Ti, Mo--Ti, W--Ti, W--Hf, W--Nb, or W--Ta. The binder phase is a combination of Ni and Al having a Ni:Al weight ratio of from about 85:15 to about 88:12, and 0-5% by weight of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Co, B, and/or C. The method involves presintering the hard phase/binder phase mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then HIPing at about 1575.degree.-1675.degree. C.Type: GrantFiled: December 21, 1990Date of Patent: August 20, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5030276Abstract: An improved temperature stable synthetic polycrystalline diamond (PCD) product includes at least one temperature stable PCD integrally and chemically bonded to a matrix carrier support through a carbide forming layer which is of a thickness of at least about 1 micron, the layer on at least one surface of the PCD is in turn bonded to the matrix carrier. A wide variety of shapes, sizes and configurations of such products is achieved through relatively low temperature and relatively low pressure processing. Various products of various geometries are described as well as the details of the processing to achieve chemical bonding of the PCD elements in a variety of support matrix carrier materials to form a unitary structure having a temperature stability up to about 1,200 degrees C.Type: GrantFiled: November 18, 1988Date of Patent: July 9, 1991Assignee: Norton CompanyInventors: Chien-Min Sung, Sy-Hwa Chen, Leo Merrill, Louis K. Bigelow
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Patent number: 5013611Abstract: A camshaft having a tubular steel shaft and a sintered cam piece joined to the shaft. The sintered cam piece has iron tetroxide film at its surface. The camshaft is produced by assembling a powder compact to the steel shaft to provide a camshaft assembly, sintering the assembly to provide an integral assembly, correcting bending to the assembly, annealing the assembly, grinding the cam piece and effecting vaporization treatment to the assembly at a temperature lower than the annealing temperature.Type: GrantFiled: January 18, 1990Date of Patent: May 7, 1991Assignee: Nippon Piston Ring Co., Ltd.Inventors: Yasuo Suzuki, Shunsuke Takeguchi
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Patent number: 4973356Abstract: The present invention relates to a method of preparing an alloy for use as a cutting tool material comprising hard principles and binder phase by which a uniform distribution of the hard principles in the binder phase is obtained, and the resulting product.Type: GrantFiled: October 23, 1989Date of Patent: November 27, 1990Assignee: Sandvik ABInventors: Peder von Holst, Hakan Morberg, Rolf Oskarsson
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Patent number: 4961778Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceramic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and presssing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressure of 60-250 kpsi employed at a rate of 5-250 kpsi/second.Type: GrantFiled: January 13, 1988Date of Patent: October 9, 1990Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Alexander Pechenik, Robert R. McDonald
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Patent number: 4954170Abstract: High density compacts are made by providing a compactable particulate combination of Class 1 metals selected from at least one of Ag, Cu and Al, with material selected from at least one of CdO, SnO, SnO.sub.2, C, Co, Ni, Fe, Cr, Cr.sub.3 C.sub.2, Cr.sub.7 C.sub.3, W, WC, W.sub.2 C, WB, Mo, Mo.sub.2 C, MoB, Mo.sub.2 B, TiC, TiN, TiB.sub.2, Si, SiC, Si.sub.3 N.sub.4, usually by mixing powders of each, step (1); uniaxially pressing the powders to a density of from 60% to 95%, to provide a compact, step (2); hot densifying the compact at a pressure between 352 kg/cm.sup.2 (5,000 psi) and 3,172 kg/cm.sup.2 (45,000 psi) and at a temperature from 50.degree. C. to 100.degree. C. below the melting point or decomposition point of the lower melting component of the compact, to provide densification of the compact to over 97% of theoretical density; step (3); and cooling the compact, step (4).Type: GrantFiled: June 30, 1989Date of Patent: September 4, 1990Assignee: Westinghouse Electric Corp.Inventors: Maurice G. Fey, Natraj C. Iyer, Alan T. Male, William R. Lovic
