Step At 300 Degrees C Or Greater After Step At Less Than 300 Degrees C Using Nonmetallic Material Which Is Liquid Under Standard Conditions Patents (Class 75/365)
  • Patent number: 11134687
    Abstract: The present invention concerns a new biomaterial used to manufacture antimicrobial dental devices, intended to control the growth of microorganisms in the oral cavity. These include removable dentures (RD) with copper nanoparticles technology and antimicrobial properties against dental pathogens, such as: Candida albicans, a pathogen responsible for denture stomatitis; Pathogenic Streptococcus mutans, responsible for the initiation and progression of caries formation; and Staphylococcus aureus, which causes periprosthetic infections. This removable dental material allows for the production of a new dental device to prevent and/or control oral infections caused by said pathogens, such as denture stomatitis, secondary caries, periodontal diseases, among others.
    Type: Grant
    Filed: December 29, 2016
    Date of Patent: October 5, 2021
    Assignee: UNIVERSIDAD DE CHILE
    Inventors: Cristián Mauricio Covarrubias Gallardo, Sebastián Adolfo Correa Hernandez, Loreto Francisca Matamala Lopez, Juan Pablo Gonzalez Rojas
  • Patent number: 11090722
    Abstract: Provided is a method for making nickel nanopowders into paste including: (a) preparing a nickel oxide configured in the form of an oxide; (b) preparing nano-sized nickel oxide nanopowders by pulverizing the nickel oxide; (c) a step of drying the nickel oxide nanopowders; (d) a step of preparing natural metal nickel nanopowders by preparing the nickel oxide nanopowders as the natural metal nickel nanopowders through a reduction process in a hydrogen atmosphere and heat-treating the same at the same time; (e) a step of simultaneously performing a step of crushing the natural metal nickel nanopowders prepared by the heat treatment and a nanopowder oxidation preventing coating step of forming an oxidation preventing film on the natural metal nickel nanopowders with an additive; and (f) a step of making the natural metal nickel nanopowders, which have been simultaneously subjected to the crushing and coating steps, into paste.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: August 17, 2021
    Assignee: SOLUETA CO., LTD.
    Inventors: Eui-Hong Min, Sang-Ho Cho, Buck-Keun Choi
  • Patent number: 10934605
    Abstract: Methods are provided for synthesizing high purity niobium or rhenium powders by a combustion reaction. The methods can include: forming a combustion synthesis solution by dissolving in water an oxidizer, a fuel, and at least one base-soluble, ammonium salt of niobium or rhenium in amounts that yield a stoichiometric burn when combusted; and heating the combustion synthesis solution to a temperature sufficient to substantially remove the water and to initiate a self-sustaining combustion reaction.
    Type: Grant
    Filed: October 17, 2017
    Date of Patent: March 2, 2021
    Assignee: Battelle Memorial Institute
    Inventors: John G. Frye, Kenneth Scott Weil, Curt A. Lavender, Jin Yong Kim
  • Patent number: 10744489
    Abstract: The invention relates to a method for preparing a solid comprising a step of mixing a set of compounds comprising at least two Cu2(OH)2CO3 powders of different particle sizes and at least one binder and the use of the solid prepared by means of this method.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: August 18, 2020
    Assignees: AXENS, IFP Energies nouvelles
    Inventors: Delphine Bazer-Bachi, David Chiche, Joseph Lopez, Thomas Serres, Tom Frising, Olivier Ducreux, Patrick Euzen
  • Patent number: 9053860
    Abstract: A tungsten powder having tungsten silicide such as W5Si3 on the surface of the particles and having a silicon content of 0.05 to 7 mass %; an anode body for capacitors; an electrolytic capacitor; a method for producing the tungsten powder; and a method for producing the anode body for capacitors. The tungsten powder has an average primary particle diameter of 0.1 to 1 ?m, wherein tungsten silicide is localized within 50 nm from the particle surface. Further, the tungsten powder contains at least one member selected from tungsten nitride, tungsten carbide and tungsten boride on a part of the particle surface.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: June 9, 2015
    Assignee: SHOWA DENKO K.K.
    Inventor: Kazumi Naito
  • Publication number: 20130315773
    Abstract: The invention relates to energy-saving manufacturing of purified hydrogenated titanium powders or alloying titanium hydride powders, by metallo-thermic reduction of titanium chlorides, including their hydrogenation, vacuum separation of titanium hydride sponge block from magnesium and magnesium chlorides, followed by crushing, grinding, and sintering of said block without need for hydrometallurgical treatment of the produced powders. Methods disclosed contain embodiments of processes for manufacturing high-purity powders and their use in manufacturing near-net shape titanium and titanium-alloy articles by sintering titanium hydride and alloyed titanium hydride powders produced from combined hydrogen-magnesium reduction of titanium chlorides, halides and hydrides of other metals.
