Abstract: Disclosed herein, in certain embodiments, are composite materials, methods, tools and abrasive materials comprising a tungsten-based metal composition, a tungsten carbide, and an alloy. In some cases, the composite materials or matrix are resistant to oxidation.

Abstract: A drawing die made from cemented carbide material is formed of tungsten carbide and a metallic binder. The cemented carbide material includes: tungsten carbide with an average grain size of 0.15-1.3 ?m, 0.5-5.0 wt.-% (Co+Ni), with a ratio Co/(Co+Ni) of 0.6-0.9; 0.1-1.0 wt.-% Cr, with 0.05?Cr/(Co+Ni)?0.22; 0.02-0.2 wt.-% Mo; and 0-0.04 wt.-% V. The cemented carbide material is substantially free from ?-phase.

Abstract: A material and method are provided for increasing catalytic activity of electrocatalysts. In use, a material comprises synthesized carbon-containing composite materials, synthesized metal-metal carbides, and a heterostructure material comprising the synthesized carbon-containing composite materials and the synthesized metal-metal carbides. The synthesized metal-metal carbides are atom-decorated, at least in part, on the synthesized carbon-containing composite material. Additionally, a method of increasing catalytic activity of an electrocatalyst includes dissolving a metal precursor into a first solution, where the metal precursor comprises a set of characteristics. A heterostructure material is created based on the first solution, wherein catalytic activity of the heterostructure material is a function of the set of characteristics, and wherein the heterostructure material includes a metal-metal carbide that is atom-decorated to synthesized carbon-containing composite materials.

Abstract: Sintered cemented carbides are described herein exhibiting enhanced high temperature properties without dramatic losses in bending strength. In some embodiments, a sintered cemented carbide composition comprises tungsten carbide, a metallic binder phase comprising at least one metal of the iron group, and at least one solid solution carbide phase comprising tantalum (Ta) and molybdenum (Mo), wherein a value of (Mo/Ta) in the sintered cemented carbide composition is from 0.3-100, and the sintered cemented carbide composition has a transverse rupture strength of at least 4000 MPa.

Abstract: A sintered composite material obtainable by a method which includes providing a composition which includes at least one hardness carrier and a base binder alloy, and sintering the composition. The base binder alloy includes from 66 to 93 wt.-% of nickel, from 7 to 34 wt.-% of iron, from 0 to 9 wt.-% of cobalt, and up to 30 wt.-% of one or more elements selected from W, Mo, Cr, V, Ta, Nb, Ti, Zr, Hf, Re, Ru, Al, Mn, B, N and C. The wt.-% proportions of the base binder alloy add up to 100 wt.-%.

Abstract: The present disclosure relates to a cutting tool of a cemented carbide substrate including WC and a binder phase having one or more of Co, Fe and Ni, wherein the cemented carbide also includes a finely dispersed eta phase of Me12C and/or Me6C carbides, where Me is one or more metals selected from W, Mo and the binder phase metals, wherein the substoichiometric carbon content in the cemented carbide is between ?0.30 to ?0.16 wt %. The disclosed cutting tool will achieve an improved resistance against comb cracks.

Abstract: Provided are a cemented carbide having excellent plastic deformation resistance and a cutting tool in which the cemented carbide is used as a substrate. A cemented carbide includes a hard phase containing tungsten carbide particles and a binder phase containing, as a main component, an iron-group element, wherein the formula B/A?0.05 is satisfied, where A represents the number of the tungsten carbide particles, and B represents the number of tungsten carbide particles whose number of contact points with other tungsten carbide particles is 1 or less. Preferably, the iron-group element includes cobalt, and the cobalt content in the cemented carbide is 8% by mass or more. Preferably, the tungsten carbide particles have an average particle diameter of 3 ?m or more.

Abstract: A hard composite composition may comprise a binder and a polymodal blend of matrix powder. The polymodal blend of matrix powder may have at least one first local maxima at a particle size of about 0.5 nm to about 30 ?m, at least one second local maxima at a particle size of about 200 ?m to about 10 mm, and at least one local minima between a particle size of about 30 ?m to about 200 ?m that has a value that is less than the first local maxima.