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Patent number: 4923512Abstract: Cobalt-bound tungsten carbide metal matrix composites having a unique microstructure are produced by consolidating partially sintered greenware under high pressures, e.g., 120,000 psi, at temperatures less than those used for conventional liquid phase sintering in a relatively short time, e.g., from less than one minute to less than about one hour. The composites have a binder phase which contains less than about 80 weight percent of the tungsten found in a composite prepared from the same or similar compositions via liquid phase sintering. These composites provide cutting tools with both toughness and wear resistance which exceed that of cutting tools made from the same or similar compositions via liquid phase sintering.Type: GrantFiled: April 7, 1989Date of Patent: May 8, 1990Assignee: The Dow Chemical CompanyInventors: Ed E. Timm, Douglas B. Schwarz
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Patent number: 4915735Abstract: A wear-resistant sintered alloy comprising an Cr-C-Fe base alloy in which 0.5 to 3% by weight of CaF.sub.2 and 5 to 20% by weight of hard particles having particle size of 44 to 150 .mu.m and a mean value of Vickers hardness of 800 to 2000 are dispersed. This wear-resistant sintered alloy is produced by a method comprising the steps of adding 1.2 to 2% by weight of carbon powder, 0.5 to 3% by weight of calcium fluoride powder, and 5 to 20% by weight of hard metal powder having the particle size of 44 to 150 .mu.m and a mean value of Vickers hardness of 800 to 2000, to an Fe-Cr-C base alloy powder containing 10 to 20% by weight of Cr and 0.8 to 1.5% by weight of C, mixing them, molding the resultant mixed powder into a desired shaped, and then sintering the compact in the temperature range of from 1180.degree. to 1260.degree. C. in a non-oxidizing atmosphere. The sintered alloy is useful as a material for parts required to have the heat resistance and wear resistance.Type: GrantFiled: May 10, 1988Date of Patent: April 10, 1990Assignee: Sumotomo Electric Industries, Ltd.Inventor: Naoki Motooka
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Patent number: 4909843Abstract: A highly wear-resistant sintered alloy is to be provided, with which, using conventional sintering technology and no additional hardening treatment, commodity parts are to be produced, which, in respect to their wear property are to be equivalent to chilled cast iron parts. They should have a surface roughness of approximately 50 Rockwell and only a slight shrinkage. This is accomplished with an iron-nickel-copper-molybdenum sintered alloy with addition of phosphorus, which contains a proportion of carbon, which exceeds the phosphorus added by at least a factor of 2. Essentially, the alloy has the following composition:1.0-5.0% (by weight) of nickel (Ni)1.0-3.0% (by weight) of copper (Cu)0.3-1.0% (by weight) of molybdenum (Mo)0.3-0.6% (by weight) of phosphorus (P)1.0-2.Type: GrantFiled: October 2, 1987Date of Patent: March 20, 1990Assignee: Etablissement SupervisInventor: Karl Leithner
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Patent number: 4909841Abstract: A process of hot pressing of materials to form articles or compacts is characterized by the steps: (A) providing a compactable particulate mixture; (B) uniaxially pressing the particles without heating to provide article or compact (22); (C) placing at least one article or compact (22) in an open pan (31) having an insertable frame (32) with edge surfaces (34) that are not significantly pressure deformable, where the inside side surfaces of the frame are parallel to the central axis B--B of the open pan, and where each article or compact is surrounded by fine particles of a separating material; (D) evacuating air from the container and sealing the articles or compacts inside the container by means of top lid (36); (E) hot pressing the compacts at a pressure from 352.5 kg/cm.sup.2 to 3,172 kg/cm.sup.Type: GrantFiled: June 30, 1989Date of Patent: March 20, 1990Assignee: Westinghouse Electric Corp.Inventors: Natraj C. Iyer, Alan T. Male, William R. Lovic
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Patent number: 4904302Abstract: Disclosed is a roller for use in a rotary compressor, which roller comprising a sintered body consisting essentially of 0.5-2.0% by weight of C, 1.0-5.0% by weight of Cu, 1.2-3.0% by weight of Mo and a balance of Fe and unavoidable impurities. In the sintered alloy, hard particles of Fe-Mo alloy are dispersed in one of pearlitic and tempering martensitic matrix, and sintered pores of the sintered body is sealed with tri-iron tetroxide. Resultant sintered body has high wear resistance and scuffing resistance capable of being used as an inverter type compressor.Type: GrantFiled: November 14, 1988Date of Patent: February 27, 1990Assignee: Nippon Piston Ring Co., Ltd.Inventor: Soichi Shimomura