    Type: Application
    Filed: May 24, 2012
    Publication date: November 28, 2013
    Applicant: Advance Materials Products, Inc. (ADMA Products, Inc.)
    Inventors: Vladimir S. Moxson, Volodymyr A. Duz, Andrey G. Klevtsov, Viktor D. Sukhoplyuyev, Mihajlo D. Sopka, Yury V. Shuvalov, Mykhailo Matviychuk
  • Publication number: 20130301769
    Abstract: A process for producing technetium-99m from a molybdenum-100 metal powder, comprising the steps of: (i) irradiating in a substantially oxygen-free environment, a hardened sintered target plate coated with a Mo-100 metal, with protons produced by a cyclotron; (ii) dissolving molybdenum ions and technetium ions from the irradiated target plate with an H2O2 solution to form an oxide solution; (iv) raising the pH of the oxide solution to about 14; (v) flowing the pH-adjusted oxide solution through a resin column to immobilize K[TcO4] ions thereon and to elute K2[MoO4] ions therefrom; (vi) eluting the bound K[TcO4] ions from the resin column; (vii) flowing the eluted K[TcO4] ions through an alumina column to immobilize K[TcO4] ions thereon; (viii) washing the immobilized K[TcO4] ions with water; (ix) eluting the immobilized K[TcO4] ions with a saline solution; and (x) recovering the eluted Na[TcO4] ions.
    Type: Application
    Filed: April 25, 2013
    Publication date: November 14, 2013
    Applicant: TRIUMF
    Inventor: TRIUMF
  • Publication number: 20130129563
    Abstract: Low temperature gas-phase methods for the preparation of faceted aluminum crystals are disclosed.
    Type: Application
    Filed: September 14, 2012
    Publication date: May 23, 2013
    Inventors: Daniel KAPLOWITZ, R. Jason JOUET, Michael R. ZACHARIAH
  • Patent number: 8444744
    Abstract: A method for extracting nickel and lithium includes solvent extraction step of using three or more extraction stages to subject a solution containing lithium and nickel to solvent extraction with 2-Ethylhexyl phosphonic acid mono-2-ethylhexyl ester at a pH of 8.0 to 8.5, whereby the nickel and the lithium are co-extracted into a resultant organic phase.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: May 21, 2013
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Makoto Narisako, Toshiyuki Yamaoka, Daisuke Kobayashi, Naoki Higuchi
  • Publication number: 20130059161
    Abstract: Fine, highly-crystallized metal powder is produced at low cost and high efficiency by a method involving: ejecting raw material powder composed of one or more kinds of thermally decomposable metal compound powders into a reaction vessel through a nozzle together with a carrier gas and producing a metal powder by heating the raw material powder at a temperature T2 which is higher than the decomposition temperature of the raw material powder and not lower than (Tm?200)° C. where Tm is the melting point (° C.) of the metal to be produced, while allowing the raw material powder to pass through the reaction vessel in a state where the raw material powder is dispersed in a gas phase at a concentration of 10 g/liter or less, wherein an ambient temperature T1 of a nozzle opening part is set to a temperature of 400° C. or higher and lower than (Tm?200)° C.
    Type: Application
    Filed: August 31, 2012
    Publication date: March 7, 2013
    Inventors: Yuji AKIMOTO, Kazuro Nagashima, Hidenori Ieda, Masayuki Maekawa
  • Patent number: 8343254
    Abstract: Composite Ni particles each having a silica coat is improved in oxidation resistance and heat shrink characteristics. A method of preparing composite Ni particles by using an organic Ni composite includes steps of: stirring and heating a nickel salt solution and a raw material of silica coat at a temperature ranging 25° C. to 80° C. for 0.5 hours to 2 hours; filtering, cleaning and drying a resultant product into an organic nickel composite; and thermally treating the organic nickel composite at a temperature ranging from 200° C. to 500° C. for 0.5 hours to 4 hours. The resultant composite Ni particles have excellent oxidation resistance and heat shrink characteristics.
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: January 1, 2013
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Young Il Lee, Jae Woo Jung, In Keun Shim
  • Publication number: 20120024110
    Abstract: A powder processing method includes degassing a metallic powder in a rotating chamber that is evacuated to a sub-atmospheric pressure. The method may also include storing the metallic powder in a rotating storage chamber that is pressurized to a super-atmospheric pressure with a dry cover gas.
