Cobalt(co) Patents (Class 75/626)
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Patent number: 11603579Abstract: The present invention concerns a slag composition having a high lithium content, suitable as additive in the manufacture of end-user products, or for the economic recovery of the contained lithium. The lithium concentration indeed compares favorably with that of spodumene, the classic mineral mined for lithium production. This slag is characterized by a composition according to: 3%<Li2O<20%; 1%<MnO<7%; 38%<Al2O3<65%; CaO<55%; and, SiO2<45%.Type: GrantFiled: January 4, 2017Date of Patent: March 14, 2023Assignee: UMICOREInventors: Maarten Quix, David Van Horebeek, Thomas Suetens
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Patent number: 8992662Abstract: A method for recovering valuable metals is provided in which the degree of oxidation of molten waste batteries is stabilized and separation between slag and an alloy is ensured. The method includes a roasting step (ST10) in which waste batteries are roasted beforehand at a low temperature of 300° C. or higher but lower than 600° C., an oxidation step (ST20) in which the waste batteries are oxidized by roasting at 1,100-1,200° C., and dry step (S20) in which the waste batteries that were oxidized in the oxidation step are melted, and slag and an alloy of valuable metals are separated from each other and recovered. By conducting the roasting step (ST10), organic carbon, which impairs the stability of the oxidation step (ST20) and which is contained, in plastic components, etc., is removed in advance prior to the oxidation step (ST20), and the efficiency of slag/alloy separation can be improved.Type: GrantFiled: February 15, 2012Date of Patent: March 31, 2015Assignee: Sumitomo Metal Mining Co. Ltd.Inventors: Kazuhiro Mori, Toshirou Tan, Jun-ichi Takahashi
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Patent number: 8951331Abstract: Provided is a method for stabilizing the degree of oxidation of molten battery waste, and definitively separating slag and alloy. The method is provided with a pre-oxidation step (ST20) for roasting and oxidizing battery waste; and a drying step (S20) for melting the battery waste oxidized in the pre-oxidation step, and separating and recovering the slag and the valuable metal alloy. By providing the pre-oxidation step (ST20) for oxidizing the battery waste by roasting in advance of the drying step (S20), it is possible to stably obtain the optimal degree of oxidization in a melting step (ST21), and to improve the slag-alloy separation efficiency.Type: GrantFiled: February 15, 2012Date of Patent: February 10, 2015Assignee: Sumitomo Metal Mining Co. LtdInventors: Jun-ichi Takahashi, Kazuhiro Mori, Toshirou Tan
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Patent number: 8840702Abstract: The invention concerns a recycling process for recovery of metals from Li-ion batteries. More particularly, an autogeneous process is disclosed for the recovery of Co from Li-ion batteries also containing Al and C, comprising the steps of: —providing a bath furnace equipped with means for 02 injection; —providing a metallurgical charge comprising CaO as a slag former, and Li-ion batteries; —feeding said metallurgical charge to the furnace while injecting O2, whereby at least part of the Co is reduced and collected in a metallic phase; —separating the slag from the metallic phase by tapping; characterized in that the fraction of Li-ion batteries, expressed as weight % of the metallurgical charge, is at least equal to 153%?3.5 (Al %+0.6 C %), Al % and C % being the weight % of Al and C in the batteries, thereby enabling to operate the smelt reduction process in autogeneous conditions.Type: GrantFiled: September 24, 2010Date of Patent: September 23, 2014Assignee: UmlcoreInventors: Karel Verscheure, Mieke Campforts, Maurits Van Camp
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Publication number: 20140260804Abstract: A method of decarburizing a molten alloy may generally comprise injecting a first gas comprising at least one of argon, carbon dioxide, and oxygen through a first fluid-conducting portion of a tuyere into the molten alloy below the surface of the molten alloy, and injecting a second gas comprising at least one of argon and carbon dioxide through a second fluid-conducting portion of the tuyere into the molten alloy below the surface of the molten alloy. The tuyere may comprise an inner portion concentrically aligned within an outer portion to define an annulus therebetween. The first gas may be injected through the inner portion, and the second gas may be injected through the annulus.Type: ApplicationFiled: March 12, 2013Publication date: September 18, 2014Applicant: ATI PROPERTIES, INC.Inventors: Roy J. Matway, Kenneth G. Malencia, Jay E. Rupert