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Patent number: 4891078Abstract: Compositions for the production of rare earth-ferromagnetic-metal permanent magnets comprise mixtures of rear earth-ferromagnetic metal alloy powder and a lesser amount of a powdered second-phase sintering aid, wherein there is added up to about 2 percent by weight of a particulate refractory oxide, carbide, or nitride additive. Permanent magnets are prepared by mixing the components, aligning the mixture in a magnetic field, pressing and sintering. The refractory material inhibits grain growth in the second phase during sintering, improving the magnetic properties of the major phase.Type: GrantFiled: January 25, 1988Date of Patent: January 2, 1990Assignee: Union Oil Company of CaliforniaInventor: Mohammad H. Ghandehari
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Patent number: 4885030Abstract: Methods are disclosed of making and of using a high density high strength titanium diboride comprising material. The method of making comprises (a) compacting a mixture of titanium diboride, 5-20% by weight of a metal group binder, and up to 1% oxygen and up to 2% graphite, the mixture having a maximum particle size of 5 microns, and (b) sintering the compact to substantially full density. The TiB.sub.2 may be replaced by up to 10% TiC. The method of use is as a cutting tool at relatively high speeds against aluminum based materials.Type: GrantFiled: July 15, 1989Date of Patent: December 5, 1989Assignee: Ford Motor CompanyInventors: David Moskowitz, Charles W. Phillips
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Patent number: 4880461Abstract: A super hard high-speed tool steel having a composition satisfying the condition of 0.ltoreq.C-Ceq.ltoreq.0.6 (where Ceq=0.06Cr+0.033 W+0.063 Mo+0.2 V within the range of 1.7.ltoreq.C.ltoreq.4.1%, the composition containing 3 to 10% of Cr, 1 to 20% of W, 1 to 15% of Mo (where 18.ltoreq.W+2Mo.ltoreq.40), 1 to 15% of V, not greater than 15% of Co, not greater than 2% of Si, not greater than 1% of Mn, and the balance substantially Fe and inevitable impurities, the steel further containing in uniformly dispersed state 2 to 12% in total of one, two or more selected from a group consisting of nitrides, carbides and carbonitrides of Ti, V, Zr, Nb, Hf and Ta in the composition. This tool steel exhibits a distinguished hardness of HRC 71 or higher, as well as toughness.Type: GrantFiled: December 21, 1987Date of Patent: November 14, 1989Assignee: Hitachi Metals, Ltd.Inventor: Norimasa Uchida
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Patent number: 4863513Abstract: An iron-based anti-wear sintered alloy member containing at least 1.5 weight % C, 0.5 to 3.5 weight % P, and one or both of Mo and W in an amount of 0.5 to 3.0 weight % in terms of Mo (the conversion rate of W being 0.5) in addition to iron and having a phosphatic film formed at sliding contact portions. In addition to the above-described elements, one or both of Ni and Cu may be incorporated in an amount of 0.5 to 5.0 weight % in terms of Ni (the conversion rate of Cu being 0.5), of 0.3 to less than 8.0 weight % of Cr may be incorporated, or one or both of Ni and Cu may be incorporated in an amount of 0.3 to 0.7 weight % in terms of Ni together with 0.3 to 0.7 weight % of Cr.Type: GrantFiled: September 8, 1987Date of Patent: September 5, 1989Inventors: Genkichi Umeha, Shigeru Urano, Osamu Hirakawa, Shunsuke Takeguchi
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Patent number: 4836848Abstract: An Fe-base sintered alloy for valve seats for use in internal combustion engines and a method of manufacturing the same are provided. The alloy consists essentially of 0.6 to 1.3% C, 1 to 5% Cr, 4 to 15% Mo, 0.5 to 2% Ni, 2 to 8% Co, 0.2 to 2% Nb, 0.2 to 2% at least one lubricating component selected from the group consisting of a CaF.sub.2 and BaF.sub.2 and the balance of Fe and inevitable impurities. Starting powders are blended into the same composition as above, and mixed into a mixed powder. The mixed powder is pressed into a green compact. Then, the green compact is presintered, hot forged, sintered, and, if required, further heat treated, in sequence to be formed into an Fe-base sintered alloy having a structure wherein particles of the at least one lubricating component and hard particles of other components are dispersed in a matrix formed principally of a pearlite phase. The resulting alloy possesses a density of at least 7.3 g/cm.sup.Type: GrantFiled: October 2, 1987Date of Patent: June 6, 1989Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Osamu Mayama, Yoshimi Ishikawa