    Type: Application
    Filed: July 30, 2010
    Publication date: February 2, 2012
    Inventor: Thomas J. Watson
  • Patent number: 7935169
    Abstract: The present invention relates to an apparatus and a method of manufacturing metal nanoparticles, and more particularly to an apparatus including: a precursor supplying part which supplies a precursor solution of metal nanoparticles; a first heating part which is connected with the precursor supplying part, includes a reactor channel having a diameter of 1 to 50 mm, and is heated to the temperature range where any particle is not produced; a second heating part which is connected with the first heating part, includes a reactor channel having a diameter of 1 to 50 mm, and is heated to the temperature range where particles are produced; and a cooler which is connected with the second heating part and collects and cools metal nanoparticles produced at the second heating part which allows continuous mass production of metal nanoparticles.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: May 3, 2011
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Young-Il Lee, Jae-Woo Joung, Byung-Ho Jun, Joon-Rak Choi, Kwi-Jong Lee
  • Patent number: 7753989
    Abstract: A method of producing passivated Ti or Ti alloy particles with oxygen concentrations of less than about 900 parts per million (ppm), which includes introducing a halide vapor of Ti or the metal constituents of the alloy at sonic velocity or greater into a stream of liquid alkali or liquid alkaline earth metal or mixtures thereof forming a reaction zone in which the halide is reduced by the liquid metal present in sufficient excess of stoichiometric such that Ti or Ti alloy powder from the reduction of the halide by the liquid metal is friable. After filtration and distillation excess liquid metal is removed from the Ti or Ti alloy powder that is then maintained at elevated temperature for a time sufficient to grow the particles to average diameters calculated from BET surface area measurement greater than about one micron. After cooling the Ti or Ti alloy powder to temperature of about 80° C.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: July 13, 2010
    Assignee: Cristal US, Inc.
    Inventors: William Ernst, Lance Jacobsen
  • Patent number: 7708800
    Abstract: There is disclosed a method for producing a supported metal nanoparticle, which has the steps of adsorbing a metal ion-containing compound to a support of an organic material and reducing the adsorbed metal ion to form a metal nanoparticle on the support. In the producing method, by using a various organic material as a matrix, the metal nanoparticle can be easily formed in situ with excellent accuracy from the metal ion-containing compound.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: May 4, 2010
    Assignee: Riken
    Inventors: Junhui He, Toyoki Kunitake
  • Patent number: 7670988
    Abstract: An aerosol-assisted method for synthesis of nanostructured metallic electrocatalysts and the electrocatalysts formed thereby. The electrocatalyst may be formed from metals such as, but not limited to, platinum, platinum group metals, and binary and tertiary compositions thereof such as, for example, platinum-ruthenium and platinum-tin. The resulting unsupported electrocatalyst is homogenous and highly disperse.
    Type: Grant
    Filed: October 17, 2007
    Date of Patent: March 2, 2010
    Assignee: STC, UNM
    Inventors: Elise Switzer, Plamen Atanassov, Abhaya Datye
  • Patent number: 7648689
    Abstract: The invention is to provide a process for industrially advantageously producing InP fine particles having a nano-meter size efficiently in a short period of time and an InP fine particle dispersion, and there are provided a process for the production of InP fine particles by reacting an In raw material containing two or more In compounds with a P raw material containing at least one P compound in a solvent wherein the process uses, as said two or more In compounds, at least one first In compound having a group that reacts with a functional group of P compound having a P atom adjacent to an In atom to be eliminated with the functional group in the formation of an In-P bond and at least one second In compound having a lower electron density of In atom in the compound than said first In compound and Lewis base solvent as said solvent, and InP fine particles obtained by the process.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: January 19, 2010
    Assignee: Hoya Corporation
    Inventor: Shuzo Tokumitsu
  • Patent number: 7601199
    Abstract: Glycerol is used as a solvent medium for the precipitation of a complex of nickel and glycerol material. The precipitate is separated from the liquid solvent and dried and calcined in air to produce small (nanometer size) particles characterized by a nickel core encased in a nickel oxide shell. The proportions of nickel core and nickel oxide shell can be controlled by management of the time and temperature of heating in air. Prolonged heating in air can produce nickel oxide particles, or calcining of the precipitate in nitrogen produces nickel particles.