Abstract: A coated cutting tool insert includes a substrate of cemented carbide, cermet, ceramics, steel or cubic boron nitride having deposited thereon a coating having a total thickness of 60 ?m, including one or more layers having a wear resistant layer of ?-Al2O3 of a thickness of 1 to 45 ?m deposited by chemical vapour deposition (CVD). The ?-Al2O3 layer includes at least two portions, a first thickness portion and a second thickness portion immediately on top of the first thickness portion. The first thickness portion has an essentially columnar ?-Al2O3 grain structure, and at a transition from the first thickness portion to the second thickness portion the grain boundaries of at least 1 out of 25 neighboring grains of the ?-Al2O3 grains undergo a directional change into a direction that is essentially perpendicular, 90±45 degrees, to the grain boundaries in the first thickness portion.

Abstract: The invention provides for a cermet powder containing 75-90% by weight of at least one hard material powder, from 10 to 25% by weight of one or more matrix metal powders and up to 3% by weight of at least one modifier, wherein the matrix metal powder or powders contain from 0 to 38% by weight of cobalt, from 0 to 38% by weight of nickel, from 0 to 20% by weight of aluminum, from 0 to 90% by weight of iron and from 10 to 35% by weight of chromium and the sum of the contents of iron and chromium is in the range from 10 to 95% by weight and the sum of the contents of cobalt, nickel and iron is in the range from 65 to 95% by weight. The invention also relates to a cermet and a process to make the cermet containing the cermet powder and shaped article coated with the cermet powder and a process to make the shaped article.

Abstract: This invention relates to powder metallurgy, more specifically, to methods of fabricating hard alloy items. The invention can be used as an iron, cobalt or nickel base binder for the fabrication of diamond cutting tools for the construction industry and stone cutting, including segmented cutting discs of different designs and wires for reinforced concrete and asphalt cutting used in the renovation of highway pavements, runways in airports, upgrading of metallurgical plants, nuclear power plants, bridges and other structures, monolithic reinforced concrete cutting drills, as well as discs and wires for the quarry production of natural stone and large scale manufacturing of facing construction materials. This invention achieves the objective of providing binders for the fabrication of diamond tools having higher wear resistance without a significant increase in the sintering temperature, as well as higher hardness, strength and impact toughness.

Abstract: In one aspect sintered cemented carbide articles are described herein which, in some embodiments, exhibit enhanced resistance to wear and thermal fatigue. Further, sintered cemented carbide articles described herein can tolerate variations in carbon content without formation of undesirable phases, including eta phase and/or free graphite (C-type porosity). Such tolerance can facilitate manufacturing and use of carbide grades where carbon content is not strictly controlled. A sintered cemented carbide body described herein comprises a hard particle phase including tungsten carbide and a metallic binder phase comprising at least one of cobalt, nickel and iron and one or more alloying additives, wherein the sintered cemented carbide has a magnetic saturation (MS) ranging from 0% to 73% and no eta phase.

Abstract: A tip for a pick tool, comprising a polycrystalline diamond (PCD) structure joined to a substrate body. The PCD structure has a strike surface including an apex opposite a boundary with the substrate body. At least an outer volume of the PCD structure contains filler material between diamond grains, the content of the filler material being more than 5 weight percent of the PCD material in the outer volume. The outer volume is proximate at least an area of the strike surface including the apex, and the thickness of the PCD structure between the apex and the boundary with the substrate body is at least 2.5 mm.

Abstract: One example of the invention relates to an indexable insert comprising a base that has flanks and at least one face. According to one example of the invention, primarily the face(s) of the indexable insert, but not the flanks thereof, are coated with a very thick layer (e.g. thicker than 50 ?m) of a hard material in a PVD process.

Abstract: A thermal spray powder, which includes granulated and sintered cermet particles that contain a metal having an indentation hardness of 500 to 5,000 N/mm2, is disclosed. The granulated and sintered cermet particles have an average size of 30 ?m or less. The granulated and sintered cermet particles are composed of primary particles having an average size of 6 ?m or less. The granulated and sintered cermet particles have a compressive strength of from 100 to 600 MPa. It is preferable that the metal contained in the granulated and sintered cermet particles includes at least one selected from the group consisting of cobalt, nickel, iron, aluminum, copper, and silver. The thermal spray powder is usable in a low-temperature thermal spraying process such as cold spraying using nitrogen as a working gas.

Abstract: A component for turbocharger applications, in particular in diesel engines, made of an iron-based alloy having an austenitic base structure which has a carbide structure.