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Patent number: 4828611Abstract: Herein is disclosed a high hardness sintered diamond compact and a process for the production of the same.The high hardness sintered diamond compact comprises 80 to 95% by volume of diamond particles, 0.5 to 5% by volume of a carbide particles selected from a group consisting of WC and (Mo,W)C and having a diameter not larger than 1 micron, and 4.5 to 15% by volume of an iron group metal, at least 95% by volume of said diamond particles having a diameter from 0.1 to 2 micron and the remainder of the diamond particles being particles having a diameter smaller than 0.1 micron.The ratio by volume of the amount of the diamond particles having a diameter from 1 to 2 micron to that of the diamond particles having a diameter from 0.1 to 1 micron ranges from 4 to 1.The high hardness sintered diamond compact according to the present invention is preferably usable as a drawing die for drawing a high hardness plated-steel wire and as a tool bit.Type: GrantFiled: December 28, 1987Date of Patent: May 9, 1989Assignee: Sumitmo ElectricInventors: Tetsuo Nakai, Syuzi Yazu, Keizo Asai, Yoshiaki Kumazawa
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Patent number: 4808557Abstract: The present invention is characterized by ceramic materials comprising ceramic sintered bodies consisting of (1) 1-90 wt % chromium carbide and the remainder carbonic titanium nitride; (2) 1-90 wt % chromium carbide, 0.1-5 wt % B.sub.4 C and the remainder titanium carbo-nitride; or (3) either of the above compositions plus less than 95 wt % of a metal boride such as Ti or Zr. Such ceramic sintered bodies are used for cutting tools or wear-resistant machine parts because of their high density, high hardness and high strength.Type: GrantFiled: June 30, 1987Date of Patent: February 28, 1989Assignees: Kyushu Director of Institute, Itaru Todoroki, Tokyo Kokyu Rozai Co., Ltd.Inventors: Tadahiko Watanabe, Kazuhisa Shobu, Yuko Tsuya, Yuji Enomoto, Junshiro Hayakawa, Osamu Yagishita, Hideki Yamamoto, Eiichi Sudoh
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Patent number: 4778521Abstract: A tough cermet made from 20-92 weight % of TiC and/or TiCN, 5-50 weight % of WC and 3-30 weight % of an iron-group metal. This tough cermet has a three phase grain microstructure consisting of a core phase rich in TiC and/or TiCN, an intermediate phase rich in WC and surrounding the core phase, and an outer phase made of (Ti,W)C and/or (Ti,W)CN and surrounding the intermediate phase. Because of this three-phase microstructure, the cermet has high toughness without sacrificing hardness. It is prepared by using WC powder of as fine as less than 3 .mu.m, without taking the course of forming a solid solution of TiC and/or TiCN and WC and pulverizing it.Type: GrantFiled: June 2, 1986Date of Patent: October 18, 1988Assignees: Hitachi Metals, Ltd., Hitachi Carbide Tools Ltd.Inventors: Yusuke Iyori, Hisaaki Ida
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Patent number: 4765836Abstract: A powder-metallurgy alloy article having a good combination of wear resistance and corrosion resistance. The article is further characterized by an attainable minimum hardness after heat treatment of 60R.sub.c and a martensitic structure. The article is made from prealloyed particles of the composition, in percent by weight, carbon 2.5-5, manganese 0.2-1, phosphorus 0.10 maximum, sulfur 0.10 maximum, silicon 1 maximum, nickel 0.5 maximum, chromium 15-30, molybdenum, 2-10 vanadium 6-11, nitrogen 0.15 maximum and balance, iron. The article has a fine, uniform distribution of a MC and other carbide phases.Type: GrantFiled: December 11, 1986Date of Patent: August 23, 1988Assignee: Crucible Materials CorporationInventors: John J. Hauser, William Stasko, Kenneth E. Pinnow
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Patent number: 4758273Abstract: A process for decreasing the embrittling tendency of lithium in aluminum-base alloy compositions containing lithium comprising incorporating silicon in the alloy composition and forming the alloy as a dispersion strengthened powder, and dispersion strengthened aluminum-base alloy compositions comprised of aluminum, lithium and silicon having improved properties.Type: GrantFiled: August 21, 1986Date of Patent: July 19, 1988Assignee: INCO Alloys International, Inc.Inventors: Paul S. Gilman, Stephen J. Donachie, Robert D. Schelleng
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Patent number: 4756754Abstract: The present invention relates to a composite formed of a mixture of ceramic particles and at least two metallic components adhered together with a glassy phase. A first of the metallic components, in particle form, enhances the flow characteristics of the mixture where the second metallic component and the glass are in the molten condition. The final composite is a continuous phase of the second metallic component having particles of the first metallic component and glass coated ceramic particles distributed therein.Type: GrantFiled: March 6, 1987Date of Patent: July 12, 1988Assignee: Olin CorporationInventor: Narendra N. SinghDeo