    Type: Grant
    Filed: January 19, 2006
    Date of Patent: October 13, 2009
    Assignees: GM Global Technology Operations, Inc., Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    Inventors: Wenjie Shen, Yong Li, Mei Cai, Jerry D. Rogers
  • Patent number: 7547347
    Abstract: A method of synthesizing nanoparticles includes: combining at least one stabilizing agent, at least one precursor and an ionic liquid to form a reaction mixture; heating the reaction mixture to a predetermined temperature to form the nanoparticles and cause the nanoparticles to self-separate from the reaction mixture; and collecting the nanoparticles from the reaction mixture. Ionic liquid from which the nanoparticles are separated may be reused.
    Type: Grant
    Filed: May 15, 2006
    Date of Patent: June 16, 2009
    Assignee: University of Rochester
    Inventors: Hong Yang, Yong Wang
  • Publication number: 20090095131
    Abstract: Method for producing molybdenum metal powder. The invention includes introducing a supply of ammonium molybdate precursor material into a furnace in a first direction and introducing a reducing gas into a cooling zone in a second direction opposite to the first direction. The ammonium molybdate precursor material is heated at an initial temperature in the presence of the reducing gas to produce an intermediate product that is heated at a final temperature in the presence of the reducing gas, thereby creating the molybdenum metal powder comprising particles having a surface area to mass ratio of between about 1 m2/g and about 4 m2/g, as determined by BET analysis, and a flowability of between about 29 s/50 g and 86 s/50 g as determined by a Hall Flowmeter. The molybdenum metal powder is moved through the cooling zone.
    Type: Application
    Filed: December 18, 2008
    Publication date: April 16, 2009
    Applicant: Climax Engineering Materials, LLC
    Inventors: Loyal M. Johnson, JR., Sunil Chandra Jha, Patrick Ansel Thompson
  • Patent number: 7470307
    Abstract: A method for producing a metal powder product involves: Providing a supply of a precursor metal powder; combining the precursor metal powder with a liquid to form a slurry; feeding the slurry into a pulsating stream of hot gas; and recovering the metal powder product.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: December 30, 2008
    Assignee: Climax Engineered Materials, LLC
    Inventor: Steven C. Larink, Jr.
  • Patent number: 7407527
    Abstract: A synthetic method of fabricating highly crystalline and monodisperse nanoparticles of metals, multi-metallic alloys, monometallic oxides and multi-metallic oxides without a size selection process are disclosed. A typical synthetic method comprises the steps of, synthesis of a metal surfactant complex from the reaction of a metal precursor and a surfactant, high temperature thermal decomposition of the metal surfactant complex to produce monodisperse metal nanoparticles, and completing the formation of synthesized metal, metal alloy or metal oxide nanoparticles by adding a poor solvent followed by centrifuging. For obtaining highly crystalline monodisperse nanoparticles, additional steps are necessary as described in the invention. The resulting nanoparticles have excellent magnetic property for many applications.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: August 5, 2008
    Assignee: Seoul National University Industry Foundation
    Inventor: Taeghwan Hyeon
  • Patent number: 7341658
    Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: March 11, 2008
    Assignee: Tatanium Corporation Inc.
    Inventor: Robert G. Reeves
  • Patent number: 7279024
    Abstract: High purity cobalt with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity cobalt targets are provided. The cobalt containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of cobalt chloride is adjusted to 0.1 kmol/m3 to 3 kmol/m3. Then, cobalt is added in the aqueous solution of cobalt chloride, and an inert gas is injected into the solution with agitating, in order to convert the divalent copper ions contained in the aqueous solution of cobalt chloride to monovalent copper ions. Then, the aqueous solution of cobalt chloride is fed into a column filled up with the anion exchange resins. Cobalt is not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of cobalt chloride.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: October 9, 2007
    Assignees: Sony Corporation
    Inventors: Masahito Uchikoshi, Norio Yokoyama, Tamas Kekesi, Minoru Isshiki
  • Patent number: 7238221
    Abstract: Provided are a method for preparing metallic nickel powders capable of decreasing the content of an alkaline metal in the metallic nickel powders, metallic nickel powders with the low content of an alkaline metal, a conductive paste including metallic nickel powders with the low content of an alkaline metal, and a multi-layer ceramic capacitor (MLCC) including a nickel inner electrode with the low content of an alkaline metal. The method for preparing the metallic nickel powders includes heating a mixture including an organic base, a nickel precursor compound, and a polyol. Wherein, the nickel precursor compound is converted to the metallic nickel powders through reduction by the organic base and the polyol. In the method, the organic base is used instead of the hydroxide of an alkaline metal such as NaOH and KOH. Therefore, the content of an alkaline metal such as sodium and potassium that can be incorporated as an impurity into the metallic nickel powders can be significantly reduced.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: July 3, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Soon-ho Kim, Jae-young Choi, Do-kyung Kim, Je-hyeong Park