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Publication number: 20140178244Abstract: A method for desulfurizing a metal alloy comprises heating the metal alloy to a molten state. A gaseous desulfurizing compound is bubbled through the molten alloy to form a solid sulfur-containing waste phase and a molten reduced-sulfur alloy phase. The solid waste phase and the molten reduced-sulfur alloy phase are separated. The gaseous desulfurizing compound includes a constituent element selected from the group: alkali metals, alkaline earth metals, and rare earth metals.Type: ApplicationFiled: December 20, 2012Publication date: June 26, 2014Applicant: UNITED TECHNOLOGIES CORPORATIONInventors: Mario P. Bochiechio, John Joseph Marcin, Kirk C. Newton, Michael A. Kmetz
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Publication number: 20120301383Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.Type: ApplicationFiled: March 20, 2012Publication date: November 29, 2012Inventor: Christopher J. Nagel
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Patent number: 8287804Abstract: In the method for recovering a metal from a target that contains a metal and a metal oxide, the target contains a sintered body of the metal oxide after being heated under a condition of melting the metal without melting or decomposing the metal oxide. The target is heated in an upper crucible of a two-level crucible that includes the upper crucible with a through hole-formed in a bottom surface thereof, and a lower crucible disposed below the through hole, the size of the through hole being set such that it does not allow the sintered body of the metal oxide contained in the target to pass therethrough, and the melted metal is caused to flow into the lower crucible, so that the metal is separated from the metal oxide.Type: GrantFiled: December 8, 2009Date of Patent: October 16, 2012Assignee: Tanaka Holdings Co., LtdInventors: Toshiya Yamamoto, Takanobu Miyashita, Kiyoshi Higuchi, Yasuyuki Goto
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Publication number: 20120240729Abstract: The invention concerns a recycling process for recovery of metals from Li-ion batteries. More particularly, an autogeneous process is disclosed for the recovery of Co from Li-ion batteries also containing Al and C, comprising the steps of: —providing a bath furnace equipped with means for O2 injection; —providing a metallurgical charge comprising CaO as a slag former, and Li-ion batteries; —feeding said metallurgical charge to the furnace while injecting O2, whereby at least part of the Co is reduced and collected in a metallic phase; —separating the slag from the metallic phase by tapping; characterized in that the fraction of Li-ion batteries, expressed as weight % of the metallurgical charge, is at least equal to 153%?3.5 (Al %+0.6 C %), Al % and C % being the weight % of Al and C in the batteries, thereby enabling to operate the smelt reduction process in autogeneous conditions.Type: ApplicationFiled: September 24, 2010Publication date: September 27, 2012Inventors: Karel Verscheure, Mieke Campforts, Maurits Van Camp
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Publication number: 20120111150Abstract: A process for the selective recovery of Mo, V, Ni, Co and Al from spent hydroprocessing catalysts includes the steps of treating the spent catalysts to recovery metals, support as well as chemicals. The process steps include deoiling, decoking, washing, dissolving, complexing agent treatment, acid treatment and solvent extraction. This process uses limited steps than conventional processes by the use of ultrasonic agitation for metal extraction and the presence of a chelating agent particularly Ethylene Diamine Tetra-Acetic Acid (EDTA). The process also discloses the compete recovery of the extracting agent EDTA with high purity for reuse.Type: ApplicationFiled: November 10, 2010Publication date: May 10, 2012Inventor: Meena Marafi
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Patent number: 8137654Abstract: Provided is a roasting method capable of reducing both C and S components in minerals down to 0.5% or less, respectively, and securing a yield ratio of 90% or more for the Mo component. In a rotary kiln 7, a V, Mo and Ni containing material containing C and S components is subjected to oxidizing roasting to remove the C and S components from the material before reducing the material by means of a reducing agent in order to recover valuable metals composed of V, Mo and Ni. The rotary kiln is equipped with a burner 11 disposed on a material charge side 8a of the roasting furnace 8 to which the material is charged. In the roasting furnace, a direction along which the material moves and a flow of oxygen-containing gas introduced into the roasting furnace 8 are set to be parallel with each other.Type: GrantFiled: February 21, 2006Date of Patent: March 20, 2012Assignees: JFE Material Co., Ltd., Sumitomo Heavy Industries, Ltd.Inventors: Kenji Takahashi, Hiroichi Sugimori, Nobuo Ehara