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Patent number: 4722751Abstract: A light weight and high strength aluminum alloy and a process for producing such an alloy, which alloy is suitable for forming automotive engine components, including pistons. In a preferred embodiment, 80 to 99.5% by volume of an aluminum alloy powder or a mixed powder composed of pure metal powders or master alloy powders is blended with 0.5 to 20% by volume of at least one of carbon or graphite powder, an oxide powder, a carbide powder and a nitride powder. The blend is then mechanically alloyed, following which the thereby-obtained powder is subjected to working such as by compaction and hot forging, hot pressing, cold isostatic pressing and hot forging, or cold isostatic pressing and hot extrusion.Type: GrantFiled: December 19, 1984Date of Patent: February 2, 1988Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kiyoaki Akechi, Nobuhito Kuroishi
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Patent number: 4715892Abstract: The present invention is directed to a cermet material comprising a matrix of metal or alloy with ceramic particles distributed therein. The cermet includes a glass binder for bonding between the metal or alloy and the ceramic particles.Type: GrantFiled: October 30, 1986Date of Patent: December 29, 1987Assignee: Olin CorporationInventor: Deepak Mahulikar
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Patent number: 4702771Abstract: Wear-resistant, sintered iron alloys are provided. The alloys have a structure in which iron-based hard particles having a relatively high Cr content and copper or copper alloy particles are dispersed in an iron alloy matrix containing a relatively low content of Cr. The alloys are prepared by compression molding powders of the matrix alloy, the hard alloy, copper or copper alloy, an Fe-P alloy and graphite and sintering the obtained molding at a temperature of 980.degree. to 1130.degree. C.Type: GrantFiled: April 4, 1986Date of Patent: October 27, 1987Assignees: Hitachi Powdered Metals Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Yoshiaki Takagi, Yoshihiro Katsui, Hiroyuki Endo, Yutaka Ikenoue
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Patent number: 4689077Abstract: A method is disclosed for manufacturing a reaction sintered composite article which comprises at least one ceramic component. The method comprises preparing a particulate mixture of precursor powders leading to the formation of said composite material upon reaction sintering, pressing said particulate mixture to a self-sustaining body, heating said body up to a temperature below the temperature at which the reaction sintering is initiated, comminuting the heat treating body, selecting particles of a suitable grain size distribution, pressing said particles into shapes of desired size and configuration, and heating said shapes up to a temperature at which the reaction sintering is initiated. The reaction sintered body comprises borides, carbides, nitrides or silicides of a transition metal of the groups IVb, Vb or VIb of the periodic table (comprising titanium, hafnium, zirconium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten), and a metal oxide.Type: GrantFiled: May 19, 1986Date of Patent: August 25, 1987Assignee: ELTECH Systems CorporationInventors: Michel Chevigne, Dominique Darracq, Jean-Pol Wiaux
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Patent number: 4661155Abstract: A molded, boron carbide-containing, sintered article which includes at least 65 percent by volume boron carbide; and from 5 to 35 percent by volume of at least one binder metal selected from the group consisting of molybdenum, molybdenum alloys, tungsten and tungsten alloys, having a melting point above 1,800.degree. C., and forming no molten borides or carbides within a temperature range of from 1,800.degree. to 1,950.degree. C. A method for producing the article includes the steps of mixing to obtain a homogeneous mixture from 20 to 80 percent by weight boron carbide particles having a particle size ranging from 1 to 1,650 microns with up to 80 percent by weight of particles of the at least one binder metal having a particle size ranging from 35 to 100 microns; introducing the homogeneous mixture into a graphite matrix mold; heating to sinter the homogeneous mixture at a temperature ranging from 1,800.degree. to 2,000.degree. C.Type: GrantFiled: May 21, 1986Date of Patent: April 28, 1987Assignee: Kernforschungszentrum Karlsruhe GmbHInventors: Volker Heinzel, Hossein-Ali Keschtkar, Ingeborg Schub