Abstract: This invention relates to thermal spray coatings, powders useful in deposition of the thermal spray coatings, methods of producing the powders, and uses of the thermal spray coatings, for example, coating of piston rings and cylinder liners of internal combustion engines. The coatings of this invention are applied by thermal spray deposition of a powder. The powder contains bimetallic carbides of chromium and molybdenum dispersed in a matrix metal. The matrix metal contains nickel/chromium/molybdenum.

Abstract: The present invention relates to a coated cutting tool comprising a PVD coating and a cemented carbide substrate comprising Co in an amount of 12.5-17 wt %, Cr in an amount such that the Cr/Co weight ratio is 0.05-0.15, a Ti of between 50 to 300 ppm by weight and a CW_Cr value between 0.8-0.97.

Abstract: The present invention includes consolidated hard materials, methods for producing them, and industrial drilling and cutting applications for them. A consolidated hard material may be produced using hard particles such as B4C or carbides or borides of W, Ti, Mo, Nb, V, Hf, Ta, Zr, and Cr in combination with an iron-based, nickel-based, nickel and iron-based, iron and cobalt-based, aluminum-based, copper-based, magnesium-based, or titanium-based alloy for a binder material. Commercially pure elements such as aluminum, copper, magnesium, titanium, iron, or nickel may also be used for the binder material. The mixture of the hard particles and the binder material may be consolidated at a temperature below the liquidus temperature of the binder material using a technique such as rapid omnidirectional compaction (ROC), the CERACON® process, or hot isostatic pressing (HIP). After sintering, the consolidated hard material may be treated to alter its material properties.

Abstract: A powder material of the present invention contains ceramic-metal composite particles, wherein at least a part of the composite particles exhibit no breaking point in a stress-strain diagram obtained by applying a compressive load that increases up to a maximum value of 10 mN or more at a loading rate of 15.0 mN/s or less.

Abstract: A refractory metal matrix-ceramic compound multi-component composite material with the super-high melting point is disclosed. At least one ceramic compound A and at least one refractory bonding metal B are fused together by the smelting process to make the multi-component composite material. The fused ingredients of the multi-component composite material are mAnB, and (m+n)max=13. The positive integer m is the number of the kinds of the ceramic components A, and the positive integer n is the number of the kinds of the refractory bonding metals B. The absolute value of the combining enthalpy of the ceramic compound A is larger than the absolute value of the combining enthalpy between the ceramic compound A and the refractory bonding metal B. The multi-component composite material has the properties including over 3000° C. melting point, high stability, hardness, ductility, and fusibility in high or low temperature, fast production, and low cost.

Abstract: The present invention relates to a fine grained WC-Co cemented carbide. By adding an extremely small amount of Ti, V, Zr, Ta or Nb alone or in combinations, a grain refined cemented carbide structure with less abnormal WC-grains has been obtained.

Abstract: A preferred embodiment of the process involves a generate a catalyst that comprises molybdenum carbide nickel material. Steps may involve heating a surface that comprises molybdenum oxide and a nickel salt while passing thereover a gaseous mixture that comprises a reductant and a carburizer. In certain embodiments, the reductant and the carburizer may both be carbon monoxide, or both be a saturated hydrocarbon. In others, the reductant may be carbon monoxide and the carburizer may be a saturated hydrocarbon.

Abstract: This invention relates to thermal spray coatings, powders useful in deposition of the thermal spray coatings, methods of producing the powders, and uses of the thermal spray coatings, for example, coating of piston rings and cylinder liners of internal combustion engines. The coatings of this invention are applied by thermal spray deposition of a powder. The powder contains bimetallic carbides of chromium and molybdenum dispersed in a matrix metal. The matrix metal contains nickel/chromium/molybdenum.

Abstract: Carbide pellets including relatively small amounts of metallic binder are produced by steps of pressing, comminuting, shaping and sintering. The carbide pellets may be used as wear resistant hard facing materials that are applied to various types of tools. The carbide pellets provide improved mechanical properties such as hardness and abrasiveness while maintaining required levels of toughness and strength.

Abstract: A process for producing a component includes providing a composition comprising hard material particles and a binder metal, and sintering the composition at a sintering temperature of from 1250° C. to 1400° C. for a period of from 3 to 15 minutes. The hard material particles comprise an inner core comprising fused tungsten carbide and an outer shell comprising tungsten carbide. The binder metal is selected from the group consisting of Co, Ni, Fe and alloys comprising at least one metal selected from Co, Ni and Fe.