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Publication number: 20120011966Abstract: The present invention relates to the use of liquid-crystal displays (LCDs), and to processes for the recycling thereof. The processes according to the invention are characterised in that the LCDs are employed at least partly as replacement for other raw materials. In general, the LCDs are thermally treated here at a temperature in the range from 900 to 1700° C.Type: ApplicationFiled: September 22, 2011Publication date: January 19, 2012Inventor: Roland MARTIN
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Publication number: 20120006157Abstract: A simple, compact burner achieves a more optimal melting of a solid charge followed by performance of combustion under distributed combustion conditions. The burner achieves this by fluidically bending the flame towards the solid charge during a melting phase with an actuating jet of oxidant, redirecting the flame in a direction away from the charge, and staging injection of oxidant among primary and secondary portions during a distributed combustion phase.Type: ApplicationFiled: December 31, 2010Publication date: January 12, 2012Inventors: Vivek GAUTAM, Kenneth KAISER, Luc JARRY, Remi Pierre TSIAVA
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Publication number: 20110243784Abstract: In the method for recovering a metal from a target that contains a metal and a metal oxide, the target contains a sintered body of the metal oxide after being heated under a condition of melting the metal without melting or decomposing the metal oxide. The target is heated in an upper crucible of a two-level crucible that includes the upper crucible with a through hole-formed in a bottom surface thereof, and a lower crucible disposed below the through hole, the size of the through hole being set such that it does not allow the sintered body of the metal oxide contained in the target to pass therethrough, and the melted metal is caused to flow into the lower crucible, so that the metal is separated from the metal oxide.Type: ApplicationFiled: December 8, 2009Publication date: October 6, 2011Applicant: TANAKA HOLDINGS CO., LTD.Inventors: Toshiya Yamamoto, Takanobu Miyashita, Kiyoshi Higuchi, Yasuyuki Goto
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Publication number: 20100326237Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.Type: ApplicationFiled: February 23, 2010Publication date: December 30, 2010Inventor: Christopher J. Nagel
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Patent number: 7678326Abstract: An apparatus for manufacturing fine particles includes a reactor; a first inlet part including at least one port introducing a reactive gas flow containing a fine particle source material; a second inlet part including at least one port introducing a diluting gas flow; a heater exciting the fine particle source material in the reactive gas flow; a first plate including through-holes which substantially equalize a flow rate of the reactive gas flow with respect to a cross section of a flow channel; a second plate including through-holes which substantially equalize a flow rate of the diluting gas flow with respect to a cross section of a flow channel; a gas exhaust port provided in a merging region where the reactive gas flow passed through the first plate and the diluting gas flow passed through the second plate are merged; and a collector which collects fine particles.Type: GrantFiled: June 25, 2007Date of Patent: March 16, 2010Assignee: Kabushiki Kaisha ToshibaInventor: Isao Matsui
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Patent number: 7297323Abstract: A method of manufacturing fine particles of the invention includes introducing a reactive gas flow containing a fine particle source material into a reactor from one side, growing fine particles in a gas phase by heating the fine particle source material in the reactive gas flow, introducing a diluting gas flow into the reactor from another side being almost counter-flow to the reactive gas flow, equalizing flow rates of the reactive gas flow and the diluting gas flow substantially with respect to a cross section of a flow channel, and then stopping growth of the fine particles by merging the reactive gas flow and the diluting gas flow.Type: GrantFiled: September 13, 2002Date of Patent: November 20, 2007Assignee: Kabushiki Kaisha ToshibaInventor: Isao Matsui