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Patent number: 4648902Abstract: A process for the production of a reinforced metal plate comprising forming a slurry of metal coated carbon fibers, binder fibers and metal powder, laying down a mat from said slurry, drying the resultant mat and then sintering said, is disclosed. The dried sintered mat may be made stronger by contacting the mat with a silicate before sintering.Type: GrantFiled: October 21, 1983Date of Patent: March 10, 1987Assignee: American Cyanamid CompanyInventor: Robert D. Giglia
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Patent number: 4639352Abstract: This invention relates to a hard alloy comprising two phases: a hard phase consisting of at least one compound having a crystal structure of simple hexagonal MC type (M: metal; C: carbon) selected from the group consisting of mixed carbides, carbonitrides and carboxynitrides of molybdenum and tungsten, and a binder phase consisting of at least one element selected from the group consisting of iron, cobalt and nickel. The hard phase is prepared by carburizing an (Mo, W) alloy obtained by reducing oxides of molybdenum and tungsten with a particle size of at most 1 micron, is composed of coarse particles with a mean particle size of at least 3 microns, and has a uniform molybdenum to tungsten ratio in the particles. The hard alloy has a gross composition within the range of the shaded portion ABCDEA in FIG. 1.Type: GrantFiled: December 13, 1985Date of Patent: January 27, 1987Assignee: Sumitomo Electric Industries, Ltd.Inventors: Mitsuo Kodama, Masaya Miyake, Minol Nakano, Tsuyoshi Asai, Akio Hara
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Patent number: 4615734Abstract: A solid particle erosion resistant coating includes angular titanium carbide particles uniformly dispersed through a high chromium iron matrix. In one form, the aggregate comprises, by weight, about 30-50% TiC, about 10-30% Cr, about 1.5-5% C and the balance essentially iron in the form of ferrite. The matrix also includes metallurgically identifiable amounts of high chromium content M.sub.7 C.sub.3 carbides therethrough. The coating does not exhibit austenitic or martensitic structure therehthough. A powder alloy consolidated body also includes a surface adjacent region having a similar TiC and high chromium iron matrix. Further, a method for obtaining the coating includes heating above the austenitization temperature of the matrix alloy and below the melting temperature of iron, and cooling the aggregate so as to attain iron in the form of ferrite in the matrix.Type: GrantFiled: February 7, 1985Date of Patent: October 7, 1986Assignee: General Electric CompanyInventor: Donald R. Spriggs
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Patent number: 4457780Abstract: The invention relates to electric contact materials for use in switches, such as moulded circuit breakers, air circuit breakers, magnetic switches, etc.The electric contact materials comprise 5-60 weight % iron group metals, 1-11 weight % graphite, 5-70 weight % refractory materials, and the residual part consisting of silver, said refractory materials being held in the state of dispersion in the iron group metals and/or silver, thereby providing welding resistance, wear resistance, and insulation resistance as well as high practical utility of low temperature rise.Type: GrantFiled: April 12, 1982Date of Patent: July 3, 1984Assignee: Sumitomo Electric Industries, Ltd.Inventors: Mitsuo Osada, Nobuhito Kuroishi, Yoshinari Amano, Akira Fukui
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Patent number: 4402744Abstract: An aluminum coated carbon article or composite, and process therefor having aluminum chemically bonded to carbon via an interface of a metal monocarbide formed in situ when an intermetallic phase comprising aluminum and a metal capable of reacting with carbon to form a metal carbide is reduced by carbon to aluminum and a metal carbide, the metal selected from the group consisting of tantalum, titanium and hafnium.Type: GrantFiled: August 29, 1980Date of Patent: September 6, 1983Assignee: Union Carbide CorporationInventor: Raymond V. Sara