  • Patent number: 7217311
    Abstract: The present invention relates to a metal nanocomposite powder reinforced with carbon nanotubes and to a process of producing a metal nanocomposite powder homogeneously reinforced with carbon nanotubes in a metal matrix powder.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: May 15, 2007
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Soon Hyung Hong, Seung Il Cha, Kyung Tae Kim, Seong Hyun Hong
  • Patent number: 7060121
    Abstract: A method for producing gold nanoparticles is disclosed. When gold salt solution is mixed with an adsorbent, gold in the form of complexes is adsorbed onto the surface of the adsorbent. The gold-loaded adsorbent, after being separated from the solution by screening, filtration, settling or other methods, is ashed to form ashes. The ashes contain gold nanoparticles and impurities such as oxides of sodium, potassium and calcium. The impurities can be removed by dissolution using dilute acids. The relatively pure gold nanoparticles are obtained after the impurities are removed. Activated carbon or gold-adsorbing resin can be used as the adsorbent. Silver or platinum group metal nanoparticles can also be produced by this method.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: June 13, 2006
    Inventors: Hsing Kuang Lin, Daniel Edward Walsh
  • Patent number: 7004993
    Abstract: A method of making intermetallic nanoscale particles comprising iron aluminide and/or iron aluminum carbide comprising the steps of preparing a mixture of a solvent, an iron salt and LiAlH4, and heating the mixture to form the intermetallic nanoscale particles. The intermetallic nanoscale particles, which can comprise intermetallic nanoscale particles of iron aluminide and/or iron aluminum carbide in an alumina matrix, are capable of reducing the amount of 1,3-butadiene in the mainstream smoke of a cigarette.
    Type: Grant
    Filed: June 13, 2003
    Date of Patent: February 28, 2006
    Assignee: Philip Morris USA Inc.
    Inventors: Yezdi B. Pithawalla, Sarojini Deevi
  • Patent number: 7004994
    Abstract: Provided are silver-containing powders and a method and apparatus for manufacturing the silver-containing particles of high quality, of a small size and narrow size distribution. An aerosol is generated from liquid feed and sent to a furnace, where liquid in droplets in the aerosol is vaporized to permit formation of the desired particles, which are then collected in a particle collector. The aerosol generation involves preparation of a high quality aerosol, with a narrow droplet size distribution, with close control over droplet size and with a high droplet loading suitable for commercial applications.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: February 28, 2006
    Assignee: Cabot Corporation
    Inventors: Mark J. Hampden-Smith, Toivo T. Kodas, Quint H. Powell, Daniel J. Skamser, James Caruso, Clive D. Chandler
  • Patent number: 6932851
    Abstract: A method of producing metal alloy nanoparticles comprising forming a cyanosol by reacting a mixture of a chlorometallate complex and a cyanometallate complex, spin-coating the mixture onto a substrate to form a film, and sintering the film to form metal alloy nanoparticles.
    Type: Grant
    Filed: November 4, 2002
    Date of Patent: August 23, 2005
    Assignee: The Trustees of Princeton University
    Inventors: Andrew B. Bocarsly, Shu Zhu
  • Patent number: 6902601
    Abstract: A method of producing an elemental material or an alloy thereof from a halide or mixtures of halides is provided. The halide or mixtures thereof are contacted with a reducing gas in the presence of reductant material, preferably in sufficient quantity to convert the halide to the elemental material or alloy and to maintain the temperature of the reactants at a temperature lower than the boiling point of the reductant material at atmospheric pressure or the sintering temperature of the produced elemental material or alloy.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: June 7, 2005
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Jason X. Nie, Robert Daniels, Dale H. Perkins-Banks, Thomas Messer
  • Patent number: 6887296
    Abstract: A process is described for the preparation of powder mixtures or composite powders from at least one first type of powder from the group consisting of high-melting metals, hard materials and ceramic powders and at least one second type of powder from the group consisting of binder metals, binder-metal mixed crystals and binder-metal alloys, where the second type of powder is formed from precursor compounds in the form of water-soluble salts in an aqueous suspension of the first type of powder by precipitation as oxalate, removal of the mother liquor and reduction to the metal.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: May 3, 2005
    Assignee: H.C. Starck GmbH
    Inventors: Bernd Mende, Gerhard Gille, Ines Lamprecht
  • Publication number: 20040250654
    Abstract: A method of making intermetallic nanoscale particles comprising iron aluminide and/or iron aluminum carbide comprising the steps of preparing a mixture of a solvent, an iron salt and LiAlH4, and heating the mixture to form the intermetallic nanoscale particles. The intermetallic nanoscale particles, which can comprise intermetallic nanoscale particles of iron aluminide and/or iron aluminum carbide in an alumina matrix, are capable of reducing the amount of 1,3-butadiene in the mainstream smoke of a cigarette.
