Abstract: A method for preparing ultra-pure silver from a crude silver halide matrix containing metallic and/or non-metallic impurities, said method comprising;
roasting the crude silver halide matrix to substantially remove carbonaceous material;
treating the roasted crude silver halide matrix with ammonium hydroxide to dissolve the silver halides and form an ammonium hydroxide reaction mixture;
adding an initial reducing agent to the ammonium hydroxide reaction mixture to precipitate a crude silver powder mixture;
separating the crude silver powder mixture from the ammonium hydroxide reaction mixture
dissolving the crude silver powder mixture in nitric acid to form a crude silver nitrate solution;
adding a first selective reducing agent to the crude silver nitrate solution to precipitate a silver/contaminant matrix and form a partially purified silver nitrate solution;
separating the partially purified silver nitrate solution from the precipitated silver/contaminant matrix;
adding a second selective reducing
Type:
Grant
Filed:
December 8, 1999
Date of Patent:
September 18, 2001
Assignee:
Eastman Kodak Company
Inventors:
Weimar W. White, Gary G. Kiehl, Brian P. Cleary
Abstract: Spent solutions from photographic processors are fed into a conduit (18) to which subsequently are added precipitating agents from a first source (22) and flocculating agents from a second source (28); so that, well grown or ripened clumps of flocculated solids are formed along the conduit before being emptied into a gravity collecting vessel and shipping container (38) from which clarified liquids are displaced by a mass (50) of accumulated flocculated solids, typically through a filter (58, 142, 150, 158, 162, 166, 220)for removal of any unsettled fines. Many of the clumps of flocculated solids become enlarged enough to individually extend across and substantially fill a cross-sectional area of the conduit. As a result, the enlarged clumps substantially block passage of and strain from the solution remaining fine particles which then adhere to the clumps.
Type:
Grant
Filed:
May 16, 1996
Date of Patent:
December 9, 1997
Assignee:
Eastman Kodak Company
Inventors:
Thomas W. Bober, Terry W. Pearl, Dominick Vacco, David C. Yeaw
Abstract: Waste liquors containing small amounts of silver salts are treated with aluminum hydroxide to produce a floc reduced in volume by the addition of an acid and mixed with a metal bicarbonate and metal carbonate in amounts sufficient to affect solidification.