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Patent number: 4380471Abstract: A polycrystalline diamond body infiltrated by a silicon atom-containing metal (e.g., silicon alloy) is bonded to a substrate comprising cemented carbide with a barrier of refractory material extending between the diamonds cemented together with silicon atom-containing binder and the substrate substantially precluding migration of the cementing medium (e.g., cobalt) from the carbide substrate into contact with the silicon atom-containing bonding medium in the diamond body. The process comprises subjecting a mass of diamond powder, a quantity of silicon atom-containing metal binder material, a cemented carbide body and a barrier made of material selected from the group consisting of tantalum, vanadium, molybdenum, zirconium, tungsten and alloys thereof to the simultaneous application of elevated temperature and pressure.Type: GrantFiled: January 5, 1981Date of Patent: April 19, 1983Assignee: General Electric CompanyInventors: Minyoung Lee, Lawrence E. Szala, Roy E. Tuft
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Patent number: 4348232Abstract: An abrasion resistant ferro-based sintered alloy comprising 0.8 to 1.5% by weight of carbon, 0.5 to 2.5% by weight of chromium, 2.0 to 6.0% by weight of molybdenum, 1.5 to 5.0% by weight of nickel, 0.1 to 2.0% by weight of tungsten, 0.2 to 5.0% by weight of copper and the balance iron wherein said alloy contains molybdenum particles around which nickel is distributed and which are uniformly dispersed in the base structure comprising a mixture of pearlite, bainite and martensite and said alloy contains composite carbide of Fe-Cr-W-C dispersed in the base structure, is disclosed.Type: GrantFiled: May 7, 1980Date of Patent: September 7, 1982Assignee: Nippon Piston Ring Co., Ltd.Inventors: Takeshi Hiraoka, Shigeru Urano, Masajiro Takeshita, Keiji Nakamura
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Patent number: 4347083Abstract: An aluminum coated carbon article or composite, and process therefor having aluminum chemically bonded to carbon via an interface of a metal monocarbide formed in situ when an intermetallic phase comprising aluminum and a metal capable of reacting with carbon to form a metal carbide is reduced by carbon to aluminum and a metal carbide, the metal selected from the group consisting of tantalum, titanium and hafnium.Type: GrantFiled: August 29, 1980Date of Patent: August 31, 1982Assignee: Union Carbide CorporationInventor: Raymond V. Sara
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Patent number: 4345943Abstract: An abrasion resistant sintered alloy for use in internal combustion engines which comprises 0.5 to 4.0% by weight of C, 5.0 to 3.0% by weight of Cr, less than 10.0% by weight of at least one of Ni, Mo, Co and Cu, 0.1 to 5.0% by weight of at least one of P, B and Si which permits liquid-phase sintering at temperatures not higher than 1,250.degree. C. and the balance iron, and have hardness after sintering of Hv 500 to 1,200, 7 to 45% by area ratio of cementite or eutectic crystal of cementite and P and 0.2 to 10% by volume of sintering pores at least 40% of which consist of pores having a pore size of not larger than 150 .mu.m.Type: GrantFiled: April 24, 1980Date of Patent: August 24, 1982Assignee: Nippon Piston Ring Co., Ltd.Inventors: Kentaro Takahashi, Yoshikatsu Nakamura, Masajiro Takeshita
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Patent number: 4345942Abstract: An abrasion resistered sintered alloy for use in internal combustion engines which comprises 0.5 to 4.0% by weight of carbon, 1.5 to 16.0% by weight of Nb, 0.1 to 4.0% by weight of Mo, 0.1 to 1.0% by weight of Ni and 0.1 to 5.0% by weight of P which permits liquid-phase sintering at temperatures not higher than 1,250.degree. C., and have 0.2 to 10% by volume of sintering pores at least 40% of which consist of pores having a pore size of not larger than 150 .mu.m is disclosed.Type: GrantFiled: April 24, 1980Date of Patent: August 24, 1982Assignee: Nippon Piston Ring Co., Ltd.Inventors: Kentaro Takahashi, Yoshikatsu Nakamura, Masajiro Takeshita
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Patent number: 4334928Abstract: A sintered compact for use in a machining tool comprising 80 to 10 volume % of a high pressure form of boron nitride, and the balance a matrix of at least one binder compound material selected from the group consisting of a carbide, nitride, carbonitride, boride or silicide of IVa and Va transition metal of the periodic table, their mixtures as well as the solid solution of these compounds; the matrix forming a continuous bonding structure in the sintered body.A method of producing the compact comprises preparing a mix of 80 to 10 volume % of a high pressure form of a boron nitride powder with 20 to 90 volume % of at least one powdered binder compound selected from the group consisting of a carbide, a nitride, a carbonitride, a boride and a silicide of a IVa, or a Va metal, mixtures thereof or solid solutions of these compounds, and sintering the mix under pressures more than 20 Kb at temperatures higher than 700.degree. C. for more than 3 minutes.Type: GrantFiled: February 8, 1980Date of Patent: June 15, 1982Assignee: Sumitomo Electric Industries, Ltd.Inventors: Akio Hara, Shuji Yazu