    Type: Application
    Filed: June 13, 2003
    Publication date: December 16, 2004
    Inventors: Yezdi B. Pithawalla, Sarojini Deevi
  • Patent number: 6830635
    Abstract: The present invention relates to spindle-shaped goethite particles having an average major axial diameter of 0.05 to 0.18 &mgr;m, spindle-shaped hematite particles having an average major axial diameter of 0.05 to 0.17 &mgr;m, spindle-shaped magnetic metal particles containing iron as a main component, which exhibit an adequate coercive force, good dispersibility, good oxidation stability and excellent coercive force distribution notwithstanding the average major axial diameter thereof is as small as 0.05 to 0.15 &mgr;m, and processes for producing the respective particles. Especially, the spindle-shaped magnetic metal particles containing iron as a main component, have an average major axial diameter of 0.05 to 0.15 &mgr;m, an aspect ratio of from 5:1 to 9:1, a size distribution (standard deviation/average major axial diameter) of not more than 0.30, a crystallite size D110 of 130 to 160 Å, a Co content of from 0.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: December 14, 2004
    Assignee: Toda Kogyo Corporation
    Inventors: Kenji Okinaka, Masayuki Uegami
  • Patent number: 6786951
    Abstract: A process of the production of high surface area tantalum and/or niobium powders via the reduction of the corresponding tantalum and/or niobium oxides is disclosed, wherein the reduction is carried out by reacting the tantalum and/or niobium oxides with at least one metal halide selected form the group consisting of halides of Mg, Ca, Sr, Ba and Ce, and an alkali metal at elevation temperature so as to form the tantalum and/or niobium powders. The process of the present invention has the advantages of: simple operation, the tantalum and/or niobium powders obtained have high surface area, high purity, good flowability, therefore are particularly suitable for manufacturing electrolytic capacitors.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: September 7, 2004
    Assignee: Ningxia Orient Tantalum Industry Co., Ltd.
    Inventors: Jilin He, Luntao Pan, Ningfeng Yuan, Xiaoli Wen, Xingbang Li
  • Patent number: 6783608
    Abstract: Secondary agglomerates of magnetic metal particles for magnetic recording, have a sodium content of not more than 20 ppm and a calcium content of not more than 40 ppm, an average particle diameter of 300 to 800 &mgr;m and an upper limit of particle diameters of 2,000 &mgr;m, and comprise magnetic metal primary particles having an average major axis diameter of 0.05 to 0.25 &mgr;m.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: August 31, 2004
    Assignee: Toda Kogyo Corporation
    Inventors: Kenji Okinaka, Kohji Mori, Masayuki Uegami
  • Patent number: 6780255
    Abstract: A magnetic powder of an Sm—Fe—N alloy, which has a mean particle diameter of 0.5 to 10 &mgr;m, and either an average acicularity of 75% or above or an average sphericity of 78% or above. The powder exhibits an extremely high residual magnetization and an extremely high coercive force, since particles characterized by the above acicularity or sphericity have particle diameters approximately equal to that of the single domain particle and nearly spherical particle shapes. The powder can be produced by preparing an Sm—Fe oxide by firing a coprecipitate corresponding to the oxide, mixing the obtained oxide with metallic calcium and subjecting the mixture to reduction/diffusion and nitriding successively.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: August 24, 2004
    Assignee: Nichia Chemical Industries, Ltd.