Abstract: The hearth roll for a continuous annealing furnace is able to suppress the occurrence of buildup on the hearth roll surface and able to be stably used for a long period under the high temperature environment. The hearth roll has a cermet coating comprised 50 to 90 vol % of ceramic and the balance of a heat resistant alloy on its surface, the ceramic containing Cr3C2: over 50 to 90 vol %, Al2O3: 1 to 40 vol %, Y2O3: 0 to 3 vol %, and ZrB2: 0 to 40 vol % and having a balance of unavoidable impurities and pores, the heat resistant alloy containing Cr: 5 to 20 mass %, Al: 5 to 20 mass %, and one or both of Y and Si: 0.1 to 6 mass % and has a balance of one or both of Co and Ni and unavoidable impurities.

Abstract: An abrasive wear-resistant material includes a matrix and sintered and cast tungsten carbide pellets. A device for use in drilling subterranean formations includes a first structure secured to a second structure with bonding material. An abrasive wear-resistant material covers the bonding material. The first structure may include a drill bit body and the second structure may include a cutting element. A method for applying an abrasive wear-resistant material to a drill bit includes providing a bit, mixing sintered and cast tungsten carbide pellets in a matrix material to provide a pre-application material, heating the pre-application material to melt the matrix material, applying the pre-application material to the bit, and solidifying the material. A method for securing a cutting element to a bit body includes providing an abrasive wear-resistant material to a surface of a drill bit that covers a brazing alloy disposed between the cutting element and the bit body.

Abstract: The present invention relates to the development of an alloy material with significantly improved low-temperature brittleness, recrystallization brittleness, and irradiation brittleness by the introduction of a recrystallization microstructure into an alloy, particularly a tungsten material, to significantly strengthen a weak grain boundary of the recrystallization microstructure. The present invention comprises the steps of: mechanically alloying at least one species selected from a group-IVA, VA, or VIA transition metal carbide and a metallic raw material; sintering base powders obtained through the mechanically alloying step, by using a hot isostatic press; and performing plastic deformation of at least 60% on the alloy obtained through the sintering step, at a strain rate between 10?5 s?1 and 10?2 S?1 and at a temperature between 500° C. and 2,000° C.

Abstract: The present invention relates to a composite material for the production of ecological ammunition characterized in that it comprises a) a metal matrix formed by a zinc and bismuth alloy, zinc and aluminum alloy, tin and bismuth alloy or zinc and tin alloy and a metal selected from aluminum, bismuth and the combination thereof and b) reinforcing metal particles distributed therein selected from wolframium, ferro-wolframium, ferro-wolframium carbides, wolframium carbides, wolframium oxides and ferro-wolframium oxides, subjected to oxidation before being added to the metal matrix.

Abstract: An article includes a working portion including cemented carbide, and a heat sink portion in thermal communication with the working portion. The heat sink portion includes a heat sink material having a thermal conductivity greater than a thermal conductivity of the cemented carbide. Also disclosed are methods of making an article including a working portion comprising cemented carbide, and a heat sink portion in thermal communication with the working portion and including a heat sink material having a thermal conductivity that is greater than a thermal conductivity of the cemented carbide. The heat sink portion conducts heat from the working portion.

Abstract: A coating is described for an airfoil blade component. The coating comprises a cermet material and has, when applied to the rotor blade, a compressive residual stress greater than about 60 ksi. In another embodiment, the compressive residual stress of the coating is in the range of approximately 90-110 ksi.

Abstract: A hardfacing composition essentially consisting of from about 50 to 75 percent by weight of a carbide phase having a particle size distribution of ±20% or less of a median particle size; and from about 25 to 50 percent by weight of binder phase is disclosed. Drill bits having such hardfacing compositions disposed thereon are also disclosed.