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Publication number: 20040187643Abstract: The invention relates to a method for obtaining metals from a cobalt and/or nickel arsenic sulfide ore or ore concentrate and/or a cobalt and/or nickel sulfide ore or ore concentrate, according to which the cobalt and/or nickel arsenic sulfide ore or ore concentrate and/or the cobalt and/or nickel sulfide ore or ore concentrate is reacted with sulfur or sulfur arsenic compounds to a reaction product, and dissolving and removing soluble metals and rare-earth metals.Type: ApplicationFiled: April 13, 2004Publication date: September 30, 2004Inventor: Alexander Beckmann
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Publication number: 20020117025Abstract: High purity cobalt with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity cobalt targets are provided. The cobalt containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of cobalt chloride is adjusted to 0.1 kmol/m3 to 3 kmol/m3. Then, cobalt is added in the aqueous solution of cobalt chloride, and an inert gas is injected into the solution with agitating, in order to convert the divalent copper ions contained in the aqueous solution of cobalt chloride to monovalent copper ions. Then, the aqueous solution of cobalt chloride is fed into a column filled up with the anion exchange resins. Cobalt is not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of cobalt chloride.Type: ApplicationFiled: September 28, 2001Publication date: August 29, 2002Inventors: Masahito Uchikoshi, Norio Yokoyama, Tamas Kekesi, Minoru Isshiki
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Patent number: 6428601Abstract: A process for producing purified cobalt from a mixture comprising metallic species of cobalt and metallic species of at least one of the group consisting of nickel and iron, comprising producing a metal carbonyl mixture of cobalt carbonyl and at least one of nickel carbonyl and iron carbonyl from the metallic species mixture; separating the nickel carbonyl and/or iron carbonyl from the cobalt carbonyl; treating the cobalt carbonyl with an effective amount of a complexing gaseous mixture of nitric oxide/carbon monoxide to produce cobalt nitrosyl tricarbonyl; and decomposing the purified cobalt nitrosyl carbonyl to provide purified cobalt and regenerated complexing gaseous mixture for recycle. The process provides cobalt of improved quality in an optionally, Continuous and closed-loop manner. Preferred processes include either aqueous and/or gaseous process steps.Type: GrantFiled: January 23, 2001Date of Patent: August 6, 2002Assignee: Chemical Vapour Metal Refining Inc.Inventor: Dmitri S Terekhov
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Patent number: 5382278Abstract: A process for protreating chromium-beating metal scrap comprises charging the chromium-bearing metal scrap with an iron oxide-bearing slag into a pyrometallurgical furnace, heating and melting the charge, and maintaining the charge molten at a temperature of at least 1550.degree. C. for a predetermined time period to allow an iron oxide/chromium exchange reaction to take place oxidizing and removing chromium to the sing phase while reducing iron to the metal phase to form an alloy product containing Fe along with the Ni and/or Co, and removing the alloy product for further processing for recovery of metal values.Type: GrantFiled: August 26, 1993Date of Patent: January 17, 1995Assignee: Falconbridge Ltd.Inventors: Gary J. O'Connell, David G. Tisdale
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Patent number: 5344510Abstract: Superalloy articles are made more oxidation resistant by a process which includes heating the article in an environment having a reduced pressure of inert gas and a low partial pressure of oxygen to a temperature at which the sulfur in the article diffuses out. The heat treatment is best carried out at a temperature within the range defined by the incipient melting temperature of the article and about 150.degree. C. below the incipient melting temperature of the article. Alternatively, the heat treatment may be carried out at a temperature above the gamma prime solvus temperature of the article and below the incipient melting temperature of the article. At such temperatures, sulfur readily diffuses out of the article, and a more oxidation resistant component is produced.Type: GrantFiled: April 14, 1993Date of Patent: September 6, 1994Assignee: United Technologies CorporationInventors: William P. Allen, Donald R. Parille