    Inventors: Yohsiyuki Kawano, Michiya Kume, Keiji Ichinomiya
  • Publication number: 20040074336
    Abstract: A novel method for preparing fine particles comprising a transition metal and a noble metal which are monodispersed and have almost no particle diameter distribution, and are transferable to a CuAu-I type L10 ordered phase, with safety and at a low cost, wherein a salt or a complex of at least one transition metal selected from Fe and Co and a salt or a complex of at least one transition metal selected from Pt and Pd (exclusive of the combination of Co-Pd) is dissolved in an organic solvent miscible with water or an alcohol in the presence of an organic protecting agent, and the resultant solution is heated under reflux in the presence of an alcohol in an inert atmosphere, to thereby prepare a binary alloy comprising a transition metal and a noble metal, or a salt or a complex of at least one element selected from the group consisting of Cu, Bi, Sb, Sn, Pb and Ag is further dissolved in the above solvent and the resultant solution is heated under reflux in the presence of an alcohol in an inert atmosphere, to
    Type: Application
    Filed: December 3, 2003
    Publication date: April 22, 2004
    Inventors: Hideo Daimon, Yukiko Kurobe, Naoki Toshima
  • Patent number: 6679938
    Abstract: A spray pyrolysis method for producing pure metal and/or metal oxide particles uses a mixture of a carrier gas and a solution of a metal salt precursor, water and a co-solvent reducing agent. The metal salt precursors preferably comprise metals from the group consisting of Fe, Co, Ni, Cu, Zn, Pd, Ag and Au, whereas the salt anions preferably comprise nitrates, acetates, oxalates and chlorides. The co-solvents are those that act as a reducing agent, are vaporizable, are inert with respect to the carrier gas, and are hydrophilic, such as alcohols, in particular, low-carbon numbered alcohols such as methanol or ethanol.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: January 20, 2004
    Assignees: University of Maryland, The United States of America as represented by the Secretary of Commerce
    Inventors: Jung Hyeun Kim, Sheryl H. Ehrman, Thomas A. Germer, George W. Mulholland, Eric B. Steel
  • Patent number: 6679937
    Abstract: Copper metal powders, methods for producing copper metal powders and products incorporating the powders. The copper metal powders have a small particle size, narrow size distribution and a spherical morphology. The method includes forming the metal particles in a continuous manner.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: January 20, 2004
    Assignee: Cabot Corporation
    Inventors: Toivo T. Kodas, Mark J. Hampden-Smith, James Caruso, Daniel J. Skamser, Quint H. Powell, Clive D. Chandler
  • Patent number: 6592645
    Abstract: A process for the production of fine powder of metallic nickel which comprises a first step of dissolving nickel carbonate and/or nickel hydroxide in aqueous ammonia or in an aqueous solution of ammonia and at least one selected from the group consisting of ammonium carbonate, ammonium hydrogencarbonate, a carbonate of an alkali metal and a hydrogencarbonate of an alkali metal to prepare an aqueous solution of a nickel salt; converting the aqueous solution of a nickel salt to a W/O emulsion, and then removing volatile components including ammonia from the droplets to form precipitates of nickel carbonate in the droplets, thereby providing fine spherical particles of nickel carbonate; and a second step of heating the particles of nickel carbonate in the presence of a fusion preventive agent that is a compound of at least one element selected from the group consisting of alkaline earth elements, aluminum, silicon and rare earth elements in an atmosphere of hydrogen, thereby reducing the nickel carbonate to meta
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: July 15, 2003
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Hideto Mizutani, Minoru Yoneda, Toshihiro Sugaya, Hiroyoshi Urasumi, Chiyo Honda, Hiroshi Nakao, Tsutomu Hatanaka, Shinji Ohgama, Kiyoshi Fukai, Kazuhiko Nagano, Shigefumi Kamisaka, Kazunobu Abe
  • Patent number: 6554885
    Abstract: A process is described for the production of metal powder and alloy powders containing at least one of the metals iron, copper, tin, cobalt or nickel, by mixing aqueous metal salt solutions with an aqueous carboxylic acid solution, separating the precipitation product from the mother liquor and reducing the precipitation product to the metal.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: April 29, 2003
    Assignee: H. C. Starck GmbH
    Inventors: Bernd Mende, Gerhard Gille, Benno Gries, Peter Aulich, Jörg Münchow
  • Patent number: 6521016
    Abstract: The present invention relates to a method of producing nanophase Cu—Al2O3 composite powder by means of 1) the producing precursor powders by centrifugal spray drying process using the water base solution, in which Cu-nitrate (Cu(NO3)23H2O) and Al-Nitrate (Al(NO3)39H2O) are solved to the point of final target composition (Cu-1 wt %/Al2O3),2) the heat treatment process (desaltation process) at the 850° C. for 30 min in air atmosphere to remove the volatile components such as the moisture and NO3 group in precursor powder and simultaneously to synthesize the nano CuO—Al2O3 composite powders by the oxidation of corresponded metal components and 3) the reduction heat treatment of CuO at 200° C. for 30 min in reducing atmosphere to produce the final nanophase Cu—Al2O3 composite powders with the size below 20 nm.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: February 18, 2003
    Assignee: Korea Institute of Machinery and Materials
    Inventors: Byoung Kee Kim, Dong Won Lee
  • Patent number: 6402807
    Abstract: A smelting process wherein very pure iron or various iron family metals are economically obtained from ores which contain iron family metals by hydrometallurgy. The process involves: (a) grinding an ore containing iron family metals to pulverize the ore into fines of 25 mesh undersize; (b) immersing the pulverized ore into at least one inorganic acid having a concentration of 1N to 8N to elute the iron family metals into the inorganic acid to carry out a leaching; (c) filtering the resultant mixture of residue and inorganic acid containing eluted iron family metals to obtain a filtrate and a gangue; (d) adding an alkali to the filtrate obtained in step (c), whereby a hydroxide of the iron family metal is precipitated; (e) filtering the resultant suspension which contains the hydroxide to collect the hydroxide of iron family metals; and (f) heating the collected hydroxide or a dried hydroxide thereof in a reducing atmosphere at a temperature of 400 to 500° C.