Abstract: A powder metal composition for high wear and temperature applications is made by atomizing a melted iron based alloy including 3.0 to 7.0 wt. % carbon; 10.0 to 25.0 wt. % chromium; 1.0 to 5.0 wt. % tungsten; 3.5 to 7.0 wt. % vanadium; 1.0 to 5.0 wt. % molybdenum; not greater than 0.5 wt. % oxygen; and at least 40.0 wt. % iron. The high carbon content reduces the solubility of oxygen in the melt and thus lowers the oxygen content to a level below which would cause the carbide-forming elements to oxidize during atomization. The powder metal composition includes metal carbides in an amount of at least 15 vol. %. The microhardness of the powder metal composition increases with increasing amounts of carbon and is typically about 800 to 1,500 Hv50.

Abstract: A hardfacing composition for downhole well tools, such as earth-boring bits, contains sintered ultrahard particles. The ultrahard particles consist of tungsten carbide grains, cobalt and vanadium. The ultrahard particles are dispersed within a matrix metal of iron, nickel or alloys thereof. The composition may also have sintered tungsten carbide particles of a larger size than the ultrahard particles. The ultrahard particles have a greater hardness than the sintered tungsten carbide particles. The ultrahard particles and the sintered tungsten carbide particles may be in a spherical pellet form. Other hard metal particles may be in the composition.

Abstract: The present invention relates to a rotary cutter knife of a cemented carbide comprising a hard phase comprising WC and a binder phase wherein the cemented carbide comprises, in wt-%, from about 7 to about 12 Co+Ni, with a weight ratio Co/Ni of from about 0 to about 4, from about 0.5 to about 3 Cr and from about 0.1 to about 0.3 Mo.

Abstract: The invention relates to a hard-metal comprising at least 13 volume % of a metal carbide selected from the group consisting of TiC, VC, ZrC, NbC, MoC, HfC, TaCl WC or a combination thereof, a binder phase comprising one or more of iron-group metals or alloy thereof and 0.1 to 10 weight % Si and 0.1 to 10 weight % Cr and having a liquidus temperature at 1280 degrees C. or lower and 3 to 39 volume % of diamond or cBN grains coated with a protective coating or a mixture thereof and a process for making the hard-metal.

Abstract: This invention relates to thermally sprayed coatings having an amorphous-nanocrystalline-microcrystalline composition structure, said thermally sprayed coating comprising from about 1 to about 95 volume percent of an amorphous phase, from about 1 to about 80 volume percent of a nanocrystalline phase, and from about 1 to about 90 volume percent of a microcrystalline phase, and wherein said amorphous phase, nanocrystalline phase and microcrystalline phase comprise about 100 volume percent of said thermally sprayed coating. This invention also relates to methods for producing the coatings, thermal spray processes for producing the coatings, and articles coated with the coatings. The thermally sprayed coatings of this invention provide enhanced wear and corrosion resistance for articles used in severe environments (e.g., landing gears, airframes, ball valves, gate valves (gates and seats), pot rolls, and work rolls for paper processing).

Abstract: An anvil including a hard phase and a metal matrix in which the hard phase is dispersed, a concentration of the metal matrix phase varying according to a concentration gradient, is disclosed. The anvil may be used in a high pressure press. Methods of making an anvil including forming a hard phase dispersed in a metal matrix phase, a concentration of the metal matrix phase varying according to a concentration gradient, are also disclosed.

Abstract: A functionally graded cemented tungsten carbide material produced via heat treating a sintered cemented tungsten carbide is disclosed and described. The heat treating process comprises at least a step that heats the sintered material to the multi-phase temperature range in which multiple phases including solid tungsten carbide, liquid metal binder, and solid metal binder coexist. Additionally, the material, after the heat treating process comprises a surface layer with lower metal binder content than the nominal value of metal binder content of the bulk of the material. The material is used to make tools for rock drilling, machining of metal alloys, and machining of non-metallic materials. The material can also be used to make engineered wear parts that are used in mechanical systems and applications where wear resistance is required or desired.

Abstract: In an embodiment, a polycrystalline diamond compact (“PDC”) comprises a cemented carbide substrate including a first cemented carbide portion and a second cemented carbide portion bonded to the first cemented carbide portion and exhibiting an erosion resistance that is greater than the first cemented carbide portion. The PDC further comprises a polycrystalline diamond (“PCD”) table bonded to the first cemented carbide portion. The PCD table includes a plurality of bonded diamond grains exhibiting diamond-to-diamond bonding therebetween, with the plurality of bonded diamond grains defining a plurality of interstitial regions.