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Patent number: 5240496Abstract: A process for pretreating chromium-bearing metal scrap comprises charging the chromium-bearing metal scrap with fayalite slag into a pyrometallurgical furnace, heating and melting the charge, and maintaining the charge molten at a temperature of at least 1550.degree. C. for a predetermined time period to allow an iron oxide/chromium exchange reaction to take place oxidizing and removing chromium to the slag phase while reducing iron to the metal phase to form an alloy product containing Fe along with the Ni and/or Co, and removing the alloy product for further processing for recovery of metal values.Type: GrantFiled: October 7, 1992Date of Patent: August 31, 1993Assignee: Falconbridge LimitedInventors: Gary J. O'Connell, David G. Tisdale
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Patent number: 5215571Abstract: A non-ferrous matte conversion process is disclosed in which molten non-ferrous matte, essentially nickel and/or copper sulfide and iron sulfide, is provided in a suitable vessel, such as a modified Pierce-Smith converter. The bath is stirred from below with a non-reactive sparging gas, such as nitrogen, and surfaceblown from above with an oxygen-containing gas. A flux is added to the melt to raise a fluid slag. In addition, cold crushed matte is added to the bath. The cold matte acts to maintain the temperature of the bath, so as to prevent overheating which can damage the converter lining. The matte addition also serves as a source for additional converter feed. As the reaction progresses, the slag layer is periodically skimmed, and additions of flux and cold matte are made when necessary. When it is no longer possible to raise a slag, a non-ferrous sulfide matte is obtained having a greatly reduced iron content.Type: GrantFiled: October 14, 1992Date of Patent: June 1, 1993Assignee: Inco LimitedInventors: Samuel W. Marcuson, Carlos Landolt, David E. Hall
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Patent number: 5190577Abstract: In a method for decarburizing metals and alloys, a two-gas component mixture consisting only of oxygen and carbon dioxide is introduced into molten metals or alloys at least during the first decarburization phase.Type: GrantFiled: December 11, 1990Date of Patent: March 2, 1993Assignee: Liquid Air CorporationInventors: Curtis L. Bermel, Sara H. Anderson, Daniel R. Urban
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Patent number: 5174812Abstract: A process for the separation and recovery of nickel from an ammoniacal ammonium carbonate liquor containing nickel II ions and cobalt III ions by liquid-liquid extraction where ammoniacal ammonium carbonate solutions are the only aqueous phases involved in the process. The process includes the successive steps of: (a) oxidizing the majority of any cobalt II ammines in the ammoniacal liquid to cobalt III; (b) extracting nickel from the ammoniacal liquor with an organic reagent, which reagent may also contain a suitable modifying reagent, to form a nickel loaded organic phase and an ammoniacal ammonium carbonate phase containing cobalt; (c) stripping the nickel loaded organic phase characterized by contacting the organic phase with an ammoniacal ammonium carbonate solution to form a nickel loaded aqueous strip liquor.Type: GrantFiled: May 14, 1990Date of Patent: December 29, 1992Assignee: MEQ Nickel Pty., Ltd.Inventors: Malcolm J. Price, John G. Reid
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Patent number: RE41099Abstract: A process for producing purified cobalt from a mixture comprising metallic species of cobalt and metallic species of at least one of the group consisting of nickel and iron, comprising producing a metal carbonyl mixture of cobalt carbonyl and at least one of nickel carbonyl and iron carbonyl from the metallic species mixture; separating the nickel carbonyl and/or iron carbonyl from the cobalt carbonyl; treating the cobalt carbonyl with an effective amount of a complexing gaseous mixture of nitric oxide/carbon monoxide to produce cobalt nitrosyl tricarbonyl; and decomposing the purified cobalt nitrosyl carbonyl to provide purified cobalt and regenerated complexing gaseous mixture for recycle. The process provides cobalt of improved quality in an optionally, Continuous and closed-loop manner. Preferred processes include either aqueous and/or gaseous process steps.Type: GrantFiled: January 22, 2009Date of Patent: February 9, 2010Assignee: Chemical Vapour Metal Refinings Inc.Inventor: Dmitri S Terekhov