    Type: Grant
    Filed: September 20, 2000
    Date of Patent: June 11, 2002
    Inventor: Takeo Misao
  • Patent number: 6352571
    Abstract: One or more metal salts of at least one iron group metal containing organic groups are dissolved in at least one polar solvent and complex bound with at least one complex former comprising functional groups in the form of OH or NR3, (R═H or alkyl). In addition, at least one insoluble, reducible salt of at least one iron group metal is suspended in the solution. Hard constituent powder and, optionally, a soluble carbon source are added to the solution. The solvent is evaporated and the powder mass is heat treated in inert and/or reducing atmosphere. As a result, a powder mixture is obtained which, after addition of a pressing agent, can be compacted and sintered according to standard practice to form a body containing hard constituents in a binder phase.
    Type: Grant
    Filed: December 4, 1998
    Date of Patent: March 5, 2002
    Assignee: Sandvik AB
    Inventors: Mats Waldenström, Rolf Svensson
  • Patent number: 6346137
    Abstract: Ultrafine cobalt metal powder consisting of fine crystallites, wherein the crystallites, wherein the crystallitex exhibit a rice-grain shaped to spherical habit and more than 90% of the crystallites have a diameter in the range of from 0.5 to 2 &mgr;m, a process for the production of the cobalt metal powder via an intermediate stage of cobalt carbonate production, and processes and products re certain uses of the cobalt metal powder and the cobalt carbonate and an intermediate oxide so produced.
    Type: Grant
    Filed: August 28, 1998
    Date of Patent: February 12, 2002
    Assignee: H. C. Starck GmbH & Co. KG
    Inventors: Matthias Höhne, Bernd Mende, Knut Eikemeyer
  • Patent number: 6168752
    Abstract: A process for producing metallic powders a chlorination step for continuously producing chloride gas of metal by reacting metal with chlorine gas, and a reduction step for continuously reducing the metallic chloride gas by reacting the metallic chloride gas produced in the chlorination step with reducing gas. Regulating the feed rate of the chlorine gas can control the feed rate of the metallic chloride gas, whereby the particle diameters of produced metal powders can be stably controlled. Thus, the invention can make the particle diameters stable and arbitrarily control the diameters in the range of 0.1 to 1.0 &mgr;m.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: January 2, 2001
    Assignee: Toho Titanium Co., Ltd.
    Inventors: Wataru Kagohashi, Takefumi Irie, Hideo Takatori
  • Patent number: 6022395
    Abstract: A method is provided for producing molybdenum metal powders having consistently high tap densities. The method involves doping an ammonium molybdate solution with a soluble potassium compound, forming an ammonium dimolybdate precipitate and reducing the precipitate to form a metal powder.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: February 8, 2000
    Assignee: Osram Sylvania Inc.
    Inventors: Jeffrey A. Eckert, David C. Sheppeck, James N. Christini, Thomas R. Pinkowski
  • Patent number: 6019813
    Abstract: The present invention relates to cobalt metal agglomerates consisting of peanut-shaped primary particles with average particle sizes in the range from 0.5 to 2 .mu.m, to a process for the production thereof and to the use thereof.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: February 1, 2000
    Assignee: H.C. Starck GmbH & Co. KG
    Inventors: Astrid Gorge, Katrin Plaga, Armin Olbrich, Dirk Naumann, Wilfried Gutknecht, Josef Schmoll
  • Patent number: 5852768
    Abstract: In order to produce precious metal powders of uniform particle size and low BET specific surface, appropriate aerosols are introduced into a flame reactor, whereby the aerosols are first freed of solvent as completely as possible by a thermal treatment.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: December 22, 1998
    Assignee: Degussa Aktiengesellschaft
    Inventors: Hauke Jacobsen, Werner Hartmann, Stipan Katusic, Karl-Anton Starz