Abstract: An abrasive wear-resistant material includes a matrix and sintered and cast tungsten carbide granules. A device for use in drilling subterranean formations includes a first structure secured to a second structure with a bonding material. An abrasive wear-resistant material covers the bonding material. The first structure may include a drill bit body and the second structure may include a cutting element. A method for applying an abrasive wear-resistant material to a drill bit includes providing a bit, mixing sintered and cast tungsten carbide granules in a matrix material to provide a pre-application material, heating the pre-application material to melt the matrix material, applying the pre-application material to the bit, and solidifying the material. A method for securing a cutting element to a bit body includes providing an abrasive wear-resistant material to a surface of a drill bit that covers a brazing alloy disposed between the cutting element and the bit body.

Abstract: A cermet has a first hard phase of a complex carbonitride solid solution, a second hard phase of WC, and a binder phase mainly comprising Co and Ni as main component(s). The first hard phase has a core/rim structure. The core is represented by (Ti1-x-yLxMoy)(C1-zNz) and the rim is represented by (Ti1-a-b-dRaMobWd)(C1-eNe), wherein L and R each represent at least one element selected from the group consisting of Zr, Hf, Nb and Ta. If a maximum thickness of the rim of the core/rim structure grains of the first hard phase is given by rmax, and a minimum thickness of the rim of the core/rim structure grains of the first hard phase is given by rmin, a number of the core/rim structure grains of the first hard phase satisfying 0.2<(rmin/rmax)<1 is 85% or more, based on the total number of the core/rim structure grains of the first hard phase.

Abstract: Methods, systems, and compositions for manufacturing downhole tools and downhole tool parts for drilling subterranean material are disclosed. A model having an external peripheral shape of a downhole tool or tool part is fabricated. Mold material is applied to the external periphery of the model. The mold material is permitted to harden to form a mold about the model. The model is eliminated and a composite matrix material is cast within the mold to form a finished downhole tool or tool part.

Abstract: An earth-boring drill bit having a bit body with a cutting component formed from a tungsten carbide composite material is disclosed. The composite material includes a binder and tungsten carbide crystals comprising sintered pellets. The composite material may be used as a hardfacing on the body and/or cutting elements, or be used to form portions or all of the body and cutting elements. The pellets may be formed with a single mode or multi-modal size distribution of the crystals.

Abstract: The present invention relates to a method of producing a cemented carbide body comprising providing: (1) a grain refiner compound comprising a grain refiner and carbon and/or nitrogen, and, (2) a grain growth promoter, on at least one portion of the surface of a compact of a WC-based starting material comprising one or more hard-phase components and a binder, and then sintering the compact. The invention also relates to a cemented carbide body comprising a WC-based hard phase and a binder phase, wherein at least one part of an intermediate surface zone has a lower average binder content than a part further into the body, and at least one part of an upper surface zone has in average a larger average WC grain size than the intermediate surface zone. The cemented carbide body can be used as a cutting tool insert for metal machining, an insert for a mining tool, or a coldforming tool.

Abstract: An annealed prealloyed water atomised iron-based powder is provided which is suitable for the production of pressed and sintered components having high wear resistance. The iron-based powder comprises 15-30% by weight of Cr, 0.5-5% by weight of each of at least one of Mo, W and V, and 0.5-2%, preferably 0.7-2% and most preferably 1-2% by weight of C. The powder has a matrix comprising less than 10% by weight of Cr, and comprises large chromium carbides. A method for production of the iron-based powder also is provided.

Abstract: A tungsten carbide material for use in precision glass molding applications having 6.06-6.13 wt. % carbon, 0.20-0.55 wt. % grain growth inhibitor, less than 0.25 wt. % binder, less than 0.6% wt. % impurities, and balance being tungsten. The tungsten carbide material has a nominal grain size of less than 0.5 microns.

Abstract: A powder mixture composition for forming a jewelry article is described, comprising about 20-44% by weight tungsten carbide, and one or more of titanium carbide, chromium, nickel, and molybdenum. Methods of forming a jewelry article also are described, as are formed jewelry articles.

Abstract: The present invention relates to a lightweight, anti-scratch and fracture resistant material for use in manufacture of jewelry prepared by sintering a powered mixture consisting essentially of 20% by weight of titanium carbide, 25% by weight of tungsten carbide, 35% by weight of titanium nitride, and balance being a binder consisting essentially of nickel, molybdenum and cobalt.