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Patent number: 4290807Abstract: This invention relates to a hard alloy consisting of a metallic phase and a hard phase having a B1 type crystal structure, and being represented by the following general formula,(M.sub.1a, M.sub.2b, M.sub.3c)(C.sub.1-x-y N.sub.y O.sub.x).sub.zin which M.sub.1 is at least one of Group IVa elements, M.sub.2 is at least one of Group VIa elements, M.sub.3 is at least one of Group Va elements, C is carbon, N is nitrogen, O is oxygen, a, b, c, x and y are respectively atomic ratios satisfying the relations of a+b+c=1, 0.1.ltoreq.(a+c)/a+b+c).ltoreq.0.7 (c can be zero), 0.05.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, 0.05.ltoreq.x+y.ltoreq.0.6 and z is an atomic ratio of (C+N+O)/M.sub.1 +M.sub.2 +M.sub.3) satisfying the relation of 0.1.ltoreq.z.ltoreq.0.5.Type: GrantFiled: September 13, 1978Date of Patent: September 22, 1981Assignee: Sumitomo Electric Industries, Ltd.Inventors: Tsuyoshi Asai, Naoji Fujimori, Takaharu Yamamoto
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Patent number: 4279651Abstract: The invention relates to a sintered hard metal having a high wear resistance and heat resistance as material for cutting tools and wear resistant tools and the method for producing the same. The sintered hard metal has a hard phase comprising a phase having a B-1 type crystal structure containing more than one kind of IVa, Va and VIa group metals in the Periodic Table and also the elements, carbon, nitrogen and oxygen and a WC phase, the hard phase and a bonding phase chiefly consisting of a ferrous metal which is sintered by a powder metallurgy technique, whereas the oxygen in particular is added thereto making it possible to obtain a sintered hard metal having said excellent properties.Type: GrantFiled: December 28, 1978Date of Patent: July 21, 1981Assignee: Sumitomo Electric Industries, Ltd.Inventors: Naoji Fujimori, Masaaki Tobioka, Tsuyoshi Asai, Takaharu Yamamoto, Masaya Miyake
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Patent number: 4268309Abstract: Wear-resisting iron base sintered alloy obtained by sintering a metal powder composed of, by weight, 15-25% chromium, 0-3% molybdenum, 1-5% copper, 0.3-0.8% phosphorus and 2.0-4.0% carbon, with the balance iron and less than 2% impurities, to a density of more than 7.3 g/cm.sup.3.Type: GrantFiled: November 14, 1978Date of Patent: May 19, 1981Assignee: Toyota Jidosha Kogyo Kabushiki KaishaInventors: Yoichi Serino, Tetsuya Suganuma, Yoshitaka Takahashi
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Patent number: 4263046Abstract: A workpiece of alloy steel is produced by sintering under a nonoxidizing atmosphere a mass of malleable-iron powder admixed with a comminuted complex ferroalloy. The latter, obtained from a molten mixture of several simple high-carbon ferroalloys saturated with graphite, is a blend of at least three nonferrous metals and iron in carbide form, including a complex carbide of formula M.sub.7 C.sub.3 containing iron and manganese with the possible addition of chromium and another carbide of formula M'.sub.2 C/M'C containing molybdenum with the possible addition of vanadium and/or niobium. The carbidically bound carbon amounts to at least 4%, by weight, of the ferroalloy composition and may constitute between 10% and 60% of the carbon of the sinterable powder mixture to which elemental carbon may be added as graphite. As the mass of iron and ferroalloy particles compacted under high pressure is sintered at temperatures between about 1150.degree. and 1300.degree. C.Type: GrantFiled: September 26, 1978Date of Patent: April 21, 1981Assignee: GfE Gesellschaft fur Elektrometallurgie mit beschrankter HaftungInventors: Rudolf Fichte, Hans-Joachim Retelsdorf, Richard Jervis, Gunter Radel
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Patent number: 4212670Abstract: The proposed titanium carbonitride-base hard alloy contains in percent by weight:nickel, from 9.5 to 49.0molybdenum, from 2.5 to 20.5,the level of carbon not exceeding 0.6 percent by weight, and the titanium carbonitride TiC.sub.x N.sub.y has the following component ratio:x, from 0.45 to 0.55y, from 0.41 to 0.55.The alloy of the invention can be employed most advantageously for manufacturing cutting tools for the metal-working industry.Type: GrantFiled: March 13, 1978Date of Patent: July 15, 1980Inventors: Gennady P. Shveikin, Vladislav D. Ljubimov, Boris V. Mitrofanov, Vladimir A. Privalov, Evgeny K. Plaxin, Dmitry S. Elinson, Stanislav I. Alyamovsky, Jury G. Zainulin, Sergei P. Makarov